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    • 2. 发明授权
    • Ion selective monoelectrode complex
    • 离子选择性单电极复合物
    • US07115195B2
    • 2006-10-03
    • US10856650
    • 2004-05-27
    • Masaaki TerashimaOsamu Seshimoto
    • Masaaki TerashimaOsamu Seshimoto
    • G01N27/333
    • G01N27/307Y10T29/49002
    • An ion selective monoelectrode complex which is favorably employable to manufacture an ion activity measuring apparatus, has on a common non-electroconductive support sheet, plural ion selective monoelectrodes each of which is composed of an electrode composite consisting of, in order, a silver metal layer, a silver halide layer, an electrolytic material layer, and an ion selective membrane, and an electroconductive terminal which is electrically connected to the silver metal layer and which has an exposed surface, under the condition that the ion selective monoelectrodes are aligned, without electric contact with each other, along an imaginary line bridging the electrode composite and the electroconductive terminal.
    • 有利地用于制造离子活性测量装置的离子选择性单电极配合物在普通的非导电性支持片上具有多个离子选择性单电极,它们由依次由银金属层 ,卤化银层,电解质层和离子选择性膜,以及在离子选择性单电极排列的情况下,电连接到银金属层并且具有暴露表面的导电端子,没有电 沿着桥接电极复合体和导电端子的假想线彼此接触。
    • 3. 发明授权
    • Device for measuring ionic activities
    • 用于测量离子活性的装置
    • US06869512B2
    • 2005-03-22
    • US10006169
    • 2001-12-06
    • Masaaki TerashimaOsamu Seshimoto
    • Masaaki TerashimaOsamu Seshimoto
    • G01N27/333G01N27/30G01N27/416
    • G01N27/307
    • A device for measuring ionic activity is composed of: a block of insulating material having a hollow space therein, a solution-receiving surface area in which a pair of openings for receiving a sample solution and a reference solution separately are provided, a plurality of solution-supplying surface areas in each of which a pair of openings for supplying outside the sample solution and the reference solution separately are provided; a bridge member fixed on the solution-receiving surface area; a guide member placed in the hollow space which assists to transmit separately the sample solution and the reference member in the hollow space; and two or more ion selective electrodes each of which is placed on each solution-supplying surface area.
    • 用于测量离子活性的装置包括:其中具有中空空间的绝缘材料块,设置有用于分别接收样品溶液的一对开口和参考溶液的溶液接收表面区域,多个溶液 提供各自的表面区域,其中分别提供用于在样品溶液和参考溶液外部供应的一对开口;固定在溶液接收表面区域上的桥接构件;设置在中空空间中的辅助传输的引导构件 分别在中空空间中的样品溶液和参考构件; 和两个或更多个离子选择性电极,每个离子选择性电极被放置在每个溶液供应表面区域上。
    • 4. 发明授权
    • Ion selective monoelectrode complex
    • 离子选择性单电极复合物
    • US06767578B2
    • 2004-07-27
    • US09981528
    • 2001-10-17
    • Masaaki TerashimaOsamu Seshimoto
    • Masaaki TerashimaOsamu Seshimoto
    • B05D512
    • G01N27/307Y10T29/49002
    • An ion selective monoelectrode complex which is favorably employable to manufacture an ion activity measuring apparatus, has on a common non-electroconductive support sheet, plural ion selective monoelectrodes each of which is composed of an electrode composite consisting of, in order, a silver metal layer, a silver halide layer, an electrolytic material layer, and an ion selective membrane, and an electroconductive terminal which is electrically connected to the silver metal layer and which has an exposed surface, under the condition that the ion selective monoelectrodes are aligned, without electric contact with each other, along an imaginary line bridging the electrode composite and the electroconductive terminal.
    • 有利地用于制造离子活性测量装置的离子选择性单电极配合物在普通的非导电性支持片上具有多个离子选择性单电极,每个离子选择性单电极由依次由银金属层 ,卤化银层,电解质层和离子选择性膜,以及在离子选择性单电极排列的情况下,电连接到银金属层并且具有暴露表面的导电端子,没有电 沿着桥接电极复合体和导电端子的假想线彼此接触。
    • 6. 发明授权
    • PH electrode
    • PH电极
    • US07276145B2
    • 2007-10-02
    • US10621400
    • 2003-07-18
    • Masaaki TerashimaOsamu Seshimoto
    • Masaaki TerashimaOsamu Seshimoto
    • G01N27/333
    • G01N27/3335G01N27/4165
    • An object of the present invention is to suppress an electric potential drift as described above and improve pH measurement precision in order to obtain practical measurement precision in the dry-type multilayered film-type pH electrode. The present invention provides a complex pH electrode which has at least two ion-selective electrodes comprising a non-conductive support, a pair of electrode layers, an electrolytic layer and an ion-selective membrane where at least one of the ion-selective electrode is a hydrogen ion-selective electrode, wherein the hydrogen ion-selective membrane is saturated with carbon dioxide gas.
    • 本发明的目的是为了在干式多层膜型pH电极中获得实用的测量精度,抑制如上所述的电位漂移并改善pH测量精度。 本发明提供一种复合pH电极,其具有至少两个离子选择性电极,其包含非导电支持体,一对电极层,电解质层和离子选择性膜,其中至少一个离子选择性电极为 氢离子选择性电极,其中氢离子选择性膜用二氧化碳气体饱和。
    • 9. 发明授权
    • Method and device of measuring ion activity
    • 测量离子活性的方法和装置
    • US4684445A
    • 1987-08-04
    • US881815
    • 1986-07-03
    • Osamu SeshimotoMituharu NirasawaMasaaki TerashimaYoshio Saito
    • Osamu SeshimotoMituharu NirasawaMasaaki TerashimaYoshio Saito
    • G01N27/28G01N27/406G01N27/30
    • G01N27/333
    • In a method of measuring ion activity of a liquid sample comprising steps of spotting a reference liquid and the liquid sample on surfaces of ion-selective membranes, respectively, of at least a pair of ion-selective electrode sheets which is electrically insulated from each other, said ion-selective membranes being provided on the top of said ion-selective electrode sheets; and measuring a potential difference between the ion-selective electrodes under the conditions that both liquids are electrically connected to each other by a bridge, the improvement wherein:said each ion-selective electrode sheet is arranged upside down in such a manner that the ion-selective membrane is positioned on the lowest side; andsaid each liquid spotted from the upper side is temporarily conveyed downwardly to the lower level than the surface of the ion-selective membrane, and then conveyed upwardly to the surface of the ion-selective membrane so as to reach the surface of the ion-selective membrane. A device employable in the method is also disclosed.
    • 在测量液体样品的离子活性的方法中,包括分别在至少一对离子选择性电极片彼此电绝缘的离子选择膜的表面上分离参考液体和液体样品的步骤 所述离子选择膜设置在所述离子选择性电极片的顶部; 并且在两个液体通过桥接器彼此电连接的条件下测量离子选择性电极之间的电势差,其改进在于:所述每个离子选择电极片以这样一种方式被布置成: 选择性膜位于最下面; 并且将从上侧点出的每个液体暂时向下输送到比离子选择性膜的表面更低的水平,然后向上输送到离子选择性膜的表面,以到达离子选择性膜的表面, 选择性膜。 还公开了可用于该方法的装置。