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1. 发明授权

US06235097B1 Phthalocyanine compounds used in inks for ink jet printing 失效
标题翻译：用于喷墨印刷油墨的酞菁化合物
公开(公告)号：US06235097B1
公开(公告)日：2001-05-22
申请号：US09486832
申请日：2000-03-02
申请人： Mark Kenworthy , Peter Gregory
发明人： Mark Kenworthy , Peter Gregory
IPC分类号： C09D1102
CPC分类号： C09D11/328 , C09B47/20 , C09B47/24
摘要： Suitable phthalocyanine compounds of Formula (1) have utility as colorants in inks for ink-jet printing, where Formula (1) represents: which comprises any form of the compound: such as salt; stereoisomer, zwitterion, polymorph, complex, isotopic form, combinations thereof in the same species and mixtures thereof; where: M represents a metal or H; Pc represents a phthalocyanine nucleus of Formula (2): L represents a linking group comprising an optionally substituted C1-30hydrocarbyl; A represents a group comprising at least one of: amino and optionally substituted C1-30hydrocarbyl comprising at least one protonable nitrogen atom; but where A comprises other than an alkyl group substituted by at least one of: hydroxy, carboxy and sulpho; R1 represents a group independently comprising at least one of: an optional substituent and optionally substituted C1-5hydrocarbyl; z represents an integer from 0 to 4; w represents an integer from 1 to 5; and the sum of w+z is from 1 to 5; and x and y each independently represent a non-zero number; and the mean of the sum of x+y is from about 1 to about 6; where the optional substituents comprise at least one of: carboxy, sulpho, hydroxy, amino, mercapto, cyano, nitro and halo.
摘要翻译：式（1）的合适的酞菁化合物可用作喷墨印刷用油墨中的着色剂，其中式（1）表示：其包含任何形式的化合物如盐; 立体异构体，两性离子，多晶型物，复合物，同位素形式，它们在同一物种及其混合物中的组合; 其中：M表示金属或H; Pc表示式（2）的酞菁核：L表示包含任选取代的C 1-30烃基的连接基团; A表示包含至少一个氨基和任选取代的C 1-30烃基包含至少一个可质子化的氮原子; 但是其中A不包括被至少一个羟基，羧基和磺基取代的烷基; R 1表示独立地包含任选的取代基和任选取代的C 1-5烃基中的至少一个的基团; z表示0至 4; w表示1〜5的整数， w + z的和为1〜5; andx和y各自独立地表示非零数; 并且x + y之和的平均值为约1至约6;其中任选的取代基包括以下中的至少一个：羧基，磺基，羟基，氨基，巯基，氰基，硝基和卤素。

