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    • 2. 发明授权
    • Light weight rubber composition containing clay
    • 轻质橡胶组合物含有粘土
    • US07055566B2
    • 2006-06-06
    • US10923071
    • 2004-08-20
    • Manoj AjbaniWen-Liang HsuAdel Farhan HalasaGinger LeeEric Sean Castner
    • Manoj AjbaniWen-Liang HsuAdel Farhan HalasaGinger LeeEric Sean Castner
    • B60C11/00B60C27/00B60C1/00
    • C08K3/346C08K9/04Y10S152/905C08L19/006
    • This invention relates to a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads; wherein said tread is adapted to be ground-contacting; wherein the tread is comprised of: (1) an amino group containing rubbery polymer, wherein said amino group containing rubbery polymer contains from about 0.1 weight percent to about 20 weight percent monomer units containing an amino group, (2) from 0.1 to about 25 phr of an organophilic 2:1 layered silicate clay selected from the group consisting of montmorillonite clays, bentonite clays, hectorite clays, saponite clays, nontronite clays, beidellite clays, fluorohectorite clays, stevensite clays, volkonskoite clays, sauconite clays, and laponite clays, and (3) a silica coupling agent.
    • 本发明涉及一种轮胎,该轮胎由具有外周胎面的大致环形胎体,两个间隔开的胎圈,从胎圈到胎圈延伸的至少一个帘布层以及从所述胎面径向延伸并将所述胎面连接到所述胎圈的侧壁构成; 其中所述胎面适于与地面接触; 其中所述胎面由以下组成:(1)含氨基的橡胶状聚合物,其中所述含氨基的橡胶状聚合物含有约0.1重量%至约20重量%的含有氨基的单体单元,(2)0.1至约25 选自蒙脱石粘土,膨润土,锂蒙脱石粘土,皂石粘土,白云石粘土,贝得石粘土,氟代锂蒙脱石粘土,硬石榴石粘土,膨润土,粘土,松节油粘土等亲水性2:1层状硅酸盐粘土, 和(3)二氧化硅偶联剂。
    • 3. 发明授权
    • Process for making light weight rubber composition containing clay
    • 制造含有粘土的轻质橡胶组合物的方法
    • US06884835B2
    • 2005-04-26
    • US10783135
    • 2004-02-20
    • Manoj AjbaniWen-Liang HsuAdel Farhan HalasaGinger LeeEric Sean Castner
    • Manoj AjbaniWen-Liang HsuAdel Farhan HalasaGinger LeeEric Sean Castner
    • B60C1/00C08K3/04C08K3/34C08K5/54C08K7/00C08K9/04C08L21/00C08K3/36
    • C08K3/346C08K9/04Y10S152/905C08L19/006
    • This invention relates to a process for making a vulcanized rubber article comprising the steps of (1) kneading at a temperature within the range of about 70° C. to about 190° C. in a bulk thermomechanical mixer (a) an amino group containing rubbery polymer, wherein said amino group containing rubbery polymer contains from about 0.1 weight percent to about 20 weight percent monomer units containing an amino group, (b) from 0.1 to about 25 phr of an organophilic 2:1 layered silicate clay selected from the group consisting of montmorillonite clays, bentonite clays, hectorite clays, saponite clays, nontronite clays, beidellite clays, fluorohectorite clays, stevensite clays, volkonskoite clays, sauconite clays, and laponite clays, and (c) at least one conventional rubber compounding ingredient selected from the group consisting of curing agents, cure accelerators, cure activators, processing aids, reinforcing fillers, oils, cure retarders, resins, and antidegradants, to produce a mixed compound; (2) discharging the said mixed compound from the bulk thermomechanical mixer; (3) forming the mixed compound into an article; and (4) vulcanizing the article.
