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1. 发明申请

US20070155968A1 Method for the production of terylene-3,4:11,12-tetracarboxydiimides by direct synthesis 失效
标题翻译：通过直接合成制备涤纶3,4：11,12-四羧酰亚胺的方法
公开(公告)号：US20070155968A1
公开(公告)日：2007-07-05
申请号：US10586133
申请日：2005-01-15
申请人： Martin Konemann , Arno Bohm , Willi Helfer , Jurgen Romeis , Jianqiang Qu , Klaus Mullen
发明人： Martin Konemann , Arno Bohm , Willi Helfer , Jurgen Romeis , Jianqiang Qu , Klaus Mullen
IPC分类号： C07D471/02
CPC分类号： C07D221/18 , C07D221/14 , C07D471/06
摘要： A process for preparing terylene-3,4:11,12-tetracarboximides I where the variables are each defined as follows: R, R′ are each independently hydrogen; if desired substituted alkyl or cycloalkyl; R1 is hydrogen or alkyl; R2 is hydrogen; alkyl; if desired substituted aryl or hetaryl, by reacting a perylene-3,4-dicarboximide II in the presence of a base-stable, high-boiling organic solvent and of an alkali metal or alkaline earth metal base, with a naphthalene-1,8-dicarboximide III in which X is hydrogen, bromine or chlorine.
摘要翻译：制备三苯醚-3,4：11,12-四甲酰亚胺I的方法，其中各变量各自定义如下：R，R'各自独立地为氢; 如果需要，取代的烷基或环烷基; R 1是氢或烷基; R 2是氢; 烷基; 如果需要取代的芳基或杂芳基，通过在碱稳定的高沸点有机溶剂和碱金属或碱土金属碱的存在下使苝-3,4-二甲酰亚胺II与萘-1,8 二甲酰亚胺III，其中X是氢，溴或氯。

2. 发明申请

US20080167467A1 Substituted Rylene Derivatives 有权
标题翻译：取代的Rylene衍生物
公开(公告)号：US20080167467A1
公开(公告)日：2008-07-10
申请号：US11994719
申请日：2006-07-06
申请人： Martin Konemann , Arno Bohm , Neil Gregory Pschirer , Jianqiang Qu , Gabriele Mattern
发明人： Martin Konemann , Arno Bohm , Neil Gregory Pschirer , Jianqiang Qu , Gabriele Mattern
IPC分类号： C07D221/18
CPC分类号： C07D493/06 , C07D471/06 , C08K5/0041 , C08K5/3437
摘要： Rylene derivatives of the general formula I in which the variables are each defined as follows: Rylene is a polycyclic conjugated ring system which comprises at least one perylene unit may comprise heteroatoms as ring atoms, may be functionalized by moieties comprising —CO— groups and/or may bear further substituents other than the A radicals; A is a radical of the formula X is oxygen or sulfur; R are identical or different radicals: optionally substituted alkyl, cycloalkyl, aryl, hetaryl, —U-aryl where U is an —O—, —S—, —NR2—, —CO—, —SO— or —SO2— moiety, or C1-C12-alkoxy, C1-C6-alkylthio, —C≡CR2, —CR2═CR22, hydroxy, mercapto, halogen, cyano, nitro, —NR3R4, —NR3COR4, —CONR3R4, —SO2NR3R4, —COOR3 or —SO3R3; R′ are identical or different radicals: hydrogen or one of the R radicals; R2 is hydrogen or alkyl, where the R2 radicals may be the same or different when they occur more than once; R3, R4 are each independently hydrogen; optionally substituted alkyl, aryl or hetaryl; n is from 1 to 8.
摘要翻译：通式I的亚芳基衍生物各自定义如下：Rylene是多环共轭环系，其包含至少一个苝单元可以包含杂原子作为环原子，可以由包含-CO-基团和/ 或者可以承担除了A基团之外的其它取代基; A是式X的基团是氧或硫; R是相同或不同的基团：任选取代的烷基，环烷基，芳基，杂芳基，-U-芳基，其中U是-O - ， - S - ， - NR 2 - ， - CO-， - SO - 或-SO 2 - 部分，或C 1 -C 12 - 烷氧基，C 1 -C -C≡CR2，-CR 2 -CR 2，2 - ， - 羟基，巯基，卤素，氰基，硝基，-NR 3，R 4，-NR 3，COR 4， SO 2，SO 2，SO 2，SO 2，SO 3，SO 4，SO 2， >，-COOR 3或-SO 3 R 3; R'是相同或不同的基团：氢或R基团之一; R 2是氢或烷基，其中R 2个基团当它们不止一次出现时可以相同或不同; R 3，R 4各自独立地为氢; 任选取代的烷基，芳基或杂芳基; n为1至8。

