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    • 1. 发明授权
    • Method for manufacturing fluoroelastomers
    • 含氟弹性体的制造方法
    • US09260543B2
    • 2016-02-16
    • US13516118
    • 2010-12-16
    • Marco ApostoloRiccardo PieriLiubov Chernysheva
    • Marco ApostoloRiccardo PieriLiubov Chernysheva
    • C08F14/18
    • C08F14/18C08F2/16C08F2/22C08F2/26C08F2/24
    • A process for manufacturing a (per)fluoroelastomer having a heat of fusion of less than 5 J/g as measured by ASTM D-3418-08, comprising polymerizing at least one fluorinated monomer in the presence of at least one initiator in a polymerization medium comprising: (A) water; (B) at least one fluorinated surfactant [surfactant (FS)] having formula (I) here below, wherein: X1, X2 and X3, equal to or different from each other, are independently selected from the group consisting of H, F and C1-C6 (per)fluoroalkyl groups, optionally comprising one or more catenary or non-catenary oxygen atoms, RF represents a divalent perfluorinated C1-C3 bridging group, L represents a bond or a divalent group and Y represents a hydrophilic functionality selected from anionic functionalities, cationic functionalities and non-ionic functionalities; (C) at least one fluorinated compound [compound (F)] different from surfactant (FS); wherein said polymerization medium has a pH value of less than 7.
    • 根据ASTM D-3418-08测定的具有小于5J / g的熔化热的(全)含氟弹性体的方法,包括在至少一种引发剂存在下在聚合介质中聚合至少一种氟化单体 包括:(A)水; (B)至少一种具有式(I)的氟化表面活性剂[表面活性剂(FS)],其中:X 1,X 2和X 3彼此相同或不同,独立地选自H,F和 任选地包含一个或多个悬链或非链状氧原子的C 1 -C 6(全)氟烷基,RF表示二价全氟化的C 1 -C 3桥连基团,L表示键或二价基团,Y表示选自阴离子 官能度,阳离子官能度和非离子官能度; (C)与表面活性剂(FS)不同的至少一种氟化化合物[化合物(F)]; 其中所述聚合介质的pH值小于7。
    • 2. 发明申请
    • Method for manufacturing fluoroelastomers
    • 含氟弹性体的制造方法
    • US20120252970A1
    • 2012-10-04
    • US13516118
    • 2010-12-16
    • Marco ApostoloRiccardo PieriLiubov Chernysheva
    • Marco ApostoloRiccardo PieriLiubov Chernysheva
    • C08L19/02
    • C08F14/18C08F2/16C08F2/22C08F2/26C08F2/24
    • A process for manufacturing a (per)fluoroelastomer having a heat of fusion of less than 5 J/g as measured by ASTM D-3418-08, comprising polymerizing at least one fluorinated monomer in the presence of at least one initiator in a polymerization medium comprising: (A) water; (B) at least one fluorinated surfactant [surfactant (FS)] having formula (I) here below, wherein: X1, X2 and X3, equal to or different from each other, are independently selected from the group consisting of H, F and C1-C6 (per)fluoroalkyl groups, optionally comprising one or more catenary or non-catenary oxygen atoms, RF represents a divalent perfluorinated C1-C3 bridging group, L represents a bond or a divalent group and Y represents a hydrophilic functionality selected from anionic functionalities, cationic functionalities and non-ionic functionalities; (C) at least one fluorinated compound [compound (F)] different from surfactant (FS); wherein said polymerization medium has a pH value of less than 7.
    • 根据ASTM D-3418-08测定的具有小于5J / g的熔化热的(全)含氟弹性体的方法,包括在至少一种引发剂的存在下在聚合介质中聚合至少一种氟化单体 包括:(A)水; (B)至少一种具有式(I)的氟化表面活性剂[表面活性剂(FS)],其中:X 1,X 2和X 3彼此相同或不同,独立地选自H,F和 任选地包含一个或多个悬链或非链状氧原子的C 1 -C 6(全)氟烷基,RF表示二价全氟化的C 1 -C 3桥连基团,L表示键或二价基团,Y表示选自阴离子 官能度,阳离子官能度和非离子官能度; (C)与表面活性剂(FS)不同的至少一种氟化化合物[化合物(F)]; 其中所述聚合介质的pH值小于7。
    • 3. 发明申请
    • Method for Manufacturing Fluoropolymers
    • 氟聚合物的制造方法
    • US20120283383A1
    • 2012-11-08
    • US13515973
    • 2010-12-16
    • Riccardo PieriValeri KapeliouchkoLiubov Chernysheva
    • Riccardo PieriValeri KapeliouchkoLiubov Chernysheva
    • C08L27/18C07C51/42C08K5/06C09K3/00
    • C08F6/14C08F14/18C08L27/12C08F2/24C08F2/32
    • The invention pertains to a process for manufacturing a (per)fluoropolymer, said process comprising polymerizing one or more fluorinated monomers in the presence of a multi-phase medium, said medium comprising: (A) a water phase [phase (W)]; (B) at least one fluorinated surfactant [surfactant (FS)] having formula (I) here below: Rf—(OCF2CF2)k-1—O—CF2—COOXa  (I) wherein Rf is a C1-C3 perfluoroalkyl group comprising, optionally, one or more ether oxygen atoms, k is 2 or 3 and Xa is a selected from a monovalent metal and an ammonium group of formula NRN4, wherein RN, equal or different at each occurrence, is a hydrogen atom or a C1-C3 alkyl group; (C) an oil phase [phase (O)] comprising: at least one non-functional (per)fluoropolyether (non-functional PFPE) comprising at least one (per)fluoropolyoxyalkylene chain [chain (RF)] and at least one functional (per)fluoropolyether (functional PFPE) comprising at least one (per)fluoropolyoxyalkylene chain [chain (R′F)] and having a number average molecular weight of at least 1000 and a solubility of less than 1% by weight in water at 25° C.
    • 本发明涉及制备(全)含氟聚合物的方法,所述方法包括在多相介质存在下聚合一种或多种氟化单体,所述介质包括:(A)水相[相(W)]; (B)至少一种具有式(I)的氟化表面活性剂(表面活性剂(FS)):Rf-(OCF2CF2)k-1-O-CF2-COOXa(Ⅰ)其中Rf是C1-C3全氟烷基, 任选地,一个或多个醚氧原子,k为2或3,Xa为选自式NRN4的一价金属和铵基团,其中每次出现时相同或不同的RN为氢原子或C1-C3 烷基; (C)油相[相(O)],其包含:至少一种包含至少一种(全)氟聚氧亚烷基链[链(RF)]的至少一种非官能(全)氟聚醚(非功能性PFPE) 包含至少一种(全)氟聚氧亚烷基链[链(R'F)]并且具有至少1000的数均分子量和小于1重量%在水中的溶解度为25的(全)氟聚醚(功能性PFPE) C。