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1. 发明申请

US20080269482A1 Use of Rylene Derivatives as Photosensitizers in Solar Cells 有权
标题翻译：在太阳能电池中使用Rylene衍生物作为光敏剂
公开(公告)号：US20080269482A1
公开(公告)日：2008-10-30
申请号：US12093081
申请日：2006-11-06
申请人： Neil Gregory Pschirer , Felix Eickemeyer , Jan Schoneboom , Jianqiang Qu , Martin Konemann , Klaus Mullen , Chen Li , Andreas Herrmann , Peter Erk , Gero Nordmann , Alfred Kuhn , Anders Hagfeldt , Tomas Edvinsson
发明人： Neil Gregory Pschirer , Felix Eickemeyer , Jan Schoneboom , Jianqiang Qu , Martin Konemann , Klaus Mullen , Chen Li , Andreas Herrmann , Peter Erk , Gero Nordmann , Alfred Kuhn , Anders Hagfeldt , Tomas Edvinsson
IPC分类号： C07D417/14 , C07D491/052 , C07D491/147 , C07D311/08
CPC分类号： H01G9/2031 , C07D221/18 , C07D311/78 , C07D311/92 , C07D405/04 , C07D405/12 , C07D409/14 , C07D413/04 , C07D417/04 , C07D417/14 , C07D471/06 , C07D491/06 , C09B5/62 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , C09K2211/1029 , C09K2211/1033 , C09K2211/1037 , C09K2211/1044 , C09K2211/1048 , C09K2211/1059 , C09K2211/1088 , H01G9/2059 , H01L51/0053 , H01L51/006 , H01L51/0067 , H01L51/0068 , H01L51/0069 , H01L51/0071 , H01L51/4226 , Y02E10/542 , Y02E10/549
摘要： Use of rylene derivatives I with the following definition of the variables: X together both —COOM; Y a radical -L-NR1R2 (y1) -L-Z-R3 (y2) the other radical hydrogen; together both hydrogen; R is optionally substituted (het)aryloxy, (het)arylthio; P is —NR1R2; B is alkylene; optionally substituted phenylene; combinations thereof; A is —COOM; —SO3M; —PO3M2; D is optionally substituted phenylene, naphthylene, pyridylene; M is hydrogen; alkali metal cation; [NR5]4+; L is a chemical bond; optionally indirectly bonded, optionally substituted (het)arylene radical; R1, R2 are optionally substituted (cyclo)alkyl, (het)aryl; together optionally substituted ring comprising the nitrogen atom; Z is —O—; —S—; R3 is optionally substituted alkyl, (het)aryl; R′ is hydrogen; optionally substituted (cyclo)alkyl, (het)aryl; R5 is hydrogen; optionally substituted alkyl (het)aryl; m is 0, 1, 2; n, p m=0: 0, 2, 4 where: n+p=2, 4, if appropriate 0; m=1: 0, 2, 4 where: n+p=0, 2, 4; m=2: 0, 4, 6 where: n+p=0, 4, 6, or of mixtures thereof as photosensitizers in solar cells.
摘要翻译：使用二烯衍生物I与以下变量的定义：X一起-COOM; Y是一个根本的<？in-line-formula description =“In-line Formulas”end =“lead”？> - L-NR <1> 2（y1）？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> - LZR < / SUP>（y2）<？in-line-formula description =“In-line Formulas”end =“tail”？>另一个自由基氢; 一起氢; R是任选取代的（het）芳氧基，（het）芳硫基; P是-NR 1 R 2 O 2; B是亚烷基; 任选取代的亚苯基; 其组合; A是-COOM; -SO 3 M; -PO 3 M 2 N 2; D是任选取代的亚苯基，亚萘基，亚吡啶基; M是氢; 碱金属阳离子; [NR 5] 4 L是化学键; 任选间接结合的，任选取代的（亚乙基）亚芳基; R 1，R 2是任选取代的（环）烷基，（het）芳基; 一起任选取代的包含氮原子的环; Z为-O- -S- R 3是任选取代的烷基，（het）芳基; R'是氢; 任选取代的（环）烷基，（het）芳基; R 5是氢; 任选取代的烷基（het）芳基; m为0,1,2; n，p m = 0：0,2,4其中：n + p = 2,4，如果合适0; m = 1：0,2,4其中：n + p = 0,2,4; m = 2：0,4,6其中：n + p = 0,4,6或其混合物作为太阳能电池中的光敏剂。