3. 发明申请

US20090124732A1 Rylene Tetracarboxylic Acid Diimides Substituted By Cyclic Amino Groups 审中-公开
标题翻译：由环状氨基取代的亚芳基四羧酸二酰亚胺
公开(公告)号：US20090124732A1
公开(公告)日：2009-05-14
申请号：US11720409
申请日：2005-11-26
申请人： Martin Konemann , Jianqiang Qu , Klaus Mullen
发明人： Martin Konemann , Jianqiang Qu , Klaus Mullen
IPC分类号： C07D471/02 , C08K5/34 , C08K5/48 , C09D11/00
CPC分类号： C09B5/62
摘要： Rylenetetracarboximides of the general formula I in which the variables are each defined as follows: R, R′ are each independently hydrogen; optionally substituted C1-C30-alkyl, C3-C8-cycloalkyl, aryl or hetaryl; R1 is hydrogen or C1-C6-alkyl; R2, R3 are each independently hydrogen; optionally substituted C1-C18-alkyl, aryl or hetaryl; A is a 5- to 9-membered ring which is bonded via a nitrogen atom and whose carbon chain may be interrupted by one or more —O—, —S—, —NR1—, —CO— and/or —SO2— moieties, to which one or two unsaturated or saturated 4- to 8-membered rings may be fused, whose carbon chain may likewise be interrupted by these moieties and/or —N═, and the overall ring system may be mono- or polysubstituted, and where the A radicals may be the same or different when m>1; X is chlorine or bromine, and the X radicals may be the same or different when x>1; Z is optionally substituted C3-C20-alkyl, C3-C20-alken-2-yl, C3-C20-alkyn-2-yl, aryloxy, arylthio, hetaryloxy or hetarylthio, where the Z radicals may be the same or different when z>1; m is 1 or 2, n is from 1 to 4 when m=1; is from 1 to 6 when m=2; x is from 0 to 3 when m=1, where n+x+z≦4, is from 0 to 5 when m=2, where n+x+z≦6; z is from 0 to 3 when m=1, where n+x+z≦4, is from 0 to 5 when m=2, where n+x+z≦6.
摘要翻译：其中各个变量各自定义如下：通式I的四环四甲酰亚胺化物：R，R'各自独立地为氢; 任选取代的C 1 -C 30 - 烷基，C 3 -C 8 - 环烷基，芳基或杂芳基; R1是氢或C1-C6-烷基; R2，R3各自独立地为氢; 任选取代的C 1 -C 18 - 烷基，芳基或杂芳基; A是通过氮原子键合并且其碳链可以被一个或多个-O - ， - S - ， - NR 1 - ， - CO - 和/或-SO 2 - 部分间隔的5至9元环可以将一个或两个不饱和或饱和的4至8元环稠合，其碳链同样可被这些部分和/或-N-间隔，并且整个环系统可以是单取代或多取代的，以及当m> 1时，A基团可以相同或不同; X是氯或溴，当x> 1时X基团可以相同或不同; Z是任选取代的C 3 -C 20 - 烷基，C 3 -C 20 - 烯-2-基，C 3 -C 20 - 炔-2-基，芳氧基，芳硫基，杂芳氧基或杂芳硫基，其中Z基可以相同或不同，当z > 1; m为1或2，当m = 1时，n为1至4; 当m = 2时为1〜6; 当m = 1时，x为0至3，其中n + x + z <= 4，当m = 2时为0至5，其中n + x + z <= 6; 当m = 1时，z为0至3，其中n + x + z <= 4，当m = 2时为0至5，其中n + x + z <= 6。

