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    • 2. 发明专利
    • Manufacturing method of exhaust gas treatment catalyst
    • 排气处理催化剂的制造方法
    • JP2007136421A
    • 2007-06-07
    • JP2005337091
    • 2005-11-22
    • Mazda Motor CorpToda Kogyo Corpマツダ株式会社戸田工業株式会社
    • IWAKUNI HIDEJIMIYOSHI SEIJITAKAMI AKIHIDEHONDA TOMOHIROURAI TOMOAKIFUJIMOTO RYOTA
    • B01J35/08B01D53/94B01J23/58B01J37/02F01N3/08F01N3/10
    • PROBLEM TO BE SOLVED: To increase the treatment efficiency of an exhaust gas treatment catalyst by increasing the specific surface area of a carrier of a Ce-Zr type compounded oxide and reliably depositing the catalyst metal even on fine pores of the carrier. SOLUTION: The manufacturing method of the catalyst involves obtaining a hollow secondary particle carrier made of a compounded oxide containing Ce and Zr and consisting of primary particles with an average particle diameter smaller than 10 nm which are agglomerated to form shells having finely small holes insides, heating a suspension obtained by dispersing the secondary particle carrier in an aqueous solution of a catalyst metal ion in a container while degassing the container in reduced pressure for evaporating water, and thereby reliably depositing the catalyst metal on not only the surface of the secondary particle carrier but also the inside of the finely small pores. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:为了通过增加Ce-Zr型复合氧化物的载体的比表面积并且甚至在载体的细孔上可靠地沉积催化剂金属来提高废气处理催化剂的处理效率。 解决方案:催化剂的制造方法包括获得由包含Ce和Zr的复合氧化物制成的中空二次粒子载体,其由平均粒径小于10nm的一次粒子组成,其被聚集形成具有细小的壳 加热通过将二次粒子载体分散在催化剂金属离子的水溶液中而获得的悬浮液,同时在减压下对容器进行脱气以蒸发水,从而可靠地将催化剂金属沉积在不仅在 二次粒子载体,也是细小孔的内部。 版权所有(C)2007,JPO&INPIT
    • 5. 发明专利
    • Exhaust gas clarifying catalyst
    • 排气净化催化剂
    • JP2006297259A
    • 2006-11-02
    • JP2005121314
    • 2005-04-19
    • Mazda Motor Corpマツダ株式会社
    • MIYOSHI SEIJIYAMADA KEIJITAKAMI AKIHIDE
    • B01J37/04B01D53/94B01J23/63F01N3/10
    • PROBLEM TO BE SOLVED: To assure expected performance of clarifying exhaust gas while reducing amount of catalyst metal as much as possible. SOLUTION: The catalyst is a mixture composed of a catalyst metal doping type multiple oxide 1, in which the catalyst metal 3 is arranged at crystal lattice point or between lattice points of the multiple oxide having oxygen occluding ability and further a part of the catalyst metal 3 is exposed on a surface of the multiple oxide, and a catalyst metal contacting carrying type oxide 2, on which the same kind of catalyst metal 3 is deposited by bringing the oxide into contact with a solution of the catalyst metal. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:尽可能地减少催化剂金属的量,以确保排气净化的预期性能。 解决方案:催化剂是由催化剂金属掺杂型多重氧化物1组成的混合物,其中催化剂金属3排列在具有阻氧能力的多重氧化物的晶格点或晶格点之间,并且还有一部分 催化剂金属3暴露在多重氧化物的表面上,并且通过使氧化物与催化剂金属的溶液接触而沉积有相同种类的催化剂金属3的催化剂金属接触型氧化物2。 版权所有(C)2007,JPO&INPIT
    • 9. 发明专利
    • Exhaust emission control device
    • 排气排放控制装置
    • JP2010265795A
    • 2010-11-25
    • JP2009117179
    • 2009-05-14
