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    • 5. 发明授权
    • Method for conditioning an organic polymeric material
    • 调理有机聚合物材料的方法
    • US5135779A
    • 1992-08-04
    • US705556
    • 1991-05-24
    • Alfred ViehbeckStephen L. BuchwalterMartin J. GoldbergCaroline A. KovacStephen L. Tisdale
    • Alfred ViehbeckStephen L. BuchwalterMartin J. GoldbergCaroline A. KovacStephen L. Tisdale
    • C23C18/16C23C18/28H05K3/38
    • H05K3/381C23C18/1608C23C18/2086C23C18/30C23C18/31
    • Certain organic polymeric materials are capable of reversibly accepting or donating electrons from a reducing entity. The redox sites in the polymer accept electrons and, as a result, a change in the properties of the polymer occurs. This change is useful in modifying or etching the polymeric material. The material can be modified by incorporation of metallic seeds into the material at a controlled depth. The seeds are incorporated by interaction of cations of the metals with the redox sites in the polymer, which cause the reduction of the cations to form the neutral metallic seeds. Subsequent exposure of the polymeric material containing the seeds to an electroless bath causes further deposition of metal having the desirable characteristic of good adhesion to the polymeric material. Etching of the polymeric material can be carried out as a result of an increase in solubility of the polymer in aprotic solvents when its redox sites have accepted electrons. The increased solubility allows openings to be etched in certain areas of the polymeric material that have been reduced, leaving other areas unchanged.
    • 某些有机聚合材料能够可逆地接受或捐赠来自还原剂的电子。 聚合物中的氧化还原位点接受电子,结果发生聚合物的性质变化。 该改变可用于改性或蚀刻聚合物材料。 可以通过在受控的深度将金属种子并入材料中来修饰材料。 种子通过金属阳离子与聚合物中的氧化还原位点的相互作用而引入,这导致阳离子还原形成中性金属种子。 随后将含有种子的聚合材料暴露于无电镀浴中,导致具有对聚合物材料具有良好粘附性的所需特性的金属的进一步沉积。 聚合物材料的蚀刻可以作为聚合物在非质子传递溶剂中当其氧化还原位点已经接受电子时的溶解度增加的结果进行。 增加的溶解度允许在已经还原的聚合物材料的某些区域中蚀刻开口,留下其它区域不变。
    • 9. 发明授权
    • Means of seeding and metallizing polymide
    • 播种和金属化聚酰亚胺的方法
    • US5178914A
    • 1993-01-12
    • US606015
    • 1990-10-30
    • Ronald D. GoldblattCaroline A. KovacDomenico Tortorella
    • Ronald D. GoldblattCaroline A. KovacDomenico Tortorella
    • B32B15/088C08G73/10C08J5/18C08J7/12C09D179/08C23C18/30C23C18/31H05K1/03H05K3/18H05K3/38
    • H05K3/181C23C18/30H05K1/0346H05K3/381
    • A method for seeding the surface of a polyimide film which has been generated from a precursor polyamic acid film comprising the steps of: generating a film of polyamic acid on a substance (which may be done by conventional spin coating or by other solution coating techniques well known in the art); then either exposing the polyamic acid film to a solution containing palladium cations; heat-treating the palladium-treated film in a time/temperature schedule that causes imidization of the polymer to occur; exposing the seeded film to an electroless plating bath which causes the deposition of blanket metal film on the surface of the polymer film; or curing the film to the polyimide form; mechanically abrading the film surface, exposing the film to a solution containing palladium cations; exposing the seeded film to an electroless plating bath which causes the deposition of blanket metal film on the surface of the polymer film.
    • 一种从前体聚酰胺酸薄膜生成的聚酰亚胺薄膜的表面接种方法,包括以下步骤:在物质上生成聚酰胺酸的膜(可以通过常规旋涂或其它溶液涂覆技术完成) 本领域已知); 然后将聚酰胺酸膜暴露于含有钯阳离子的溶液中; 在导致聚合物酰亚胺化的时间/温度表中热处理钯处理的膜; 将接种的膜暴露于化学镀浴,其导致在聚合物膜的表面上沉积橡皮布金属膜; 或将膜固化成聚酰亚胺形式; 机械研磨膜表面,将膜暴露于含有钯阳离子的溶液中; 将接种的膜暴露于化学镀浴,其导致覆盖金属膜沉积在聚合物膜的表面上。