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1. 发明授权

US5328978A Triazine/formaldehyde resin 失效
标题翻译：三嗪/甲醛树脂
公开(公告)号：US5328978A
公开(公告)日：1994-07-12
申请号：US142006
申请日：1993-10-28
申请人： Manfred Schon , Jurgen Ott , Uwe Kubillus , Elif Tas
发明人： Manfred Schon , Jurgen Ott , Uwe Kubillus , Elif Tas
IPC分类号： C08G12/30 , C09D163/00 , C09D167/00 , C09D167/08
CPC分类号： C09D167/00 , C08G12/30 , C09D163/00 , C09D167/08 , Y10T428/31942
摘要： The present invention relates to a triazine/formaldehyde resin which contains a compound of the general formula I ##STR1## wherein R.sup.1 and R.sup.2 are defined as stated in claim 1, a process for its preparation and its use as a curing agent in surface coating systems.
摘要翻译：本发明涉及三嗪/甲醛树脂，其含有通式Ⅰ的化合物，其中R 1和R 2如权利要求1中所定义，其制备方法及其用作表面涂层中的固化剂系统。

2. 发明授权

US5670572A Impregnating resins for films and edgings 失效
标题翻译：浸渍树脂用于膜和边缘
公开(公告)号：US5670572A
公开(公告)日：1997-09-23
申请号：US552726
申请日：1995-11-03
申请人： Jurgen Ott , Manfred Schon , Wilhelm Adam , Frank Scholl , Alfons Wolf
发明人： Jurgen Ott , Manfred Schon , Wilhelm Adam , Frank Scholl , Alfons Wolf
IPC分类号： C08L61/28 , C08G12/30 , C08G12/32 , C08G12/42 , C08G14/10 , C08L61/20 , D06M15/423 , D06M23/18 , D21H17/51 , C08K5/05 , C09J161/32
CPC分类号： D21H17/51 , C08G12/30 , C08G12/42 , D06M15/423 , D06M23/18 , Y10T442/60 , Y10T442/659 , Y10T442/674
摘要： The present invention relates to melamine-formaldehyde resins comprising a guanamine, to processes for their preparation and to their use for the production of melamine resin films and edgings.
摘要翻译：本发明涉及包含胍胺的三聚氰胺 - 甲醛树脂，其制备方法及其用于生产三聚氰胺树脂膜和边缘的用途。

3. 发明授权

US4039493A Melamine-formaldehyde condensates and mixtures thereof 失效
标题翻译：三聚氰胺 - 甲醛缩合物及其混合物
公开(公告)号：US4039493A
公开(公告)日：1977-08-02
申请号：US590215
申请日：1975-06-25
申请人： Manfred Schon , Helmut Durr , Dieter Plath , Karlfried Keller , Walter Michel
发明人： Manfred Schon , Helmut Durr , Dieter Plath , Karlfried Keller , Walter Michel
IPC分类号： C08G12/00 , C08G12/32 , C08G12/42 , C08L61/20 , C08L67/00 , C09D133/06 , C08K5/05 , C08L91/00
CPC分类号： C08L67/00 , C08G12/427 , C09D133/064 , C08L61/20
摘要： Low-viscosity high-solids-content melamine-formaldehyde condensates having high reactivity, low content of free formaldehyde and good compatibility, are prepared by effecting condensation in an alcohol having up to 3 carbons, then concentrating the condensate and heating the concentrate in a higher alcohol having from 3 to 18 carbons and again concentrating. The final product cures on heating to a hard glossy film and can be added to other uncured resins to improve the hardness of their films.
摘要翻译：通过在具有最多3个碳的醇中进行缩合制备具有高反应性，低游离甲醛含量和良好相容性的低粘度高固含量三聚氰胺 - 甲醛缩合物，然后浓缩冷凝物并将浓缩物加热至更高具有3至18个碳原子并再次浓缩的醇。最终产品在加热至硬质光泽膜时固化，并可加入其他未固化的树脂中以提高其膜的硬度。

