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1. 发明授权

US4286962A Phthalocyanine reactive dyestuffs, their preparation and their use for dyeing materials containing hydroxyl groups or amide groups 失效
标题翻译：酞菁活性染料，它们的制备及其用于含有羟基或酰胺基团的染料的用途
公开(公告)号：US4286962A
公开(公告)日：1981-09-01
申请号：US108312
申请日：1979-12-31
申请人： Volker Ehrig , Manfred Groll , Klaus Wunderlich
发明人： Volker Ehrig , Manfred Groll , Klaus Wunderlich
IPC分类号： C09B62/10
CPC分类号： C09B62/10 , Y10S8/917 , Y10S8/918 , Y10S8/919
摘要： Dyestuffs of the formula ##STR1## wherein the substituents have the meaning indicated in the description,and their use for dyeing and printing materials containing hydroxyl groups or amide groups, such as textile fibres, filaments and fabrics of wool, silk or synthetic polyamide or polyurethane fibres and for dyeing and printing natural or regenerated cellulose with dyeings and prints which are fast to washing.The dyeings obtained with the dyestuffs are distinguished by good to very good fastness properties, in particular by outstanding fastness to wet processing.
摘要翻译：具有式（IMAGE）的染料，其中取代基具有说明书中指出的含义，以及它们用于染色和印刷含有羟基或酰胺基的材料，例如纺织纤维，长丝和羊毛，丝绸或合成聚酰胺或聚氨酯的织物纤维和用于染色和印刷具有快速洗涤的染色和印花的天然或再生纤维素。用染料获得的染色的特征在于良好至非常好的坚牢度性质，特别是通过优异的湿润处理牢度。

2. 发明授权

US4267107A Reactive dyestuffs 失效
标题翻译：活性染料
公开(公告)号：US4267107A
公开(公告)日：1981-05-12
申请号：US43120
申请日：1979-05-29
申请人： Manfred Groll , Klaus Wunderlich
发明人： Manfred Groll , Klaus Wunderlich
IPC分类号： C09B62/10 , C09B47/04
CPC分类号： C09B62/10
摘要： Phthalocyanine reactive dyestuffs of the formula ##STR1## wherein Pc, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, B, R.sub.6, R.sub.7, R.sub.8, a, b and c have the meaning indicated in the description,and their use for dyeing textile materials containing hydroxyl groups and textile materials containing nitrogen, in particular textile materials made of natural and regenerated cellulose and furthermore made of wool, silk and synthetic polyamide fibers and polyurethane fibers. The resulting dyeings are distinguished by excellent fastness to wet processing.
摘要翻译：其中Pc，R1，R2，R3，R4，R5，B，R6，R7，R8，a，b和c具有说明书中指出的含义的酞菁活性染料，其用于染色纺织材料含有羟基和含氮的纺织材料，特别是由天然和再生纤维素制成的纺织材料，并且还由羊毛，丝绸和合成聚酰胺纤维和聚氨酯纤维制成。所得到的染色的特征在于优良的耐湿牢度。

