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1. 发明授权

US07263822B2 Catalytic conversion of fuel and converter therefor 失效
标题翻译：燃料和转炉的催化转化
公开(公告)号：US07263822B2
公开(公告)日：2007-09-04
申请号：US10021346
申请日：2001-12-19
申请人： Michael Bender , Signe Unverricht
发明人： Michael Bender , Signe Unverricht
IPC分类号： F01N3/00
CPC分类号： F01N3/2066 , F01N13/009 , F01N13/0093 , F01N2610/03 , F01N2610/04 , F02M63/0225 , Y02T10/24
摘要： For a process for the catalytic conversion of furl for removing oxides of nitrogen from exhaust gases of internal combustion engines, in which fuel and a part-stream of the exhaust gas or of the intake air are converted in a converter, the fuel and the part-stream of the exhaust gas or of the intake air are fed separately from one another into the converter and the fuel is vaporized in the converter.A converter for the catalytic conversion of fuel, comprising a vaporization space and a conversion space connected thereto is furthermore described, the vaporization space having separate feeds for exhaust gas or intake air and fuel, the conversion space having a catalyst for the catalytic conversion of fuel and the vaporization space and the conversion space being connected to one another so that heat transport from the conversion space into the vaporization space is possible.
摘要翻译：对于其中燃料和排气或进气的一部分流在转炉中转化的内燃机废气的催化转化用于除去氮氧化物的燃料的方法，燃料和部分排气或进气的流量彼此分离地进入转化器，并且燃料在转化器中蒸发。还描述了用于催化转化燃料的转化器，其包括蒸发空间和与其连接的转化空间，所述蒸发空间具有用于排气或进气和燃料的单独进料，所述转化空间具有用于催化转化燃料的催化剂并且蒸发空间和转化空间彼此连接，使得从转化空间到蒸发空间的热传递是可能的。

2. 发明申请

US20070032680A1 Heterogeneously catalyzed gas-phase partial oxidation of precursor compounds of (meth)acrylic acid 审中-公开
标题翻译：（甲基）丙烯酸前体化合物的非均相催化气相部分氧化
公开(公告)号：US20070032680A1
公开(公告)日：2007-02-08
申请号：US11443135
申请日：2006-05-31
申请人： Raimund Felder , Signe Unverricht , Heiko Arnold , Jochen Petzoldt
发明人： Raimund Felder , Signe Unverricht , Heiko Arnold , Jochen Petzoldt
IPC分类号： C07C51/16 , C07C51/235
CPC分类号： C07C51/235 , B01J19/30 , B01J23/28 , B01J23/31 , B01J23/8876 , B01J23/8877 , B01J35/002 , B01J35/026 , B01J2219/30223 , B01J2219/30242 , B01J2219/30475 , C07C45/35 , C07C51/252 , C07C47/22 , C07C57/04
摘要： In a process for the heterogeneously catalyzed gas-phase partial oxidation of precursor compounds of (meth)acrylic acid over a fixed catalyst bed which contains, as a catalyst, a mixed oxide active material shaped into a geometric body, the geometric body is a geometric base body into whose surface a cavity has been introduced.
摘要翻译：在（甲基）丙烯酸前体化合物在固定催化剂床上的非均相催化气相部分氧化的方法中，该固定催化剂床含有形成几何体的混合氧化物活性物质作为催化剂，几何体是几何体基体已经被引入其表面。

3. 发明授权

US07005554B2 Method for continuous hydrogenation of citronellal to form citronellol 有权
标题翻译：香茅醛连续氢化形成香茅醇的方法
公开(公告)号：US07005554B2
公开(公告)日：2006-02-28
申请号：US10519686
申请日：2003-07-14
申请人： Hans-Georg Göbbel , Till Gerlach , Günter Wegner , Hartwig Fuchs , Signe Unverricht , Axel Salden
发明人： Hans-Georg Göbbel , Till Gerlach , Günter Wegner , Hartwig Fuchs , Signe Unverricht , Axel Salden
IPC分类号： C07C29/141
CPC分类号： C07C29/141 , C07C33/025
摘要： A process is described for selectively hydrogenating citronellal to citronellol in which a liquid phase, in which the citronellal is dissolved and particles of a catalyst are suspended which is capable of preferentially hydrogenating carbon-oxygen double bonds over carbon—carbon double bonds, is conducted through a device which inhibits the transport of the catalyst particles in the presence of a hydrogen-containing gas.
摘要翻译：描述了一种用于选择性地将香茅醛氢化成香茅醇的方法，其中将香茅醛溶解的液相和悬浮的催化剂颗粒悬浮，其能够优先在碳 - 碳双键上氢化碳 - 氧双键，通过在含氢气体的存在下抑制催化剂颗粒的输送的装置。

