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1. 发明申请

US20100249362A1 APPARATUS AND METHOD BOTH RELATING TO POLYMER SYNTHESIS 审中-公开
标题翻译：与聚合物合成相关的装置和方法
公开(公告)号：US20100249362A1
公开(公告)日：2010-09-30
申请号：US12741489
申请日：2008-11-04
申请人： Masayuki Kamikawa , Toshiaki Matsuo , Naruyasu Okamoto , Kenichiro Oka , Takashi Yatsugi , Yasuhiro Fujii , Tatsushi Kawamoto
发明人： Masayuki Kamikawa , Toshiaki Matsuo , Naruyasu Okamoto , Kenichiro Oka , Takashi Yatsugi , Yasuhiro Fujii , Tatsushi Kawamoto
IPC分类号： C07D319/10 , C08G63/08 , B01J8/02 , B01J19/00
CPC分类号： C07D319/12 , B01J19/1862 , B01J19/1887 , B01J19/20 , B01J2219/00009 , B01J2219/00083 , B01J2219/00779 , C08G63/08 , C08G63/78 , C08J11/16 , C08J2367/04 , Y02P20/584 , Y02W30/705
摘要： The present invention provides a method and apparatus for producing polylactic acid by depolymerizing lactic acid oligomers and subjecting the obtained lactide to ring-opening polymerization, through which lactide can be efficiently obtained. The present invention relates to a lactide production apparatus for continuously or intermittently producing lactide, comprising: a depolymerization device 11 for subjecting lactic acid oligomers to a depolymerization reaction; a catalyst regeneration device 27 for subjecting a residue in the depolymerization device to a depolymerization reaction in order to reduce the molecular weights of lactic acid oligomers contained in the residue; and a distillation column 29 for condensing lactide generated in a gas form as a result of the depolymerization reaction.
摘要翻译：本发明提供了一种通过解聚乳酸低聚物并使得到的丙交酯进行开环聚合制备聚乳酸的方法和装置，可以有效地获得丙交酯。本发明涉及一种用于连续或间断地生产丙交酯的丙交酯生产设备，包括：用于使乳酸低聚物进行解聚反应的解聚装置11; 用于使解聚装置中的残余物进行解聚反应以降低残留物中所含的乳酸低聚物的分子量的催化剂再生装置27; 以及用于冷凝由于解聚反应而以气体形式产生的丙交酯的蒸馏塔29。

2. 发明申请

US20050222379A1 Method and apparatus for synthesis of lactide 审中-公开
标题翻译：合成丙交酯的方法和装置
公开(公告)号：US20050222379A1
公开(公告)日：2005-10-06
申请号：US11066998
申请日：2005-02-28
申请人： Toshiaki Matsuo , Takayuki Matsumoto , Naruyasu Okamoto , Hitomi Ohara , Seiji Sawa , Yasuhiro Fujii , Tatsushi Kawamoto , Takashi Yatsugi
发明人： Toshiaki Matsuo , Takayuki Matsumoto , Naruyasu Okamoto , Hitomi Ohara , Seiji Sawa , Yasuhiro Fujii , Tatsushi Kawamoto , Takashi Yatsugi
IPC分类号： C08G63/78 , B01J19/18 , C07C67/08 , C08G63/08 , C08L101/16
CPC分类号： B01J19/1862 , B01J2219/00031 , B01J2219/0004 , B01J2219/00094 , B01J2219/00135 , B01J2219/002 , C07D319/12 , C08G63/08
摘要： The present invention is envisaged to provide an apparatus and a process for synthesizing lactide, according to which the water content in the produced lactide can be reduced. In operation of the system, lactic acid oligomer discharge valve 10 is closed, allowing transfer of lactic acid to its polycondensing apparatus 2, and concentration and polycondensation of lactic acid are advanced by heating and evacuation, with the produced water being evaporated. Lactic acid, lactic acid oligomer and lactide are removed from the produced gaseous body by condenser 11 and refluxed to the polycondensing apparatus, and then water content in the gaseous body is measured by pressure gauge 12. After confirming that the water content is below a specified value, lactic acid oligomer discharge valve 10 is opened to allow transfer of the lactic acid oligomer, said oligomer being depolymerized to produce gaseous lactide, which is condensed and recovered.
摘要翻译：本发明设想提供一种用于合成丙交酯的装置和方法，根据该方法可以减少所生产的丙交酯中的水含量。在该系统的操作中，乳酸低聚物排出阀10关闭，允许将乳酸转移到其缩聚装置2中，并且通过加热和抽真空来促进乳酸的浓缩和缩聚，产生的水被蒸发。乳酸，乳酸低聚物和丙交酯通过冷凝器11从产生的气体中除去并回流到缩聚装置，然后通过压力计12测量气体中的含水量。在确认水分低于规定值后，打开乳酸低聚物排出阀10，使乳酸低聚物转移，将所述低聚物解聚，生成气态丙交酯，将其冷凝回收。

