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1. 发明申请

US20060148957A1 Blends of oxygen scavenging polyamides with polyesters which contain zinc and cobalt 审中-公开
标题翻译：除氧聚酰胺与含有锌和钴的聚酯的共混物
公开(公告)号：US20060148957A1
公开(公告)日：2006-07-06
申请号：US11294249
申请日：2005-12-05
申请人： Mark Stewart , Robert Estep , Benjamin Gamble , Michael Cliffton , Donna Quillen , Lavonna Buehrig , Venkat Govindarajan , Matthew Dauzvardis
发明人： Mark Stewart , Robert Estep , Benjamin Gamble , Michael Cliffton , Donna Quillen , Lavonna Buehrig , Venkat Govindarajan , Matthew Dauzvardis
IPC分类号： C08K3/08
CPC分类号： C08K3/08 , B29B2911/1402 , B29B2911/14026 , B29B2911/14033 , B29B2911/1404 , B29B2911/14106 , B29B2911/14113 , B29B2911/1412 , B29B2911/14126 , B29B2911/14133 , B29B2911/1414 , B29B2911/14146 , B29B2911/14153 , B29B2911/1416 , B29B2911/14166 , B29B2911/14173 , B29B2911/1418 , C08K2003/0843 , C08K2003/0893 , C08L67/00
摘要： The present invention concerns a method for forming an article by combining a polyester polymer and an oxygen scavenging composition comprising a polyamide in the presence of zinc and a cobalt in a melt processing zone to form a melt; and forming an article such as a sheet or preform from the melt. Also provided are molten formulated polyester polymer compositions containing a blend of a polyethylene terephthalate polymer and a polyamide polymer along with zinc and cobalt. Articles made from the composition are resistant to the transmission of oxygen, possess short induction periods, and have high capacity for sustaining lengthy periods of low oxygen transmission through the wall of the article.
摘要翻译：本发明涉及通过在熔融加工区中将含有聚酰胺的聚酯聚合物和含氧清除组合物在锌和钴的存在下组合以形成熔体而形成制品的方法; 以及从所述熔体形成诸如片材或预成型件的制品。还提供了含有聚对苯二甲酸乙二醇酯聚合物和聚酰胺聚合物以及锌和钴的共混物的熔融配制的聚酯聚合物组合物。由该组合物制成的制品对氧气的传播具有抗性，具有短的诱导期，并且具有高的容量以维持通过制品壁的低氧传递的长时间段。

2. 发明申请

US20080045637A1 POLYESTER BASED COBALT CONCENTRATES FOR OXYGEN SCAVENGING COMPOSITIONS 审中-公开
标题翻译：用于氧气组合物的基于聚酯的钴浓度
公开(公告)号：US20080045637A1
公开(公告)日：2008-02-21
申请号：US11843258
申请日：2007-08-22
申请人： Mark Stewart , Emerson Sharpe , Benjamin Gamble , Steven Stafford , Robert Estep , James Williams , Thomas Clark
发明人： Mark Stewart , Emerson Sharpe , Benjamin Gamble , Steven Stafford , Robert Estep , James Williams , Thomas Clark
IPC分类号： C08K5/053 , C08K3/08 , C08K3/10
CPC分类号： C08K5/098 , C08L67/02 , C08L77/00 , Y10T428/1352 , Y10T428/1383 , C08L2666/14
摘要： A solid concentrate is provided having a combination of a transition metal present in an amount ranging from 1,000 to 40,000 ppm (weight by metal) and a polyester polymer present in an amount of at least 40 wt. % based on the weight of the concentrate. Concentrates made with highly modified polyester polymers are easy to compound with transition metals forming less brittle polymer upon melt extrusion. Bottle preforms and oxygen scavenging bottles can be made from these concentrates by combining solid polyester particles, solid polyamide particles, and solid these concentrate particles c into an melt processing zone, forming a melt, and forming an article directly from the melt. The b* color and the L* color and the haze levels of the preforms are improved over the preforms made with liquid carriers instead of solid concentrates. The particles are also advantageously simultaneously dried in a drying zone under conditions effective to at least partially remove moisture from the blend to thereby further improve the b* color and L* color.
摘要翻译：提供了一种固体浓缩物，其具有以1,000至40,000ppm（金属重量）的量存在的过渡金属和以至少40重量％的量存在的聚酯聚合物的组合。基于浓缩物的重量％。用高度改性的聚酯聚合物制成的浓缩物易于与熔融挤出时形成较少脆性聚合物的过渡金属复合。通过将固体聚酯颗粒，固体聚酰胺颗粒和固体这些浓缩颗粒c结合到熔融加工区域中，形成熔体并从熔体直接形成制品，可以从这些浓缩物制备瓶预成型件和除氧瓶。相对于用液体载体代替固体浓缩物制成的预成型件，预型件的b *颜色和L *颜色和雾度水平得到改善。在有效地至少部分地从共混物中除去水分的条件下，还可以在干燥区中同时干燥颗粒，从而进一步改善b *颜色和L *颜色。