    • 本发明涉及一种硫化橡胶制品的制造方法,其包括以下步骤:(1)在体积热机械混合器(a)中在约70℃至约190℃的温度范围内捏合含氨基 橡胶质聚合物,其中所述含氨基的橡胶状聚合物含有约0.1重量%至约20重量%的含氨基的单体单元,(b)0.1至约25phr的有机亲水性2:1层状硅酸盐粘土,其选自 由蒙脱石粘土,膨润土,锂蒙脱石粘土,皂石粘土,白云石粘土,白垩纪粘土,氟代锂蒙脱石粘土,滑石岩粘土,膨润土粘土,松香石粘土和锂皂石粘土组成,和(c)至少一种常规的橡胶配混成分, 由固化剂,固化促进剂,固化活化剂,加工助剂,增强填料,油,固化缓凝剂,树脂和抗降解剂组成的组,以产生混合c ; (2)从本体热机械混合器排出所述混合化合物; (3)将混合的化合物形成制品; 和(4)硫化该制品。
    • 4. 发明申请
    • Light weight rubber composition containing clay
    • 轻质橡胶组合物含有粘土
    • US20050020753A1
    • 2005-01-27
    • US10923071
    • 2004-08-20
    • Manoj AjbaniWen-Liang HsuAdel HalasaGinger LeeEric Castner
    • Manoj AjbaniWen-Liang HsuAdel HalasaGinger LeeEric Castner
    • B60C1/00C08K3/04C08K3/34C08K5/54C08K7/00C08K9/04C08L21/00C08F36/14
    • C08K3/346C08K9/04Y10S152/905C08L19/006
    • This invention relates to a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads; wherein said tread is adapted to be ground-contacting; wherein the tread is comprised of: (1) an amino group containing rubbery polymer, wherein said amino group containing rubbery polymer contains from about 0.1 weight percent to about 20 weight percent monomer units containing an amino group, (2) from 0.1 to about 25 phr of an organophilic 2:1 layered silicate clay selected from the group consisting of montmorillonite clays, bentonite clays, hectorite clays, saponite clays, nontronite clays, beidellite clays, fluorohectorite clays, stevensite clays, volkonskoite clays, sauconite clays, and laponite clays, and (3) a silica coupling agent.
    • 本发明涉及一种轮胎,该轮胎由具有外周胎面的大致环形胎体,两个间隔开的胎圈,从胎圈到胎圈延伸的至少一个帘布层以及从所述胎面径向延伸并将所述胎面连接到所述胎圈的侧壁构成; 其中所述胎面适于与地面接触; 其中所述胎面由以下组成:(1)含氨基的橡胶状聚合物,其中所述含氨基的橡胶状聚合物含有约0.1重量%至约20重量%的含有氨基的单体单元,(2)0.1至约25 选自蒙脱石粘土,膨润土,锂蒙脱石粘土,皂石粘土,白云石粘土,贝得石粘土,氟代锂蒙脱石粘土,硬石榴石粘土,膨润土,粘土,松节油粘土等亲水性2:1层状硅酸盐粘土, 和(3)二氧化硅偶联剂。
    • 6. 发明授权
    • Polymeric composition for seals and gaskets
    • 用于密封和垫圈的聚合物组合物
    • US07560504B2
    • 2009-07-14
    • US12249000
    • 2008-10-10
    • Manoj AjbaniChristopher KiehlThierry Florent Edme Materne
    • Manoj AjbaniChristopher KiehlThierry Florent Edme Materne
    • C08F2/00
    • C08L23/16C08L9/02C08L9/06C08L15/00C08L15/005C08L21/00C08L23/10C08L23/12C08L23/14C08L25/00C08L53/005C08L53/02C08L53/025C08L71/12C08L91/00C08L2205/02C08L2205/03C08L2205/035C08L2312/00Y10T428/31826Y10T428/31931Y10T428/31935C08L2666/24C08L2666/06C08L2666/02C08L2666/08C08L2666/04
    • The present invention relates to a polymeric composition which has an excellent combination of properties for use in making seals and gaskets for utilization in appliances, automotive applications, and building applications, such as window glazing gaskets. These polymeric compositions offer excellent dimensional stability, low compression set, outstanding sealing characteristics, low temperature flexibility, heat resistance and ultra-violet light resistance. The present invention more specifically discloses a polymeric composition having excellent characteristics for utilization in manufacturing seals and gaskets including dimensional stability, low compression set and outstanding sealing characteristics, said polymeric composition being comprised of a blend of (A) a thermoplastic resin selected from the group consisting of polypropylene, polyethylene, poly phenylene ether polystyrene, and styrene containing copolymer resins, (B) an elastomeric polymer selected from the group consisting of block copolymer comprising a first polymeric block that is comprised of repeat units that are derived from a vinyl aromatic monomer and a second block that is comprised of repeat units that are derived from a conjugated diolefin monomer, wherein the repeat units in the second block are hydrogenated, and wherein the repeat units in the second block are elastomeric in nature, and a crosslinked olefinic elastomer, (C) a high molecular weight crosslinked diene elastomer comprised of repeat units that are derived from conjugated diene monomer selected from the group consisting of 1,3-butadiene and isoprene, wherein the high molecular weight diene elastomer has a weight average molecular weight of at least about 200,000, and (D) an oil.