2. 发明授权

US5820661A Ink compositions containing disazo dyes 失效
标题翻译：含有双偶氮染料的油墨组合物
公开(公告)号：US5820661A
公开(公告)日：1998-10-13
申请号：US831938
申请日：1997-04-02
申请人： Peter Gregory , Mark Kenworthy , Andrew Hunter Morris Renfrew
发明人： Peter Gregory , Mark Kenworthy , Andrew Hunter Morris Renfrew
IPC分类号： C09B43/40 , C09B62/09 , C09B62/44 , C09D11/00 , D06P5/30 , G03G9/09 , C09D11/02
CPC分类号： C09D11/328 , C09B43/40 , C09B62/09 , C09B62/4415 , D06P5/30 , G03G9/091 , G03G9/0914 , Y10T428/24802
摘要： An ink composition comprising: (i) a dye of Formula (1) or a salt thereof: ##STR1## wherein: A is optionally substituted phenylene; B and E each independently is optionally substituted phenylene or optionally substituted naphthylene; D is a coupling component; each R.sup.1 independently is H or optionally substituted alkyl; X is a labile or non-labile atom or group; each Z independently is --OR.sup.3, --SR.sup.3, --NR.sup.4 R.sup.5 or --Y--SO.sub.3 H in which Y is O or S; and R.sup.3, R.sup.4 and R.sup.5 each independently is H, optionally substituted alkyl, optionally substituted alkenyl, cycloalkyl, optionally substituted aralkyl, optionally substituted aryl or R.sup.4 or R.sup.5 together with the nitrogen atom to which they are attached form a 5 or 6 membered ring; and (ii) a medium comprising a low melting point solid, an organic solvent, or a mixture of water and one or more water-soluble organic solvent(s). Also claimed is a process for ink jet printing using the inks, a process for ink jet printing of textiles using the inks and a toner containing a dye with at least one group of Formula (1).
摘要翻译：一种油墨组合物，其包含：（i）式（1）的染料或其盐：式（1）ESO 2 NHCH 2 CH 2 Z其中：A是任选取代的亚苯基; B和E各自独立地为任选取代的亚苯基或任选取代的亚萘基; D是耦合元件; 每个R 1独立地是H或任选取代的烷基; X是不稳定或不稳定的原子或组; 各Z独立地为-OR3，-SR3，-NR4R5或-Y-SO3H，其中Y为O或S; 并且R 3，R 4和R 5各自独立地为H，任选取代的烷基，任选取代的烯基，环烷基，任选取代的芳烷基，任选取代的芳基或R 4或R 5与它们所连接的氮原子一起形成5或6元环; 和（ii）包含低熔点固体，有机溶剂或水与一种或多种水溶性有机溶剂的混合物的介质。还要求保护的是使用油墨的喷墨印刷方法，使用该油墨的纺织品的喷墨印刷方法和含有至少一种式（1）的染料的调色剂。

3. 发明公开

US20240367023A1 HANDLEBAR EXTENSION APPARATUS AND ASSOCIATED BICYCLE EXERCISE ARRANGEMENT 审中-公开
公开(公告)号：US20240367023A1
公开(公告)日：2024-11-07
申请号：US18562158
申请日：2022-05-18
申请人： Peter Gregory , Andrew Johnson
发明人： Peter Gregory , Andrew Johnson
IPC分类号： A63B69/16
CPC分类号： A63B69/16 , A63B2069/163 , A63B2069/165
摘要： Provided is bicycle handlebar extension apparatus (10) comprising a strut arrangement (12) having a lower end (14) configured to releasably engage a front wheel (34) of a bicycle (8) and an upper end (18) configured to releasably engage a handlebar stem (20) of said bicycle (8). Apparatus (10) also includes a brace (22) hingedly attached at a bottom end (24) thereof to the upper end (18) of the strut arrangement (12), said brace (22) defining at a top end (26) thereof a pivotable receptacle (28) configured to receive handlebars (30). In this manner, the strut arrangement (12) operatively engaged with the front axle (16) and handlebar stem (20) provides stationary stability to the bicycle (8) whilst angles between the strut arrangement (12), brace (22) and receptacle (28) are adjustable to facilitate desired rider ergonomics.

4. 发明授权

US07481522B2 Compositions and inks containing disazo dyes 失效
标题翻译：含有双偶氮染料的组合物和油墨
公开(公告)号：US07481522B2
公开(公告)日：2009-01-27
申请号：US10516496
申请日：2003-06-05
申请人： Alan Dickinson , Neil James Thompson , Paul Wight , Peter Gregory , Philip John Double , Roy Bradbury
发明人： Alan Dickinson , Neil James Thompson , Paul Wight , Peter Gregory , Philip John Double , Roy Bradbury
IPC分类号： G01D11/00
CPC分类号： C09D11/30
摘要： A process for printing an image on a substrate including applying thereto a composition including a liquid medium and a compound of Formula (1) A-N═N-L-N═N-A wherein: each A independently is optionally substituted aryl or heteroaryl; and L is an optionally substituted, optionally metallised 1,8-dihydroxynaphthylene group; provided that: (i) at most one of the groups represented by A has a hydroxy substituent ortho to the —N═N— groups shown in Formula (1); and (ii) Formula (1) is not: Also claimed are compositions for printing, compounds and processes for making the compounds.
摘要翻译：一种在基材上印刷图像的方法，包括向其施涂包含液体介质和式（1）A-N-N-L-N-N-A的化合物的组合物，其中：每个A独立地为任选取代的芳基或杂芳基; 并且L是任选取代的任选金属化的1,8-二羟基萘基; 条件是：（i）由A表示的至多一个基团具有与式（1）所示的-N-N-基邻位的羟基取代基; 和（ii）式（1）不是：还要求的是用于印刷的组合物，化合物和制备该化合物的方法。