3. 发明申请

US20060128861A1 Polyester based cobalt concentrates for oxygen scavenging compositions 有权
标题翻译：用于除氧组合物的聚酯基钴精矿
公开(公告)号：US20060128861A1
公开(公告)日：2006-06-15
申请号：US11292441
申请日：2005-12-02
申请人： Mark Stewart , Emerson Sharpe , Benjamin Gamble , Steven Stafford , Robert Estep , James Williams , Thomas Clark
发明人： Mark Stewart , Emerson Sharpe , Benjamin Gamble , Steven Stafford , Robert Estep , James Williams , Thomas Clark
IPC分类号： C08K5/09 , C08G63/60
CPC分类号： C08K5/098 , C08L67/02 , C08L77/00 , Y10T428/1352 , Y10T428/1383 , C08L2666/14
摘要： A solid concentrate is provided having a combination of a transition metal present in an amount ranging from 1000 to 40,000 ppm (weight by metal) and a polyester polymer present in an amount of at least 40 wt. % based on the weight of the concentrate. Concentrates made with highly modified polyester polymers are easy to compound with transition metals forming less brittle polymer upon melt extrusion. Bottle preforms and oxygen scavenging bottles can be made from these concentrates by combining solid polyester particles, solid polyamide particles, and solid these concentrate particles c into an melt processing zone, forming a melt, and forming an article directly from the melt. The b* color and the L* color and the haze levels of the preforms are improved over the preforms made with liquid carriers instead of solid concentrates. The particles are also advantageously simultaneously dried in a drying zone under conditions effective to at least partially remove moisture from the blend to thereby further improve the b* color and L* color.
摘要翻译：提供了一种固体浓缩物，其具有的存在量为1000至40,000ppm（金属重量）的过渡金属和以至少40重量％的量存在的聚酯聚合物的组合。基于浓缩物的重量％。用高度改性的聚酯聚合物制成的浓缩物易于与熔融挤出时形成较少脆性聚合物的过渡金属复合。通过将固体聚酯颗粒，固体聚酰胺颗粒和固体这些浓缩颗粒c结合到熔融加工区域中，形成熔体并从熔体直接形成制品，可以从这些浓缩物制备瓶预成型件和除氧瓶。相对于用液体载体代替固体浓缩物制成的预成型件，预型件的b *颜色和L *颜色和雾度水平得到改善。在有效地至少部分地从共混物中除去水分的条件下，还可以在干燥区中同时干燥颗粒，从而进一步改善b *颜色和L *颜色。