4. 发明授权

US5084536A Reaction product of olefinically unsaturated compounds with compounds containing active hydrogen, processes for their preparation and 2-component lacquers based thereon 失效
公开(公告)号：US5084536A
公开(公告)日：1992-01-28
申请号：US371517
申请日：1989-06-26
申请人： Gerhard Brindopke , Gerd Walz , Karl Waldmann , Manfred Schon , Hans-Jerg Kleiner
发明人： Gerhard Brindopke , Gerd Walz , Karl Waldmann , Manfred Schon , Hans-Jerg Kleiner
IPC分类号： C08G61/12 , C07D487/04 , C07D487/10 , C08F8/00 , C08F236/02 , C08F299/02 , C08G16/00 , C08G18/81 , C08G18/83 , C08G61/00 , C08G61/10 , C09D165/00
CPC分类号： C07D487/04 , C07D487/10 , C08F299/02 , C08F8/00 , C08G16/00 , C08G18/8141 , C08G18/83 , C08G61/00
摘要： A 3-component lacquer composed of A) compounds containing at least two R.sup.1 R.sup.2 C.dbd.CR.sup.3 --X groups (I) wherein R.sup.1 denotes hydrogen or a hydrocarbon radical having 1 to 10 carbon atoms, R.sup.2 and R.sup.3 are individually hydrogen, a hydrocarbon radical having 1 to 10 carbon atoms, an ester group containing the radical R.sup.4 of a monohydric alcohol having up to 12 carbon atoms, --CN, --NO.sub.2 or a --CO--NHR.sup.1 or --CO--R.sup.1 group, X is --CO-- which is attached to a further R.sup.1 R.sup.2 C.dbd.CR.sup.3 -- group either directly or via the radical of a polyhydric alcohol or of an amine and B) compounds containing:(a) at least two active H atoms or(b) at least two groups having active H atoms of the type --AH (II) or(c) at least one active H atom and at least one group of the type (II)and A is --CH-- or --NH-- or --S-- and optionally with customary additives and C) at least one catalyst selected from the group consisting of diazabicyclooctane (DABCO), fluorides of quaternary ammonium compounds on their own or as a mixture with alkyl silicates, amidines, tertiary phosphanes of the formula P(CH.sub.2 --Y).sub.3 in which the Ys are identical or different and are --OH, --CH.sub.2 CN or --N(Z).sub.2 in which Z is an alkyl having 1 to 5 carbon atoms, tertiary phosphanes of the formula P(R.sup.4,R.sup.5,R.sup.6) in which R.sup.4, R.sup.5 and R.sup.6 are alkyl of 1 to 12 carbon atoms or a phenyl which is unsubstituted or substituted by at least one alkyl, alkoxy or dialkylamino, each of which has 1 to 4 carbon atoms in the alkyl, and R.sup.4, R.sup.5 and R.sup.6 are identical or different, but at least one of them is phenyl, and aminophosphoranes of the formula (R.sup.7,R.sup.8,R.sup.9) P.dbd.N--C (R.sup.10, R.sup.11,R.sup.12) in which R.sup.7, R.sup.8 and R.sup.9 are identical or different and denote an alkyl having 1 to 12 carbon atoms or a alkoxy or dialkylamino group, each of which has 1 to 4 carbon atoms in the alkyl, and R.sup.10, R.sup.11 and R.sup.12 are identical or different and each represents an alkyl having 1 to 5 carbon atoms or a phenyl.