3. 发明申请

US20120116100A1 SYSTEM AND METHOD FOR PRODUCING POLYHYDROXYCARBOXYLIC ACID 审中-公开
标题翻译：用于生产聚羟基羧酸的系统和方法
公开(公告)号：US20120116100A1
公开(公告)日：2012-05-10
申请号：US13287144
申请日：2011-11-02
申请人： Masayuki KAMIKAWA , Toshiaki Matsuo , Naruyasu Okamoto , Kenichiro Oka , Takeyuki Kondo , Akira Tomura , Kazutaka Suzuki
发明人： Masayuki KAMIKAWA , Toshiaki Matsuo , Naruyasu Okamoto , Kenichiro Oka , Takeyuki Kondo , Akira Tomura , Kazutaka Suzuki
IPC分类号： C07D319/12 , B01J19/00
CPC分类号： C08G63/78 , B01J19/2415 , B01J19/2425 , B01J2219/00006 , B01J2219/00085 , C07D319/12 , C08G63/08
摘要： An object of the present invention is to provide a method and a system by which hydroxycarboxylic acid cyclic dimers are efficiently generated, allowing high yields of high-quality polyhydroxycarboxylic acid to be obtained. The method for synthesizing polyhydroxycarboxylic acid comprises a depolymerization step for depolymerizing hydroxycarboxylic acid oligomers to produce hydroxycarboxylic acid cyclic dimers, wherein, in the depolymerization step, a reaction solution is heated via heat transfer from a heat medium passage under reduced pressure while the reaction solution is being flowing through a horizontally provided reaction solution passage.
摘要翻译：本发明的目的是提供一种有效地产生羟基羧酸环状二聚体的方法和系统，可以获得高产率的高品质聚羟基羧酸。聚羟基羧酸的合成方法包括使羟基羧酸低聚物解聚以产生羟基羧酸环状二聚体的解聚步骤，其中在解聚步骤中，将反应溶液通过热介质通道在减压下的热传递加热，同时反应溶液为流过水平提供的反应溶液通道。

4. 发明授权

US08153754B2 Equipment and method for producing polyhydroxycarboxylic acid 有权
标题翻译：多羟基羧酸的制备方法和设备
公开(公告)号：US08153754B2
公开(公告)日：2012-04-10
申请号：US12544477
申请日：2009-08-20
申请人： Masayuki Kamikawa , Toshiaki Matsuo , Naruyasu Okamoto , Kenichiro Oka , Takeyuki Kondo
发明人： Masayuki Kamikawa , Toshiaki Matsuo , Naruyasu Okamoto , Kenichiro Oka , Takeyuki Kondo
IPC分类号： C08G63/08 , B01D53/00 , B01J19/18
CPC分类号： C08G63/785 , B01J4/002 , B01J19/24 , B01J2219/00006 , B01J2219/00777 , B01J2219/185 , C08G63/06 , Y02P20/582
摘要： An equipment for producing polyhydroxycarboxylic acid, includes a ring-opening polymerization apparatus, a liquid phase devolatilizing apparatus, and a drying apparatus, wherein an indirect heat exchanger is connected to a vent gas discharge path of the liquid phase devolatilizing apparatus. The indirect heat exchanger captures a dispersed in-process substance containing hydroxycarboxylic acid cyclic dimers and transfers the substance to the ring-opening polymerization apparatus; a wet condenser and a hot well are connected to a vent gas discharge path of the indirect heat exchanger and that of the drying apparatus, respectively. The wet condenser captures a dispersed in process substance containing the cyclic dimers with the use of a refrigerant containing hydroxycarboxylic acid corresponding to the cyclic dimers and transfers the substance to the hot well; the hot well causes hydrolysis of the cyclic dimers for generation of hydroxycarboxylic acid; the generated hydroxycarboxylic acid is mixed with a refrigerant and the mixture is circulated to the wet condenser; and hydroxycarboxylic acid is highly concentrated via circulation between the wet condenser and the hot well and then discharged.
摘要翻译：用于制备聚羟基羧酸的设备包括开环聚合设备，液相脱挥发酵设备和干燥设备，其中间接热交换器连接到液相脱挥发设备的通气气体排放路径。间接热交换器捕获含有羟基羧酸环二聚体的分散的在线物质并将物质转移到开环聚合装置中; 湿式冷凝器和热井分别连接到间接热交换器和干燥装置的排放气体排出路径。湿式冷凝器使用含有对应于环状二聚体的羟基羧酸的制冷剂捕获含有环状二聚体的分散过程物质，并将物质转移到热井中; 热阱引起环状二聚体的水解产生羟基羧酸; 将所生成的羟基羧酸与制冷剂混合，并将混合物循环至湿式冷凝器; 并且羟基羧酸通过湿式冷凝器和热井之间的循环高度浓缩，然后排出。