4. 发明授权

US06916964B2 Selective hydrogenation of olefinically unsaturated carbonyl compounds 有权
标题翻译：烯属不饱和羰基化合物的选择性氢化
公开(公告)号：US06916964B2
公开(公告)日：2005-07-12
申请号：US10309181
申请日：2002-12-04
申请人： Hans-Georg Göbbel , Till Gerlach , Frank Funke , Klaus Ebel , Signe Unverricht , Gerd Kaibel
发明人： Hans-Georg Göbbel , Till Gerlach , Frank Funke , Klaus Ebel , Signe Unverricht , Gerd Kaibel
IPC分类号： C07B61/00 , C07C29/141 , C07C33/03 , C07C29/136 , C07C29/14 , C07C29/143 , C07C29/147
CPC分类号： C07C29/141 , C07B2200/07 , C07C33/02 , C07C33/025
摘要： The present invention relates to a continuous process for the selective hydrogenation of olefinically unsaturated carbonyl compounds to give unsaturated alcohols in particular of citral to give a mixture of geraniol and nerol, in a reactor containing a liquid phase, in which at least one catalyst is suspended, and which can additionally contain a gas phase, wherein the liquid phase and, if present, the gas phase are passed through a device in the reactor having openings or channels.
摘要翻译：本发明涉及一种用于选择性氢化烯属不饱和羰基化合物的连续方法，以在含有液相的反应器中提供不饱和醇，特别是柠檬醛，得到香叶醇和橙花醇的混合物，其中悬浮有至少一种催化剂并且其还可以包含气相，其中液相和（如果存在的话）气相通过具有开口或通道的反应器中的装置。

5. 发明申请

US20050065371A1 Preparation of annular unsupported catalysts 有权
标题翻译：环状无载体催化剂的制备
公开(公告)号：US20050065371A1
公开(公告)日：2005-03-24
申请号：US10934525
申请日：2004-09-07
申请人： Jochen Petzoldt , Klaus Mueller-Engel , Signe Unverricht
发明人： Jochen Petzoldt , Klaus Mueller-Engel , Signe Unverricht
IPC分类号： B01J23/00 , B01J23/887 , B01J23/888 , B01J35/00 , B01J35/02 , B01J35/10 , B01J37/00 , B01J37/08 , C07C45/35 , C07C45/37 , C07C51/25 , C07C51/16 , C07C51/235
CPC分类号： C07C51/252 , B01J23/002 , B01J23/8876 , B01J23/8877 , B01J23/8885 , B01J35/0006 , B01J35/026 , B01J35/1009 , B01J35/1014 , B01J35/1038 , B01J35/108 , B01J37/0018 , B01J37/0063 , B01J37/08 , B01J2523/00 , C07C45/35 , C07C45/37 , C07C47/22 , C07C57/04 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845
摘要： A process for preparing annular unsupported catalysts by thermally treating annular shaped unsupported catalyst precursor bodies, wherein the side crushing strength of the annular shaped unsupported catalyst precursor bodies is ≧12 N and ≦23 N. In addition, resulting annular unsupported catalysts having a specific pore structure and also the use of such annular unsupported catalysts for the catalytic partial oxidative preparation in the gas phase of (meth)acrolein.
摘要翻译：环形无载体催化剂前体体的热处理制备环状无载体催化剂的方法，其中环形无载体催化剂前体体的侧面破碎强度> = 12N且≤23N。此外，得到的环状无载体催化剂具有并且还使用这种环状无载体催化剂用于（甲基）丙烯醛气相中的催化部分氧化制备。