5. 发明授权

US5925487A Composition, compound and use 失效
标题翻译：组成，复合和使用
公开(公告)号：US5925487A
公开(公告)日：1999-07-20
申请号：US860491
申请日：1997-06-27
申请人： David Melville Fawkes , Peter Gregory , James Stanley Campbell
发明人： David Melville Fawkes , Peter Gregory , James Stanley Campbell
IPC分类号： C07C65/11 , C07C229/38 , C08K5/09 , C08L101/00 , G03G9/097 , C03G9/097 , C07F3/04 , C07F15/02 , C03G13/08
CPC分类号： G03G9/09775 , C07C229/38 , C07C65/11 , G03G9/09733 , G03G9/09783
摘要： A toner resin composition comprising a toner resin and the metal salt or complex of a carbocyclic hydroxy caboxylic acid containing at least one methylene group optionally substituted by hydroxy or amino such as 4-(N-methyl-N-2-hydroxyethyl)aminomethyl-3-hydroxy-2-naphthoic acid. Iron and zinc salts are preferred.
摘要翻译： PCT No.PCT / GB95 / 02852 Sec。 371日期：1997年6月27日 102（e）日期1997年6月27日PCT提交1995年12月7日PCT公布。公开号WO96 / 20436 日期1996年7月4日一种调色剂树脂组合物，其包含调色剂树脂和含有至少一个任选被羟基或氨基取代的亚甲基的碳环羟基甲醛酸的金属盐或络合物，例如4-（N-甲基-N-2- 羟乙基）氨基甲基-3-羟基-2-萘甲酸。优选铁和锌盐。

6. 发明授权

US5847114A Poly-substituted phthalocyantines 失效
标题翻译：多取代酞菁酮
公开(公告)号：US5847114A
公开(公告)日：1998-12-08
申请号：US548173
申请日：1995-10-25
申请人： Dean Thetford , Peter Gregory
发明人： Dean Thetford , Peter Gregory
IPC分类号： A61K31/40 , A61K31/409 , A61K31/555 , A61K41/00 , A61K51/00 , A61P35/00 , C07D487/22 , C09B47/04 , C09B47/067 , C09B47/18 , C11D3/00 , C11D3/16 , C11D3/39 , C11D3/395 , C11D7/54 , C11D11/00 , D06L3/02
CPC分类号： C07D487/22 , A61K31/40 , C09B47/045 , C09B47/0675 , C09B47/18 , C11D11/0017 , C11D3/0063 , C11D3/168 , C11D3/3932
摘要： The use of substituted phthalocyanines for the generation of singlet oxygen in which at least one of the peripheral carbon atoms in the 1-16 positions of the phthalocyanine nucleus (M.sub.k Pc) of Formula (1): ##STR1## wherein: M is selected from H, metal, halometal, oxymetal and hydroxymetal; and k is the inverse of 1/2 of the valency of M; is linked via an oxygen atom to an aromatic radical and the remaining peripheral carbon atoms are unsubstituted or substituted by any combination of atoms or groups and sulphonated derivatives thereof provided that the phthalocyanine absorbs electromagnetic radiation at a wavelength from 650 nm to 800 nm.
摘要翻译：取代酞菁用于产生其中式（1）的酞菁核的1-16位的末端碳原子（MkPc）中的至少一个的单线态氧：其中：M 选自H，金属，卤素，氧化金属和羟基金属; 并且k是+ E的倒数，f 1的化合价的1/2 + EE; 通过氧原子连接到芳族基团，并且剩余的外围碳原子是未取代的或被原子或基团和磺化衍生物的任何组合取代，条件是酞菁吸收在650nm至800nm的波长的电磁辐射。

