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1. 发明授权

US5660937A Thermosetting compositions, methods of coating and coated articles 失效
标题翻译：热固组合物，涂层方法和涂层制品
公开(公告)号：US5660937A
公开(公告)日：1997-08-26
申请号：US401368
申请日：1995-03-09
申请人： Masahiro Ishidoya , Kishio Shibato , Keiji Komoto , Kenji Shibamoto , Mitsuyuki Mashita , Osamu Ohe
发明人： Masahiro Ishidoya , Kishio Shibato , Keiji Komoto , Kenji Shibamoto , Mitsuyuki Mashita , Osamu Ohe
IPC分类号： B32B27/30 , B32B27/36 , B32B27/38 , C08L29/00 , C08L33/00 , C08L33/02 , C08L33/06 , C08L37/00 , C08L63/00 , C08L67/00 , C08L67/02 , C08L101/02 , C09D133/10 , C09D163/00 , C09D167/00 , C09D201/02 , C09J167/00
CPC分类号： C08L67/00 , C08L101/02 , C09D133/10 , C09D163/00 , C09D167/00 , C09D201/02 , C09J167/00 , C08L33/06 , C08L63/00 , Y10T428/31511 , Y10T428/31518 , Y10T428/31529 , Y10T428/31551 , Y10T428/31699 , Y10T428/31786 , Y10T428/31794 , Y10T428/31797 , Y10T428/31928 , Y10T428/31935
摘要： Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistance and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.
摘要翻译：热固性组合物包含在分子中具有被乙烯基醚化合物封闭的两个或多个羧基的化合物，乙烯基硫醚化合物或具有乙烯基型双键的杂化合物和氧或硫作为杂原子的化合物，具有两个或更多个可通过加热与封端的羧基化合物形成化学键的反应性官能团，特定的乙烯基醚或乙烯基硫醚和热潜在酸催化剂。第一化合物的封端羧基和第二化合物的反应性官能团可以包含在相同的分子中。热固性组合物提供具有优异的化学性质，物理性能，耐候性和储存稳定性的固化产物，并且有利地用于涂料组合物，油墨，粘合剂和模制塑料。

2. 发明授权

US5516839A Thermal latent carboxyl compounds and methods of preparation thereof 失效
标题翻译：热潜羧基化合物及其制备方法
公开(公告)号：US5516839A
公开(公告)日：1996-05-14
申请号：US260002
申请日：1994-06-15
申请人： Masahiro Ishidoya , Kishio Shibato , Keiji Komoto , Kenji Shibamoto , Mitsuyuki Mashita , Osamu Ohe
发明人： Masahiro Ishidoya , Kishio Shibato , Keiji Komoto , Kenji Shibamoto , Mitsuyuki Mashita , Osamu Ohe
IPC分类号： C08F299/02 , C07C69/00 , C08F8/14 , C08F290/00 , C08G18/42 , C08G18/82 , C08G59/00 , C08G59/20 , C08G59/32 , C08G59/40 , C08G59/68 , C08G63/00 , C08G63/91 , C08G69/00 , C08L33/02 , C08L63/00 , C08L67/00 , C08L67/02 , C08L67/06 , C09D163/00 , C09D167/00 , C09D167/06 , C09J167/00 , C09J167/06
CPC分类号： C09D167/00 , C08L67/00 , C09D163/00 , C09J167/00
摘要： A thermal latent compound which is prepared by a reaction of a polycarboxyl compound having two or more carboxyl groups in the molecule, having an acid equivalent of not more than 1000 g/mole and a number average molecular weight of not more than 4000, with a monovinyl ether compound, wherein at least two carboxyl groups are transformed into a functional group of the formula (1): ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are each a hydrogen atom or an organic group of 1 to 18 carbon atoms, R.sup.4 is an organic group of 1 to 18 carbon atoms, Y.sup.1 is an oxygen atom or R.sup.3 and R.sup.4 are bonded together to form a heterocyclic with Y.sup.1 as a heteroatom.
摘要翻译：通过在分子中具有两个以上羧基的多羧基化合物反应制备的热潜组合物，其酸当量不大于1000克/摩尔，数均分子量不大于4000，与其中至少两个羧基被转化成式（1）的官能团：其中R 1，R 2和R 3各自为氢原子或1至18个碳原子的有机基团 R4是1〜18个碳原子的有机基团，Y1是氧原子，R3和R4键合在一起形成与Y1作为杂原子的杂环。