5. 发明申请

US20080004469A1 METHOD AND APPARATUS FOR PRODUCING POLYHYDROXY CARBOXYLIC ACID 有权
标题翻译：用于生产聚羟基羧酸的方法和装置
公开(公告)号：US20080004469A1
公开(公告)日：2008-01-03
申请号：US11770165
申请日：2007-06-28
申请人： Masayuki KAMIKAWA , Toshiaki Matsuo , Kenichiro Oka , Naruyasu Okamoto , Ryuji Kaziya
发明人： Masayuki KAMIKAWA , Toshiaki Matsuo , Kenichiro Oka , Naruyasu Okamoto , Ryuji Kaziya
IPC分类号： C07C59/10 , B01J19/00
CPC分类号： C08G63/785 , B01J19/0066 , B01J19/1806 , B01J19/1862 , B01J19/1887 , B01J19/20 , B01J2219/00006 , B01J2219/00083 , B01J2219/00779 , B01J2219/182 , B01J2219/1946 , C08G63/06
摘要： The object is to provide a method and apparatus for producing a polyhydroxy carboxylic acid according to which an annular diner can be efficiently obtained in the production of polyhydroxy carboxylic acid which is small in distribution breadth of molecular weight in depolymerization and opening ring polymerization steps. There are provided a depolymerization device 11 which depolymerizes hydroxy carboxylic acid or a polycondensate thereof into an annular dimer, a upper distillation column 13 which condenses the annular dimer vaporized in the depolymerization device 11, and lower distillation column 12 which refluxes the annular dimer and is provided between the depolymerization device 11 and the upper distillation column 13, said depolymerization device 11 having a polycondensate feed opening 54 and an annular dimer discharge opening 55 which are provided at a casing 50, a liquid film being formed inside the casing 50 and heated by a heating part.
摘要翻译：本发明的目的是提供一种生产多羟基羧酸的方法和装置，根据该方法和装置，在解聚和开环聚合步骤中分子量分布宽度小的多羟基羧酸的制备中可以有效地获得环形餐具。提供了将羟基羧酸或其缩聚物解聚成环状二聚体的解聚装置11，使在解聚装置11中蒸发的环状二聚体冷凝的上部蒸馏塔13和回流该环状二聚体的下馏分12，在解聚装置11和上部蒸馏塔13之间，所述解聚装置11具有设置在壳体50处的缩聚物供给口54和环状二聚体排出口55，液体膜形成在壳体50的内部并被加热加热部件。