4. 发明申请

US20080021142A1 POLYESTER BASED COBALT CONCENTRATES FOR OXYGEN SCAVENGING COMPOSITIONS 审中-公开
标题翻译：用于氧气组合物的基于聚酯的钴浓度
公开(公告)号：US20080021142A1
公开(公告)日：2008-01-24
申请号：US11843275
申请日：2007-08-22
申请人： Mark Stewart , Emerson Sharpe , Benjamin Gamble , Steven Stafford , Robert Estep , James Williams , Thomas Clark
发明人： Mark Stewart , Emerson Sharpe , Benjamin Gamble , Steven Stafford , Robert Estep , James Williams , Thomas Clark
IPC分类号： C08K5/098 , C08K3/10 , C08K3/22 , C08K3/28 , C08K3/30 , C08K3/32 , C08K3/34 , C08K3/38
CPC分类号： C08K5/098 , C08L67/02 , C08L77/00 , Y10T428/1352 , Y10T428/1383 , C08L2666/14
摘要： A solid concentrate is provided having a combination of a transition metal present in an amount ranging from 1000 to 40,000 ppm (weight by metal) and a polyester polymer present in an amount of at least 40 wt. % based on the weight of the concentrate. Concentrates made with highly modified polyester polymers are easy to compound with transition metals forming less brittle polymer upon melt extrusion. Bottle preforms and oxygen scavenging bottles can be made from these concentrates by combining solid polyester particles, solid polyamide particles, and solid these concentrate particles c into an melt processing zone, forming a melt, and forming an article directly from the melt. The b* color and the L* color and the haze levels of the preforms are improved over the preforms made with liquid carriers instead of solid concentrates. The particles are also advantageously simultaneously dried in a drying zone under conditions effective to at least partially remove moisture from the blend to thereby further improve the b* color and L* color.
摘要翻译：提供了一种固体浓缩物，其具有的存在量为1000至40,000ppm（金属重量）的过渡金属和以至少40重量％的量存在的聚酯聚合物的组合。基于浓缩物的重量％。用高度改性的聚酯聚合物制成的浓缩物易于与熔融挤出时形成较少脆性聚合物的过渡金属复合。通过将固体聚酯颗粒，固体聚酰胺颗粒和固体这些浓缩颗粒c结合到熔融加工区域中，形成熔体并从熔体直接形成制品，可以从这些浓缩物制备瓶预成型件和除氧瓶。相对于用液体载体代替固体浓缩物制成的预成型件，预型件的b *颜色和L *颜色和雾度水平得到改善。在有效地至少部分地从共混物中除去水分的条件下，还可以在干燥区中同时干燥颗粒，从而进一步改善b *颜色和L *颜色。

5. 发明申请

US20060199921A1 Preparation of transparent multilayered articles from polyesters and homogeneous polyamide blends 有权
标题翻译：从聚酯和均相聚酰胺共混物制备透明多层制品
公开(公告)号：US20060199921A1
公开(公告)日：2006-09-07
申请号：US11363481
申请日：2006-02-27
申请人： Wesley Hale , Thomas Pecorini , Mark Stewart , Martin Rogers , Spencer Gilliam , Michael Cliffton
发明人： Wesley Hale , Thomas Pecorini , Mark Stewart , Martin Rogers , Spencer Gilliam , Michael Cliffton
IPC分类号： C08G69/48 , C08L69/00
CPC分类号： C08L69/00 , B32B2272/00 , B32B2305/70 , B32B2307/412 , C08K3/08 , C08L67/00 , C08L67/02 , C08L77/00 , C08L77/02 , C08L77/06 , C08L2205/02 , C08L2666/20 , C08L2666/14
摘要： Disclosed is a process for the preparation of multilayered, shaped articles having high transparency and low haze having at least one layer contains one or more thermoplastic polymers selected from polyesters, polycarbonates, and homogeneous blends thereof, and a separate layer which contains a transamidized, homogeneous blend of a least two polyamides. The thermoplastic polymer components and the polyamide components have refractive indices which differ by about 0.006 to about −0.0006. The small difference in the refractive indices enable the incorporation of regrind into one or more of the layers of the article while maintaining high clarity. These articles can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into one or more layers to impart oxygen-scavenging properties.
摘要翻译：公开了一种制备具有高透明度和低雾度的多层成型制品的方法，其具有至少一层包含一种或多种选自聚酯，聚碳酸酯及其均匀共混物的热塑性聚合物，以及含有酰胺化均匀的单独层混合至少两种聚酰胺。热塑性聚合物组分和聚酰胺组分的折射率相差约0.006至约-0.0006。折射率的小差异使得可以将再研磨物掺入制品的一层或多层中同时保持高透明度。这些制品可以表现出改进的优异的阻隔性能和良好的熔融加工性，同时保持优异的机械性能。可以将金属催化剂并入一个或多个层中以赋予氧气清除性能。