4. 发明申请

US20080269482A1 Use of Rylene Derivatives as Photosensitizers in Solar Cells 有权
标题翻译：在太阳能电池中使用Rylene衍生物作为光敏剂
公开(公告)号：US20080269482A1
公开(公告)日：2008-10-30
申请号：US12093081
申请日：2006-11-06
申请人： Neil Gregory Pschirer , Felix Eickemeyer , Jan Schoneboom , Jianqiang Qu , Martin Konemann , Klaus Mullen , Chen Li , Andreas Herrmann , Peter Erk , Gero Nordmann , Alfred Kuhn , Anders Hagfeldt , Tomas Edvinsson
发明人： Neil Gregory Pschirer , Felix Eickemeyer , Jan Schoneboom , Jianqiang Qu , Martin Konemann , Klaus Mullen , Chen Li , Andreas Herrmann , Peter Erk , Gero Nordmann , Alfred Kuhn , Anders Hagfeldt , Tomas Edvinsson
IPC分类号： C07D417/14 , C07D491/052 , C07D491/147 , C07D311/08
CPC分类号： H01G9/2031 , C07D221/18 , C07D311/78 , C07D311/92 , C07D405/04 , C07D405/12 , C07D409/14 , C07D413/04 , C07D417/04 , C07D417/14 , C07D471/06 , C07D491/06 , C09B5/62 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , C09K2211/1029 , C09K2211/1033 , C09K2211/1037 , C09K2211/1044 , C09K2211/1048 , C09K2211/1059 , C09K2211/1088 , H01G9/2059 , H01L51/0053 , H01L51/006 , H01L51/0067 , H01L51/0068 , H01L51/0069 , H01L51/0071 , H01L51/4226 , Y02E10/542 , Y02E10/549
摘要： Use of rylene derivatives I with the following definition of the variables: X together both —COOM; Y a radical -L-NR1R2 (y1) -L-Z-R3 (y2) the other radical hydrogen; together both hydrogen; R is optionally substituted (het)aryloxy, (het)arylthio; P is —NR1R2; B is alkylene; optionally substituted phenylene; combinations thereof; A is —COOM; —SO3M; —PO3M2; D is optionally substituted phenylene, naphthylene, pyridylene; M is hydrogen; alkali metal cation; [NR5]4+; L is a chemical bond; optionally indirectly bonded, optionally substituted (het)arylene radical; R1, R2 are optionally substituted (cyclo)alkyl, (het)aryl; together optionally substituted ring comprising the nitrogen atom; Z is —O—; —S—; R3 is optionally substituted alkyl, (het)aryl; R′ is hydrogen; optionally substituted (cyclo)alkyl, (het)aryl; R5 is hydrogen; optionally substituted alkyl (het)aryl; m is 0, 1, 2; n, p m=0: 0, 2, 4 where: n+p=2, 4, if appropriate 0; m=1: 0, 2, 4 where: n+p=0, 2, 4; m=2: 0, 4, 6 where: n+p=0, 4, 6, or of mixtures thereof as photosensitizers in solar cells.
摘要翻译：使用二烯衍生物I与以下变量的定义：X一起-COOM; Y是一个根本的<？in-line-formula description =“In-line Formulas”end =“lead”？> - L-NR <1> 2（y1）？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> - LZR < / SUP>（y2）<？in-line-formula description =“In-line Formulas”end =“tail”？>另一个自由基氢; 一起氢; R是任选取代的（het）芳氧基，（het）芳硫基; P是-NR 1 R 2 O 2; B是亚烷基; 任选取代的亚苯基; 其组合; A是-COOM; -SO 3 M; -PO 3 M 2 N 2; D是任选取代的亚苯基，亚萘基，亚吡啶基; M是氢; 碱金属阳离子; [NR 5] 4 L是化学键; 任选间接结合的，任选取代的（亚乙基）亚芳基; R 1，R 2是任选取代的（环）烷基，（het）芳基; 一起任选取代的包含氮原子的环; Z为-O- -S- R 3是任选取代的烷基，（het）芳基; R'是氢; 任选取代的（环）烷基，（het）芳基; R 5是氢; 任选取代的烷基（het）芳基; m为0,1,2; n，p m = 0：0,2,4其中：n + p = 2,4，如果合适0; m = 1：0,2,4其中：n + p = 0,2,4; m = 2：0,4,6其中：n + p = 0,4,6或其混合物作为太阳能电池中的光敏剂。