3. 发明授权

US4268267A Phthalocyanine reactive dyestuffs 失效
标题翻译：酞菁活性染料
公开(公告)号：US4268267A
公开(公告)日：1981-05-19
申请号：US86611
申请日：1979-10-19
申请人： Karl H. Duchardt , Manfred Groll , Klaus Wunderlich
发明人： Karl H. Duchardt , Manfred Groll , Klaus Wunderlich
IPC分类号： C09B62/10 , D06P1/382 , C09B62/06 , C09B47/04
CPC分类号： D06P1/382 , C09B62/10 , Y10S8/918
摘要： Dyestuffs of the formula ##STR1## wherein Pc, R.sub.1, R.sub.2, R.sub.3, R.sub.4, Ar, R.sub.5, R.sub.6, a, b and c have the meaning indicated in the description, and their use for dyeing and printing materials which contain hydroxyl or amide groups, such as textile fibres, filaments and fabrics made of wool, silk and synthetic polyamide and polyurethane fibres and for wash-fast dyeing and printing of natural or regenerated cellulose.The invention relates to new water-soluble phthalocyanine dyestuffs which, in the form of their free acids, have the formula ##STR2## wherein Pc is the radical of a copper phthalocyanine or nickel phthalocyanine,R.sub.1 and R.sub.2 are hydrogen or optionally substituted alkyl, or R.sub.1 +R.sub.2 together with N are a 5-membered or 6-membered heterocyclic ring,R.sub.3 and R.sub.4 are hydrogen or optionally substituted alkyl,Ar is arylene substituted by SO.sub.3 H or/and COOH and optionally by other atoms or groups of atoms,R.sub.5 and R.sub.6 are hydrogen, optionally substituted alkyl, cycloalkyl or aralkyl or an optionally substituted aryl radical which is free from sulphonic acid and carboxylic acid groups, or R.sub.5 +R.sub.6 together with N are a 5-membered or 6-membered heterocyclic ring,a is 1 to 3,b is 0 to 2,c is 1 or 2 anda+b+c.ltoreq.4,and mixtures thereof.In the dyestuffs of the formula (I), each sulphonic acid group or sulphonamide group is bonded to a different benzene ring of the phthalocyanine in the 3-position or 4-position.The radicals R.sub.1 and R.sub.2, R.sub.3 and R.sub.4 and also R.sub.5 and R.sub.6 can be identical or different.Examples which may be mentioned of optionally substituted alkyl radicals R.sub.1 and R.sub.2 are: C.sub.1 --C.sub.5 -alkyl radicals, such as methyl, ethyl, propyl, butyl and amyl, .beta.-hydroxyethyl and .gamma.-hydroxypropyl, .beta.-carboxyethyl and .eta.-sulphoethyl.Examples of optionally substituted alkyl radicals R.sub.3 and R.sub.4 are C.sub.1 --C.sub.5 -alkyl radicals, such as methyl, ethyl and propyl radicals, .beta.-hydroxyethyl and .beta.-hydroxypropyl.The arylene radical Ar is substituted by at least one sulphonic acid and/or carboxylic acid group. In addition, it can be substituted by further atoms or groups of atoms, for example by C.sub.1 --C.sub.4 -alkyl groups, C.sub.1 --C.sub.4 -alkoxy groups, halogen atoms or sulphonamide or carboxamide groups, or interrupted by keto groups, sulphone groups, carboxamido groups, urea groups, amino groups, imino groups, ethylene groups or oxygen atoms.Examples of which may be mentioned of such arylene radicals are 2-carboxy-1,4-phenylene, 2-carboxy-1,5-phenylene, 3-carboxy-1,5-phenylene, N,N'-bis-(3-carboxy-4-phenylene)-urea, 1-carboxy-3,4-phenylene, 3,3'-dicarboxy-4,4'-diphenylene, 4-sulpho-1,3-phenylene, 3-sulpho-1,4-phenylene, 2-methyl-5-sulpho-1,3-phenylene, N,N'-bis-(3-sulpho-4-phenylene)-urea, 2-sulpho-4-methyl-1,5-phenylene, 2-methyl-5-sulpho-1,3-phenylene, 1-sulpho-3,4-naphthylene, 1-sulpho-4,5 -naphthylene, 5-sulpho-1,2-naphthylene, 5-sulpho-2,4-naphthylene, 2-sulpho-5,8-naphthylene, 3-sulpho-4,4'-diphenylene, 1,3-disulpho-4,6-phenylene, 1,3-disulpho-5,6-naphthylene, 1,5-disulpho-3,7-naphthylene, 1-sulpho-4-methoxy-2,5-phenylene, 2-carboxy-5-chloro-1,4-phenylene, 2,2'-disulpho-5,5'-dimethyl-4,4'-diphenylene and 2,2'-disulpho-4,4'-stilbenylene.Examples of radicals R.sub.5 and R.sub.6 are: hydrogen, C.sub.1 --C.sub.5 -alkyl radicals, such as methyl, ethyl, propyl, butyl, isobutyl and amyl; substituted C.sub.1 --C.sub.5 -alkyl radicals, such as .beta.-hydroxyethyl, .gamma.-hydroxypropyl, .beta.-methoxyethyl, .gamma.-methoxypropyl, .beta.-ethoxyethyl, .gamma.-ethoxypropyl, carboxymethyl, .beta.-carboxyethyl and .beta.-sulphoethyl; cycloalkyl radicals, such as cyclohexyl, 2-methylcyclohexyl, 3-methylcyclohexyl and 4-methylcyclohexyl; aralkyl radicals, such as benzyl and .beta.