5. 发明授权

US4871822A Reaction product of olefinically unsaturated compounds with compounds containing active hydrogen, processes for their preparation and 2-component lacquers based thereon HOE 85/F O36J 失效
公开(公告)号：US4871822A
公开(公告)日：1989-10-03
申请号：US874688
申请日：1986-06-16
申请人： Gerhard Brindopke , Gerd Walz , Karl Waldmann , Manfred Schon , Hans-Jerg Kleiner
发明人： Gerhard Brindopke , Gerd Walz , Karl Waldmann , Manfred Schon , Hans-Jerg Kleiner
IPC分类号： C08G61/12 , C07D487/04 , C07D487/10 , C08F8/00 , C08F236/02 , C08F299/02 , C08G16/00 , C08G18/81 , C08G18/83 , C08G61/00 , C08G61/10 , C09D165/00
CPC分类号： C07D487/04 , C07D487/10 , C08F299/02 , C08F8/00 , C08G16/00 , C08G18/8141 , C08G18/83 , C08G61/00
摘要： A reaction product of (A) compounds containing at least two R.sup.1 R.sup.2; C.dbd.CR.sup.3 --X groups (I) with (B) compounds which contain(a) at least two active H atoms or(b) at least two groups containing active H atoms of the type --AH-- (II) or(c) at least one active H atom and at least one group of the type (III),or which form the corresponding amount of this group (II), in which, the formula (I),X denotes --CO-- which is attached to a further R.sup.1 R.sup.2 C.dbd.CR.sup.3 group either directly or via the radical of a polyhydric alcohol or of an amine,R.sup.1 denotes hydrogen or a hydrocarbon radical having 1 to 10, preferably 1 to 4, carbon atoms, such as alkyl, phenyl, benzyl or naphthyl,R.sup.2 denotes hydrogen, a hydrocarbon radical having 1 to 10, preferably 1 to 4, carbon atoms, such as alkyl, phenyl, benzyl or naphthyl, an ester group containing the radical R.sup.4 of a monohydric alcohol having up to 12 carbon atoms, --CN, --NO.sub.2 or a CO--NHR.sup.1 or CO--R.sup.1 group, andR.sup.3 has the same meaning as R.sup.2 and is identical with or different from the latter, and in formula (II), --AH-- denotes one of the grouping --CH--, --NH-- and --SH, subject to the proviso that reaction products of (A) polyacrylates containing at least two free acrylic acid groups, reaction products of polyisocyanates with acrylic acid esters containing OH groups or reaction products of epoxy resins, with acrylic acid, with (B) diketene or acetoacetic acid esters of hydroxyethyl acrylate or methacrylate are excluded. In the reaction product, component (A) is a Michael acceptor and component (B) is a Michael donor. The product of the invention has the advantage that it is prepared from components which contain no toxic constituents and can therefore be used without special precautionary measures.

6. 发明授权

US4535031A Modified aminoplast, its preparation and its use 失效
标题翻译：改性氨基塑料，其制备及其用途
公开(公告)号：US4535031A
公开(公告)日：1985-08-13
申请号：US586108
申请日：1984-03-05
申请人： Peter Dorries , Thomas Gotze , Steffen Piesch , Manfred Schon , Gunther Wulff , Karl Hintermeier
发明人： Peter Dorries , Thomas Gotze , Steffen Piesch , Manfred Schon , Gunther Wulff , Karl Hintermeier
IPC分类号： C08L61/20 , C08L61/32 , D21H17/51 , D21H17/53 , B32B27/10 , C08L67/02
CPC分类号： D21H17/53 , C08L61/20 , C08L61/32 , D21H17/51 , Y10T428/31786 , Y10T428/3179 , Y10T428/31794 , Y10T428/31957
摘要： Modified aminoplast resin comprising:(a) 60 to 99.5% by weight of an aminoplast precondensate which has been etherified with a lower alkanol to an extent not exceeding 10% and(b) 0.5 to 40% by weight of a modifying agent which comprises a mixture of (i) a water-soluble polyester prepared from carboxylic acids with at least one carboxyl and dihydric or polyhydric alcohols, and (ii) sufficient free diol or polyol whereby the mixture has a ratio of the sum of free and esterified hydroxyls of 0.8 to 4.5 moles for each mole of the sum of free and esterified carboxyls which resins are useful in impregnating webs for producing laminates and panels of wood-based materials.
摘要翻译：改性氨基塑料树脂，其包含：（a）60至99.5重量％的已经用低级链烷醇醚化至不超过10％的氨基塑料预缩合物，和（b）0.5至40重量％的改性剂，其包含（i）由羧酸与至少一种羧基和二元醇或多元醇制备的水溶性聚酯的混合物，和（ii）足够的游离二醇或多元醇，由此混合物的游离和酯化羟基之和的比例为0.8 对于每摩尔游离和酯化的羧基的总和为4.5摩尔，这些树脂可用于浸渍用于生产层压板和木基材料的板的网。

