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1. 发明授权

US06743956B1 Selective liquid phase hydrogenation of carbonyl compounds to give the corresponding alcohols in the presence of a Pt/ZnO catalyst 失效
标题翻译：在Pt / ZnO催化剂存在下，羰基化合物的选择性液相氢化得到相应的醇
公开(公告)号：US06743956B1
公开(公告)日：2004-06-01
申请号：US10309255
申请日：2002-12-04
申请人： Mathias Haake , Till Gerlach , Frank Funke
发明人： Mathias Haake , Till Gerlach , Frank Funke
IPC分类号： C07C2700
CPC分类号： C07C29/141 , C07C33/02
摘要： The present invention relates to a process for selective liquid phase hydrogenation of carbonyl compounds of the general formula I, where R1 and R2 are identical or different and are each independently hydrogen or a saturated or a mono- or polyunsaturated straight-chain or branched, optionally substituted C1-C20-alkyl radical, an optionally substituted aryl radical or an optionally substituted heterocyclic group, to give the corresponding alcohols of the general formula II where R1 and R2 are each as defined above, in the presence of hydrogen and a Pt/ZnO catalyst.
摘要翻译：本发明涉及通式I的羰基化合物的选择性液相氢化方法，其中R 1和R 2相同或不同，并且各自独立地为氢或饱和或单或多不饱和直链，链或支链，任选取代的C 1 -C 20烷基，任选取代的芳基或任选取代的杂环基，得到相应的通式II的醇，其中R 1和R 2各自如上所定义，在氢气和Pt / ZnO催化剂的存在下。

2. 发明授权

US07183438B2 Catalysts and method for the production of amines 有权
标题翻译：用于生产胺的催化剂和方法
公开(公告)号：US07183438B2
公开(公告)日：2007-02-27
申请号：US10507602
申请日：2003-03-07
申请人： Till Gerlach , Frank Funke , Johann-Peter Melder , Stefan Iselborn , Martin Rudloff , Michael Hüllmann
发明人： Till Gerlach , Frank Funke , Johann-Peter Melder , Stefan Iselborn , Martin Rudloff , Michael Hüllmann
IPC分类号： C07C209/16 , C07C209/18 , C07C209/29 , B01J23/40 , B01J23/42
CPC分类号： C07C213/02 , B01J23/70 , B01J23/755 , B01J37/03 , B01J37/06 , C07C209/16 , C07C209/26 , C07D295/023 , C07C211/03 , C07C217/08
摘要： Disclosed are catalysts, the catalytically active mass of which contains 22 to 40 percent by weight of oxygen-containing compounds of zirconium, calculated as ZrO2, 1 to 30 percent by weight of oxygen-containing compounds of copper, calculated as CuO, 15 to 50 percent by weight of oxygen-containing compounds of nickel, calculated as NiO, the molar ratio between nickel and copper being greater than 1, 15 to 50 percent by weight of oxygen-containing compounds of cobalt, calculated as CoO, and less than 1 percent by weight of an alkali metal, calculated as alkali metal oxide, prior to being treated with hydrogen. Also disclosed is a method for the production of amines by reacting primary and secondary alcohols, aldehydes, or ketones with hydrogen and nitrogen compounds selected from the group ammonia, primary and secondary amines, in the presence of said catalysts at an elevated temperature and an elevated pressure.
摘要翻译：公开了催化剂，其催化活性物质含有22至40重量％的以ZrO 2计算的含氧化合物的锆，1至30重量％的含氧化合物的铜，以CuO计，15至50重量％的含氧化合物的镍，以NiO计算，镍和铜之间的摩尔比大于15重量％，含氧化合物的化合物为15至50重量％作为CoO，并且在用氢处理之前少于1重量％的碱金属（以碱金属氧化物计）。还公开了一种通过使伯醇和仲醇，醛或酮与选自氨，伯胺和仲胺的氢和氮化合物在所述催化剂存在下在升高的温度和升高的温度下生产胺的方法压力。