5. 发明申请

US20080245411A1 Fluorescent Solar Conversion Cells Based on Fluorescent Terylene Dyes 审中-公开
标题翻译：基于荧光三聚氰染料的荧光太阳能转换电池
公开(公告)号：US20080245411A1
公开(公告)日：2008-10-09
申请号：US12065620
申请日：2006-09-05
申请人： Markus Hammermann , Martin Konemann , Alfred Rennig , Axel Grimm , Arno Bohm , Peter Erk
发明人： Markus Hammermann , Martin Konemann , Alfred Rennig , Axel Grimm , Arno Bohm , Peter Erk
IPC分类号： H01L31/0216
CPC分类号： C09K11/06 , C09B5/62 , C09K2211/1011 , C09K2211/1029 , C09K2211/1044 , C09K2211/1088 , H01L31/055 , Y02E10/52
摘要： A fluorescence conversion solar cell based on one or more panels composed of polymer doped with at least one fluorescent dye and/or glass panels coated with the doped polymer and photovoltaic cells mounted on the edges of the panels, which comprise one or more fluorescent dyes based on terrylenecarboxylic acid derivatives or a combination of these fluorescent dyes with further fluorescent dyes.
摘要翻译：一种荧光转换太阳能电池，其基于由掺杂有至少一种荧光染料的聚合物组成的一个或多个面板，和/或涂覆有掺杂聚合物的玻璃面板和安装在面板边缘上的光伏电池，其包含一种或多种基于荧光染料的荧光染料对这些荧光染料与其他荧光染料的组合。

6. 发明申请

US20080255357A1 Terrylene and Quaterrylene Derivatives 有权
公开(公告)号：US20080255357A1
公开(公告)日：2008-10-16
申请号：US11913333
申请日：2006-05-03
申请人： Neil Gregory Pschirer , Jianqiang Qu , Martin Konemann
发明人： Neil Gregory Pschirer , Jianqiang Qu , Martin Konemann
IPC分类号： C07D221/18 , C07D487/06 , C07D235/02
CPC分类号： C07D493/06 , C07C1/2078 , C07D221/18 , C07D311/78 , C07D491/06 , C07F5/025 , C09B3/14 , C09B5/62 , C07C13/62
摘要： Rylene derivatives of the general formula I in which the variables are each defined as follows: X are joined to one another with formation of a six-membered ring to give a radical of the formula (a), (b) or (c) are both a —COOM radical; are both hydrogen or one of the two radicals is hydrogen and the other radical is halogen or a radical of the formula (d) Y are joined to one another with formation of a six-membered ring to give a radical of the formula (a) when one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d) or when both X radicals are hydrogen or together are a radical of the formula (a), (b) or (c); are joined to one another with formation of a six-membered ring to give a radical of the formula (b) when one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d) or when both X radicals are hydrogen or a —COOM radical or together are a radical of the formula (c); are joined to one another with formation of a six-membered ring to give a radical of the formula (c) when one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d) or when both X radicals are hydrogen or a —COOM radical or together are a radical of the formula (c) which may be arranged in the cis or trans position to the other (c) radical; are both a —COOM radical when one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d) or when both X radicals are hydrogen or a —COOM radical, M being different from hydrogen in the case that one X radical is a radical of the formula (d); are both hydrogen or one of the two radicals is hydrogen and the other radical is halogen or a radical of the formula (d) when both X radicals are hydrogen or one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d); R are identical or different radicals: substituted or unsubstituted aryloxy, arylthio, hetaryloxy or hetarylthio; R′ is hydrogen; substituted or unsubstituted alkyl, cycloalkyl, aryl or hetaryl; A are each independently substituted or unsubstituted phenylene, naphthylene or pyridylene; M is hydrogen, ammonium or alkali metal cation; R″ are each independently hydrogen, alkyl, cycloalkyl, aryl or hetaryl, or are joined together with formation of a 5- to 7-membered, fused or unfused and substituted or unsubstituted ring comprising the two oxygen atoms and also the boron atom; R1 is hydrogen or alkyl, where the R1 radicals may be the same or different when they occur more than once; R2, R3 are each independently hydrogen; substituted or unsubstituted alkyl, aryl or hetaryl; m is 1 or 2; n is from 3 to 6 where m=1; is from 2 to 8 where m=2, and mixtures thereof.