-phenylethyl; and aryl radicals which are free from sulphonic acid groups and carboxylic acid groups, such as phenyl, 2-naphthyl, 3-methylphenyl, 4-methylphenyl, 3,4-dimethylphenyl, 3,5-dimethylphenyl, 3-ethylphenyl, 3-chlorophenyl, 4-chlorophenyl, 3,4-dichlorophenyl, 3,5-dichlorophenyl, 3-methyl-4-chlorophenyl, 4-methyl-4-chlorophenyl, 3-methoxyphenyl, 4-methoxyphenyl, 3-ethoxyphenyl, 4-ethoxyphenyl, 3-nitrophenyl, 4-nitrophenyl, 3-carboxamidophenyl and 3-acetylaminophenyl.Examples in which R.sub.5 and R.sub.6 together with N form a heterocyclic ring are given when R.sub.5 and R.sub.6 together represent the pentamethylene group or the grouping --C.sub.2 H.sub.5 --O--C.sub.2 H.sub.4.A preferred group of dyestuffs amongst the dyestuffs according to the invention are those of the general formula (I)whereinPc is the radical of a copper phthalocyanine or nickel phthalocyanine,R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are hydrogen, methyl or ethyl,Ar is an arylene radical substituted by SO.sub.3 H or COOH and optionally by other atoms or groups of atoms,R.sub.5 and R.sub.6 are hydrogen, optionally substituted alkyl with 1 to 5 C atoms, optionally substituted cycloalkyl or aralkyl, or an optionally substituted aryl radical which is free from sulphonic acid groups and carboxylic acid groups, or R.sub.5 and R.sub.6 together with N are a 5-membered or 6-membered heterocyclic ring,a is 1 to 3,b is 0 to 2,c is 1 or 2 anda+b+c.ltoreq.4.A particularly preferred group of dyestuffs amongst the dye-stuffs according to the invention are those of the general formula (I)in whichPc is the radical of a copper phthalocyanine or nickel phthalocyanine,R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are hydrogen, methyl or ethyl,Ar is an arylene radical which is substituted by SO.sub.3 H or COOH and optionally by other atoms or groups of atoms,R.sub.5 and R.sub.6 are hydrogen, optionally substituted alkyl with 1 to 5 C atoms, optionally substituted cycloalkyl or aralkyl or an optionally substituted aryl radical which is free from sulphonic acid groups and carboxylic acid groups, or R.sub.5 and R.sub.6 together with N are a 5-membered or 6-membered heterocyclic ring,1 0,c is 1 anda+b+c=3 or 4.A further particularly preferred group of dyestuffs amongst the dyestuffs according to the invention are those of the general formula (I)in whichPc is the radical of a copper phthalocyanine or nickel phthalocyanine,R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are hydrogen, methyl or ethyl,Ar is an arylene radical which is substituted by SO.sub.3 H or COOH and optionally by other atoms or groups of atoms,R.sub.5 and R.sub.6 are hydrogen, optionally substituted alkyl with 1 to 5 C atoms, optionally substituted cycloalkyl or aralkyl or an optionally substituted aryl radical which is free from sulphonic acid groups and carboxylic acid groups, or R.sub.5 and R.sub.6 together with N are a 5-membered or 6-membered heterocyclic ring,1 0,c is 1 anda+b+c=3 or 4.A further particularly preferred group of dyestuffs amongst the dyestuffs according to the invention are those of the general formula (I)in whichPc is the radical of a copper phthalocyanine or nickel phthalocyanine,R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are hydrogen, methyl or ethyl,Ar is an arylene radical which is substituted by SO.sub.3 H or COOH and optionally by other atoms or groups of atoms,R.sub.5 and R.sub.6 are hydrogen, optionally substituted alkyl with 1 to 5 C atoms, optionally substituted cycloalkyl or aralkyl or an optionally substituted aryl radical which is free from sulphonic acid groups and carboxylic acid groups, or R.sub.5 and R.sub.6 together with N are a 5-membered or 6-membered heterocyclic ring,a is 1 or 2,b is 0,c is 1 anda+c=2 or 3.The new dyestuffs of the formula (I) are prepared by a condensation reaction of suitable starting components. For this purpose, dyestuffs which in the form of their free acids have the formula ##STR3## can be reacted either first with trifluorotriazine and then with an amine of the formula ##STR4## or with a difluorotriazine derivative of the formula ##STR5##When compounds (II) in which Ar represents sulphoarylene with the sulpho group in the o-position relative to the --NH--R.sub.4 group are used, these are appropriately reacted first with trifluorotriazine and then with (III).In the formulae (II), (III) and (IV), R.sub.1 to R.sub.6 and also Ar, a, b and c have the meaning indicated above.Examples of suitable compounds of the formula (III) are: ammonia, methylamine, dimethylamine, ethylamine, diethylamine, propylamine, butylamine, dibutylamine, isobutylamine, amylamine, .beta.-hydroxyethylamine, .gamma.-hydroxypropylamine, methyl-.beta.-hydroxyethylamine, methoxyethylamine, ethoxyethylamine, N-.beta.