3. 发明授权

US07034186B2 Preparation of an amine 失效
标题翻译：胺的制备
公开(公告)号：US07034186B2
公开(公告)日：2006-04-25
申请号：US10731158
申请日：2003-12-10
申请人： Till Gerlach , Frank Funke , Johann-Peter Melder
发明人： Till Gerlach , Frank Funke , Johann-Peter Melder
IPC分类号： C07C209/26 , C07C209/16 , C07C209/18
CPC分类号： C07C209/16 , B01J21/066 , B01J23/002 , B01J23/755 , B01J37/0063 , B01J37/18 , B01J2523/00 , C07C209/26 , B01J2523/17 , B01J2523/48 , B01J2523/845 , B01J2523/847 , C07C211/07
摘要： Process for preparing an amine by reacting a primary or secondary alcohol, aldehyde or ketone with hydrogen and a nitrogen compound selected from the group consisting of ammonia and primary and secondary amines in the presence of a catalyst whose preparation has involved precipitation of catalytically active components onto monoclinic, tetragonal or cubic zirconium dioxide.
摘要翻译：通过使伯或仲醇，醛或酮与氢和选自氨和伯胺和仲胺的氮化合物在催化剂的存在下反应制备胺的方法，所述催化剂的制备涉及将催化活性组分沉淀到单斜晶，四方晶或立方二氧化锆。

4. 发明申请

US20050107637A1 Catalysts and method for the production of amines 有权
标题翻译：用于生产胺的催化剂和方法
公开(公告)号：US20050107637A1
公开(公告)日：2005-05-19
申请号：US10507602
申请日：2003-03-07
申请人： Till Gerlach , Frank Funke , Johann-Peter Melder , Stefan Iselborn , Martin Rudloff , Michael Hullmann
发明人： Till Gerlach , Frank Funke , Johann-Peter Melder , Stefan Iselborn , Martin Rudloff , Michael Hullmann
IPC分类号： C07D295/02 , B01J23/70 , B01J23/755 , B01J23/78 , B01J37/03 , B01J37/06 , C07B61/00 , C07C209/16 , C07C209/26 , C07C209/60 , C07C211/03 , C07C211/07 , C07C213/02 , C07C217/08 , C07D295/023 , C07C29/24 , C07C29/14
CPC分类号： C07C213/02 , B01J23/70 , B01J23/755 , B01J37/03 , B01J37/06 , C07C209/16 , C07C209/26 , C07D295/023 , C07C211/03 , C07C217/08
摘要： Disclosed are catalysts, the catalytically active mass of which contains 22 to 40 percent by weight of oxygen-containing compounds of zirconium, calculated as ZrO2, 1 to 30 percent by weight of oxygen-containing compounds of copper, calculated as CuO, 15 to 50 percent by weight of oxygen-containing compounds of nickel, calculated as NiO, the molar ratio between nickel and copper being greater than 1, 15 to 50 percent by weight of oxygen-containing compounds of cobalt, calculated as CoO, and less than 1 percent by weight of an alkali metal, calculated as alkali metal oxide, prior to being treated with hydrogen. Also disclosed is a method for the production of amines by reacting primary and secondary alcohols, aldehydes, or ketones with hydrogen and nitrogen compounds selected from the group ammonia, primary and secondary amines, in the presence of said catalysts at an elevated temperature and an elevated pressure.
摘要翻译：公开了催化剂，其催化活性物质含有22至40重量％的以ZrO 2计算的含氧化合物的锆，1至30重量％的含氧化合物的铜，以CuO计，15至50重量％的含氧化合物的镍，以NiO计算，镍和铜之间的摩尔比大于15重量％，含氧化合物的化合物为15至50重量％作为CoO，并且在用氢处理之前少于1重量％的碱金属（以碱金属氧化物计）。还公开了一种通过使伯醇和仲醇，醛或酮与选自氨，伯胺和仲胺的氢和氮化合物在所述催化剂存在下在升高的温度和升高的温度下生产胺的方法压力。