6. 发明授权

US08106150B2 Polylactide manufacturing apparatus and method for manufacturing polylactide 有权
标题翻译：聚丙交酯制造装置和聚丙交酯的制造方法
公开(公告)号：US08106150B2
公开(公告)日：2012-01-31
申请号：US12453912
申请日：2009-05-27
申请人： Kenichiro Oka , Toshiaki Matsuo , Masayuki Kamikawa , Naruyasu Okamoto
发明人： Kenichiro Oka , Toshiaki Matsuo , Masayuki Kamikawa , Naruyasu Okamoto
IPC分类号： C08G63/08 , B01D53/78 , B01J19/18
CPC分类号： C08G63/08 , B01J19/1818 , B01J2219/00006
摘要： In a process of manufacturing polylactide, synthesis of high-quality polymers is achieved with a sufficient degree of vacuum secured. Provided is an apparatus for manufacturing polylactide which includes the steps of preparing lactide through oligomerization of lactic acid and depolymerization of the resulting oligomers, effecting ring-opening polymerization of the lactide, and removing unreacted lactide. The apparatus comprises an exhausting gas treatment device for reducing pressure in the step of removing unreacted lactide. The exhausting gas treatment device includes boilers (81-83) for generating water vapor; a pressure-reducing section having stages each including an ejector (71-73) driven with the water vapor, a condenser (61-63) connected downstream of the ejector, and a hot well tank (41-43) connected to the condenser; and a main condenser 60 and a main hot well tank 40 connected to the main condenser that are disposed on a pipe line through which a gas of the unreacted lactide is suctioned into the pressure-reducing section. The gas of the unreacted lactide is washed away in the main condenser using a liquid containing lactic acid as a main component that has been collected in the main hot well tank.
摘要翻译：在制备聚丙交酯的过程中，通过确保足够的真空度实现高质量聚合物的合成。提供了一种制备聚丙交酯的装置，包括通过乳酸低聚制备丙交酯并使所得低聚物解聚，进行丙交酯的开环聚合和除去未反应的丙交酯的步骤。该装置包括用于在去除未反应的丙交酯的步骤中降低压力的排气处理装置。排气处理装置包括用于产生水蒸汽的锅炉（81-83）减压部，其具有各自包括由水蒸气驱动的喷射器（71-73）的台阶，连接在喷射器下游的冷凝器（61-63）和连接到冷凝器的热井箱（41-43）; 以及主冷凝器60和连接到主冷凝器的主热水箱40，所述主冷凝器60设置在管道上，未反应的丙交酯的气体被吸入减压部。未反应的丙交酯的气体在主冷凝器中使用含有乳酸作为主要成分的液体在主要热水槽中被收集。

7. 发明授权

US08450531B2 Method for synthesizing acrolein 失效
标题翻译：丙烯醛合成方法
公开(公告)号：US08450531B2
公开(公告)日：2013-05-28
申请号：US12979459
申请日：2010-12-28
申请人： Takeyuki Kondo , Masayuki Kamikawa , Kenichiro Oka , Toshiaki Matsuo , Masashi Tanto , Yasunari Sase , Hiroyuki Ito , Tomofumi Shiraishi , Tsutomu Kawamura , Naruyasu Okamoto
发明人： Takeyuki Kondo , Masayuki Kamikawa , Kenichiro Oka , Toshiaki Matsuo , Masashi Tanto , Yasunari Sase , Hiroyuki Ito , Tomofumi Shiraishi , Tsutomu Kawamura , Naruyasu Okamoto
IPC分类号： C07C45/64 , C07D307/46 , C07H1/00
CPC分类号： C07D307/48 , B01F5/0057 , B01F5/0615 , B01F5/0682 , B01F5/0688 , C07C45/52 , Y02P20/544 , C07C47/22
摘要： An object of the present invention is to provide a method for commercially manufacturing acrolein in a large flow rate by making supercritical water and an acid interact with glycerin, wherein by efficiently mixing high-concentration glycerin and supercritical water with each other, the method is made capable of making the synthesis stably proceed with a high yield while the occlusion and abrasion of the pipes and devices due to the generation of by-products are being suppressed. The method for synthesizing acrolein of the present invention is a method for synthesizing acrolein by making supercritical water and an acid interact with glycerin, the method using a reaction apparatus including: a cylindrical mixing flow path for mixing a fluid including glycerin and a fluid including supercritical water with each other; a first inlet flow path, disposed offset from the central axis of the mixing flow path, for making the fluid including glycerin flow into the mixing flow path; and a second inlet flow path, disposed offset from the central axis of the mixing flow path, for making the fluid including supercritical water flow into the mixing flow path, wherein the first inlet flow path and the second inlet flow path are each provided in a plurality of numbers in such a way that the first inlet flow paths and the second inlet flow paths are alternately arranged so as to encircle the central axis of the mixing flow path.
摘要翻译：本发明的目的是提供一种通过使超临界水和酸与甘油相互作用而大量流动丙烯醛的方法，其中通过将高浓度甘油和超临界水相互有效地混合，制备方法能够以高产率稳定地进行合成，同时由于副产物的产生而引起的管道和装置的堵塞和磨损被抑制。本发明的丙烯醛的合成方法是通过使超临界水和酸与甘油相互作用来合成丙烯醛的方法，使用反应装置的方法包括：将含有甘油的液体和包含超临界流体的流体混合的圆筒状混合流路水相互; 第一入口流动路径，设置为偏离混合流动路径的中心轴线，用于使包含甘油的流体流入混合流动路径; 以及第二入口流动路径，其设置成偏离混合流动路径的中心轴线，用于使包括超临界水流的流体流入混合流动路径，其中第一入口流动路径和第二入口流动路径分别设置在多个数字，使得第一入口流动路径和第二入口流动路径交替地布置成环绕混合流动路径的中心轴线。