-hydroxyethyl-N-ethylamine, aminoacetic acid, aminopropionic acid, .beta.-amino-ethanesulphonic acid, cyclohexylamine, 3-methylcyclohexylamine, benzylamine, aniline, 2-naphthylamine, m-toluidine, p-toluidine, 3,4-dimethylaniline, 3,5-dimethylaniline, 3-ethylaniline, 3-chloroaniline, 4-chloroaniline, 3,4-dichloroaniline, 3,5-dichloroaniline, 3-methyl-4-chloroaniline, 4-methyl-3-chloroaniline, 3-methoxyaniline, 4-methoxyaniline, 3-ethoxyaniline, 4-ethoxyaniline, 3-nitroaniline, 4-nitroaniline, 3-aminobenzoic acid amide, N-methylaniline, N-ethylaniline, 3-amino-acetanilide, 4-methylamino--acetanilide, piperidine, morpholine, o-toluidine, 2-methoxy-aniline, 2-ethoxyaniline, 2,4-dimethylaniline, 2,5-dimethylaniline and 2-chloroaniline.These reactions are acylation reactions and can be carried out in an aqueous, aqueous-organic or organic, preferably weakly acid to weakly alkaline medium at temperatures of -10.degree. to +80.degree. C. and preferably of -5.degree. to +10.degree. C.The phthalocyanine compounds of the formula (II) which are used in the process according to the invention can be prepared by reacting a phthalocyaninesulphonic acid chloride--preferably in the form of an aqueous suspension of the formula ##STR6## wherein Pc has the meaning indicated above,m designates the numbers 0, 1 or 2 andn designates the numbers 2, 3 or 4 andthe sum m plus n is not greater than 4,with diamines or monoacylated diamines of the formula ##STR7## and optionally with a compound of the formula ##STR8## in which formulae R.sub.1, R.sub.2, R.sub.3, R.sub.4 and Ar have the meaning indicated above,and, if monoacylated diamines of the formula (VIb) are used, subjecting the terminal acylamino group in the resulting phthalocyanine compounds to acid or alkaline saponification. In this reaction unconverted sulphonic acid chloride groups are converted to sulphonic acid groups.Phthalocyaninesulphonyl chlorides and phthalocyaninesulphonyl chloride-sulphonic acids of the formula (V) can be obtained by treating the corresponding phthalocyanine or the phthalocyaninesulphonic acid with chlorosulphonic acid and, optionally, an acid halide, such as thionyl chloride, phosphorus pentachloride, phosphorus oxychloride or phosphorus trichloride, as described in British Pat. Nos. 708,543, 784,834 and 785,629 and U.S. Pat. No. 2,219,330.According to the invention it is possible to use phthalocyanine dyestuffs which are single compounds, that is to say those in which the letters a, b and c characterise the numbers 0, 1, 2 or 3. In addition, however, it is also possible to use mixtures of these dyestuffs. Sometimes mixtures of this type have particular advantages in respect of solubility and substantivity. In such mixtures the average value of the numbers varies.Mixtures, according to the invention, of this type are prepared, for example, from two or more end dyestuffs of the formula (I), each of which is a single compound, or, particularly advantageously by using a mixture of the starting components. The latter frequently is necessarily formed since the phthalocyaninesulphonyl chloridesulphonic acids (V) are frequently obtained industrially in the form of mixtures, in respect of the degree of sulphonation and the ratio of sulphonyl chloride groups and sulphonic acid groups contained therein.The following may be mentioned as examples of suitable diamines of the formula (VIa) and suitable monoacylated diamines of the formula (VIb): 1,4-diaminobenzenesulphonic acid, 1,3-diaminobenzene-4-sulphonic acid, 2-sulpho-4-methyl-1,3-phenylenediamine, N,N'-bis-(3-sulpho-4-aminophenyl)-urea, 2-sulpho-4-methyl-1,5-phenylenediamine, 2-methyl-5-sulpho-1,3-phenylenediamine, 4,4'-diamino-(1,1'-biphenyl)-3-sulphonic acid, 1-sulpho-3,4-naphthenediamine, 1-sulpho-4,5-naphthylenediamine, 5-sulpho-1,2-naphthylenediamine, 5-sulpho-2,4-naphthylenediamine, 2-sulpho-5-acetylamino-8-aminonaphthalene, 2-amino-5-acetylamino-benzoic acid, 2-amino-4-acetylamino-benzoic acid, 3-amino-5-acetylaminobenzoic acid, 2-sulpho-4-aminophenyl-oxamic acid, N,N'-bis-(4-amino-3-carboxyphenyl)-urea, 6-amino-2-acetylaminotoluene-4-sulphonic acid, 4-amino-4'-acetylaminodiphenylamine-2-sulphonic acid, 2-amino-5-[(3-aminobenzoyl)-amino]-benzenesulphonic acid, 4-amino-2-acetylamino-benzoic acid and 4,6-diaminotoluene-3-sulphonic acid.The new dyestuffs are extremely valuable products which are suitable for very diverse applications.As water-soluble compounds they are of interest for dyeing