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    • 9. 发明授权
    • Fuel cell nanocatalyst with voltage reversal tolerance
    • 具有电压反转容限的燃料电池纳米催化剂
    • US08637193B2
    • 2014-01-28
    • US12546775
    • 2009-08-25
    • Andrew J. L. SteinbachGeorge D. VernstromMark K. DebeRadoslav Atanasoski
    • Andrew J. L. SteinbachGeorge D. VernstromMark K. DebeRadoslav Atanasoski
    • H01M8/00H01M4/02H01M4/36H01M4/62H01M4/92B01J23/00B01J21/00
    • H01M4/8657H01M4/92H01M2008/1095
    • In some embodiments, the present disclosure provides a fuel cell catalyst having a catalyst surface bearing a non-occluding layer of iridium. In some embodiments, the present disclosure provides a fuel cell catalyst comprising a catalyst surface bearing a sub-monolayer of iridium. In some embodiments, the present disclosure provides a fuel cell catalyst comprising a catalyst surface bearing a layer of iridium having a planar equivalent thickness of between 1 and 100 Angstroms. In some embodiments, the fuel cell catalyst comprises nanostructured elements comprising microstructured support whiskers bearing a thin film of nanoscopic catalyst particles. The layer of iridium typically has a planar equivalent thickness of between 1 and 100 Angstroms and more typically between 5 and 60 Angstroms. The fuel cell catalyst typically comprises no electrically conductive carbon material and typically comprises at least a portion of the iridium in the zero oxidation state.
    • 在一些实施方案中,本公开提供了具有带有非阻挡层铱的催化剂表面的燃料电池催化剂。 在一些实施方案中,本公开提供了一种燃料电池催化剂,其包含具有铱的亚单层的催化剂表面。 在一些实施方案中,本公开内容提供了一种燃料电池催化剂,其包含具有平面当量厚度为1至100埃的铱层的催化剂表面。 在一些实施方案中,燃料电池催化剂包含纳米结构元素,其包含具有纳米级催化剂颗粒薄膜的微结构化支撑晶须。 铱层通常具有1至100埃的平面当量厚度,更典型地在5至60埃之间。 燃料电池催化剂通常不包括导电碳材料,并且通常包含处于零氧化状态的铱的至少一部分。
    • 10. 发明授权
    • Platinum nickel catalyst alloy
    • 铂镍催化剂合金
    • US08557484B2
    • 2013-10-15
    • US13643353
    • 2011-04-26
    • Mark K. DebeGeorge D. VernstromAndrew J. L. Steinbach
    • Mark K. DebeGeorge D. VernstromAndrew J. L. Steinbach
    • H01M4/02H01M4/36H01M4/92
    • C22C30/00C22C5/04C22C19/03
    • A Pt—Ni catalyst is provided which demonstrates an unusually high oxygen reduction mass activity. In some embodiments, the Pt—Ni catalyst is a Pt—Ni binary alloy. In some embodiments, the catalyst may be characterized as having a Pt fcc lattice parameter of less than 3.71 Angstroms or 0.371 nm. In some embodiments the catalyst has a Pt fcc lattice parameter of between 3.69 Angstroms (or 0.369 nm) and 3.73 Angstroms (or 0.373 nm). In some embodiments, the catalyst may be characterized as having a composition of close to PtxNi(1-x), where x is between 0.2 and 0.4. In some embodiments the catalyst comprises nanostructured elements comprising microstructured support whiskers bearing a thin film of nanoscopic catalyst particles comprising a catalyst material described above. The catalyst may be particularly useful as a fuel cell catalyst and more specifically as a fuel cell cathode catalyst.
    • 提供了Pt-Ni催化剂,其表现出异常高的氧还原质量活性。 在一些实施方案中,Pt-Ni催化剂是Pt-Ni二元合金。 在一些实施方案中,催化剂的特征在于具有小于3.71埃或0.371nm的Pt fcc晶格参数。 在一些实施方案中,催化剂具有3.69埃(或0.369nm)和3.73埃(或0.373nm)之间的Pt fcc晶格参数。 在一些实施方案中,催化剂的特征在于具有接近PtxNi(1-x)的组成,其中x在0.2和0.4之间。 在一些实施方案中,催化剂包含纳米结构元素,其包含微结构化支撑晶须,其载有包含上述催化剂材料的纳米级催化剂颗粒的薄膜。 催化剂可以特别用作燃料电池催化剂,更具体地可用作燃料电池阴极催化剂。