7. 发明授权

US5779780A Ink and toner compositions containing a mixture of bis-azo dyes 失效
标题翻译：含有双偶氮染料混合物的油墨和调色剂组合物
公开(公告)号：US5779780A
公开(公告)日：1998-07-14
申请号：US825920
申请日：1997-04-02
申请人： Peter Gregory , John Anthony Taylor
发明人： Peter Gregory , John Anthony Taylor
IPC分类号： C09B62/09 , C09B67/22 , C09D11/00 , D06P5/30 , G03G9/09 , C09D11/02
CPC分类号： C09D11/328 , C09B62/09 , C09B67/0058 , D06P5/30 , G03G9/091
摘要： An ink composition comprising a medium comprising at least one of a low melting point solid, an organic solvent and a mixture of water and one or more water-soluble organic solvent(s); and a mixture of a first, second, third and fourth dye, each of which is of Formula (1) or a salt thereof: ##STR1## wherein: X is a labile or non labile atom or group; A and B are each independently an optionally substituted phenylene group; one or R.sup.1 and R.sup.2 is H and the other is sulpho; one of R.sup.3 and R.sup.4 is H and the other is sulpho; R.sup.5 and R.sup.6 are each independently C.sub.1-4 -alkyl. Also claimed is an ink jet printing process using the inks, a process for ink jet printing textile materials using the inks and a toner containing a mixture of a first, second, third and fourth dyes of the Formula (1).
摘要翻译：一种油墨组合物，其包含包含低熔点固体，有机溶剂和水与一种或多种水溶性有机溶剂的混合物中的至少一种的介质; （1）的第一种，第二种，第三种和第四种染料的混合物或其盐：其中：X是不稳定或非不稳定的原子或基团; A和B各自独立地为任选取代的亚苯基; 一个或R1和R2是H，另一个是磺基; R3和R4之一是H，另一个是磺基; R 5和R 6各自独立地为C 1-4 - 烷基。还要求保护的是使用油墨的喷墨印刷方法，使用该油墨的喷墨印花纺织品的方法和含有式（1）的第一，第二，第三和第四染料的混合物的调色剂。

8. 发明授权

US5756693A Disazo Compound 失效
标题翻译：二唑类化合物
公开(公告)号：US5756693A
公开(公告)日：1998-05-26
申请号：US737613
申请日：1997-01-30
申请人： Ronald Wynford Kenyon , Peter Gregory
发明人： Ronald Wynford Kenyon , Peter Gregory
IPC分类号： B41J2/01 , C09B31/08 , C09D11/00
CPC分类号： C09D11/328 , C09B31/08
摘要： A compound of the Formula (1) and salts thereof: ##STR1## wherein: A is optionally substituted phenyl or optionally substituted naphthyl; R.sup.1 is NR.sup.4 R.sup.5 ; R.sup.2 is H, halo, --COOH, --SO.sub.2 0H, optionally substituted alkyl, optionally substituted alkoxy, or optionally substituted alkylthio; R.sup.3, R.sup.4 & R.sup.5 are each independently H or optionally substituted alkyl; T is H or sulpho; and B is H, optionally substituted alkyl or optionally substituted phenyl; provided that the compound does not contain a piperazinyl group. The compound is suitable for use as a black colorant in ink jet printing inks especially for printing on plain paper.
摘要翻译： PCT No.PCT / GB95 / 01110 Sec。 371日期1997年1月30日 102（e）日期1997年1月30日PCT提交1995年5月17日PCT公布。公开号WO95 / 31505 日期：1995年11月23日一种式（1）化合物及其盐：其中：A为任选取代的苯基或任选取代的萘基; R1为NR4R5; R 2是H，卤素，-COOH，-SO 2 OH，任选取代的烷基，任选取代的烷氧基或任选取代的烷硫基; R 3，R 4和R 5各自独立地为H或任选取代的烷基; T是H或磺基; 且B为H，任选取代的烷基或任选取代的苯基; 条件是该化合物不含哌嗪基。该化合物适合用作喷墨印刷油墨中的黑色着色剂，特别用于在普通纸上印刷。