3. 发明授权

US5521011A Thermosetting compositions, thermal latent acid catalysts, methods of coating and coated articles 失效
标题翻译：热固性组合物，热潜伏酸催化剂，涂覆方法和涂层制品
公开(公告)号：US5521011A
公开(公告)日：1996-05-28
申请号：US444160
申请日：1995-05-18
申请人： Masahiro Ishidoya , Kishio Shibato , Keiji Komoto , Kenji Shibamoto , Mitsuyuki Mashita , Osamu Ohe
发明人： Masahiro Ishidoya , Kishio Shibato , Keiji Komoto , Kenji Shibamoto , Mitsuyuki Mashita , Osamu Ohe
IPC分类号： B32B27/30 , B32B27/36 , B32B27/38 , C08L29/00 , C08L33/00 , C08L33/02 , C08L33/06 , C08L37/00 , C08L63/00 , C08L67/00 , C08L67/02 , C08L101/02 , C09D133/10 , C09D163/00 , C09D167/00 , C09D201/02 , C09J167/00
CPC分类号： C08L67/00 , C08L101/02 , C09D133/10 , C09D163/00 , C09D167/00 , C09D201/02 , C09J167/00 , C08L33/06 , C08L63/00 , Y10T428/31511 , Y10T428/31518 , Y10T428/31529 , Y10T428/31551 , Y10T428/31699 , Y10T428/31786 , Y10T428/31794 , Y10T428/31797 , Y10T428/31928 , Y10T428/31935
摘要： An article coated by a method of coating which comprises coating a substrate with a top coating material comprising at least one pigment and a thermosetting composition, the at least one pigment being in an amount of 0 to 100 weight parts based on 100 weight parts of the thermosetting composition, the thermosetting composition comprising (A) a compound having in the molecule two or more functional groups of the formula (I): ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are each selected from the group consisting of a hydrogen atom and an organic group of 1 to 18 carbon atoms, R.sup.4 is an organic group of 1 to 18 carbon atoms, Y.sup.1 is oxygen or sulfur, or R.sup.3 and R.sup.4 are bonded with each other to form a heterocyclic structure which comprises Y.sup.1 as the hetero atom; (B) a compound having in the molecule two or more reactive functional groups which can form chemical bonds with the functional groups of the compound (A) by heating, the reactive functional groups of the compound (B) are epoxy groups; and (F) a complex compound formed by coordination of a conjugated base of a Bronsted acid or a Bronsted salt to a vacant orbital of a Lewis acid in a mol ratio of the Bronsted acid or Bronsted salt to the vacant orbital of the Lewis acid of 0.1 to 4.
摘要翻译：一种通过涂覆方法涂覆的制品，其包括用包含至少一种颜料和热固性组合物的顶部涂料涂覆基材，所述至少一种颜料的量为0至100重量份，基于100重量份的所述热固性组合物包含（A）分子中具有式（I）的两个或多个官能团的化合物：其中R 1，R 2和R 3各自选自氢原子和1至18个碳原子的有机基团，R 4是1至18个碳原子的有机基团，Y 1是氧或硫，或者R 3和R 4彼此键合，形成杂环结构，其包含Y1作为杂原子原子; （B）化合物在分子中具有两个或更多个可通过加热与化合物（A）的官能团形成化学键的反应性官能团，化合物（B）的反应性官能团是环氧基; 和（F）通过将布朗斯台德酸或布朗斯台德盐的共轭碱与布朗斯台德酸或布朗斯特盐的摩尔比与路易斯酸的空位轨道配位的络合物与路易斯酸的空位轨道 0.1至4。