    • Mazda Motor Corpマツダ株式会社
    • MIYOSHI SEIJIKURAMASU HIROSHIYAMADA HIDEKISUNANAGARE TAKETAKASHIGETSU MASAHIKOSHIMIZU TAEKOKAWABATA HISAYA
    • F01N3/28B01D53/94B01J23/63B01J37/02F01N3/10F01N3/24F02D19/08
    • PROBLEM TO BE SOLVED: To purify the exhaust gas from an engine 1 to work with a fuel containing alcohol. SOLUTION: In the exhaust gas passage 2 of the engine 1, a first catalyst 3 and a second catalyst 4 are installed in such an arrangement that the second catalyst 4 is positioned downstream of the first catalyst 3 with respect to the exhaust gas flow, wherein the first catalyst 3 positioned upstream is structured so that a catalyst layer containing Pt, Pd, and Rh is formed on the cell wall of a honeycomb carrier, the catalyst layer includes a layer containing Pd as inevitable component laid lower and another layer containing Rh as inevitable component laid upper. The second catalyst 4 positioned downstream includes a catalyst layer containing Pt-carrying alumina and Rh-doped CeZr based composite oxide is formed on the cell wall of honeycomb carrier. COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:净化来自发动机1的废气以与含有酒精的燃料一起工作。 解决方案:在发动机1的废气通道2中,第一催化剂3和第二催化剂4安装成使得第二催化剂4相对于废气位于第一催化剂3的下游 流动,其中位于上游的第一催化剂3被构造成使得在蜂窝状载体的细胞壁上形成含有Pt,Pd和Rh的催化剂层,催化剂层包括含有Pd作为不可避免的成分的层,另一层 含Rh作为不可避免的成分。 位于下游的第二催化剂4包括在蜂窝载体的细胞壁上形成含有载Pt的氧化铝和Rh掺杂的CeZr基复合氧化物的催化剂层。 版权所有(C)2011,JPO&INPIT
    • 10. 发明专利
    • Exhaust gas purifying device
    • 排气净化装置
    • JP2010264371A
    • 2010-11-25
    • JP2009117180
    • 2009-05-14
    • Mazda Motor Corpマツダ株式会社
    • KAWABATA HISAYAOCHI YASUHIROMIYOSHI SEIJIKURAMASU HIROSHIFUJII IKUKO
    • B01D53/94B01J23/63B01J35/04B01J37/02F01N3/10F01N3/28F02D19/08
    • PROBLEM TO BE SOLVED: To purify the exhaust gas of an engine 1 using an alcohol-containing fuel. SOLUTION: A first catalyst 3 and a second catalyst 4 are arranged in the exhaust gas passage 2 of the engine 1 so that the latter is positioned on the downstream side of an exhaust gas flow of the former. The first catalyst 3 on the upstream side is provided to the cell walls of a honeycomb carrier so that a Pt-containing layer, which contains CeMg composite oxide particles, and a Rh-containing layer are formed on the upper side of a Pd-containing layer and the Pt-containing layer is provided to the range from the edge surface on the upstream side of the honeycomb carrier to the intermediate region of the honeycomb carrier. The second catalyst 4 on the downstream side is constituted so that a catalyst layer, which contains Pt-carrying alumina and an Rh-doped CeZr composite oxide or a Rh-carrying CeZr composite oxide, is formed on the cell walls of the honeycomb carrier. COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:使用含酒精的燃料净化发动机1的废气。 解决方案:第一催化剂3和第二催化剂4布置在发动机1的排气通道2中,使得后者位于前者的废气流的下游侧。 将上游侧的第一催化剂3设置在蜂窝载体的细胞壁上,使含有CeMg复合氧化物粒子的含Pt层和含Rh层形成在含Pd的上层 层和含Pt层设置在从蜂窝载体的上游侧的边缘表面到蜂窝载体的中间区域的范围内。 在下游侧的第二催化剂4构成为在蜂窝载体的孔壁上形成含有载Pt的氧化铝和Rh掺杂的CeZr复合氧化物或负载Rh的CeZr复合氧化物的催化剂层。 版权所有(C)2011,JPO&INPIT