6. 发明申请

US20060234073A1 Multilayered, transparent articles containing polyesters comprising a cyclobutanediol and a process for their preparation 审中-公开
标题翻译：含有包含环丁二醇的聚酯的多层透明制品及其制备方法
公开(公告)号：US20060234073A1
公开(公告)日：2006-10-19
申请号：US11391124
申请日：2006-03-28
申请人： Wesley Hale , Thomas Pecorini , Mark Stewart , Martin Rogers , Spencer Gilliam , Michael Cliffton , Emmett Crawford , David Porter , Gary Connell
发明人： Wesley Hale , Thomas Pecorini , Mark Stewart , Martin Rogers , Spencer Gilliam , Michael Cliffton , Emmett Crawford , David Porter , Gary Connell
IPC分类号： B32B27/34
CPC分类号： C08L69/00 , B32B1/08 , B32B7/02 , B32B27/08 , B32B27/16 , B32B27/18 , B32B27/34 , B32B27/36 , B32B2250/02 , B32B2250/24 , B32B2264/105 , B32B2270/00 , B32B2272/00 , B32B2274/00 , B32B2307/412 , B32B2307/50 , B32B2307/7242 , B32B2307/74 , B32B2439/60 , B32B2439/62 , B32B2439/70 , B32B2597/00 , C08K3/08 , C08L67/00 , C08L67/02 , C08L77/00 , C08L2205/02 , Y10T428/31725 , C08L2666/20 , C08L2666/14
摘要： Disclosed are transparent, multilayered articles having high transparency and low haze and a process for their preparation. The multilayer articles comprise at least one layer which contains at least one polyester comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol and a separate layer which contains copolyamide or homogeneous blend of polyamides. The polyester component and the polyamide component have refractive indices which differ by about 0.006 to about −0.0006. The small difference in the refractive indices enable the incorporation of regrind into one or more of the layers of the article while maintaining high clarity. These articles can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into one or more layers to impart oxygen-scavenging properties.
摘要翻译：公开了具有高透明度和低雾度的透明多层制品及其制备方法。多层制品包含至少一层，其含有至少一种包含2,2,4,4-四甲基-1,3-环丁二醇的聚酯和含有共聚酰胺或聚酰胺的均匀共混物的单独层。聚酯组分和聚酰胺组分的折射率相差约0.006至约-0.0006。折射率的小差异使得可以将再研磨物掺入制品的一层或多层中同时保持高透明度。这些制品可以表现出改进的优异的阻隔性能和良好的熔融加工性，同时保持优异的机械性能。可以将金属催化剂并入一个或多个层中以赋予氧气清除性能。

7. 发明申请

US20060226565A1 Preparation of transparent, multilayered articles containing polyesters comprising a cyclobutanediol and homogeneous polyamide blends 有权
标题翻译：制备含有包含环丁二醇和均相聚酰胺共混物的聚酯的透明多层制品
公开(公告)号：US20060226565A1
公开(公告)日：2006-10-12
申请号：US11390908
申请日：2006-03-28
申请人： Wesley Hale , Thomas Pecorini , Mark Stewart , Martin Rogers , Spencer Gilliam , Michael Cliffton , Emmett Crawford , David Porter , Gary Connell
发明人： Wesley Hale , Thomas Pecorini , Mark Stewart , Martin Rogers , Spencer Gilliam , Michael Cliffton , Emmett Crawford , David Porter , Gary Connell
IPC分类号： B29B17/00 , B29C47/06 , B29C45/16
CPC分类号： B29B17/0042 , B29B11/08 , B29B11/14 , B29B2911/1402 , B29B2911/14026 , B29B2911/14033 , B29B2911/1404 , B29B2911/14053 , B29B2911/14066 , B29B2911/1408 , B29B2911/14093 , B29B2911/14106 , B29B2911/14113 , B29B2911/1412 , B29B2911/14126 , B29B2911/14133 , B29B2911/1414 , B29B2911/14146 , B29B2911/14153 , B29B2911/14906 , B29C45/0001 , B29C47/0004 , B29C47/0023 , B29C47/0026 , B29C47/043 , B29C47/061 , B29C47/065 , B29C49/0005 , B29C49/04 , B29C49/06 , B29C49/22 , B29C51/002 , B29C51/14 , B29K2067/00 , B29K2069/00 , B29K2077/00 , B29K2105/0008 , B29K2105/0026 , B29K2105/0032 , B29K2105/0044 , B29K2105/256 , B29K2105/258 , B29K2105/26 , B29K2995/0025 , B29L2031/7158 , B32B1/08 , B32B7/02 , B32B27/08 , B32B27/16 , B32B27/18 , B32B27/34 , B32B27/36 , B32B2250/02 , B32B2250/24 , B32B2264/105 , B32B2270/00 , B32B2272/00 , B32B2274/00 , B32B2307/412 , B32B2307/50 , B32B2307/7242 , B32B2307/74 , B32B2439/60 , B32B2439/62 , B32B2439/70 , B32B2597/00 , C08J11/06 , Y02P70/279 , Y02W30/62 , Y02W30/701
摘要： Disclosed is a process for the preparation of multilayered, shaped articles having high transparency and low haze and in which at least one layer contains at least one polyester comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol and a separate layer which contains a transamidized, homogeneous blend of a least two polyamides. The polyester component and the polyamide component have refractive indices which differ by about 0.006 to about −0.0006. The small difference in the refractive indices enable the incorporation of regrind into one or more of the layers of the article while maintaining high clarity. These articles can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into one or more layers to impart oxygen-scavenging properties.
摘要翻译：公开了一种制备具有高透明度和低雾度的多层成型制品的方法，其中至少一层包含至少一种包含2,2,4,4-四甲基-1,3-环丁二醇的聚酯和分开的层其包含至少两种聚酰胺的酰胺化均匀共混物。聚酯组分和聚酰胺组分的折射率相差约0.006至约-0.0006。折射率的小差异使得可以将再研磨物掺入制品的一层或多层中同时保持高透明度。这些制品在保持优异的机械性能的同时可显示出优异的阻隔性能和良好的熔融加工性。可以将金属催化剂并入一个或多个层中以赋予氧气清除性能。