2. 发明申请

US20070155968A1 Method for the production of terylene-3,4:11,12-tetracarboxydiimides by direct synthesis 失效
标题翻译：通过直接合成制备涤纶3,4：11,12-四羧酰亚胺的方法
公开(公告)号：US20070155968A1
公开(公告)日：2007-07-05
申请号：US10586133
申请日：2005-01-15
申请人： Martin Konemann , Arno Bohm , Willi Helfer , Jurgen Romeis , Jianqiang Qu , Klaus Mullen
发明人： Martin Konemann , Arno Bohm , Willi Helfer , Jurgen Romeis , Jianqiang Qu , Klaus Mullen
IPC分类号： C07D471/02
CPC分类号： C07D221/18 , C07D221/14 , C07D471/06
摘要： A process for preparing terylene-3,4:11,12-tetracarboximides I where the variables are each defined as follows: R, R′ are each independently hydrogen; if desired substituted alkyl or cycloalkyl; R1 is hydrogen or alkyl; R2 is hydrogen; alkyl; if desired substituted aryl or hetaryl, by reacting a perylene-3,4-dicarboximide II in the presence of a base-stable, high-boiling organic solvent and of an alkali metal or alkaline earth metal base, with a naphthalene-1,8-dicarboximide III in which X is hydrogen, bromine or chlorine.
摘要翻译：制备三苯醚-3,4：11,12-四甲酰亚胺I的方法，其中各变量各自定义如下：R，R'各自独立地为氢; 如果需要，取代的烷基或环烷基; R 1是氢或烷基; R 2是氢; 烷基; 如果需要取代的芳基或杂芳基，通过在碱稳定的高沸点有机溶剂和碱金属或碱土金属碱的存在下使苝-3,4-二甲酰亚胺II与萘-1,8 二甲酰亚胺III，其中X是氢，溴或氯。

3. 发明申请

US20090124732A1 Rylene Tetracarboxylic Acid Diimides Substituted By Cyclic Amino Groups 审中-公开
标题翻译：由环状氨基取代的亚芳基四羧酸二酰亚胺
公开(公告)号：US20090124732A1
公开(公告)日：2009-05-14
申请号：US11720409
申请日：2005-11-26
申请人： Martin Konemann , Jianqiang Qu , Klaus Mullen
发明人： Martin Konemann , Jianqiang Qu , Klaus Mullen
IPC分类号： C07D471/02 , C08K5/34 , C08K5/48 , C09D11/00
CPC分类号： C09B5/62
摘要： Rylenetetracarboximides of the general formula I in which the variables are each defined as follows: R, R′ are each independently hydrogen; optionally substituted C1-C30-alkyl, C3-C8-cycloalkyl, aryl or hetaryl; R1 is hydrogen or C1-C6-alkyl; R2, R3 are each independently hydrogen; optionally substituted C1-C18-alkyl, aryl or hetaryl; A is a 5- to 9-membered ring which is bonded via a nitrogen atom and whose carbon chain may be interrupted by one or more —O—, —S—, —NR1—, —CO— and/or —SO2— moieties, to which one or two unsaturated or saturated 4- to 8-membered rings may be fused, whose carbon chain may likewise be interrupted by these moieties and/or —N═, and the overall ring system may be mono- or polysubstituted, and where the A radicals may be the same or different when m>1; X is chlorine or bromine, and the X radicals may be the same or different when x>1; Z is optionally substituted C3-C20-alkyl, C3-C20-alken-2-yl, C3-C20-alkyn-2-yl, aryloxy, arylthio, hetaryloxy or hetarylthio, where the Z radicals may be the same or different when z>1; m is 1 or 2, n is from 1 to 4 when m=1; is from 1 to 6 when m=2; x is from 0 to 3 when m=1, where n+x+z≦4, is from 0 to 5 when m=2, where n+x+z≦6; z is from 0 to 3 when m=1, where n+x+z≦4, is from 0 to 5 when m=2, where n+x+z≦6.
摘要翻译：其中各个变量各自定义如下：通式I的四环四甲酰亚胺化物：R，R'各自独立地为氢; 任选取代的C 1 -C 30 - 烷基，C 3 -C 8 - 环烷基，芳基或杂芳基; R1是氢或C1-C6-烷基; R2，R3各自独立地为氢; 任选取代的C 1 -C 18 - 烷基，芳基或杂芳基; A是通过氮原子键合并且其碳链可以被一个或多个-O - ， - S - ， - NR 1 - ， - CO - 和/或-SO 2 - 部分间隔的5至9元环可以将一个或两个不饱和或饱和的4至8元环稠合，其碳链同样可被这些部分和/或-N-间隔，并且整个环系统可以是单取代或多取代的，以及当m> 1时，A基团可以相同或不同; X是氯或溴，当x> 1时X基团可以相同或不同; Z是任选取代的C 3 -C 20 - 烷基，C 3 -C 20 - 烯-2-基，C 3 -C 20 - 炔-2-基，芳氧基，芳硫基，杂芳氧基或杂芳硫基，其中Z基可以相同或不同，当z > 1; m为1或2，当m = 1时，n为1至4; 当m = 2时为1〜6; 当m = 1时，x为0至3，其中n + x + z <= 4，当m = 2时为0至5，其中n + x + z <= 6; 当m = 1时，z为0至3，其中n + x + z <= 4，当m = 2时为0至5，其中n + x + z <= 6。