    • 本发明涉及一种聚合物组合物,其具有用于制造用于制造密封件的特性和用于家用电器,汽车应用以及建筑应用(例如窗玻璃垫片)的垫圈的优异组合。 这些聚合物组合物具有优异的尺寸稳定性,低压缩永久变形,优异的密封特性,低温柔韧性,耐热性和耐紫外光性。 本发明更具体地公开了一种聚合物组合物,其具有用于制造密封件和垫片的优异特性,包括尺寸稳定性,低压缩永久变形和优异的密封特性,所述聚合物组合物由(A)选自组 由聚丙烯,聚乙烯,聚苯醚聚苯乙烯和含苯乙烯的共聚物树脂组成的弹性体聚合物,(B)弹性体聚合物,其选自由包含衍生自乙烯基芳族单体的重复单元组成的第一聚合物嵌段的嵌段共聚物 以及由衍生自共轭二烯烃单体的重复单元组成的第二嵌段,其中第二嵌段中的重复单元被氢化,并且其中第二嵌段中的重复单元本质上是弹性体,并且交联的烯属弹性体, (C)高分子量交联模头 由高分子量二烯弹性体的重均分子量至少约为20万的衍生自共轭二烯单体的1,3-丁二烯和异戊二烯衍生的重复单元组成的弹性体,和(D) 一种油
    • 9. 发明申请
    • Polymeric composition for seals and gaskets
    • 用于密封和垫圈的聚合物组合物
    • US20050182193A1
    • 2005-08-18
    • US11052703
    • 2005-02-07
    • Manoj AjbaniChristopher KiehlThierry Materne
    • Manoj AjbaniChristopher KiehlThierry Materne
    • C08L9/02C08L9/06C08L15/00C08L23/10C08L23/16C08L25/00C08L53/00C08L53/02C08L71/12
    • C08L23/16C08L9/02C08L9/06C08L15/00C08L15/005C08L21/00C08L23/10C08L23/12C08L23/14C08L25/00C08L53/005C08L53/02C08L53/025C08L71/12C08L91/00C08L2205/02C08L2205/03C08L2205/035C08L2312/00Y10T428/31826Y10T428/31931Y10T428/31935C08L2666/24C08L2666/06C08L2666/02C08L2666/08C08L2666/04
    • The present invention relates to a polymeric composition which has an excellent combination of properties for use in making seals and gaskets for utilization in appliances, automotive applications, and building applications, such as window glazing gaskets. These polymeric compositions offer excellent dimensional stability, low compression set, outstanding sealing characteristics, low temperature flexibility, heat resistance and ultra-violet light resistance. The present invention more specifically discloses a polymeric composition having excellent characteristics for utilization in manufacturing seals and gaskets including dimensional stability, low compression set and outstanding sealing characteristics, said polymeric composition being comprised of a blend of (A) a thermoplastic resin selected from the group consisting of polypropylene, polyethylene, poly phenylene ether, polystyrene, and styrene containing copolymer resins, (B) an elastomeric polymer selected from the group consisting of block copolymer comprising a first polymeric block that is comprised of repeat units that are derived from a vinyl aromatic monomer and a second block that is comprised of repeat units that are derived from a conjugated diolefin monomer, wherein the repeat units in the second block are hydrogenated, and wherein the repeat units in the second block are elastomeric in nature, and a crosslinked olefinic elastomer, (C) a high molecular weight crosslinked diene elastomer comprised of repeat units that are derived from conjugated diene monomer selected from the group consisting of 1,3-butadiene and isoprene, wherein the high molecular weight diene elastomer has a weight average molecular weight of at least about 200,000, and (D) an oil.