7. 发明授权

US4271286A Process for the preparation of etherified methylolaminotriazines 失效
标题翻译：制备醚化羟甲基氨基三嗪的方法
公开(公告)号：US4271286A
公开(公告)日：1981-06-02
申请号：US136416
申请日：1980-04-02
申请人： Walter Michel , Hans Honel , Manfred Schon , Wolfgang Kaiser
发明人： Walter Michel , Hans Honel , Manfred Schon , Wolfgang Kaiser
IPC分类号： C07D251/64 , C08G12/00 , C08G12/26 , C08G12/40 , C08G12/42 , C08G12/30
CPC分类号： C08G12/425 , C07D251/64
摘要： An improved process for the preparation of methylolaminotriazines etherified with alkanols and having per mol of the aminotriazine, an analytically determined average of 0.6 n to 2 n preferably 0.7 to 2 n methylol groups, which are etherified to the extent of 30 to 60%, n being the number of amino groups in the aminotriazine, wherein an aminotriazine is warmed to 80.degree. to 130.degree. C. with 0.7 n to 3 n mols of formaldehyde, 2 n to 10 n mols alkanol or a mixture of alkanols having 1 to 8 carbon atoms, the carbon chain of which, if having more than 2 carbon atoms, can also be interrupted by an oxygen atom, and 0 to 5 n mols of water, per mol of the aminotriazine, for 0.2 to 20 minutes, under elevated pressure, wherein the improvement comprises said aminotriazine being first heated to a temperature of 60.degree.-90.degree. C. in the presence of the formaldehyde and 0 to 30% by weight of the total amount of alkanol or alkanol mixture for 1 to 30 minutes at a pH 8 to 11 whereupon the remainder of the alkanol or alkanol mixture is added and the mixture is subsequently heated to 80.degree. to 130.degree. C. under elevated pressure in the presence of a strong inorganic or organic acid, at a pH of 3 to 8, for 0.2 to 20 minutes.
摘要翻译：制备用烷醇醚化并具有每摩尔氨基三嗪的羟甲基氨基三嗪的改进方法，分析测定的平均值为0.6n至2n，优选0.7至2个羟甲基，其醚化程度为30至60％，n 是氨基三嗪中的氨基数，其中氨基三嗪用0.7至3 n摩尔甲醛，2至10摩尔醇或1至8个碳原子的醇的混合物加热至80至130℃ 原子，如果碳原子数多于2个碳原子，碳原子数也可以被氧原子间隔，并且在高压下，每摩尔氨基三嗪为0至5微摩尔的水，为0.2至20分钟，其中所述改进包括在甲醛存在下将所述氨基三嗪首先加热至60〜90℃，在pH为0〜30％的条件下，将烷基醇或链烷醇混合物的总量为0〜30重量％加热1〜30分钟 8到11，其余的t 加入烷醇或链烷醇混合物，随后在强度无机或有机酸存在下，在3至8的pH下，在高压下将混合物加热至80至130℃，时间为0.2至20分钟。

8. 发明授权

US4081426A Preparation of aminoplasts 失效
标题翻译：氨基塑料的制备
公开(公告)号：US4081426A
公开(公告)日：1978-03-28
申请号：US677131
申请日：1976-04-15
申请人： Walter Michel , Hans Honel , Manfred Schon
发明人： Walter Michel , Hans Honel , Manfred Schon
IPC分类号： C07D251/18 , C07D251/64 , C07D251/70 , C08G12/00 , C08G12/30 , C08G12/32 , C08G12/42 , C08G12/26
CPC分类号： C08G12/30 , C07D251/64 , C08G12/425
摘要： Aminoplast preparation is greatly speeded by condensing an aminotriazine such as melamine with formaldehyde and etherifying alkanol under superatmospheric pressure and at a temperature between about 80.degree. and about 130.degree. C.
摘要翻译：通过在超大气压和约80℃至约130℃之间的温度下将氨基三嗪如三聚氰胺与甲醛和醚化链烷醇缩合，大大加快了氨基塑料的制备。