4. 发明申请

US20070043218A1 Monofunctionalized perylenetetracarboxylic acid bisimides 失效
标题翻译：单官能化苝四羧酸双酰亚胺
公开(公告)号：US20070043218A1
公开(公告)日：2007-02-22
申请号：US10547516
申请日：2004-02-27
申请人： Christopher Kohl , Jianqiang Qu , Klaus Mullen
发明人： Christopher Kohl , Jianqiang Qu , Klaus Mullen
IPC分类号： C09B5/62
CPC分类号： C07H21/00 , C09B5/62
摘要： The invention relates to novel perylenetetracarboxylic acid bisimide derivatives with improved performance properties.
摘要翻译：本发明涉及具有改进性能的新型苝四羧酸双酰亚胺衍生物。

5. 发明授权

US08541583B2 Monofunctionalized perylenetetracarboxylic acid bismides 失效
标题翻译：单官能化苝四羧酸二抗
公开(公告)号：US08541583B2
公开(公告)日：2013-09-24
申请号：US12852687
申请日：2010-08-09
申请人： Christopher Kohl , Jianqiang Qu , Klaus Mullen
发明人： Christopher Kohl , Jianqiang Qu , Klaus Mullen
IPC分类号： C07D471/08 , C07D471/02
CPC分类号： C07H21/00 , C09B5/62
摘要： The invention relates to novel perylenetetracarboxylic acid bisimide derivatives with improved performance properties.
摘要翻译：本发明涉及具有改进性能的新型苝四羧酸双酰亚胺衍生物。

6. 发明申请

US20070004919A1 Water-souluble, fluorescent perylenetetracarboxylic acid bisimides 失效
标题翻译：水溶性荧光苝四羧酸双酰亚胺
公开(公告)号：US20070004919A1
公开(公告)日：2007-01-04
申请号：US10547521
申请日：2004-02-27
申请人： Christopher Kohl , Jianqiang Qu , Klaus Mullen
发明人： Christopher Kohl , Jianqiang Qu , Klaus Mullen
IPC分类号： C07D471/02
CPC分类号： C09B5/62
摘要： The invention relates to novel perylenetetracarboxdiimide derivatives with improved performance properties.
摘要翻译：本发明涉及具有改进性能的新颖的苝四羰基二酰亚胺衍生物。