and printing textile materials which contain hydroxyl groups and textile materials which contain nitrogen, especially textile materials made of natural and regenerated cellulose, and also materials made of wool, silk and synthetic polyamide and polyurethane fibres. They are particularly suitable as reactive dyestuffs for dyeing and printing cellulose materials by the techniques recently disclosed for this purpose. The resulting fastness properties, especially the wet-fastness properties, are excellent.For dyeing and printing cellulose, the dyestuffs are preferably employed in an aqueous solution, to which substances having an alkaline reaction, such as an alkali metal hydroxide or alkali metal carbonate, or compounds which are converted to substances having an alkaline reaction, such as an alkali metal bicarbonate or Cl.sub.3 C--COONa, can be added. Further auxiliaries can be added to the solution but these should not react in an undesirable manner with the dyestuffs. Such additives are, for example, surface-active substances, such as alkyl sulphates, or substances which prevent the migration of the dyestuff, or dyeing auxiliaries, such as urea or inert thickeners, such as oil/water emulsions, tragacanth, starch, alginate or methylcellulose.The solutions or pastes prepared in this way are applied to the material to be dyed, for example by padding in a padder (short liquor) or by printing, and then heated for some time at elevated temperature, preferably 40.degree. to 150.degree. C. Heating can be carried out in a hot flue, in a steaming apparatus, on heated rollers or by introducing the material into heated concentrated salt baths and these operations can be carried out either on their own or successively in any order.When a padding or dyeing liquor without alkali is used, passage of the dry goods through a solution which has an alkaline reaction and to which sodium chloride or Glauber's salt is added follows dyeing. The addition of a salt reduces the migration of the dyestuff from the fibre.The material to be dyed can also be pre-treated with one of the abovementioned acid-binding agents, then treated with the solution or paste of the dyestuff and finally fixed at elevated temperature, as indicated.For dyeing from a long liquor, the material is introduced into an aqueous solution of the dyestuff (liquor ratio 1:5 to 1:40) at room temperature and dyed for 40 to 90 minutes, raising the temperature to 95.degree. C. if necessary and optionally adding, in portions, a salt, for example sodium sulphate and then alkali, for example sodium phosphates, sodium carbonate, NaOH or KOH.The chemical reaction between the dyestuff and the fibre than takes place. After chemical fixing has been carried out, the dyed material is rinsed hot and finally soaped, by which means non-fixed residues of the dyestuff are removed. Dyeings with excellent fastness properties, especially wet-fastness properties and fastness to light, are obtained.In the so-called cold pad-batch method, subsequent heating of the padded fabric can be saved by storing the fabric at room temperature for some time, for example 2 to 20 hours. In this process, a stronger alkali is employed than in the case of the dyeing method from a long liquor, which has been described above.For printing materials containing hydroxyl groups, a printing paste consisting of the dyestuff solution, a thickener, such as sodium alginate, and a compound which has an alkaline reaction or splits off alkali on heating, such as sodium carbonate, sodium phosphate, potassium carbonate, potassium acetate or sodium bicarbonate and potassium bicarbonate, is used and the printed material is rinsed and soaped.Textile materials containing amide groups, such as wool, silk and synthetic polyamide and polyurethane fibres, are generally dyed in the acid to neutral range by the dyeing methods customary for this purpose.The dyeings obtainable with the new dyestuffs are in general distinguished by good to very good fastness properties, especially by outstanding wet-fastness properties.The present invention also relates to difluorotriazinyl compounds, which, in the form of the free acid, have the formula ##STR9## wherein Pc, R.sub.1 -R.sub.4 and a, b and c have the meaning indicated above.These compounds are obtained as defined above, by reacting trifluorotriazine with (II).
摘要翻译：其中Pc，R 1，R 2，R 3，R 4，Ar，R 5，R 6，a，b和c具有说明书中所示的含义，以及它们在含有羟基或酰胺的染色和印刷材料中的用途组织，如纺织纤维，长丝和由羊毛，丝绸和合成聚酰胺和聚氨酯纤维制成的织物，以及用于洗涤快速染色和印刷天然或再生纤维素。