4. 发明授权

US5549932A Thermosetting compositions, methods of coating and coated articles 失效
标题翻译：热固组合物，涂层方法和涂层制品
公开(公告)号：US5549932A
公开(公告)日：1996-08-27
申请号：US401198
申请日：1995-03-09
申请人： Masahiro Ishidoya , Kishio Shibato , Keiji Komoto , Kenji Shibamoto , Mitsuyuki Mashita , Osamu Ohe
发明人： Masahiro Ishidoya , Kishio Shibato , Keiji Komoto , Kenji Shibamoto , Mitsuyuki Mashita , Osamu Ohe
IPC分类号： B32B27/30 , B32B27/36 , B32B27/38 , C08L29/00 , C08L33/00 , C08L33/02 , C08L33/06 , C08L37/00 , C08L63/00 , C08L67/00 , C08L67/02 , C08L101/02 , C09D133/10 , C09D163/00 , C09D167/00 , C09D201/02 , C09J167/00
CPC分类号： C08L67/00 , C08L101/02 , C09D133/10 , C09D163/00 , C09D167/00 , C09D201/02 , C09J167/00 , C08L33/06 , C08L63/00 , Y10T428/31511 , Y10T428/31518 , Y10T428/31529 , Y10T428/31551 , Y10T428/31699 , Y10T428/31786 , Y10T428/31794 , Y10T428/31797 , Y10T428/31928 , Y10T428/31935
摘要： Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxy group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistant and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.
摘要翻译：热固性组合物包含在分子中具有被乙烯基醚化合物封闭的两个或多个羧基的化合物，乙烯基硫醚化合物或具有乙烯基型双键的杂化合物和氧或硫作为杂原子的化合物，具有两个或更多个可通过加热与封端的羧基化合物形成化学键的反应性官能团，特定的乙烯基醚或乙烯基硫醚和热潜在酸催化剂。第一化合物的封端羧基和第二化合物的反应性官能团可以包含在相同的分子中。热固性组合物提供具有优异的化学性质，物理性质，耐候性和储存稳定性的固化产物，并且有利地用于涂料组合物，油墨，粘合剂和模制塑料。

5. 发明授权

US5578677A Thermosetting compositions 失效
标题翻译：热固性组合物
公开(公告)号：US5578677A
公开(公告)日：1996-11-26
申请号：US578083
申请日：1995-12-27
申请人： Masahiro Ishidoya , Kishio Shibato , Keiji Komoto , Kenji Shibamoto , Mitsuyuki Mashita , Osamu Ohe
发明人： Masahiro Ishidoya , Kishio Shibato , Keiji Komoto , Kenji Shibamoto , Mitsuyuki Mashita , Osamu Ohe
IPC分类号： C08F299/02 , C07C69/00 , C08F8/14 , C08F290/00 , C08G18/42 , C08G18/82 , C08G59/00 , C08G59/20 , C08G59/32 , C08G59/40 , C08G59/68 , C08G63/00 , C08G63/91 , C08G69/00 , C08L33/02 , C08L63/00 , C08L67/00 , C08L67/02 , C08L67/06 , C09D163/00 , C09D167/00 , C09D167/06 , C09J167/00 , C09J167/06
CPC分类号： C09D167/00 , C08L67/00 , C09D163/00 , C09J167/00
摘要： A thermosetting composition which comprises:(D) a self-crosslinking compound having in the molecule (a) one or more functional groups of the formula (2): ##STR1## wherein R.sup.5, R.sup.6 and R.sup.7 are each hydrogen or an organic group of 1 to 18 carbons, R.sup.8 is an organic group of 1 to 18 carbons, Y.sup.2 is oxygen or sulfur, or R.sup.7 and R.sup.8 are bonded with each other to form a heterocyclic structure which comprises Y.sup.2 as the heteroatom component; and (b) one or more reactive functional groups which can form a chemical bond with carboxyl functional groups which are regenerated from (a) by heating; (C) optionally, a thermal latent acid catalyst which is activated during curing of the composition by heating; (A) optionally, a compound having in the molecule two or more functional groups of the formula (1): ##STR2## wherein R.sup.1, R.sup.2 and R.sup.3 are each hydrogen or an organic group of 1 to 18 carbons, R.sup.4 is an organic group of 1 to 18 carbons, Y.sup.1 is oxygen or sulfur, or R.sup.3 and R.sup.4 are bonded with each other to form a heterocyclic structure which comprises Y.sup.1 as the heteroatom component; and/or, (B) optionally, a compound having in the molecule two or more reactive functional groups which can form a chemical bond by heating with either one or both of the functional group of the formula (1) and the functional group of the formula (2).
摘要翻译：一种热固性组合物，其包含：（D）在分子（a）中具有一个或多个式（2）的官能团的自交联化合物：其中R5，R6和R7各自为氢或碳原子数为1〜18的有机基团，R 8为碳原子数为1〜18的有机基团，Y2为氧或硫，或者R 7和R 8相互结合形成杂环结构，该杂环结构包含Y2作为杂原子成分。和（b）可以与（a）通过加热再生的羧基官能团形成化学键的一个或多个反应性官能团; （C）任选地，通过加热在组合物固化期间活化的热潜伏酸催化剂; （A）任选地，在分子中具有式（1）的两个或更多个官能团的化合物：其中R 1，R 2和R 3各自为氢或碳原子数为1至18的有机基团，R 4为 1到18个碳的有机基团，Y1是氧或硫，或者R3和R4彼此键合，形成包含Y1作为杂原子成分的杂环结构; 和/或（B）任选地，在分子中具有两个或更多个反应性官能团的化合物，所述反应性官能团可以通过用式（1）的官能团中的一个或两个加成而形成化学键，公式（2）。