6. 发明授权

US06794539B2 Method for producing multiple-phase multi-metal oxide materials 失效
标题翻译：多相多金属氧化物材料的制造方法
公开(公告)号：US06794539B2
公开(公告)日：2004-09-21
申请号：US10380159
申请日：2003-03-17
申请人： Signe Unverricht , Raimund Felder , Heiko Arnold , Jochen Petzoldt
发明人： Signe Unverricht , Raimund Felder , Heiko Arnold , Jochen Petzoldt
IPC分类号： C07C5116
CPC分类号： B01J37/00 , B01J23/002 , B01J23/887 , B01J35/0006 , B01J2523/00 , C07C51/252 , C07C57/04 , B01J2523/17 , B01J2523/55 , B01J2523/68 , B01J2523/69
摘要： In a process for preparing a multiplephase multimetal oxide composition comprising Mo, V, Cu and, if desired, further elements, at least one phase is preformed separately and dispersed in a plastically deformable precursor composition of a further phase. The mixture is dried and calcined. The multimetal oxide composition is suitable as active composition of catalysts for the catalytically oxidation of organic compounds in the gas phase, in particular for the oxidation of acrolein to acrylic acid.
摘要翻译：在制备包含Mo，V，Cu的多相多金属氧化物组合物的方法中，并且如果需要，另外的元素，至少一个相分别预成型并分散在另一相的可塑变形的前体组合物中。将混合物干燥并煅烧。多金属氧化物组合物适合用作气相中有机化合物催化氧化的催化剂的活性组合物，特别是用于将丙烯醛氧化成丙烯酸。

7. 发明授权

US06525217B1 Method for the catalytic gas-phase oxidation of propene to acrylic acid 有权
标题翻译：丙烯催化气相氧化丙烯酸的方法
公开(公告)号：US06525217B1
公开(公告)日：2003-02-25
申请号：US09914591
申请日：2001-08-30
申请人： Signe Unverricht , Heiko Arnold , Andreas Tenten , Ulrich Hammon , Hans-Peter Neumann , Klaus Harth
发明人： Signe Unverricht , Heiko Arnold , Andreas Tenten , Ulrich Hammon , Hans-Peter Neumann , Klaus Harth
IPC分类号： C07C5125
CPC分类号： C07C51/252 , B01J23/002 , B01J23/31 , B01J23/8872 , B01J23/8876 , B01J23/8885 , B01J35/0006 , B01J37/0221 , B01J2523/00 , C07C45/35 , C07C47/22 , C07C57/04 , B01J2523/13 , B01J2523/17 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845 , B01J2523/55
摘要： A process for the catalytic gas-phase oxidation of propene to acrylic acid, in which the reaction gas starting mixture is oxidized, with an increased propene loading, in a first reaction stage, over a first fixed-bed catalyst and then the acrolein-containing product gas mixture of the first reaction stage is oxidized, in a second reaction stage, with an increased acrolein loading, over a second fixed-bed catalyst, the catalyst moldings in both reaction stages having an annular geometry.
摘要翻译：在第一个反应阶段，在第一个固定床催化剂上催化气相氧化丙烯到丙烯酸的方法，其中反应气体起始混合物在丙烯负载量增加，丙烯含量增加的情况下被氧化，然后含有丙烯醛在第二反应阶段，第一反应阶段的产物气体混合物在第二反应阶段被氧化，丙烯醛加载量增加，在第二固定床催化剂上，两个反应阶段的催化剂模制品具有环形几何形状。

8. 发明授权

US06403829B1 Method for the catalytic gas phase oxidation of acrolein into acrylic acid 有权
标题翻译：丙烯醛催化气相氧化成丙烯酸的方法
公开(公告)号：US06403829B1
公开(公告)日：2002-06-11
申请号：US09936177
申请日：2001-09-10
申请人： Signe Unverricht , Heiko Arnold , Andreas Tenten , Ulrich Hammon
发明人： Signe Unverricht , Heiko Arnold , Andreas Tenten , Ulrich Hammon
IPC分类号： C07C5116
CPC分类号： B01J37/0223 , B01J23/002 , B01J23/8877 , B01J2523/00 , C07C51/252 , C07C57/04 , B01J2523/17 , B01J2523/55 , B01J2523/68 , B01J2523/69
摘要： In a process for the catalytic gas-phase oxidation of acrolein to acrylic acid, the reaction gas starting mixture is passed, with an acrolein loading of ≧150 l (s.t.p.)/l.h, over a fixed-bed catalyst which is housed in two spatially successive reaction zones A, B, the reaction zone B being kept at a higher temperature than the reaction zone A.
摘要翻译：在将丙烯醛催化气相氧化成丙烯酸的过程中，使反应气起始混合物通过固定床催化剂上丙烯醛负载大于等于150l（stp）/ lh）空间连续的反应区A，B，反应区B保持在比反应区A高的温度。

