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    • 2. 发明授权
    • Thermoplastic elastomer composition
    • 热塑性弹性体组合物
    • US07485682B2
    • 2009-02-03
    • US11268037
    • 2005-11-07
    • Manoj AjbaniChristopher KiehlLawson Gibson WidemanRajesh Varma
    • Manoj AjbaniChristopher KiehlLawson Gibson WidemanRajesh Varma
    • C08L53/00
    • C08L53/005C08L53/025C08L2666/04
    • The present invention relates to a soft thermoplastic elastomer composition that is free of thermoplastic resin that can be utilized in manufacturing shoe sole inserts, seals, gaskets, wheels, and that can be overmolded on a hard substrate, such as a metal or a thermoplastic resin, for grips or handles on various household items. The present invention more specifically discloses a thermoplastic elastomer composition that is made by a process comprising: (1) mixing (A) a block copolymer comprising a first polymeric block that is comprised of repeat units that are derived from a vinyl aromatic monomer and a second block that is comprised of repeat units that are derived from a conjugated diolefin monomer, wherein the repeat units in the second block are hydrogenated, and wherein the repeat units in the second block are elastomeric in nature, (B) a crosslinkable elastomer, and (C) an oil, to produce an un-crosslinked three component blend; and (2) dynamically crosslinking the crosslinkable elastomer in the un-crosslinked three component blend during a thermo-mechanical mixing step; wherein the thermoplastic elastomer composition is void of thermoplastic resins.
    • 本发明涉及一种不含热塑性树脂的软质热塑性弹性体组合物,其可用于制造鞋底插入件,密封件,垫圈,轮子,并且可以包覆成型在硬质基材如金属或热塑性树脂上 ,用于各种家居用品上的把手或手柄。 本发明更具体地公开了一种热塑性弹性体组合物,其通过以下方法制备,该方法包括:(1)混合(A)包含第一聚合物嵌段的嵌段共聚物,所述第一聚合物嵌段由衍生自乙烯基芳族单体的重复单元组成, 其包含衍生自共轭二烯单体的重复单元,其中第二嵌段中的重复单元被氢化,并且其中第二嵌段中的重复单元本质上是弹性体,(B)可交联的弹性体和( C)油,以产生未交联的三组分共混物; 和(2)在热机械混合步骤期间动态交联未交联的三组分共混物中的可交联弹性体; 其中所述热塑性弹性体组合物不含热塑性树脂。
    • 3. 发明授权
    • Liquid polymer
    • 液体聚合物
    • US08030397B2
    • 2011-10-04
    • US12263504
    • 2008-11-02
    • Michael Joseph RachitaVanessa Marika GuscoffLawson Gibson Wideman
    • Michael Joseph RachitaVanessa Marika GuscoffLawson Gibson Wideman
    • A61K9/16B60C1/00C08L9/00C07C211/00
    • B29C67/246B29B7/7495C08C19/25C08C19/30C08K5/5419C08L19/006
    • This invention discloses a process for manufacturing an elastomeric article by liquid injection molding, said process comprising the steps of: (I) heating a curable composition comprised of (1) a liquid polymer comprised of repeat units that are derived from a conjugated diolefin monomer, wherein said liquid polymer has a weight average molecular weight which is within the range of 5,000 to 100,000, and wherein the liquid polymer is functionalized with an amine moiety, (2) a carbonyl inhibited platinum catalyst, and (3) a tetrakis(dialkyl siloxy) silane crosslinking agent, to a temperature which is within the range of 30° C. to 100° C.; (II) injecting the heated curable composition into a mold at a temperature which is within the range of 100° C. to 210° C. to produce the elastomeric article; and (III) removing the elastomeric article from the mold.