8. 发明申请

US20060247388A1 Transparent, oxygen-scavenging compositions containing polyesters comprising a cyclobutanediol and articles prepared therefrom 有权
标题翻译：透明的含氧清除组合物，其含有包含环丁二醇的聚酯和由其制备的制品
公开(公告)号：US20060247388A1
公开(公告)日：2006-11-02
申请号：US11390809
申请日：2006-03-28
申请人： Wesley Hale , Thomas Pecorini , Mark Stewart , Martin Rogers , Spencer Gilliam , Michael Cliffton , Emmett Crawford , David Porter , Gary Connell
发明人： Wesley Hale , Thomas Pecorini , Mark Stewart , Martin Rogers , Spencer Gilliam , Michael Cliffton , Emmett Crawford , David Porter , Gary Connell
IPC分类号： C08G69/48 , C08F283/04
CPC分类号： C08F283/04 , C08K3/08 , C08L67/02 , C08L69/00 , C08L77/00 , C08L2205/02 , C08L2205/035 , Y10T428/13 , Y10T428/1334 , Y10T428/1352 , Y10T428/1355 , Y10T428/1359 , Y10T428/1379 , Y10T428/1383 , Y10T428/31725 , Y10T428/31736 , Y10T428/31739 , C08L2666/14 , C08L2666/20 , C08L2666/18
摘要： Disclosed are oxygen-scavenging polymer compositions having high transparency and low haze comprising immiscible blends of at least one polyester comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol, a copolyamide or a transamidized, homogeneous blend of a least two polyamides, and a metal catalyst. The components of the immiscible blend which have refractive indices which differ by about 0.006 to about −0.0006. The small difference in the refractive indices enable the incorporation of regrind into the polymer composition to produce transparent shaped articles. The blends of the present invention are useful in producing shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties.
摘要翻译：公开了具有高透明度和低雾度的除氧聚合物组合物，其包含至少一种包含2,2,4,4-四甲基-1,3-环丁二醇的聚酯的不混溶共混物，共聚酰胺或转酰胺化均匀的至少两种聚酰胺和金属催化剂。不混溶共混物的组分具有约0.006至约-0.0006的折射率。折射率的小差异使得能够将再研磨物掺入聚合物组合物中以产生透明成型制品。本发明的共混物可用于生产成形制品，例如片材，薄膜，管，瓶，预型件和型材。这些制品可以具有一层或多层，并且可以表现出改进的优异的阻隔性能和良好的熔融加工性，同时保持优异的机械性能。