9. 发明授权

US07777082B2 Preparation of annular unsupported catalysts 有权
标题翻译：环状无载体催化剂的制备
公开(公告)号：US07777082B2
公开(公告)日：2010-08-17
申请号：US10934525
申请日：2004-09-07
申请人： Jochen Petzoldt , Klaus Joachim Mueller-Engel , Signe Unverricht
发明人： Jochen Petzoldt , Klaus Joachim Mueller-Engel , Signe Unverricht
IPC分类号： B01J23/16 , B01J23/18 , B01J23/28 , B01J23/31 , B01J23/745 , C07C45/27
CPC分类号： C07C51/252 , B01J23/002 , B01J23/8876 , B01J23/8877 , B01J23/8885 , B01J35/0006 , B01J35/026 , B01J35/1009 , B01J35/1014 , B01J35/1038 , B01J35/108 , B01J37/0018 , B01J37/0063 , B01J37/08 , B01J2523/00 , C07C45/35 , C07C45/37 , C07C47/22 , C07C57/04 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845
摘要： A process for preparing annular unsupported catalysts by thermally treating annular shaped unsupported catalyst precursor bodies, wherein the side crushing strength of the annular shaped unsupported catalyst precursor bodies is ≧12 N and ≦23 N; such precursor bodies per se; annular unsupported catalysts having a specific pore structure; and a method of using such annular unsupported catalysts for the catalytic partial oxidative preparation in the gas phase of (meth)acrolein.
摘要翻译：一种通过热处理环形的未负载的催化剂前体体来制备环形的未负载的催化剂的方法，其中环形的未负载的催化剂前体体的侧面破碎强度为≥12N和＆lt; NlE; 23N; 这样的前体体本身; 具有特定孔结构的环状无载体催化剂; 以及在（甲基）丙烯醛气相中使用这种环状无载体催化剂用于催化部分氧化制备的方法。

10. 发明授权

US07589046B2 Thermal treatment of the precursor material of a catalytically active material 有权
标题翻译：催化活性材料的前体材料的热处理
公开(公告)号：US07589046B2
公开(公告)日：2009-09-15
申请号：US10843632
申请日：2004-05-12
申请人： Martin Dieterle , Wolfgang Juergen Poepel , Silke Berndt , Raimund Felder , Signe Unverricht , Klaus Joachim Mueller-Engel
发明人： Martin Dieterle , Wolfgang Juergen Poepel , Silke Berndt , Raimund Felder , Signe Unverricht , Klaus Joachim Mueller-Engel
IPC分类号： B01J23/00
CPC分类号： B01J23/002 , B01J23/885 , B01J37/0009 , B01J37/0045 , B01J37/0223 , B01J37/08 , B01J2523/00 , C07C51/252 , C21B13/006 , C21B13/0073 , C21B13/08 , C21B2100/44 , C22B1/216 , C22B34/00 , C22B34/30 , Y02P10/136 , C07C57/04 , B01J2523/17 , B01J2523/55 , B01J2523/68 , B01J2523/69
摘要： In a process for the thermal treatment of the precursor material of a catalytically active material in a rotary tube furnace through which a gas stream flows, at least a proportion of the gas stream flowing through the rotary tube furnace is circulated, and the associated rotary tube furnace apparatus and tube-bundle reactors for the partial gas-phase oxidation of acrolein to acrylic acid are loaded with catalysts whose catalytically active material is obtainable by the process for the thermal treatment.
摘要翻译：在用于热处理旋转管式炉中的催化活性材料的前体材料的方法中，气流流过该方法，使流过旋转管式炉的气流的至少一部分循环，并将相关的旋转管用于将丙烯醛部分气相氧化成丙烯酸的炉装置和管束反应器装载有催化活性物质可通过热处理方法获得的催化剂。

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