4. 发明授权

US07398650B2 Internal combustion engine comprising a mechanical charger and a turbo-compound 失效
标题翻译：内燃机包括机械充电器和涡轮组合
公开(公告)号：US07398650B2
公开(公告)日：2008-07-15
申请号：US11441418
申请日：2006-05-25
申请人： Michael Böttcher , Christian Enderle , Jochen Hufendiek , Klaus Wunderlich
发明人： Michael Böttcher , Christian Enderle , Jochen Hufendiek , Klaus Wunderlich
IPC分类号： F02G3/00 , F02G5/04 , F02B33/00 , F02B37/00 , F02B37/10
CPC分类号： F02B37/005 , F02B33/36 , F02B37/105 , F02B37/16 , F02B37/18 , F02B39/04 , F02B39/08 , F02B39/12 , F02B41/10 , F02B67/06 , Y02T10/144 , Y02T10/163
摘要： In an internal combustion engine comprising a mechanical charger in the form of a positive displacement compressor connected to the engine intake duct for supplying compressed air to the engine and a turbo-compound including an exhaust gas turbine connected to the engine exhaust duct for converting energy remaining in the exhaust gas to power, the exhaust gas turbine being connected to the engine via a reduction gear drive, the mechanical charger and the turbo-compound are coupled to the engine by a common belt drive including a first belt pulley mounted on the crankshaft of the engine, a second belt pulley mounted on the shaft of the reduction gear drive, and a third belt pulley mounted on the shaft of the mechanical charger.
摘要翻译：在内燃机中，包括连接到发动机进气管道的正排量压缩机形式的机械充气器，用于向发动机供应压缩空气，以及包括连接到发动机排气管道的排气涡轮的涡轮混合器，用于转换能量剩余在排气通过动力的情况下，排气涡轮通过减速齿轮传动与发动机连接，机械充电器和涡轮组合体通过共同的皮带传动装置联接到发动机，该皮带传动装置包括安装在曲轴上的第一皮带轮所述发动机，安装在所述减速齿轮传动装置的轴上的第二皮带轮，以及安装在所述机械充电器的所述轴上的第三皮带轮。

5. 发明申请

US20060254565A1 Internal combustion engine comprising a mechanical charger and a turbo-compound 失效
标题翻译：内燃机包括机械充电器和涡轮组合
公开(公告)号：US20060254565A1
公开(公告)日：2006-11-16
申请号：US11441418
申请日：2006-05-25
申请人： Michael Bottcher , Christian Enderle , Jochen Hufendiek , Klaus Wunderlich
发明人： Michael Bottcher , Christian Enderle , Jochen Hufendiek , Klaus Wunderlich
IPC分类号： F02B33/00
CPC分类号： F02B37/005 , F02B33/36 , F02B37/105 , F02B37/16 , F02B37/18 , F02B39/04 , F02B39/08 , F02B39/12 , F02B41/10 , F02B67/06 , Y02T10/144 , Y02T10/163
摘要： In an internal combustion engine comprising a mechanical charger in the form of a positive displacement compressor connected to the engine intake duct for supplying compressed air to the engine and a turbo-compound including an exhaust gas turbine connected to the engine exhaust duct for converting energy remaining in the exhaust gas to power, the exhaust gas turbine being connected to the engine via a reduction gear drive, the mechanical charger and the turbo-compound are coupled to the engine by a common belt drive including a first belt pulley mounted on the crankshaft of the engine, a second belt pulley mounted on the shaft of the reduction gear drive, and a third belt pulley mounted on the shaft of the mechanical charger.
摘要翻译：在内燃机中，包括连接到发动机进气管道的正排量压缩机形式的机械充气器，用于向发动机供应压缩空气，以及包括连接到发动机排气管道的排气涡轮的涡轮混合器，用于转换能量剩余在排气通过动力的情况下，排气涡轮通过减速齿轮传动与发动机连接，机械充电器和涡轮组合体通过共同的皮带传动装置联接到发动机，该皮带传动装置包括安装在曲轴上的第一皮带轮所述发动机，安装在所述减速齿轮传动装置的轴上的第二皮带轮，以及安装在所述机械充电器的所述轴上的第三皮带轮。

