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    • 4. 发明授权
    • Semiconductor device employing crystallization catalyst
    • 采用结晶催化剂的半导体装置
    • US5569936A
    • 1996-10-29
    • US207124
    • 1994-03-08
    • Hongyong ZhangHideki UochiToru TakayamaYasuhiko TakemuraMutsuo Yamamoto
    • Hongyong ZhangHideki UochiToru TakayamaYasuhiko TakemuraMutsuo Yamamoto
    • G02F1/1362H01L21/20H01L21/336H01L21/8238H01L27/092H01L27/12H01L29/786H01L29/76H01L29/04H01L31/036H01L27/01
    • H01L27/1251H01L21/2022H01L21/8238H01L27/0922H01L27/1237H01L27/1277H01L29/66757H01L29/78618H01L29/78675G02F1/13454Y10S148/016
    • A substance containing a catalyst element is formed so as to closely contact with an amorphous silicon film, or a catalyst element is introduced into the amorphous silicon film. The amorphous silicon film is annealed at a temperature which is lower than a crystallization temperature of usual amorphous silicon, thereby selectively crystallizing the amorphous silicon film. The crystallized region is used as a crystalline silicon TFT which can be used in a peripheral driver circuit of an active matrix circuit. The region which remains amorphous is used as an amorphous silicon TFT which can be used in a pixel circuit. A relatively small amount of a catalyst element for promoting crystallization is added to an amorphous silicon film, and an annealing process is conducted at a temperature which is lower than the distortion temperature of a substrate, thereby crystallizing the amorphous silicon film. A gate insulating film, and a gate electrode are then formed, and an impurity is implanted in a self-alignment manner. A film containing a catalyst element for promoting crystallization is closely contacted with the impurity region, or a relatively large amount of a catalyst element is introduced into the impurity region by an ion implantation or the like. Then, an annealing process is conducted at a temperature which is lower than the distortion temperature of the substrate, thereby activating the doping impurity.
    • 形成含有催化剂元素的物质,以与非晶硅膜紧密接触,或将催化剂元素引入到非晶硅膜中。 非晶硅膜在比通常的非晶硅的结晶温度低的温度下退火,从而选择性地使非晶硅膜结晶。 结晶区域用作可用于有源矩阵电路的外围驱动电路的晶体硅T​​FT。 保持非晶形的区域用作可用于像素电路中的非晶硅TFT。 在非晶硅膜中添加相对少量的促进结晶的催化剂元素,并且在比基板的变形温度低的温度下进行退火处理,从而使非晶硅膜结晶。 然后形成栅极绝缘膜和栅电极,并以自对准的方式注入杂质。 含有促进结晶的催化剂元素的膜与杂质区紧密接触,或者通过离子注入等将相对大量的催化剂元素引入杂质区。 然后,在比基板的变形温度低的温度下进行退火处理,从而激活掺杂杂质。
    • 6. 发明授权
    • Method of forming a thin film transistor
    • 形成薄膜晶体管的方法
    • US5595923A
    • 1997-01-21
    • US467986
    • 1995-06-06
    • Hongyong ZhangHideki UochiToru TakayamaYasuhiko TakemuraMutsuo Yamamoto
    • Hongyong ZhangHideki UochiToru TakayamaYasuhiko TakemuraMutsuo Yamamoto
    • G02F1/1362H01L21/20H01L21/336H01L21/8238H01L27/092H01L27/12H01L29/786H01L21/84
    • H01L27/1251H01L21/2022H01L21/8238H01L27/0922H01L27/1237H01L27/1277H01L29/66757H01L29/78618H01L29/78675G02F1/13454Y10S148/016
    • A substance containing a catalyst element is formed so as to closely contact with an amorphous silicon film, or a catalyst element is introduced into the amorphous silicon film. The amorphous silicon film is annealed at a temperature which is lower than a crystallization temperature of usual amorphous silicon, thereby selectively crystallizing the amorphous silicon film. The crystallized region is used as a crystalline silicon TFT which can be used in a peripheral driver circuit of an active matrix circuit. The region which remains amorphous is used as an amorphous silicon TFT which can be used in a pixel circuit. A relatively small amount of a catalyst element for promoting crystallization is added to an amorphous silicon film, and an annealing process is conducted at a temperature which is lower than the distortion temperature of a substrate, thereby crystallizing the amorphous silicon film. A gate insulating film, and a gate electrode are then formed, and an impurity is implanted in a self-alignment manner. A film containing a catalyst element for promoting crystallization is closely contacted with the impurity region, or a relatively large amount of a catalyst element is introduced into the impurity region by an ion implantation or the like. Then, an annealing process is conducted at a temperature which is lower than the distortion temperature of the substrate, thereby activating the doping impurity.
    • 形成含有催化剂元素的物质,以与非晶硅膜紧密接触,或将催化剂元素引入到非晶硅膜中。 非晶硅膜在比通常的非晶硅的结晶温度低的温度下退火,从而选择性地使非晶硅膜结晶。 结晶区域用作可用于有源矩阵电路的外围驱动电路的晶体硅T​​FT。 保持非晶形的区域用作可用于像素电路中的非晶硅TFT。 在非晶硅膜中添加相对少量的促进结晶的催化剂元素,并且在比基板的变形温度低的温度下进行退火处理,从而使非晶硅膜结晶。 然后形成栅极绝缘膜和栅电极,并以自对准的方式注入杂质。 含有促进结晶的催化剂元素的膜与杂质区紧密接触,或者通过离子注入等将相对大量的催化剂元素引入杂质区。 然后,在比基板的变形温度低的温度下进行退火处理,从而激活掺杂杂质。
    • 8. 发明授权
    • Method for manufacturing thin film transistor
    • 制造薄膜晶体管的方法
    • US5811326A
    • 1998-09-22
    • US372911
    • 1995-01-17
    • Mutsuo Yamamoto
    • Mutsuo Yamamoto
    • H01L21/316H01L21/336H01L21/77H01L21/84H01L29/49H01L29/786
    • H01L29/66757H01L21/31687H01L27/1214H01L29/4908H01L29/78621
    • In a thin film transistor (TFT), a part of a surface or a whole surface of aluminum used as a gate electrode is covered by anodic oxide. In a process after anodization process, ultraviolet light is irradiated to a gate electrode in an oxidizing atmosphere containing oxygen, ozone, or nitrous oxide. Or, in a process after anodization process, a TFT is leaved (placed) in plasma in an oxidizing atmosphere. Or, ultraviolet light is irradiated to a gate electrode in plasma in an oxidizing atmosphere. A substrate temperature is a room temperature (50.degree. C.) to 500.degree. C., for example, 200.degree. to 300.degree. C. By ultraviolet light irradiation or plasma processing, metallic aluminum contained in anodic oxide is oxidized.
    • 在薄膜晶体管(TFT)中,用作栅电极的铝的一部分表面或整个表面被阳极氧化物覆盖。 在阳极氧化处理之后的过程中,紫外线在含有氧,臭氧或一氧化二氮的氧化气氛中照射到栅电极。 或者,在阳极氧化处理之后的过程中,在氧化气氛中将TFT留在等离子体中。 或者,在氧化气氛中将紫外线照射到等离子体中的栅电极。 基板温度为室温(50℃)至500℃,例如200℃至300℃。通过紫外光照射或等离子体处理,阳极氧化物中所含的金属铝被氧化。