6. 发明授权

US5419929A Thermosetting compositions, thermal latent acid catalysts, methods of coating and coated articles 失效
标题翻译：热固性组合物，热潜伏酸催化剂，涂覆方法和涂层制品
公开(公告)号：US5419929A
公开(公告)日：1995-05-30
申请号：US948017
申请日：1992-09-21
申请人： Masahiro Ishidoya , Kishio Shibato , Keiji Komoto , Kenji Shibamoto , Mitsuyuki Mashita , Osamu Ohe
发明人： Masahiro Ishidoya , Kishio Shibato , Keiji Komoto , Kenji Shibamoto , Mitsuyuki Mashita , Osamu Ohe
IPC分类号： B32B27/30 , B32B27/36 , B32B27/38 , C08L29/00 , C08L33/00 , C08L33/02 , C08L33/06 , C08L37/00 , C08L63/00 , C08L67/00 , C08L67/02 , C08L101/02 , C09D133/10 , C09D163/00 , C09D167/00 , C09D201/02 , C09J167/00
CPC分类号： C08L67/00 , C08L101/02 , C09D133/10 , C09D163/00 , C09D167/00 , C09D201/02 , C09J167/00 , C08L33/06 , C08L63/00 , Y10T428/31511 , Y10T428/31518 , Y10T428/31529 , Y10T428/31551 , Y10T428/31699 , Y10T428/31786 , Y10T428/31794 , Y10T428/31797 , Y10T428/31928 , Y10T428/31935
摘要： Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistance and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.
摘要翻译：热固性组合物包含在分子中具有被乙烯基醚化合物封闭的两个或多个羧基的化合物，乙烯基硫醚化合物或具有乙烯基型双键的杂化合物和氧或硫作为杂原子的化合物，具有两个或更多个可通过加热与封端的羧基化合物形成化学键的反应性官能团，特定的乙烯基醚或乙烯基硫醚和热潜在酸催化剂。第一化合物的封端羧基和第二化合物的反应性官能团可以包含在相同的分子中。热固性组合物提供具有优异的化学性质，物理性能，耐候性和储存稳定性的固化产物，并且有利地用于涂料组合物，油墨，粘合剂和模制塑料。