    • 本发明涉及一种聚合物组合物,其具有用于制造用于制造密封件的特性和用于家用电器,汽车应用以及建筑应用(例如窗玻璃垫片)的垫圈的优异组合。 这些聚合物组合物具有优异的尺寸稳定性,低压缩永久变形,优异的密封特性,低温柔韧性,耐热性和耐紫外光性。 本发明更具体地公开了一种聚合物组合物,其具有用于制造密封件和垫片的优异特性,包括尺寸稳定性,低压缩永久变形和优异的密封特性,所述聚合物组合物由(A)选自组 由聚丙烯,聚乙烯,聚苯醚,聚苯乙烯和含苯乙烯的共聚物树脂组成的弹性体聚合物,(B)弹性体聚合物,其选自由包含衍生自乙烯基芳族化合物的重复单元组成的第一聚合物嵌段的嵌段共聚物 单体和由衍生自共轭二烯烃单体的重复单元组成的第二嵌段,其中第二嵌段中的重复单元被氢化,并且其中第二嵌段中的重复单元本质上是弹性体,并且交联的烯属弹性体 ,(C)高分子量交联二 烯属弹性体由衍生自选自1,3-丁二烯和异戊二烯的共轭二烯单体的重复单元组成,其中高分子量二烯弹性体的重均分子量为至少约20万,(D) 一种油
    • 10. 发明授权
    • Thermoplastic elastomer composition
    • 热塑性弹性体组合物
    • US07485682B2
    • 2009-02-03
    • US11268037
    • 2005-11-07
    • Manoj AjbaniChristopher KiehlLawson Gibson WidemanRajesh Varma
    • Manoj AjbaniChristopher KiehlLawson Gibson WidemanRajesh Varma
    • C08L53/00
    • C08L53/005C08L53/025C08L2666/04
    • The present invention relates to a soft thermoplastic elastomer composition that is free of thermoplastic resin that can be utilized in manufacturing shoe sole inserts, seals, gaskets, wheels, and that can be overmolded on a hard substrate, such as a metal or a thermoplastic resin, for grips or handles on various household items. The present invention more specifically discloses a thermoplastic elastomer composition that is made by a process comprising: (1) mixing (A) a block copolymer comprising a first polymeric block that is comprised of repeat units that are derived from a vinyl aromatic monomer and a second block that is comprised of repeat units that are derived from a conjugated diolefin monomer, wherein the repeat units in the second block are hydrogenated, and wherein the repeat units in the second block are elastomeric in nature, (B) a crosslinkable elastomer, and (C) an oil, to produce an un-crosslinked three component blend; and (2) dynamically crosslinking the crosslinkable elastomer in the un-crosslinked three component blend during a thermo-mechanical mixing step; wherein the thermoplastic elastomer composition is void of thermoplastic resins.
    • 本发明涉及一种不含热塑性树脂的软质热塑性弹性体组合物,其可用于制造鞋底插入件,密封件,垫圈,轮子,并且可以包覆成型在硬质基材如金属或热塑性树脂上 ,用于各种家居用品上的把手或手柄。 本发明更具体地公开了一种热塑性弹性体组合物,其通过以下方法制备,该方法包括:(1)混合(A)包含第一聚合物嵌段的嵌段共聚物,所述第一聚合物嵌段由衍生自乙烯基芳族单体的重复单元组成, 其包含衍生自共轭二烯单体的重复单元,其中第二嵌段中的重复单元被氢化,并且其中第二嵌段中的重复单元本质上是弹性体,(B)可交联的弹性体和( C)油,以产生未交联的三组分共混物; 和(2)在热机械混合步骤期间动态交联未交联的三组分共混物中的可交联弹性体; 其中所述热塑性弹性体组合物不含热塑性树脂。