9. 发明授权

US5730759A Poly-substituted phthalocyanines 失效
标题翻译：聚取代酞菁
公开(公告)号：US5730759A
公开(公告)日：1998-03-24
申请号：US548171
申请日：1995-10-25
申请人： Dean Thetford , Peter Gregory
发明人： Dean Thetford , Peter Gregory
IPC分类号： A61K31/40 , A61K31/409 , A61K31/555 , A61K41/00 , A61K51/00 , A61P35/00 , C07D487/22 , C09B47/04 , C09B47/067 , C09B47/18 , C11D3/00 , C11D3/16 , C11D3/39 , C11D3/395 , C11D7/54 , C11D11/00 , D06L3/02 , D06L3/04
CPC分类号： C07D487/22 , A61K31/40 , C09B47/045 , C09B47/0675 , C09B47/18 , C11D11/0017 , C11D3/0063 , C11D3/168 , C11D3/3932
摘要： The use of substituted phthalocyaines for removing stains from fabrics which comprises treating the stained fabrics with an aqueous composition comprising a phthalocyanine in which at least one of the peripheral carbon atoms in the 1-16 position of the phthalocyanine nucleus (M.sub.k Pc) of Formula (1), ##STR1## wherein: M is selected from H, metal, halometal, oxymetal and hydroxymetal; and k is the inverse of 1/2 the valency of M; is linked via an oxygen atom to an aromatic radical and the remaining peripheral carbon atoms are unsubstituted or substituted by any combination of atoms or groups and sulphonated derivatives thereof provided that the phthalocyanine absorbs electromagnetic radiation at a wavelength from 650 nm to 800 nm.
摘要翻译：使用取代的酞菁素从织物中除去污渍，其中包括用包含酞菁的水性组合物处理染色的织物，其中式（1）的酞菁核的1-16位的至少一个外周碳原子（MkPc）），m H，金属，卤素，氧化金属和羟基金属; 并且k是+ E的倒数，f 1/2 + EE是M的化合价; 通过氧原子连接到芳族基团，并且剩余的外围碳原子是未取代的或被原子或基团和磺化衍生物的任何组合取代，条件是酞菁吸收在650nm至800nm的波长的电磁辐射。

10. 发明授权

US5629417A Phthalocyanines 失效
标题翻译：酞菁
公开(公告)号：US5629417A
公开(公告)日：1997-05-13
申请号：US594412
申请日：1996-01-31
申请人： James S. Campbell , Peter Gregory , Dean Thetford
发明人： James S. Campbell , Peter Gregory , Dean Thetford
IPC分类号： C07D487/22 , C09B47/20 , C09B47/22
CPC分类号： C09B47/20 , C09B47/22
摘要： A phthalocyanine of Formula (1): ##STR1## wherein: M.sub.k PC is a phthalocyanine nucleus of Formula (2): ##STR2## M is a metal atom, a chloro-metal group, and oxy-metal group or hydrogen; k is inverse of 1/2 valency of M; R and R.sup.1 each independently is an organic radical;R.sup.2 is H or optionally substituted alkyl;a is an average value from 15 to 8;b is an average value from 1 to 8; anda+b is from 15 to 16; and sulphonated derivatives thereof and process for their preparation.The phthalocyanines of the present invention are useful for absorbing electro-magnetic radiation from for example a laser source and may be used in a coating for optical data storage disks, or in security applications such as printing banknotes or cheques, or in the preparation of lithographic printing plates or in washing powders to assist in bleaching.
摘要翻译：式（1）的酞菁：式（1）其中：MkPC是式（2）的酞菁核：式（2）M是金属原子，氯 - 金属基和氧 - 金属基团或氢; k为+ E的倒数，为M的1/2 + EE化合价; R和R 1各自独立地为有机基团; R2是H或任选取代的烷基; a是从15到8的平均值; b为1〜8的平均值; a + b为15〜16; 及其磺化衍生物及其制备方法。本发明的酞菁可用于从例如激光源吸收电磁辐射，并且可用于光学数据存储盘的涂层中，或用于诸如印刷纸币或支票的安全应用中，或用于制备光刻印刷板或洗涤粉以帮助漂白。

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