8. 发明申请

US20110319667A1 REACTION PROCESS UTILIZING CRITICAL 失效
标题翻译：反应过程利用关键
公开(公告)号：US20110319667A1
公开(公告)日：2011-12-29
申请号：US13148760
申请日：2010-02-05
申请人： Takeyuki Kondo , Hiroyuki Ito , Naruyasu Okamoto , Yasunari Sase , Toshiaki Matsuo , Kenichiro Oka , Masayuki Kamikawa
发明人： Takeyuki Kondo , Hiroyuki Ito , Naruyasu Okamoto , Yasunari Sase , Toshiaki Matsuo , Kenichiro Oka , Masayuki Kamikawa
IPC分类号： C07C45/00 , B01J19/00
CPC分类号： B01J3/008 , B01J2219/00006 , B01J2219/00168 , C07C45/52 , Y02P20/544 , C07C47/22
摘要： In order to perform organic synthesis process through action with supercritical water and acid stably while suppressing a trouble caused by a by-product, a method and an apparatus are provided, including the following steps. Water is supplied to high-pressure pumps (110) and (210) from water headers (101) and (201), and a pressure-reducing valve (324) is regulated to increase the pressure to 35 MPa. Temperatures of preheaters (120) and (220) and a heater (310) are increased until the reaction solution is at a temperature of 400° C. Acid (sulfuric acid) and an organic compound raw material (glycerin) are supplied from an acid header (203) and a raw-material header (203′) for action with the supercritical water to obtain a reaction solution. The obtained reaction solution is cooled to 100 to 200° C. by first cooling (420) and a solid component included in the reaction solution is separated for removal from the reaction solution by a filter (320), and then the reaction solution is cooled to a temperature of about 100° C. or lower by second cooling (620) and pressure thereof is reduced (324). Further, the reaction solution is cooled by third cooling (720) and then a synthesized product (acrolein) is captured.
摘要翻译：为了通过超临界水和酸稳定地进行有机合成工艺，同时抑制由副产物引起的故障，提供了包括以下步骤的方法和装置。从集水管（101）和（201）向高压泵（110）和（210）供水，调节减压阀（324）以将压力增加至35MPa。增加预热器（120）和（220）和加热器（310）的温度，直到反应溶液处于400℃的温度。酸（硫酸）和有机化合物原料（甘油）由酸标题（203）和原料头（203'），用于与超临界水作用以获得反应溶液。将得到的反应溶液通过第一次冷却（420）冷却至100〜200℃，分离包含在反应溶液中的固体成分，通过过滤器（320）从反应溶液中除去，然后将反应溶液冷却通过第二冷却（620）至约100℃或更低的温度，并且其压力降低（324）。此外，将反应溶液通过第三次冷却（720）冷却，然后捕获合成产物（丙烯醛）。

