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    • 7. 发明授权
    • Thermosetting compositions
    • 热固性组合物
    • US5578677A
    • 1996-11-26
    • US578083
    • 1995-12-27
    • Masahiro IshidoyaKishio ShibatoKeiji KomotoKenji ShibamotoMitsuyuki MashitaOsamu Ohe
    • Masahiro IshidoyaKishio ShibatoKeiji KomotoKenji ShibamotoMitsuyuki MashitaOsamu Ohe
    • C08F299/02C07C69/00C08F8/14C08F290/00C08G18/42C08G18/82C08G59/00C08G59/20C08G59/32C08G59/40C08G59/68C08G63/00C08G63/91C08G69/00C08L33/02C08L63/00C08L67/00C08L67/02C08L67/06C09D163/00C09D167/00C09D167/06C09J167/00C09J167/06
    • C09D167/00C08L67/00C09D163/00C09J167/00
    • A thermosetting composition which comprises:(D) a self-crosslinking compound having in the molecule (a) one or more functional groups of the formula (2): ##STR1## wherein R.sup.5, R.sup.6 and R.sup.7 are each hydrogen or an organic group of 1 to 18 carbons, R.sup.8 is an organic group of 1 to 18 carbons, Y.sup.2 is oxygen or sulfur, or R.sup.7 and R.sup.8 are bonded with each other to form a heterocyclic structure which comprises Y.sup.2 as the heteroatom component; and (b) one or more reactive functional groups which can form a chemical bond with carboxyl functional groups which are regenerated from (a) by heating; (C) optionally, a thermal latent acid catalyst which is activated during curing of the composition by heating; (A) optionally, a compound having in the molecule two or more functional groups of the formula (1): ##STR2## wherein R.sup.1, R.sup.2 and R.sup.3 are each hydrogen or an organic group of 1 to 18 carbons, R.sup.4 is an organic group of 1 to 18 carbons, Y.sup.1 is oxygen or sulfur, or R.sup.3 and R.sup.4 are bonded with each other to form a heterocyclic structure which comprises Y.sup.1 as the heteroatom component; and/or, (B) optionally, a compound having in the molecule two or more reactive functional groups which can form a chemical bond by heating with either one or both of the functional group of the formula (1) and the functional group of the formula (2).
    • 一种热固性组合物,其包含:(D)在分子(a)中具有一个或多个式(2)的官能团的自交联化合物:其中R5,R6和R7各自为氢或 碳原子数为1〜18的有机基团,R 8为碳原子数为1〜18的有机基团,Y2为氧或硫,或者R 7和R 8相互结合形成杂环结构,该杂环结构包含Y2作为杂原子成分。 和(b)可以与(a)通过加热再生的羧基官能团形成化学键的一个或多个反应性官能团; (C)任选地,通过加热在组合物固化期间活化的热潜伏酸催化剂; (A)任选地,在分子中具有式(1)的两个或更多个官能团的化合物:其中R 1,R 2和R 3各自为氢或碳原子数为1至18的有机基团,R 4为 1到18个碳的有机基团,Y1是氧或硫,或者R3和R4彼此键合,形成包含Y1作为杂原子成分的杂环结构; 和/或(B)任选地,在分子中具有两个或更多个反应性官能团的化合物,所述反应性官能团可以通过用式(1)的官能团中的一个或两个加成而形成化学键, 公式(2)。