6. 发明授权

US5582005A Exhaust arrangement for a gasoline 失效
标题翻译：汽油排气装置
公开(公告)号：US5582005A
公开(公告)日：1996-12-10
申请号：US448985
申请日：1995-05-24
申请人： Klaus Wunderlich , Stefan Pischinger , Bernd Krutzsch , Martin Bechtold
发明人： Klaus Wunderlich , Stefan Pischinger , Bernd Krutzsch , Martin Bechtold
IPC分类号： F01N3/08 , F01N3/20 , F01N13/02 , F02D41/14 , F01N3/16
CPC分类号： F02D41/1475 , F01N13/009 , F01N3/0871 , F01N3/0878 , F01N3/2053 , F01N2250/12 , F01N2410/12 , F01N2570/16 , Y02T10/20 , Y02T10/22
摘要： The invention relates to a gasoline engine having a catalyst for reducing the emission pollutants, with an oxygen absorption device located in the exhaust line upstream of the catalyst. According to the invention, the gasoline engine is operated in a first operating range with a lean air/fuel ratio (.lambda.), and oxygen is removed from the exhaust by the absorption device. In a second operating range, the gasoline engine is operated at .lambda.=1, and the absorption device is bypassed or deactivated. In the case of a gasoline engine with a Denox catalyst the gasoline engine is operated constantly with a lean air/fuel ratio, with the active surface of the Denox catalyst being "depoisoned" temporarily by activating the oxygen absorption device.
摘要翻译：本发明涉及具有用于减少排放污染物的催化剂的汽油发动机，其中氧吸收装置位于催化剂上游的排气管线中。根据本发明，汽油发动机在具有稀薄空气/燃料比（λ）的第一操作范围内操作，并且通过吸收装置从排气中除去氧气。在第二操作范围内，汽油发动机以λ= 1运行，并且吸收装置被旁路或停用。在具有脱氧催化剂的汽油发动机的情况下，汽油发动机以稀薄的空气/燃料比恒定运行，通过激活氧吸收装置，Denox催化剂的活性表面暂时被“去污”。

7. 发明授权

US5335500A Internal combustion engine with combined pressure charging 失效
标题翻译：内燃机组合式充气
公开(公告)号：US5335500A
公开(公告)日：1994-08-09
申请号：US34712
申请日：1993-03-19
申请人： Klaus Wunderlich , Franz Neubrand , Erwin Schmidt , Hans-Wilhelm Buhl , Friedrich Wirbeleit , Horst Hanauer
发明人： Klaus Wunderlich , Franz Neubrand , Erwin Schmidt , Hans-Wilhelm Buhl , Friedrich Wirbeleit , Horst Hanauer
IPC分类号： F02B3/06 , F02B37/04 , F02B37/16 , F02B39/04 , F02B39/16 , F02B33/44
CPC分类号： F02B37/16 , F02B37/04 , F02B39/04 , F02B39/16 , F02B3/06 , Y02T10/144
摘要： An internal combustion engine with combined pressure charging has an exhaust turbocharger turbine arranged in an exhaust conduit of the internal combustion engine driving a compressor arranged in an intake conduit. A mechanically driven supercharger is arranged downstream of the compressor and is coupled continuously variably to the engine via a Fottinger speed transformer with variable-pitch guide vanes and variable speed slip. To bypass the mechanically driven supercharger, a bypass conduit is provided. A circulating-air slide is arranged in the bypass conduit for controlling the air quantity bypassing the mechanically driven supercharger. The degree of opening of the circulating-air slide and the slip of the Fottinger speed transformer are controlled as a function of operating parameters such that the charge-air pressure is adjusted to a predetermined set point value.
摘要翻译：具有组合式加压的内燃机具有布置在内燃机的排气管道中的排气涡轮增压器涡轮，其驱动布置在进气管道中的压缩机。机械驱动的增压器设置在压缩机的下游，并通过具有可变桨距导向叶片和变速滑移的Föttinger变速器连续地可变地联接到发动机。为了绕过机械驱动的增压器，提供旁路管道。循环空气滑块布置在旁路管道中，用于控制绕过机械驱动的增压器的空气量。控制循环空气滑块的开度和Föttinger变速器的滑动作为操作参数的函数，使得增压 - 空气压力被调节到预定的设定值。