5. 发明授权

US07053246B2 Preparation of a symmetrical secondary amine 失效
标题翻译：对称仲胺的制备
公开(公告)号：US07053246B2
公开(公告)日：2006-05-30
申请号：US10731095
申请日：2003-12-10
申请人： Till Gerlach , Frank Funke , Christoph Benisch , Johann-Peter Melder
发明人： Till Gerlach , Frank Funke , Christoph Benisch , Johann-Peter Melder
IPC分类号： C07C29/04
CPC分类号： C07C209/64 , C07C211/14
摘要： Process for preparing a symmetrical secondary amine by reaction of a primary amine in the presence of hydrogen and a catalyst whose preparation has involved precipitation of catalytically active components onto monoclinic, tetragonal or cubic zirconium dioxide.
摘要翻译：通过伯胺在氢气和催化剂的反应下制备对称仲胺的方法，其制备涉及将催化活性组分沉淀到单斜晶，四方晶或立方二氧化锆上。

6. 发明授权

US06916964B2 Selective hydrogenation of olefinically unsaturated carbonyl compounds 有权
标题翻译：烯属不饱和羰基化合物的选择性氢化
公开(公告)号：US06916964B2
公开(公告)日：2005-07-12
申请号：US10309181
申请日：2002-12-04
申请人： Hans-Georg Göbbel , Till Gerlach , Frank Funke , Klaus Ebel , Signe Unverricht , Gerd Kaibel
发明人： Hans-Georg Göbbel , Till Gerlach , Frank Funke , Klaus Ebel , Signe Unverricht , Gerd Kaibel
IPC分类号： C07B61/00 , C07C29/141 , C07C33/03 , C07C29/136 , C07C29/14 , C07C29/143 , C07C29/147
CPC分类号： C07C29/141 , C07B2200/07 , C07C33/02 , C07C33/025
摘要： The present invention relates to a continuous process for the selective hydrogenation of olefinically unsaturated carbonyl compounds to give unsaturated alcohols in particular of citral to give a mixture of geraniol and nerol, in a reactor containing a liquid phase, in which at least one catalyst is suspended, and which can additionally contain a gas phase, wherein the liquid phase and, if present, the gas phase are passed through a device in the reactor having openings or channels.
摘要翻译：本发明涉及一种用于选择性氢化烯属不饱和羰基化合物的连续方法，以在含有液相的反应器中提供不饱和醇，特别是柠檬醛，得到香叶醇和橙花醇的混合物，其中悬浮有至少一种催化剂并且其还可以包含气相，其中液相和（如果存在的话）气相通过具有开口或通道的反应器中的装置。

7. 发明授权

US06790995B2 Preparation of primary and secondary amines from nitriles 失效
标题翻译：从腈制备伯胺和仲胺
公开(公告)号：US06790995B2
公开(公告)日：2004-09-14
申请号：US10033912
申请日：2002-01-03
申请人： Joachim Pfeffinger , Michael Hüllmann , Arthur Höhn , Frank Funke , Frank Ohlbach , Till Gerlach
发明人： Joachim Pfeffinger , Michael Hüllmann , Arthur Höhn , Frank Funke , Frank Ohlbach , Till Gerlach
IPC分类号： C07C20948
CPC分类号： C07C213/02 , C07C209/48 , C07C211/11 , C07C215/08
摘要： Mixtures of primary amines of the formula (I) X—CH2—NH2 (I) and secondary amines of the formula (II) (X—CH2—)2NH (II) where X is C1-20-alkyl, C2-20-alkenyl or C3-8-cycloalkyl which may be unsubstituted or substituted by C1-20-alkyl, C3-8-cycloalkyl, C4-20-alkylcycloalkyl, C4-20-cycloalkylalkyl, C2-20-alkoxyalkyl, C6-14-aryl, C7-20-alkylaryl, C7-20-aralkyl, C1-20-alkoxy, hydroxy, C1-20-hydroxyalkyl, amino, C1-20-alkylamino, C2-20-dialkylamino, C2-12-alkenylamino. C3-8-cycloalkylamino, arylamino, diarylamino, aryl-C1-8-alkylamino, halogen, mercapto, C2-20-alkenyloxy, C3-8-cycloalkoxy, aryloxy and/or C2-8-alkoxycarbonyl are prepared by reacting nitriles of the formula (III) X—CN (III) with hydrogen at from 50 to 250° C. and pressures of from 5 to 350 bar in the presence of a Pd-containing catalyst comprising, based on the total weight of the catalyst, from 0.1 to 10% by weight of Pd on a support.
摘要翻译：式（I）的伯胺和式（II）的仲胺的混合物，其中X是可以未被取代或被C 1-20烷基取代的C 1-20 - 烷基，C 2-20 - 烯基或C 3-8 - 环烷基，C 3-8 - 环烷基，C 4-20 - 烷基环烷基，C 4-20 - 环烷基烷基，C 2-20烷氧基烷基，C 6-14 - 芳基，C 7-20 - 烷基芳基，C 7-20 - 芳烷基，C 1-20 - 烷氧基，羟基，C 1-20羟烷基，氨基，C 1-20烷基氨基，C 2-20 - 二烷基氨基，C 2-12 - 烯基氨基。 C 3-8 - 环烷基氨基，芳基氨基，二芳基氨基，芳基-C 1-8 - 烷基氨基，卤素，巯基，C 2-20 - 烯氧基，C 3-8 - 环烷氧基，芳氧基和/或C 2-8烷氧基羰基，（III）与氢气在50-250℃下反应，压力为5-350巴，在含Pd催化剂的存在下，基于催化剂的总重量计，为0.1-10重量％的Pd 在支持上。

