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    • 1. 发明申请
    • Yellow Azo Dyes for Ink Jet Printing
    • 用于喷墨印刷的黄色偶氮染料
    • US20100068472A1
    • 2010-03-18
    • US12083840
    • 2006-10-13
    • Gavin WrightRachel Anne JamesRoy BradburyLynn Patricia Bradbury
    • Gavin WrightRachel Anne JamesRoy BradburyLynn Patricia Bradbury
    • B32B3/10B05D5/00C09D11/00C09B29/36C09B31/14
    • C09B29/3669C09B29/0007C09B29/0014C09B35/03C09D11/328Y10T428/24802
    • Monomers and dimers of mono-azo compounds of formula wherein: D is an optionally substituted aryl or an optionally substituted heteroaryl group; R1 and R2 are each independently optionally substituted alkyl: halo: amino: —NR4R5; wherein R4 is H, optionally substituted alkyl, optionally substituted alkoxy, optionally substituted acyl, optionally substituted aryl, optionally substituted heterocyclyl; and R5 is optionally substituted alkyl, optionally substituted alkoxy, optionally substituted acyl, optionally substituted aryl, optionally substituted heterocyclyl or R4 together with R5 and the nitrogen to which they are attached forms an optionally substituted 5 or 6 membered ring: —OR6; wherein R6 is H or optionally substituted alkyl: or —SR7; wherein R7 is optionally substituted alkyl; R3 is amino: halo; —NR4R5; wherein R4 is H, optionally substituted alkyl, optionally substituted alkoxy, optionally substituted acyl, optionally substituted aryl, optionally substituted heterocyclyl; and R5 is optionally substituted alkyl, optionally substituted alkoxy, optionally substituted acyl, optionally substituted aryl, optionally substituted heterocyclyl or R4 together with R5 and the nitrogen to which they are attached forms an optionally substituted 5 or 6 membered ring: hydroxy: —OR6; wherein R6 is H or optionally substituted alkyl: or —SR7; wherein R7 is optionally substituted alkyl. Also compositions, inks and ink-jet cartridges containing these compounds and ink-jet printing processes using these compounds.
    • 单偶氮和二聚体的单偶氮化合物其中:D是任选取代的芳基或任选取代的杂芳基; R 1和R 2各自独立地是任选取代的烷基:卤素:氨基:-NR 4 R 5; 其中R 4为H,任选取代的烷基,任选取代的烷氧基,任选取代的酰基,任选取代的芳基,任选取代的杂环基; R 5是任选取代的烷基,任选取代的烷氧基,任选取代的酰基,任选取代的芳基,任选取代的杂环基或R 4与R 5一起,它们所连接的氮形成任选取代的5或6元环:-OR 6; 其中R 6是H或任选取代的烷基:或-SR 7; 其中R 7为任选取代的烷基; R3是氨基:卤素; -NR4R5; 其中R 4为H,任选取代的烷基,任选取代的烷氧基,任选取代的酰基,任选取代的芳基,任选取代的杂环基; R 5为任选取代的烷基,任选取代的烷氧基,任选取代的酰基,任选取代的芳基,任选取代的杂环基或R 4与R 5一起并与它们相连的氮形成任选取代的5或6元环:羟基:-OR 6; 其中R 6是H或任选取代的烷基:或-SR 7; 其中R 7是任选取代的烷基。 也包含这些化合物的组合物,油墨和喷墨墨盒以及使用这些化合物的喷墨印刷方法。
    • 2. 发明授权
    • Trisazo-dyestuffs
    • 三唑类染料
    • US07638609B2
    • 2009-12-29
    • US10579783
    • 2004-11-18
    • Prahalad Manibhai MistryRoy Bradbury
    • Prahalad Manibhai MistryRoy Bradbury
    • C09B31/28C09D11/00
    • C09D11/328C09B31/28
    • A compound of Formula (1) or salt thereof: wherein: A is optionally substituted phenyl or naphthyl; B is optionally substituted phenylene or naphthylene; n is 0 or 1; and D is a pyrazolyl group, with the proviso that when A is an optionally substituted phenyl group and B is a phenylene group of Formula T, wherein Ra is OH or a C1-4-alkoxy group; and Rb is H or a C1-4-alkyl group, hydroxy group, C1-4-alkoxy group, C1-3-dialkyamino group or a group of the formula NHCORc (wherein Rc is C1-3-alkyl or an amino group); and * shows the point of attachment to the azo linkages on B in Formula (1); A is free from nitro groups. Also, claimed are compounds, compositions and ink-jet cartridges for use in an ink-jet printer and substrate printed with an ink-jet printer.