7. 发明申请

US20090030206A1 METHOD FOR PRODUCING QUATERRYLENE-3,4:13, 14-TETRACARBOXY DIIMIDES BY DIRECT SYNTHESIS 有权
标题翻译：通过直接合成生产季戊四醇3,4：13,14-TETRACARBOXY DIIMID的方法
公开(公告)号：US20090030206A1
公开(公告)日：2009-01-29
申请号：US11573948
申请日：2005-08-04
申请人： Martin Konemann , Arno Bohm , Hermann Bidlingmaier , Reinhold Rieger , Peter Blaschka , Helmut Reichelt , Matthias Krieger
发明人： Martin Konemann , Arno Bohm , Hermann Bidlingmaier , Reinhold Rieger , Peter Blaschka , Helmut Reichelt , Matthias Krieger
IPC分类号： C07D471/06
CPC分类号： C07D471/06 , C09B5/62
摘要： A process for preparing quaterrylene-3,4:13,14-tetracarboximides of the general formula I in which R, R′ are each independently hydrogen or optionally substituted C1-C30-alkyl, C5-C8-cycloalky or aryl or hetaryl; which comprises reacting a perylene-3,4-dicarboximide of the general formula IIa in the presence of a base-stable, high-boiling, organic solvent and of an alkali metal base or alkaline earth metal base, with a perylene-3,4-dicarboximide of the general formula IIb in which X is hydrogen, bromine or chlorine.
摘要翻译：制备通式I的四亚甲基-3,4：13,14-四甲酰亚胺的方法，其中R，R'各自独立地为氢或任选取代的C 1 -C 30 - 烷基，C 5 -C 8 - 环烷基或芳基或杂芳基; 其包括在碱稳定的高沸点有机溶剂和碱金属碱金属或碱土金属碱的存在下使通式IIa的苝-3,4-二羧酰亚胺与苝-3,4 通式IIb的二酰亚胺，其中X是氢，溴或氯。

8. 发明申请

US20080287678A1 Multiple Chromophores Based on Rylene 有权
标题翻译：基于Rylene的多重发色团
公开(公告)号：US20080287678A1
公开(公告)日：2008-11-20
申请号：US11996074
申请日：2006-07-27
申请人： Martin Konemann
发明人： Martin Konemann
IPC分类号： C07D471/04
CPC分类号： C09K11/06 , C09B5/62 , C09K19/60 , C09K19/606 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , C09K2211/1029 , C09K2211/1044 , C09K2211/1416 , C09K2211/1433 , C09K2211/1466
摘要： A rylene-based polychromophore of the general formula I in which the variables are each defined as follows: rylene is a radical of the formula which has been functionalized by at least one imide group, ester group or amide group and which may additionally be substituted by aryloxy, arylthio, hetaryloxy and/or hetarylthio; X is a rylenedicarboximide radical which absorbs at a different wavelength from the rylene radical, is bonded to the X radical in the peri-position via Y via a moiety —Y′-A-Y—, is bonded to the rylene radical and may likewise be substituted by aryloxy, arylthio, hetaryloxy and/or hetarylthio; A is a bridging member having at least one aromatic or heteroaromatic radical, the Y or Y and Y′ groups being bonded to the aromatic or heteroaromatic radical; Y is a moiety Y′ is a moiety where the moieties (i) and (ii) may be part of the ester groups of the rylene radical and the moieties (iii) are part of the imide groups of the rylene radical and the moieties (iv) are part of the amide groups of the rylene radical; R1 is hydrogen or C1-C18-alkyl, where the R1 radicals may be the same or different when they occur repeatedly; n is 1, 2 or 3; x is from 1 to 7.
摘要翻译：通式I的亚芳基多色荧光团，其中各变量各自定义如下：亚芳基是已经被至少一个酰亚胺基，酯基或酰胺基官能化并且可以另外被芳氧基，芳硫基，杂芳氧基和/或杂芳硫基; X是在不同波长下从二芳基吸收的二芳基二酰亚胺基，经由Y经由Y经由部分<？in-line-formula description =“In-Line Formulas”end =“ 引线“→Y'-AY-，<？在线公式描述=”在线公式“end =”tail“？>与二芳基键合，同样可以被芳氧基，芳硫基，和/或杂芳硫基; A是具有至少一个芳族或杂芳族基团的桥连构件，Y或Y和Y'基团键合到芳族或杂芳族基团; Y是部分Y'是其中部分（i）和（ii）可以是亚芳基的酯基的一部分的部分，并且部分（iii）是亚芳基的酰亚胺基团和部分（ iv）是亚芳基的酰胺基团的一部分; R 1是氢或C 1 -C 18 - 烷基，其中R 1个基团可以相同或反复出现时不同; n为1,2或3; x为1至7。

