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    • 4. 发明授权
    • Aromatic polyester carbonate and method for producing the same
    • 芳香族聚碳酸酯及其制造方法
    • US4107143A
    • 1978-08-15
    • US765333
    • 1977-02-03
    • Hiroo InataTsuto MorinagaTakatoshi KuratsujiTakanori UrasakiShoji Kawase
    • Hiroo InataTsuto MorinagaTakatoshi KuratsujiTakanori UrasakiShoji Kawase
    • C08G63/64C08G63/62
    • C08G63/64
    • The present invention provides a substantially linear aromatic polyester carbonate consisting essentially of hydroxybenzoic acid unit, hydroquinone unit, and carbonate unit as well as, depending on the circumstances, aromatic carboxylic acid unit, and having an inherent viscosity of at least 0.5. The present invention also provides an industrially advantageous method for producing such linear aromatic polyester carbonate through the process steps of melt-polycondensation, and, if necessary, followed by a further polycondensation in solid phase.Such aromatic polyester carbonate which the present invention provides exhibits excellent melt-forming property and melt anisotropy, hence any shaped article obtained by melt-forming of this aromatic polyester carbonate exhibits superior mechanical properties, in particular, excellent Young's modulus of longitudinal elasticity, and so on, which is highly useful as the material for industrial applications. The present invention also provides shaped articles in fiber and film forms having such excellent Young's modulus of longitudinal elasticity as produced from the abovementioned aromatic polyester carbonate.
    • 本发明提供基本上由羟基苯甲酸单元,氢醌单元和碳酸酯单元组成的基本上线性的芳族聚酯碳酸酯,以及根据具体情况,芳族羧酸单元,并且具有至少0.5的特性粘度。 本发明还提供了通过熔融缩聚的方法制备这种线性芳族聚酯碳酸酯的工业上有利的方法,并且如果需要,随后进一步在固相中缩聚。
    • 8. 发明授权
    • Naphthalate polyester filaments
    • 萘二甲酸酯聚酯长丝
    • US4060516A
    • 1977-11-29
    • US646645
    • 1976-01-05
    • Takatoshi KuratsujiShoji KawaseTakeo Shima
    • Takatoshi KuratsujiShoji KawaseTakeo Shima
    • C08G63/189D01F6/62C08G63/18C08G63/70
    • C08G63/189D01F6/62
    • Naphthalate polyester filaments, yarns or fibers consisting essentially of a naphthalate polyester which has an intrinsic viscosity of 0.3 to 3.5 and a softening point of at least 200.degree. C, and in which at least 85 mol% of the total recurring units consist of units of the formula ##STR1## wherein n is 4 or 6, and having at least one diffraction peak at a Bragg scattering angle 2.theta. = 16.3.degree. -- 16.7.degree. and/or 2.theta. = 25.3.degree. - 25.8.degree. in their X-ray diffraction. These filaments, yarns or fibers are useful especially as an electrically insulating material, an elastomeric reinforcing material, a fluid filter material, a paper-making canvas and a fastener component material.Of these, filaments, yarns or fibers of poly(tetramethylene 2,6-naphthalate) are prepared by melt-spinning the polymer thereby to form undrawn filaments having a birefringence of at lest 0.01 and a density of not more than 1.300, drawing the undrawn filaments in at least one step at a temperature of at least 60.degree. C. at a total draw ratio of at least 1.8, and then heat-treating the drawn filaments at a temperature higher than the temperature employed in the drawing step and within a range of 100.degree. to 240.degree. C. at constant length, under a restricted shrinkage of not more than 15%, or under a stretch of not more than 15%.
    • 萘二甲酸酯聚酯长丝,基本上由萘甲酸酯聚酯组成的纱线或纤维,其特性粘度为0.3-3.5,软化点为至少200℃,其中至少85mol%的总重复单元由 其中n为4或6,并且在其X射线衍射中在布喇格散射角2θ= 16.3°-16.7°和/或2θ= 25.3°-25.8°处具有至少一个衍射峰的式。 这些长丝,纱线或纤维特别用作电绝缘材料,弹性体增强材料,流体过滤材料,造纸帆布和紧固件组件材料。