8. 发明授权

US06525223B2 Preparation of secondary amines from nitriles 失效
标题翻译：从腈制备仲胺
公开(公告)号：US06525223B2
公开(公告)日：2003-02-25
申请号：US10026900
申请日：2001-12-27
申请人： Joachim Pfeffinger , Michael Hüllmann , Arthur Höhn , Frank Funke , Frank Ohlbach , Till Gerlach
发明人： Joachim Pfeffinger , Michael Hüllmann , Arthur Höhn , Frank Funke , Frank Ohlbach , Till Gerlach
IPC分类号： C07C20948
CPC分类号： C07C209/48 , C07C211/11
摘要： Secondary amines of the formula (II) (X—CH2—)2NH (II) where X is a C1-20-alkyl, C2-20-alkenyl or C3-8-cycloalkyl group which may be unsubstituted or substituted by C1-20-alkyl, C3-8-cycloalkyl, C4-20-alkylcycloalkyl, C4-20-cycoalkylalkyl, C2-20-alkoxyalkyl, C6-14-aryl, C7-20-alkylaryl, C7-20-aralkyl, C1-20-alkoxy, hydroxy, C1-20-hydroxyalkyl, amino, C1-20-alkylamino, C2-20-dialkylamino, C2-12-alkenylamino, C3-8-cycloalkylamino, arylamino, diarylamino, aryl-C1-8-alkylamino, halogen, mercapto, C2-20-alkenyloxy, C3-8-cycloalkoxy, aryloxy and/or C2-8-alkoxycarbonyl, are prepared by reacting nitriles of the formula (III) X—CN (III) with hydrogen at from 20 to 250° C. and pressures of from 60 to 350 bar in the presence of an Rh-containing catalyst comprising from 0.1 to 5% by weight, based on the total weight of the catalyst, of Rh on a support to give mixtures of primary amines of the formula (I) X—CH2—NH2 (I) and secondary amines of the formula (II) (X—CH2—)2NH (II) and returning at least part of the primary amines separated from the mixtures obtained to the reaction.
摘要翻译：式（II）的仲胺，其中X是可以是未取代的或被C 1-20 - 烷基，C 3-8 - 环烷基，C 4 -C 18环烷基，C 3-8 - C 20-20烷基烷基，C 2-20 - 烷氧基烷基，C 6-14 - 芳基，C 7-20 - 烷基芳基，C 7-20 - 芳烷基，C 1-20 - 烷氧基，羟基，C 1-20 - 羟基烷基，氨基， C 1-20 - 烷基氨基，C 2-20 - 二烷基氨基，C 2-12 - 烯基氨基，C 3-8 - 环烷基氨基，芳基氨基，二芳基氨基，芳基-C 1-8 - 烷基氨基，卤素，巯基，C 2-20 - 烯氧基，环烷氧基，芳氧基和/或C 2-8 - 烷氧基羰基，通过在含Rh的催化剂存在下，使式（III）的腈与20至250℃的压力和60至350巴的压力反应来制备包含基于催化剂总重量的0.1至5重量％的Rh在载体上以得到式（I）的伯胺和式（II）的仲胺的混合物，并使至少部分从获得的混合物中分离出伯胺反应。

