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    • 2. 发明授权
    • Fuel oils having improved cold flow properties
    • 燃油具有改善的冷流特性
    • US07713316B2
    • 2010-05-11
    • US10735490
    • 2003-12-12
    • Matthias KrullMarkus KupetzRaimund Wildfang
    • Matthias KrullMarkus KupetzRaimund Wildfang
    • C10L1/18C10L1/22
    • C10L1/143C08F210/02C10L1/195C10L1/1973C10L1/1981C10L1/1985C10L1/221C10L1/224C08F4/34C08F218/08C08F218/02C08F2500/17
    • The invention relates to fuel oils comprising a larger proportion of middle distillates having a sulfur content of at most 350 ppm and an aromatics content of at most 22% by weight, and also a smaller proportion of at least one copolymer of ethylene and vinyl esters, said copolymer containing a) bivalent structural units derived from ethylene of the formula 1 —CH2—CH2—  (1) b) from 5 to 12 mol % of bivalent structural units of the formula 2 where R1 is saturated, branched C5-C18-alkyl, and c) from 4 to 13 mol % of bivalent structural units of the formula 3 and the sum of the molar proportions of structural units of the formulae 2 and 3 being between 12 and 16 mol %, to the corresponding polymers, and also to their use for improving the cold flow behavior of middle distillates having a sulfur content of at most 350 ppm and an aromatics content of at most 22% by weight.
    • 本发明涉及燃料油,其包含较大比例的硫含量至多为350ppm,芳烃含量至多为22重量%的中间馏分,以及乙烯和乙烯基酯的至少一种共聚物的较小比例, 所述共聚物含有a)衍生自式1 -CH 2 -CH 2 - (1)的乙烯的二价结构单元b)5至12mol%的式2的二价结构单元,其中R 1是饱和的,支链C 5 -C 18 - 烷基 ,和c)4至13摩尔%的式3的2价结构单元和式2和3的结构单元的摩尔比例之和为12至16摩尔%,相应的聚合物,以及 它们用于改善硫含量至多为350ppm且芳族化合物含量至多为22重量%的中间馏分的冷流行为。
    • 10. 发明授权
    • Use of hydroxyl-containing copolymers for the preparation of fuel oils having improved lubricity
    • 使用含羟基的共聚物来制备具有改善的润滑性的燃料油
    • US06391071B1
    • 2002-05-21
    • US09591236
    • 2000-06-09
    • Matthias KrullMarkus Kupetz
    • Matthias KrullMarkus Kupetz
    • C10L118
    • C10L10/08C10L1/195C10L1/1955C10L1/1963C10L1/1973C10L1/236
    • The present invention relates to the use of oil-soluble copolymers which comprise A) from 5 to 80 mol-% of structural units derived from olefinically unsaturated compounds containing at least one free hydroxyl group, B) from 5 to 95 mol-% of structural units derived from olefinically unsaturated compounds carrying a hydrocarbon radical having at least 6 carbon atoms, and, if desired, C) from 0 to 40 mol-% of further structural units selected from the group consisting of acrylic acid, acrylates, vinyl esters, vinylethane and alkenes, with the proviso that the structural units mentioned under C) are different from the structural units mentioned under A) and B), and have a mean molecular weight Mw of from 500 to 100,000 g/mol and an OH number of from 10 to 300 mg of KOH/g, for improving the lubricity and cold flow properties of middle distillates having a sulfur content of less than 0.5% by weight.
    • 本发明涉及油溶性共聚物的用途,该共聚物包含A)5至80mol%的衍生自含有至少一个游离羟基的烯属不饱和化合物的结构单元,B)5至95mol%的结构单元 衍生自携带具有至少6个碳原子的烃基的烯属不饱和化合物,如果需要,C)0至40摩尔%的选自丙烯酸,丙烯酸酯,乙烯酯,乙烯基乙烷和 烯烃,条件是C)中提到的结构单元不同于A)和B)中提及的结构单元,并且具有500至100,000g / mol的平均分子量Mw和10至 300mg KOH / g,用于改善硫含量小于0.5重量%的中间馏分的润滑性和冷流动性。