    • 式(1)的化合物或其盐:其中:A为任选取代的苯基或萘基; B是任选取代的亚苯基或亚萘基; n为0或1; 并且D是吡唑基,条件是当A是任选取代的苯基且B是式T的亚苯基时,其中R a是OH或C 1-4 - 烷氧基; 和R b是H或C 1-4 - 烷基,羟基,C 1-4 - 烷氧基,C 1-3 - 二氨基或式NHCORc基团(其中R c是C 1-3 - 烷基或氨基) ; 和*表示式(1)中B上偶氮键的连接点; A不含硝基。 此外,要求的是用于喷墨打印机的化合物,组合物和喷墨盒以及用喷墨打印机印刷的基材。
    • 4. 发明申请
    • Trisazo-dyestuffs
    • 三唑类染料
    • US20070062409A1
    • 2007-03-22
    • US10579783
    • 2004-11-18
    • Prahalad MistryRoy Bradbury
    • Prahalad MistryRoy Bradbury
    • C09B29/46B41J2/01
    • C09D11/328C09B31/28
    • A compound of Formula (1) or salt thereof: wherein: A is optionally substituted phenyl or naphthyl; B is optionally substituted phenylene or naphthylene; n is 0 or 1; and D is a pyrazolyl group, with the proviso that when A is an optionally substituted phenyl group and B is a phenylene group of Formula T, wherein Ra is OH or a C1-4-alkoxy group; and Rb is H or a C1-4-alkyl group, hydroxy group, C1-4-alkoxy group, C1-3-dialkyamino group or a group of the formula NHCORc (wherein Rc is C1-3-alkyl or an amino group); and * shows the point of attachment to the azo linkages on B in Formula (1); A is free from nitro groups. Also, claimed are compounds, compositions and ink-jet cartridges for use in an ink-jet printer and substrate printed with an ink-jet printer.
    • 式(1)的化合物或其盐:其中:A为任选取代的苯基或萘基; B是任选取代的亚苯基或亚萘基; n为0或1; 并且D是吡唑基,条件是当A是任选取代的苯基且B是式T的亚苯基时,其中R a是OH或C 1-4烷氧基; 且R b为H或C 1-4烷基,羟基,C 1-4烷氧基,C 1-3烷基, 二烷基氨基或式NHCORc基团(其中R c为C 1-3烷基或氨基); 和*表示式(1)中B上偶氮键的连接点; A不含硝基。 此外,要求的是用于喷墨打印机的化合物,组合物和喷墨盒以及用喷墨打印机印刷的基材。
    • 8. 发明授权
    • AZO dyes and compositions comprising such dyes
    • AZO染料和包含这种染料的组合物
    • US06290763B1
    • 2001-09-18
    • US09269061
    • 1999-03-18
    • Christine MillardPeter GregoryRoy Bradbury
    • Christine MillardPeter GregoryRoy Bradbury
    • C09D1102
    • C09D11/328C09B43/16
    • Azo dyes of Formula (1) have utility as dyes for ink-jet printing, where Formula (1) represents: which comprises any suitable form of the compound: such as salt; stereoisomer, zwitterion, polymorph, complex, isotopic form, combinations thereof in the same species and mixtures thereof; where: n represents from 1 to 5 inclusive; R1, R1B, R4 and R4B each independently comprises at least one of the following substituents, optionally substituted: H, C1-8alkyl; C1-8,alkoxy; —NHCOH, C1-8alkylcarbonylamino; and —NHCONR5R6 where R5 and R6 each independently comprises at least one of the following substituents: H, C1-8alkyl and aryl; and R2 and R3 each independently comprises at least one of the following substituents, optionally substituted: H; C1-8alkoxy; -NHC1-8alkyleneOH, —SC1-8-alkyleneSO3H; -NHC1-8alkyleneN(C1-8alkyl)2; where X comprises one of the following: —NHC1-8alkylene; —NHphenylSO2NHC1-8alkylene; and a direct link, where X comprises one of the following: —NHC1-8alkylene; —NHphenylSO2NHC1-8alkylene; and a direct link; a moiety of Formula (2) where m and p is each independently from 0 to 5 inclusive, provided that (m+p) is from 1 to 5 inclusive; and R1A, R2A, R4A and R4C each independently comprises at least one of those optionally substituted substituents as defined herein for R1, R2, R4 and R4B respectively; and any other suitable labile or non-labile substituent not mentioned above; where the optional substituents herein comprise: C1-4alkyl (optionally substituted with at least one halo)., C1-4alkoxy (optionally substituted with at least one halo), carboxy, sulpho, hydroxy, amino, mercapto, cyano, nitro and halo.
    • 式(1)的偶氮染料可用作喷墨印刷用染料,其中式(1)表示:其包含任何合适形式的化合物:例如盐; 立体异构体,两性离子,多晶型物,复合物,同位素形式,它们在同一物种及其混合物中的组合; 其中:n表示1〜5; R1,R1B,R4和R4B各自独立地包含至少一个以下取代基,任选被取代:H,C 1-8烷基; C 1-8,烷氧基; -NHCOH,C 1-8烷基羰基氨基; 和-NHCONR 5 R 6,其中R 5和R 6各自独立地包含以下取代基中的至少一个:H,C 1-8烷基和芳基; 且R 2和R 3各自独立地包含至少一个以下取代基,任选地被取代:H; C 1-8烷氧基 -NHC1-8亚烷基OH,-SC1-8-亚烷基SO3H; -NHC1-8亚烷基N(C1-8烷基)2;其中X包括以下之一:-NHC1-8亚烷基; -NH 2 SO 2 NHC 1-8亚烷基; 和直链,其中X包含以下之一:-NHC1-8亚烷基; -NH 2 SO 2 NHC 1-8亚烷基; 和直链;式(2)的部分,其中m和p各自独立地为0至5,其中(m + p)为1至5(包括端值); R1A,R2A,R4A和R4C各自独立地包含至少一种如本文定义的对于R 1,R 2,R 4和R 4B定义的那些取代的取代基; 以及上文未提及的其他合适的不稳定或非不稳定取代基; 其中本文的任选取代基包括:C 1-4烷基(任选被至少一个卤素取代),C 1-4烷氧基(任选被至少一个卤素取代),羧基,磺基,羟基,氨基,巯基,氰基,硝基和卤素。