7. 发明授权

US5986099A Substituted quaterrylene tetracarboxylic acid diimides 失效
标题翻译：取代的四亚甲基四羧酸二酰亚胺
公开(公告)号：US5986099A
公开(公告)日：1999-11-16
申请号：US860928
申请日：1997-07-21
申请人： Klaus Mullen , Heribert Quante , Arno Bohm
发明人： Klaus Mullen , Heribert Quante , Arno Bohm
IPC分类号： C07D221/18 , C07D471/06 , C09B5/62 , C09B57/08
CPC分类号： C07D221/18 , C09B5/62
摘要： Quaterrylenetetracarboxylic diimides I ##STR1## where R is hydrogen;C.sub.1 -C.sub.30 -alkyl whose carbon chain may be interrupted by one or e of --O--, --S--, --NR.sup.1 --, --CO-- and/or --SO.sub.2 -- and which may be monosubstituted or polysubstituted by cyano, C.sub.1 -C.sub.6 -alkoxy or a 5-, 6- or 7-membered heterocyclic radical which is attached via a nitrogen atom and which may contain further heteroatoms and may be aromatic, whereR.sup.1 is hydrogen or C.sub.1 -C.sub.6 -alkyl;C.sub.5 -C.sub.8 -cycloalkyl whose carbon skeleton may be interrupted by one or more of --O--, --S-- and/or --NR.sup.1 --;aryl or hetaryl, which may each be monosubstituted or poly-substituted by C.sub.1 -C.sub.18 -alkyl, C.sub.1 -C.sub.6 -alkoxy, cyano, --CONHR.sup.2, --NHCOR.sup.2 and/or aryl- or hetaryl-azo, which may each be substituted by C.sub.1 -C.sub.10 -alkyl, C.sub.1 -C.sub.6 -alkoxy or cyano, whereR.sup.2 is hydrogen; C.sub.1 -C.sub.18 -alkyl; aryl or hetaryl, which may each be substituted by C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, halogen or cyano;X is halogen; C.sub.1 -C.sub.18 -alkyl; aryloxy, arylthio, hetaryloxy or hetarylthio, which may each be substituted by C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy;n is from 2 to 12,their preparation and use as pigments or fluorescent dyes.
摘要翻译： PCT No.PCT / EP96 / 00118 Sec。 371日期1997年7月21日 102（e）日期1997年7月21日PCT 1996年1月12日PCT PCT。公开号WO96 / 22332 日期：1996年7月25日四氢四羧酸二酰亚胺其中R为氢; 其碳链可以被-O - ， - S - ， - NR 1 - ， - CO - 和/或-SO 2 - 中的一个或多个中断的C 1 -C 30 - 烷基，并且其可以被氰基，C 1 -C 6单取代或多取代 - 烷氧基或5-，6-或7-元杂环基，其通过氮原子连接并且可以含有另外的杂原子并且可以是芳族的，其中R 1是氢或C 1 -C 6 - 烷基; 碳骨架可被-O - ， - S-和/或-NR1-中的一个或多个中断的C 5 -C 8 - 环烷基; 芳基或杂芳基，其可以各自被C1-C18-烷基，C1-C6-烷氧基，氰基，-CONHR2，-NHCOR2和/或芳基 - 或杂芳基 - 偶氮基单取代或多取代，其可以各自被C1 C 1-10 - 烷基，C 1 -C 6 - 烷氧基或氰基，其中R 2是氢; C1-C18-烷基; 芳基或杂芳基，其各自可被C 1 -C 6 - 烷基，C 1 -C 6 - 烷氧基，卤素或氰基取代; X是卤素; C1-C18-烷基; 芳氧基，芳硫基，杂芳氧基或杂芳硫基，其各自可被C 1 -C 4 - 烷基或C 1 -C 4 - 烷氧基取代; n为2至12，它们的制备和用作颜料或荧光染料。

8. 发明授权

US5712361A Conjugated polymers containing ANSA substructures and their use as electroluminescence materials 失效
标题翻译：含有ANSA亚结构的共轭聚合物及其作为电致发光材料的用途
公开(公告)号：US5712361A
公开(公告)日：1998-01-27
申请号：US496202
申请日：1995-06-28
申请人： Roland Stern , Donald Lupo , Josef Salbeck , Hermann Schenk , Thomas Stehlin , Klaus Mullen , Ullrich Scherf , Joachim Huber
发明人： Roland Stern , Donald Lupo , Josef Salbeck , Hermann Schenk , Thomas Stehlin , Klaus Mullen , Ullrich Scherf , Joachim Huber
IPC分类号： C08G61/00 , C08G61/02 , C09K11/06 , H01L51/50 , H05B33/14 , C08G61/12
CPC分类号： H05B33/14 , C08G61/02 , C09K11/06 , Y10S428/917
摘要： Conjugated polymers containing ansa substructures and their use as electroluminescence materials. Conjugated polymers containing ansa substructures, which contain aromatic groups and in which adjacent aromatic groups are connected to one another in such a way that one ring atom of one aromatic group is directly linked to one ring atom of the other aromatic group and any further linkages of these two aromatic groups are possible only via a bridge containing at least one tetravalent carbon atom and/or heteroatom. The polymers of the invention having ansa substructures are outstandingly suitable as electroluminescence materials, since they have a very high color purity.
摘要翻译：含有ansa亚结构的共轭聚合物及其作为电致发光材料的用途。含有芳族基团的共轭聚合物，其中相邻芳族基团彼此连接，其中一个芳族基团的一个环原子直接与另一个芳族基团的一个环原子连接，这两个芳族基团仅通过含有至少一个四价碳原子和/或杂原子的桥可能。具有ansa子结构的本发明的聚合物非常适合作为电致发光材料，因为它们具有非常高的色纯度。