9. 发明授权

US3954900A Heat hardening mixtures 失效
标题翻译：加热硬化混合物
公开(公告)号：US3954900A
公开(公告)日：1976-05-04
申请号：US561438
申请日：1975-03-24
申请人： Wolfgang Schmalz , Walter Michel , Manfred Schon
发明人： Wolfgang Schmalz , Walter Michel , Manfred Schon
IPC分类号： C08L67/00 , C08G12/00 , C08G12/30 , C08G12/40 , C08G18/00 , C08G18/54 , C08G18/80 , C08L67/08 , C08L75/00 , C09D175/06 , C08L61/28 , C08L67/02
CPC分类号： C08G18/8074 , C08G18/544 , C09D175/06
摘要： High quality coatings and the like are formed from dispersions in a reactive liquid of finely divided solid isocyanated polyester resin having isocyanate groups part of which are masked but become unmasked upon heating and then react with the liquid. The liquid is essentially one or more highly etherified methylolated aminotriazine in which some of etherifying is with alkoxyethyl groups that provide relatively low viscosity and good reactivity.
摘要翻译：由具有异氰酸酯基团的细分固体异氰酸酯化聚酯树脂的反应性液体中的分散体形成高品质涂料等，其部分被掩蔽，但在加热时不被掩蔽，然后与液体反应。液体基本上是一种或多种高度醚化的羟甲基化氨基三嗪，其中一些醚化与提供相对低粘度和良好反应性的烷氧基乙基。

10. 发明授权

US4289672A Sizing glass fibers for thermoplastic resin reinforcement 失效
标题翻译：调整热塑性树脂增强玻璃纤维
公开(公告)号：US4289672A
公开(公告)日：1981-09-15
申请号：US13648
申请日：1979-02-21
申请人： Klaus Friederich , Gerhard Heinze , Helmut Reiff , Dietrich Michael , Manfred Schon , Peter Markusch , Ulrich Haberland , Dieter Dieterich , Josef Merten
发明人： Klaus Friederich , Gerhard Heinze , Helmut Reiff , Dietrich Michael , Manfred Schon , Peter Markusch , Ulrich Haberland , Dieter Dieterich , Josef Merten
IPC分类号： C03C25/32 , C08J5/08 , C08L75/06
CPC分类号： C03C25/326 , C08J5/08 , Y10T428/2938
摘要： Glass fibers for reinforcing thermoplastic resins are sized with an aqueous dispersion comprising a polyurethane-ionomer as a film-forming agent and a bonding agent comprising an epoxy-containing alkoxysilane. Advantageously the polyurethane is a very small particle ionomer and the bonding agent is selected from the group consisting of(a) an epoxyalkyl alkoxysilane+an aminoalkyl alkoxysilane,(b) an epoxyalkyl alkoxysilane+a low-molecular weight aliphatic primary or secondary mono-amine,(c) an aminoalkyl alkoxysilane+a low-molecular weight monoepoxide, and(d) an epoxyalkyl alkoxysilane.
摘要翻译：用于增强热塑性树脂的玻璃纤维的尺寸为包含作为成膜剂的聚氨酯 - 离子交联聚合物和包含含环氧烷氧基硅烷的粘合剂的水分散体。有利地，聚氨酯是非常小的颗粒离聚物，并且粘合剂选自（a）环氧烷基烷氧基硅烷+氨基烷基烷氧基硅烷，（b）环氧烷基烷氧基硅烷+低分子量脂族伯或仲单胺，（c）氨基烷基烷氧基硅烷+低分子量单环氧化物，和（d）环氧烷基烷氧基硅烷。

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