9. 发明申请

US20080255351A1 Method for Preparing Aminodiglycol (Adg) and Morpholine 审中-公开
标题翻译：制备氨基二甘醇（Adg）和吗啉的方法
公开(公告)号：US20080255351A1
公开(公告)日：2008-10-16
申请号：US12088718
申请日：2006-09-25
申请人： Bram Willem Hoffer , Holger Evers , Petr Kubanek , Till Gerlach , Johann-Peter Melder , Frank Funke , Matthias Frauenkron , Helmut Schmidtke
发明人： Bram Willem Hoffer , Holger Evers , Petr Kubanek , Till Gerlach , Johann-Peter Melder , Frank Funke , Matthias Frauenkron , Helmut Schmidtke
IPC分类号： C07D265/30
CPC分类号： C07D295/023 , C07C213/02 , C07C217/08
摘要： Processes comprising: providing a starting material comprising diethylene glycol; and reacting the starting material with ammonia in the presence of a heterogeneous transition metal catalyst to form a reaction product comprising aminodiglycol and morpholine; wherein the catalyst comprises a catalytically active composition, which prior to treatment with hydrogen, comprises a mixture of oxygen-containing compounds of copper, nickel, cobalt and at least one of aluminum and zirconium; and wherein the catalyst is present as one or more shaped catalyst particles selected from spheres, extrudates, pellets and other geometries, wherein the sphere or extradate has a diameter of
摘要翻译：方法包括：提供包含二甘醇的原料; 并在非均相过渡金属催化剂存在下使原料与氨反应形成包含氨基二甘醇和吗啉的反应产物; 其中所述催化剂包含催化活性组合物，其在用氢处理之前包含铜，镍，钴和铝和锆中的至少一种的含氧化合物的混合物; 并且其中所述催化剂作为选自球体，挤出物，丸粒和其它几何形状的一种或多种成型催化剂颗粒存在，其中所述球体或引体具有<3mm的直径，所述颗粒具有<3mm的高度，而另一个几何形状具有等效直径L = 1 / a'<0.70mm，其中a'是每单位体积的外表面积（mm×s×2 / 由 ${定义的}^{3 MI> a =A/ MSUB>Vp其中A < SUB>是催化剂颗粒的外表面积（mm 2），V p是催化剂颗粒的体积（mm 3） 3＆lt; 3＆gt; 3＆lt; 3＆gt;）。}$

10. 发明授权

US07122702B2 Catalytic hydrogenation of an aliphatically unsaturated group in an organic compound 失效
标题翻译：有机化合物中脂肪族不饱和基团的催化氢化
公开(公告)号：US07122702B2
公开(公告)日：2006-10-17
申请号：US10731167
申请日：2003-12-10
申请人： Till Gerlach , Frank Funke , Johann-Peter Melder
发明人： Till Gerlach , Frank Funke , Johann-Peter Melder
IPC分类号： C07C209/26 , C07C209/48
CPC分类号： C07C209/26 , B01J23/002 , B01J37/03 , B01J2523/00 , C07C211/03
摘要： Process for the catalytic hydrogenation of an aliphatically unsaturated group in an organic compound in the presence of a catalyst whose preparation has involved precipitation of catalytically active components onto monoclinic, tetragonal or cubic zirconium dioxide.
摘要翻译：在催化剂存在下，有机化合物中的脂族不饱和基团的催化氢化方法，其催化剂的制备涉及将催化活性组分沉淀在单斜晶，四方晶或立方二氧化锆上。

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