9. 发明申请

US20110160447A1 METHOD FOR SYNTHESIZING ACROLEIN 失效
标题翻译：用于合成ACROLEIN的方法
公开(公告)号：US20110160447A1
公开(公告)日：2011-06-30
申请号：US12979459
申请日：2010-12-28
申请人： Takeyuki KONDO , Masayuki Kamikawa , Kenichiro Oka , Toshiaki Matsuo , Masashi Tanto , Yasunari Sase , Hiroyuki Ito , Tomofumi Shiraishi , Tsutomu Kawamura , Naruyasu Okamoto
发明人： Takeyuki KONDO , Masayuki Kamikawa , Kenichiro Oka , Toshiaki Matsuo , Masashi Tanto , Yasunari Sase , Hiroyuki Ito , Tomofumi Shiraishi , Tsutomu Kawamura , Naruyasu Okamoto
IPC分类号： C08B37/00 , C07C45/61 , C07D307/34
CPC分类号： C07D307/48 , B01F5/0057 , B01F5/0615 , B01F5/0682 , B01F5/0688 , C07C45/52 , Y02P20/544 , C07C47/22
摘要： An object of the present invention is to provide a method for commercially manufacturing acrolein in a large flow rate by making supercritical water and an acid interact with glycerin, wherein by efficiently mixing high-concentration glycerin and supercritical water with each other, the method is made capable of making the synthesis stably proceed with a high yield while the occlusion and abrasion of the pipes and devices due to the generation of by-products are being suppressed. The method for synthesizing acrolein of the present invention is a method for synthesizing acrolein by making supercritical water and an acid interact with glycerin, the method using a reaction apparatus including: a cylindrical mixing flow path for mixing a fluid including glycerin and a fluid including supercritical water with each other; a first inlet flow path, disposed offset from the central axis of the mixing flow path, for making the fluid including glycerin flow into the mixing flow path; and a second inlet flow path, disposed offset from the central axis of the mixing flow path, for making the fluid including supercritical water flow into the mixing flow path, wherein the first inlet flow path and the second inlet flow path are each provided in a plurality of numbers in such a way that the first inlet flow paths and the second inlet flow paths are alternately arranged so as to encircle the central axis of the mixing flow path.
摘要翻译：本发明的目的是提供一种通过使超临界水和酸与甘油相互作用而大量流动丙烯醛的方法，其中通过将高浓度甘油和超临界水相互有效地混合，制备方法能够以高产率稳定地进行合成，同时由于副产物的产生而引起的管道和装置的堵塞和磨损被抑制。本发明的丙烯醛的合成方法是通过使超临界水和酸与甘油相互作用来合成丙烯醛的方法，使用反应装置的方法包括：将含有甘油的液体和包含超临界流体的流体混合的圆筒状混合流路水相互; 第一入口流动路径，设置为偏离混合流动路径的中心轴线，用于使包含甘油的流体流入混合流动路径; 以及第二入口流动路径，其设置成偏离混合流动路径的中心轴线，用于使包括超临界水流的流体流入混合流动路径，其中第一入口流动路径和第二入口流动路径分别设置在多个数字，使得第一入口流动路径和第二入口流动路径交替地布置成环绕混合流动路径的中心轴线。

10. 发明授权

US08558035B2 Reaction process utilizing critical water 失效
标题翻译：使用临界水的反应过程
公开(公告)号：US08558035B2
公开(公告)日：2013-10-15
申请号：US13148760
申请日：2010-02-05
申请人： Takeyuki Kondo , Hiroyuki Ito , Naruyasu Okamoto , Yasunari Sase , Toshiaki Matsuo , Kenichiro Oka , Masayuki Kamikawa
发明人： Takeyuki Kondo , Hiroyuki Ito , Naruyasu Okamoto , Yasunari Sase , Toshiaki Matsuo , Kenichiro Oka , Masayuki Kamikawa
IPC分类号： C07C45/52 , B01J19/00
CPC分类号： B01J3/008 , B01J2219/00006 , B01J2219/00168 , C07C45/52 , Y02P20/544 , C07C47/22
摘要： In order to perform organic synthesis process through action with supercritical water and acid stably while suppressing a trouble caused by a by-product, a method and an apparatus are provided, including the following steps. Water is supplied to high-pressure pumps (110) and (210) from water headers (101) and (201), and a pressure-reducing valve (324) is regulated to increase the pressure to 35 MPa. Temperatures of preheaters (120) and (220) and a heater (310) are increased until the reaction solution is at a temperature of 400° C. Acid (sulfuric acid) and an organic compound raw material (glycerin) are supplied from an acid header (203) and a raw-material header (203′) for action with the supercritical water to obtain a reaction solution. The obtained reaction solution is cooled to 100 to 200° C. by first cooling (420) and a solid component included in the reaction solution is separated for removal from the reaction solution by a filter (320), and then the reaction solution is cooled to a temperature of about 100° C. or lower by second cooling (620) and pressure thereof is reduced (324). Further, the reaction solution is cooled by third cooling (720) and then a synthesized product (acrolein) is captured.
摘要翻译：为了通过超临界水和酸稳定地进行有机合成工艺，同时抑制由副产物引起的故障，提供了包括以下步骤的方法和装置。从集水管（101）和（201）向高压泵（110）和（210）供水，调节减压阀（324）以将压力增加至35MPa。增加预热器（120）和（220）和加热器（310）的温度，直到反应溶液处于400℃的温度。酸（硫酸）和有机化合物原料（甘油）由酸标题（203）和原料头（203'），用于与超临界水作用以获得反应溶液。将得到的反应溶液通过第一次冷却（420）冷却至100〜200℃，分离包含在反应溶液中的固体成分，通过过滤器（320）从反应溶液中除去，然后将反应溶液冷却通过第二冷却（620）至约100℃或更低的温度，并且其压力降低（324）。此外，将反应溶液通过第三次冷却（720）冷却，然后捕获合成产物（丙烯醛）。

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