9. 发明授权

US5376507A Method to produce nonlinear optical microcomponents 失效
标题翻译：制造非线性光学微元件的方法
公开(公告)号：US5376507A
公开(公告)日：1994-12-27
申请号：US2822
申请日：1993-01-08
申请人： Wolfgang Ehrfeld , Herbert O. Moser , Klaus Mullen , Christoph Bubeck , Hans-Dieter Bauer
发明人： Wolfgang Ehrfeld , Herbert O. Moser , Klaus Mullen , Christoph Bubeck , Hans-Dieter Bauer
IPC分类号： G02F1/35 , G02F1/065 , G03F7/00 , G03F7/20 , G02B6/10
CPC分类号： G03F7/00 , G02F1/065 , G03F7/2039 , Y10S430/168
摘要： A method to produce nonlinear optical microcomponents is described which employs hitherto not yet used material combinations. Not only waveguide structures are produced by means of X-ray depth lithography, but also microcell structures, into which materials having nonlinear optical properties are introduced. The microstructure is produced as a positive mold part, from which there is subsequently generated, by means of electroforming, a mold insert, a negative of which is made using a polymer material. After the molding operation the microstructure is applied to a substrate, and nonlinear optical material, covered by a cover plate if needed or desired, is introduced into the microcell structure.
摘要翻译：描述了一种生产非线性光学微元件的方法，该方法采用迄今未使用的材料组合。不仅通过X射线深度光刻产生波导结构，而且还引入了具有非线性光学特性的材料的微单元结构。微结构作为正模具部件生产，随后通过电铸产生模具插入件，模具插件的负极由聚合物材料制成。在模制操作之后，将微结构施加到基板上，并且如果需要或期望，则由盖板覆盖的非线性光学材料被引入到微单元结构中。

10. 发明申请

US20060075585A1 Rylene dyes 失效
标题翻译：二烯染料
公开(公告)号：US20060075585A1
公开(公告)日：2006-04-13
申请号：US10522990
申请日：2003-07-25
申请人： Matthias Krieger , Arno Bohm , Lorenz Siggel , Stefan Becker , Klaus Mullen , Christopher Kohl
发明人： Matthias Krieger , Arno Bohm , Lorenz Siggel , Stefan Becker , Klaus Mullen , Christopher Kohl
IPC分类号： C09B49/00
CPC分类号： C09B5/62
摘要： Rylene dyes of the general formula I where the variables are defined as follows: R is hydrogen; optionally substituted C1-C30-alkyl, C5-C8-cycloalkyl, aryl or hetaryl; R′ is bromine; cyano; —NR32; optionally substituted aryloxy, arylthio, hetaryloxy or hetarylthio; optionally substituted C3-C18-alk-1-ynyl; X, Y are both hydrogen or together are a radical of the formula Ia n is 2, 3, 4 or additionally 1 when X and Y are a radical of the formula Ia; n′ is from 1 to 4; m is from 0 to 6.
摘要翻译：通式I的Rylene染料，其中变量定义如下：R是氢; 芳基或杂芳基;任选取代的C 1 -C 30 - 烷基，C 5 -C 8 - 环烷基，芳基或杂芳基; R'是溴; 氰基; -NR 3 3; 任选取代的芳氧基，芳硫基，杂芳氧基或杂芳硫基; 任选取代的C 3 -C 18 - 烷-1-基; 当X和Y是式Ia的基团时，X，Y都是氢或一起是式Ia n的基团是2,3,4或另外1， n'为1至4; m为0〜6。

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