7. 发明授权

US5352740A Thermosetting compositions, thermal latent carboxyl compounds and methods of preparation thereof 失效
标题翻译：热固性组合物，热潜伏性羧基化合物及其制备方法
公开(公告)号：US5352740A
公开(公告)日：1994-10-04
申请号：US680356
申请日：1991-04-04
申请人： Masahiro Ishidoya , Kishio Shibato , Keiji Komoto , Kenji Shibamoto , Mitsuyuki Mashita , Osamu Ohe
发明人： Masahiro Ishidoya , Kishio Shibato , Keiji Komoto , Kenji Shibamoto , Mitsuyuki Mashita , Osamu Ohe
IPC分类号： C08F299/02 , C07C69/00 , C08F8/14 , C08F290/00 , C08G18/42 , C08G18/82 , C08G59/00 , C08G59/20 , C08G59/32 , C08G59/40 , C08G59/68 , C08G63/00 , C08G63/91 , C08G69/00 , C08L33/02 , C08L63/00 , C08L67/00 , C08L67/02 , C08L67/06 , C09D163/00 , C09D167/00 , C09D167/06 , C09J167/00 , C09J167/06
CPC分类号： C09D167/00 , C08L67/00 , C09D163/00 , C09J167/00
摘要： Thermosetting composition is excellent in storage stability, useful as one component thermosetting composition, gives cured products having excellent chemical properties, physical properties and weathering resistance and is favorably utilized in coating compositions, ink, adhesive and molded plastics.The thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating and optionally a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule.
摘要翻译：热固性组合物的储存稳定性优异，可用作一种组分的热固性组合物，具有优异的化学性质，物理性能和耐候性的固化产物，并且有利地用于涂料组合物，油墨，粘合剂和模塑料中。热固性组合物包含在分子中具有被乙烯基醚化合物封闭的两个或多个羧基，乙烯基硫醚化合物或具有乙烯基型双键的杂化合物和氧或硫作为杂原子的化合物，具有两个或多个可以通过加热和任选的热潜酸催化剂与封端的羧基化合物形成化学键的更多的反应性官能团。第一化合物的封端羧基和第二化合物的反应性官能团可以包含在相同的分子中。

8. 发明授权

US5319024A Thermosetting compositions, thermal latent hydroxyl compounds, thermal latent thiol compounds and methods of preparation thereof 失效
标题翻译：热固性组合物，热潜羟基化合物，热潜硫醇化合物及其制备方法
公开(公告)号：US5319024A
公开(公告)日：1994-06-07
申请号：US683301
申请日：1991-04-10
申请人： Masahiro Ishidoya , Kishio Shibato , Keiji Komoto , Kenji Shibamoto , Yoshinori Nakane
发明人： Masahiro Ishidoya , Kishio Shibato , Keiji Komoto , Kenji Shibamoto , Yoshinori Nakane
IPC分类号： C08F299/02 , C08F290/00 , C08G18/62 , C08G59/00 , C08G59/20 , C08G59/32 , C08G59/40 , C08G59/68 , C08G63/00 , C08K5/00 , C08L63/00 , C08L67/00 , C08L67/06 , C08L101/02 , C09D167/00 , C09D167/06 , C09D187/00 , C09J159/00 , C09J167/00 , C09J167/06 , C09J187/00 , C08F8/30
CPC分类号： C08L101/02 , C08L63/00 , C08L67/00
摘要： Thermosetting compositions which are excellent in storage stability, useful as one component thermosetting compositions, give cured products having excellent chemical properties, physical properties and weathering resistance and favorably utilized in coating compositions, ink, adhesive and molded plastics. The thermosetting compositions comprises a compound having in the molecule two or more hydroxyl groups and/or thiol groups blocked by a vinyl ether compound, a vinyl thioether compound or a heterocyclic compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked hydroxyl and/or thiol compound by heating and a thermal latent acid catalyst. The blocked hydroxyl and/or thiol group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule.
摘要翻译：作为一种组分的热固性组合物，具有优异的储存稳定性的热固性组合物，得到具有优异的化学性质，物理性能和耐候性的固化产物，并且有利地用于涂料组合物，油墨，粘合剂和模制塑料中。热固性组合物包含在分子中具有由乙烯基醚化合物，乙烯基硫醚化合物或具有乙烯基型双键和氧或硫作为杂原子的杂环化合物封闭的羟基和/或硫醇基的分子中的化合物，具有两个或更多个反应性官能团的化合物，其可以通过加热与封闭的羟基和/或硫醇化合物形成化学键和热潜酸催化剂。第一化合物的封端羟基和/或硫醇基团和第二化合物的反应性官能团可以包含在相同的分子中。

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