9. 发明申请

US20060235167A1 Process for the preparation of transparent, shaped articles containing polyesters comprising a cyclobutanediol 有权
标题翻译：制备含有包含环丁二醇的聚酯的透明成型制品的方法
公开(公告)号：US20060235167A1
公开(公告)日：2006-10-19
申请号：US11390812
申请日：2006-03-28
申请人： Wesley Hale , Thomas Pecorini , Mark Stewart , Martin Rogers , Spencer Gilliam , Michael Cliffton , Emmett Crawford , David Porter , Gary Connell
发明人： Wesley Hale , Thomas Pecorini , Mark Stewart , Martin Rogers , Spencer Gilliam , Michael Cliffton , Emmett Crawford , David Porter , Gary Connell
IPC分类号： C08G69/48
CPC分类号： C08L77/00 , C08K3/08 , C08L67/02 , C08L69/00 , C08L2205/02 , C08L2205/03 , Y10T428/13 , Y10T428/1334 , Y10T428/1352 , Y10T428/1355 , Y10T428/1359 , Y10T428/1379 , Y10T428/1383 , Y10T428/31725 , Y10T428/31736 , Y10T428/31739 , C08L2666/14 , C08L2666/20 , C08L2666/18
摘要： Disclosed is a process for the preparation of shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles, having high transparency and low haze, and comprising immiscible blends of at least one polyester comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol, and a copolyamide or a transamidized, homogeneous blend of a least two polyamides. The components of the immiscible blend have refractive indices which differ by about 0.006 to about −0.0006. The small difference in the refractive indices enable the incorporation of regrind into the polymer composition to produce transparent shaped articles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into the compositions to produce shaped articles having oxygen-scavenging properties.
摘要翻译：公开了一种制备成形制品的方法，例如片状，薄膜，管，瓶，预成型件和型材，具有高透明度和低雾度，并且包括至少一种聚酯的不混溶共混物，包括2,2,4 ，4-四甲基-1,3-环丁二醇，以及共聚酰胺或至少两种聚酰胺的酰胺化均匀共混物。不混溶共混物的组分具有约0.006至约-0.0006的折射率。折射率的小差异使得能够将再研磨物掺入聚合物组合物中以产生透明成型制品。这些制品可以具有一层或多层，并且可以表现出改进的优异的阻隔性能和良好的熔融加工性，同时保持优异的机械性能。可以将金属催化剂引入到组合物中以产生具有除氧性能的成形制品。

10. 发明申请

US20060199871A1 Multilayered, transparent articles and a process for their preparation 审中-公开
标题翻译：多层透明的物品及其准备过程
公开(公告)号：US20060199871A1
公开(公告)日：2006-09-07
申请号：US11363418
申请日：2006-02-27
申请人： Wesley Hale , Thomas Pecorini , Mark Stewart , Martin Rogers , Spencer Gilliam , Michael Cliffton
发明人： Wesley Hale , Thomas Pecorini , Mark Stewart , Martin Rogers , Spencer Gilliam , Michael Cliffton
IPC分类号： C08J11/04
CPC分类号： C08L69/00 , B32B1/08 , B32B7/02 , B32B27/08 , B32B27/16 , B32B27/18 , B32B27/34 , B32B27/36 , B32B2250/02 , B32B2250/24 , B32B2264/105 , B32B2270/00 , B32B2272/00 , B32B2274/00 , B32B2307/412 , B32B2307/50 , B32B2307/7242 , B32B2307/74 , B32B2439/60 , B32B2439/62 , B32B2439/70 , B32B2597/00 , C08K3/08 , C08L67/00 , C08L67/02 , C08L77/00 , C08L2205/02 , Y10T428/31725 , C08L2666/20 , C08L2666/14
摘要： Disclosed is a process for the preparation of multilayered, shaped articles having high transparency and low haze and comprising one or more thermoplastic polymers selected from polyesters, polycarbonates, and polyarylates, and a copolyamide or a transamidized, homogeneous blend of a least two polyamides. The thermoplastic polymer components and the polyamide components have refractive indices which differ by about 0.006 to about −0.0006. The small difference in the refractive indices enable the incorporation of regrind into one or more of the layers of the article while maintaining high clarity. These articles can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into one or more layers to impart oxygen-scavenging properties.
摘要翻译：公开了一种用于制备具有高透明度和低雾度并且包含一种或多种选自聚酯，聚碳酸酯和聚芳酯的热塑性聚合物的多层成型制品的方法，以及至少两种聚酰胺的共聚酰胺或酰胺化的均匀共混物。热塑性聚合物组分和聚酰胺组分的折射率相差约0.006至约-0.0006。折射率的小差异使得可以将再研磨物掺入制品的一层或多层中同时保持高透明度。这些制品在保持优异的机械性能的同时可显示出优异的阻隔性能和良好的熔融加工性。可以将金属催化剂并入一个或多个层中以赋予氧气清除性能。

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