    • 本发明公开了一种通过液体注射成型制造弹性制品的方法,所述方法包括以下步骤:(I)加热可固化组合物,其包含(1)由衍生自共轭二烯烃单体的重复单元组成的液体聚合物, 其中所述液体聚合物的重均分子量在5,000至100,000的范围内,并且其中所述液体聚合物用胺部分官能化,(2)羰基抑制铂催化剂,和(3)四(二烷基甲硅烷氧基 )硅烷交联剂,温度在30℃至100℃的范围内。 (II)将加热的可固化组合物以100℃至210℃的温度注入模具中以制备弹性体制品; 和(III)从模具中去除弹性制品。
    • 4. 发明授权
    • Liquid polymer
    • 液体聚合物
    • US07417089B2
    • 2008-08-26
    • US11546716
    • 2006-10-12
    • Michael Joseph RachitaVanessa Marika GuscoffLawson Gibson Wideman
    • Michael Joseph RachitaVanessa Marika GuscoffLawson Gibson Wideman
    • C08L83/06
    • C08K5/14C08L9/00C08L23/06C08L19/006C08L15/00C08L2666/08
    • This invention discloses a process for manufacturing an elastomeric article by liquid injection molding, wherein the article has improved tensile strength and improved tear strength, said process comprising the steps of: (I) heating a curable composition comprised of (1) a liquid polymer comprised of repeat units that are derived from a conjugated diolefin monomer, wherein said liquid polymer has a weight average molecular weight which is within the range of 5,000 to 100,000, and wherein the liquid polymer is functionalized with an ether moiety, (2) a carbonyl inhibited platinum catalyst, and (3) a tetrakis(dialkyl siloxy) silane crosslinking agent, to a temperature which is within the range of 30° C. to 100° C.; (II) injecting the heated curable composition into a mold at a temperature which is within the range of 100° C. to 210° C. to produce the elastomeric article; and (III) removing the elastomeric article from the mold. This invention also discloses that the elasticity of such cured elastomeric articles can be increased without reducing cure levels by incorporating a liquid C5 tackifier resin into the liquid polymer.
    • 本发明公开了一种通过液体注射成型制造弹性体制品的方法,其中制品具有改进的拉伸强度和改善的撕裂强度,所述方法包括以下步骤:(I)加热可固化组合物,其包含(1) 的衍生自共轭二烯单体的重复单元,其中所述液体聚合物的重均分子量在5,000至100,000的范围内,并且其中液体聚合物用醚部分官能化,(2)羰基被抑制 铂催化剂和(3)四(二烷基甲硅烷氧基)硅烷交联剂,温度在30℃至100℃的范围内。 (II)将加热的可固化组合物以100℃至210℃的温度注入模具中以制备弹性体制品; 和(III)从模具中去除弹性制品。 本发明还公开了这种固化的弹性体制品的弹性可以通过将液体C 5+增粘树脂掺入到液体聚合物中而不降低固化水平。
    • 6. 发明授权
    • Liquid polymer
    • 液体聚合物
    • US07271218B2
    • 2007-09-18
    • US10876941
    • 2004-06-25
    • Lawson Gibson WidemanVanessa Marika GuscoffMichael Joseph Rachita
    • Lawson Gibson WidemanVanessa Marika GuscoffMichael Joseph Rachita
    • C08L83/06
    • C08K5/14C08L9/00C08L23/06C08L19/006C08L15/00C08L2666/08
    • This invention discloses a process for manufacturing an elastomeric article by liquid injection molding, wherein the article has improved tensile strength and improved tear strength, said process comprising the steps of: (I) heating a curable composition comprised of (1) a liquid polymer comprised of repeat units that are derived from a conjugated diolefin monomer, wherein said liquid polymer has a weight average molecular weight which is within the range of 5,000 to 100,000, and wherein the liquid polymer is functionalized with an ether moiety, (2) a carbonyl inhibited platinum catalyst, and (3) a tetrakis(dialkyl siloxy)silane crosslinking agent, to a temperature which is within the range of 30° C. to 100° C.; (II) injecting the heated curable composition into a mold at a temperature which is within the range of 100° C. to 210° C. to produce the elastomeric article; and (III) removing the elastomeric article from the mold. This invention also discloses that the elasticity of such cured elastomeric articles can be increased without reducing cure levels by incorporating a liquid C5 tackifier resin into the liquid polymer.
    • 本发明公开了一种通过液体注射成型制造弹性体制品的方法,其中制品具有改进的拉伸强度和改善的撕裂强度,所述方法包括以下步骤:(I)加热可固化组合物,其包含(1) 的衍生自共轭二烯单体的重复单元,其中所述液体聚合物的重均分子量在5,000至100,000的范围内,并且其中液体聚合物用醚部分官能化,(2)羰基被抑制 铂催化剂和(3)四(二烷基甲硅烷氧基)硅烷交联剂,温度在30℃至100℃的范围内。 (II)将加热的可固化组合物以100℃至210℃的温度注入模具中以制备弹性体制品; 和(III)从模具中去除弹性制品。 本发明还公开了这种固化的弹性体制品的弹性可以通过将液体C 5+增粘树脂掺入到液体聚合物中而不降低固化水平。