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    • 4. 发明授权
    • Procedure for starting up a fuel cell system having an anode exhaust recycle loop
    • 启动具有阳极排气循环回路的燃料电池系统的步骤
    • US07250229B2
    • 2007-07-31
    • US11231285
    • 2005-09-20
    • Deliang YangMargaret M. SteinbuglerRichard D. SawyerLeslie L. Van DineCarl A. Reiser
    • Deliang YangMargaret M. SteinbuglerRichard D. SawyerLeslie L. Van DineCarl A. Reiser
    • H01M8/06
    • H01M8/04302H01M8/0258H01M8/04007H01M8/04022H01M8/04097H01M8/04223H01M8/04231H01M8/04238H01M8/241H01M8/2457H01M16/003
    • A procedure for starting up a fuel cell system that is disconnected from its primary load and that has air in both its cathode and anode flow fields includes a) connecting an auxiliary resistive load across the cell to reduce the cell voltage; b) initiating a recirculation of the anode flow field exhaust through a recycle loop and providing a limited flow of hydrogen fuel into that recirculating exhaust; c) catalytically reacting the added fuel with oxygen present in the recirculating gases until substantially no oxygen remains within the recycle loop; disconnecting the auxiliary load; and then d) providing normal operating flow rates of fuel and air into respective anode and cathode flow fields and connecting the primary load across the cell. The catalytic reaction may take place on the anode or within a catalytic burner disposed within the recycle loop. The procedure allows start-up of the fuel cell system without the use of an inert gas purge while minimizing dissolution of the catalyst and corrosion of the catalyst support during the start-up process.
    • 用于启动与其主负载断开且在其阴极和阳极流场中具有空气的燃料电池系统的过程包括:a)在电池之间连接辅助电阻负载以降低电池电压; b)启动阳极流场排气通过循环回路的再循环,并向该再循环排气提供有限的氢气燃料流; c)使添加的燃料与存在于再循环气体中的氧直接催化反应,直到基本上没有氧气残留在循环回路内; 断开辅助负载; 然后d)将燃料和空气的正常操作流量提供到相应的阳极和阴极流场中,并将主负载连接在电池上。 催化反应可以在阳极上或在设置在循环回路内的催化燃烧器中进行。 该程序允许在不使用惰性气体吹扫的情况下启动燃料电池系统,同时最小化催化剂的溶解和在启动过程中催化剂载体的腐蚀。