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    • 2. 发明申请
    • Polyester based cobalt concentrates for oxygen scavenging compositions
    • 用于除氧组合物的聚酯基钴精矿
    • US20060128861A1
    • 2006-06-15
    • US11292441
    • 2005-12-02
    • Mark StewartEmerson SharpeBenjamin GambleSteven StaffordRobert EstepJames WilliamsThomas Clark
    • Mark StewartEmerson SharpeBenjamin GambleSteven StaffordRobert EstepJames WilliamsThomas Clark
    • C08K5/09C08G63/60
    • C08K5/098C08L67/02C08L77/00Y10T428/1352Y10T428/1383C08L2666/14
    • A solid concentrate is provided having a combination of a transition metal present in an amount ranging from 1000 to 40,000 ppm (weight by metal) and a polyester polymer present in an amount of at least 40 wt. % based on the weight of the concentrate. Concentrates made with highly modified polyester polymers are easy to compound with transition metals forming less brittle polymer upon melt extrusion. Bottle preforms and oxygen scavenging bottles can be made from these concentrates by combining solid polyester particles, solid polyamide particles, and solid these concentrate particles c into an melt processing zone, forming a melt, and forming an article directly from the melt. The b* color and the L* color and the haze levels of the preforms are improved over the preforms made with liquid carriers instead of solid concentrates. The particles are also advantageously simultaneously dried in a drying zone under conditions effective to at least partially remove moisture from the blend to thereby further improve the b* color and L* color.
    • 提供了一种固体浓缩物,其具有的存在量为1000至40,000ppm(金属重量)的过渡金属和以至少40重量%的量存在的聚酯聚合物的组合。 基于浓缩物的重量%。 用高度改性的聚酯聚合物制成的浓缩物易于与熔融挤出时形成较少脆性聚合物的过渡金属复合。 通过将固体聚酯颗粒,固体聚酰胺颗粒和固体这些浓缩颗粒c结合到熔融加工区域中,形成熔体并从熔体直接形成制品,可以从这些浓缩物制备瓶预成型件和除氧瓶。 相对于用液体载体代替固体浓缩物制成的预成型件,预型件的b *颜色和L *颜色和雾度水平得到改善。 在有效地至少部分地从共混物中除去水分的条件下,还可以在干燥区中同时干燥颗粒,从而进一步改善b *颜色和L *颜色。
    • 7. 发明申请
    • Spheroidal polyester polymer particles
    • 球状聚酯聚合物颗粒
    • US20060047102A1
    • 2006-03-02
    • US11018357
    • 2004-12-21
    • Stephen WeinholdFrederick ColhounMichael EkartBenjamin Gamble
    • Stephen WeinholdFrederick ColhounMichael EkartBenjamin Gamble
    • C08G63/02
    • C08G63/88Y10T428/1334Y10T428/1355
    • Spheroidal polyester polymer particles, as well as preforms and stretch blow molded bottles made from the spheroidal particles, are provided which have: A) an It.V. of at least 0.72 dL/g, and either B) at least two melting peaks (on a DSC first heating scan), wherein one of said at least two melting peaks is a low peak melting point having a peak temperature within a range of 140° C. to 220° C. and having a melting endotherm area of at least the absolute value of 1 J/g, or C) a low degree of crystallinity within a range of at least 20% and a maximum degree of crystallinity Tcmax defined by the equation: Tcmax=50%−CA−OH where CA is the total mole % of all carboxylic acid residues other than terephthalic acid residues, based on 100 mole % of carboxylic acid residues in the polyester polymer, and OH is the total mole % of hydroxyl functional compound residues other than ethylene glycol residues, based on 100 mole % of the hydroxyl functional compounds residues; or both B) and C); and optionally but preferably D) 10 ppm or less of residual acetaldehyde.
    • 提供球形聚酯聚合物颗粒,以及由球形颗粒制成的预成型件和拉伸吹塑瓶,其具有:A)It.V. 至少0.72dL / g,和B)至少两个熔融峰(在DSC第一次加热扫描上),其中所述至少两个熔融峰中的一个是具有峰值温度在140℃范围内的低峰值熔点 具有至少绝对值为1J / g的熔融吸热面积,或C)在至少20%的范围内的低结晶度和最大结晶度T < 由以下等式定义的SUB> cmax :<?in-line-formula description =“In-line formula”end =“lead”?> Taxaxax = 50%-CA-OH <?in-line-formula description =“In-line Formulas”end =“tail”?>其中CA是除对苯二甲酸残基之外的所有羧酸残基的总摩尔%,基于100摩尔%的羧酸残基 基于100摩尔%的羟基官能化合物残基,聚酯聚合物和OH是除乙二醇残基之外的羟基官能化合物残基的总摩尔%; 或B)和C); 和任选但优选D)10ppm或更少的残留乙醛。