9. 发明申请

US20080058526A1 Halogenation of Rylen-Carboximides with Elementary Halogene in a Two-Phase Mixture Comprising an Organic Solvent and Water, Wherein Formed Halogene Hydrocide is Continously Removable from the Organic Solvent 失效
标题翻译：在含有有机溶剂和水的两相混合物中含有基本卤素的环烯 - 二羧酸的卤化，其中形成的卤素氢氧化物可从有机溶剂中连续地除去
公开(公告)号：US20080058526A1
公开(公告)日：2008-03-06
申请号：US11576157
申请日：2005-09-28
申请人： Martin Konemann , Neil Pschirer
发明人： Martin Konemann , Neil Pschirer
IPC分类号： C07D221/18
CPC分类号： C08K5/3437 , C07D221/18 , C07D471/06 , C09B5/62
摘要： A process for preparing halogenated rylenecarboximides of the general formula I in which the variables are each defined as follows: A, B together are an imide radical or, in the case that n is 1, A and B are also each Hal or one radical is Hal and the other radical is halogen; R, R′ are each independently hydrogen; optionally substituted alkyl, cycloalkyl, aryl or hetaryl; Hal is chlorine, bromine or iodine; n is 1, 2 or 3; x is from 2 to 8, by reacting a rylenecarboximide of the general formula II in which the A′ and B′ radicals together are an imide radical or, in the case that n is 1, are also each hydrogen with elemental halogen in the presence of an inert organic solvent S1, which comprises continuously withdrawing the hydrogen halide formed in the course of the reaction from the solvent S1.
摘要翻译：一种制备通式Ⅰ的卤化en bo xim A A A A A A A A A A A A A is is：：：：：：：：：：：：is is is is is is is is is is is is is is is is is is is is is Hal和其他基团是卤素; R，R'各自独立地为氢; 烷基，环烷基，芳基或杂芳基; 卤素是氯，溴或碘; n为1,2或3; x为2至8，通过使通式II的亚环己酰亚胺（其中A'和B'基团一起为酰亚胺基团），或者在n为1的情况下，在存在的情况下也各自为含有元素卤素的氢的惰性有机溶剂S1，其包括在溶剂S1中连续抽出在反应过程中形成的卤化氢。

10. 发明申请

US20080300405A1 Naphthalenetetracarboxylic Aicd Derivatives and their Use as Semiconductors 有权
标题翻译：萘四甲酸衍生物及其作为半导体的用途
公开(公告)号：US20080300405A1
公开(公告)日：2008-12-04
申请号：US12097774
申请日：2006-12-22
申请人： Martin Konemann
发明人： Martin Konemann
IPC分类号： C07D239/70 , C07D311/02 , C07D471/22
CPC分类号： C07D471/22 , C07D471/06 , C07D493/06 , C09B57/08 , H01L51/0053 , Y02E10/549
摘要： The present invention relates to naphthalenetetracarboxylic acid derivates, to a process for their preparation and to their use, especially as an n-type semiconductor.
摘要翻译：本发明涉及萘四羧酸衍生物，其制备方法及其用途，特别是作为n型半导体。

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