8. 发明授权

US4355163A Anthraquinone reactive dyestuffs 失效
标题翻译：蒽醌类活性染料
公开(公告)号：US4355163A
公开(公告)日：1982-10-19
申请号：US96084
申请日：1979-11-20
申请人： Klaus von Oertzen , Wolfgang Harms , Klaus Wunderlich
发明人： Klaus von Oertzen , Wolfgang Harms , Klaus Wunderlich
IPC分类号： C09B62/06 , C09B62/44 , D06P3/66 , C07D231/38 , C07C143/665
CPC分类号： C09B62/4409 , C09B62/06
摘要： Dyestuffs of the formula ##STR1## wherein X, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 have the meaning indicated in the description,and their use for dyeing and printing materials containing hydroxyl groups or amide groups, such as textile fibres, filaments and fabrics of wool, silk or synthetic polyamide or polyurethane fibres, and for dyeing and printing natural or regenerated cellulose with dyeings and prints which are fast to washing.
摘要翻译：其中X，R 1，R 2，R 3和R 4具有说明书中指出的含义的化学式＆lt; IMAGE＆gt;的染料及其用于染色和印刷含有羟基或酰胺基的材料，例如纺织纤维，长丝和羊毛织物，丝绸或合成聚酰胺或聚氨酯纤维，以及染色和印刷天然或再生纤维素，其染色和印刷品快速洗涤。

9. 发明授权

US4332938A Anthaquinone reactive dyestuffs, their preparation and their use for dyeing materials containing OH groups or amide groups 失效
标题翻译：蒽醌类活性染料及其制备方法及其用于染色含有OH基团或酰胺基团的物质
公开(公告)号：US4332938A
公开(公告)日：1982-06-01
申请号：US99120
申请日：1979-11-30
申请人： Wolfgang Harms , Klaus Wunderlich , Klaus von Oertzen
发明人： Wolfgang Harms , Klaus Wunderlich , Klaus von Oertzen
IPC分类号： C09B62/06 , C07D251/00
CPC分类号： C09B62/06 , Y10S8/917 , Y10S8/918 , Y10S8/924
摘要： Dyestuffs of the formula ##STR1## wherein R.sub.1 and R.sub.2 have the meaning given in the description,and their use for dyeing and printing materials containing hydroxyl groups or amide groups, such as textile fibres, filaments and fabrics of wool, silk or synthetic polyamide or polyurethane fibres, and for dyeing and printing natural or regenerated cellulose with dyeings and prints which are fast to washing. The dyeings obtained are distinguished by good fastness to light and wet processing.
摘要翻译：其中R1和R2具有说明书中给出的含义，以及它们用于染色和印刷含有羟基或酰胺基团的材料，例如纺织纤维，长丝和羊毛，丝绸或合成聚酰胺的织物的用途的染料，聚氨酯纤维，以及用于染色和印刷天然或再生纤维素的染色和印刷品，其快速洗涤。所得到的染色具有良好的耐光牢度和湿润性。

10. 发明授权

US4294580A Reactive dyestuffs, their preparation and their use for dyeing materials containing OH or N 失效
标题翻译：活性染料及其制备方法及其用于含有OH或N的染料的用途
公开(公告)号：US4294580A
公开(公告)日：1981-10-13
申请号：US108307
申请日：1979-12-31
申请人： Hermann Henk , Klaus Wunderlich , Peter Wild
发明人： Hermann Henk , Klaus Wunderlich , Peter Wild
IPC分类号： C09B62/04 , D06P3/66 , C09B62/06
CPC分类号： C09B62/04 , Y10S8/917 , Y10S8/918
摘要： Dyestuffs of the formula ##STR1## wherein Fb, W, R.sub.1, R.sub.2, R.sub.3, n and m have the meaning given in the description,and their use for dyeing and printing materials containing hydroxyl groups or nitrogen, such as textile fibres, filaments and fabrics of wool, silk or synthetic polyamide or polyurethane fibres, and for washfast dyeing and printing natural or regenerated cellulose.The dyeings obtained are distinguished by good fastness to wet processing.
摘要翻译：其中Fb，W，R1，R2，R3，n和m具有说明书中给出的含义及其用于染色和印刷含有羟基或氮的材料（例如纺织纤维，长丝）的用途的式羊毛，丝绸或合成聚酰胺或聚氨酯纤维的织物，以及用于洗涤快速染色和印刷天然或再生纤维素的织物。所得到的染色具有良好的耐湿牢度。

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