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1. 发明申请

US20060020093A1 Ion-polymer gel electrolyte and its precursor composition 有权
标题翻译：离子聚合物凝胶电解质及其前体组成
公开(公告)号：US20060020093A1
公开(公告)日：2006-01-26
申请号：US11184263
申请日：2005-07-18
申请人： Manabu Kikuta , Akiyoshi Hatakeyama
发明人： Manabu Kikuta , Akiyoshi Hatakeyama
IPC分类号： C08F12/28
CPC分类号： H01M10/0565 , H01B1/122 , H01G11/56 , H01M6/181 , H01M8/103 , H01M8/1072 , H01M10/052 , H01M2300/0085 , Y02E60/13 , Y02P70/56
摘要： A precursor composition capable to form a solid-state electrolyte having good ion conductivity and high heat-resistance, by simple curing procedure, comprising; (A) a polymerizable ion pair compound represented by formula I, (B) a cross-linker having two or more unsaturated groups co-polymerizable with the polymerizable ion pair compound (A), and (C) non-polymerizable ion pair compound. Each of R1, R2, R3, R4, R5 and R6 represents hydrogen atom, alkyl or aryl group having 1-12 carbon atoms; and each of R7 and R8 represents alkyl or aryl group having 1-12 carbon atoms. X designates either of halogen atom, AlCl4−, PF6−, BF4−, bis (oxalato) borate anion, Rf1SO3−, (NC)2N−, (Rf2Y)2N−, (Rf2Y)3C−, and (Rf2Y)2C−Q, where Rf1 designates perfluoro alkyl or aryl group having 1-8 carbon atoms; each Rf2 designates fluorine atom, perfluoro alkyl or aryl group having 1-8 carbon atoms; Y designates —SO2—or —PO—Rf2; and Q designates —H or —CO—Rf2.
摘要翻译：通过简单的固化方法能够形成具有良好离子传导性和高耐热性的固态电解质的前体组合物，其包含：（A）由式I表示的可聚合离子对化合物，（B）具有两个或多个与可聚合离子对化合物（A）可共聚的不饱和基团的交联剂，和（C）不可聚合离子对化合物。 R1，R2，R3，R4，R5和R6各自表示氢原子，具有1-12个碳原子的烷基或芳基; 并且R 7和R 8各自表示具有1-12个碳原子的烷基或芳基。 X表示卤素原子，AlCl 4，SO 4，SO 4，SO 4，双（草酸）硼酸盐阴离子，R 1，SO 3，SO 3， - （NC）（R＆lt; 2＆gt; 2）＆lt; / SUP＆gt;，（R＆lt; SUB＆gt; （R 2，Y 2）2 C 2 O 3，其中R 1，R 2， Q，其中R f1表示具有1-8个碳原子的全氟烷基或芳基; 每个R f2表示氟原子，具有1-8个碳原子的全氟烷基或芳基; Y表示-SO 2 - 或-PO-R 1/2; 并且Q表示-H或-CO-R <！ - SIPO <

2. 发明授权

US07279540B2 Ion-polymer gel electrolyte and its precursor composition 有权
标题翻译：离子聚合物凝胶电解质及其前体组成
公开(公告)号：US07279540B2
公开(公告)日：2007-10-09
申请号：US11184263
申请日：2005-07-18
申请人： Manabu Kikuta , Akiyoshi Hatakeyama
发明人： Manabu Kikuta , Akiyoshi Hatakeyama
IPC分类号： C08F12/28
CPC分类号： H01M10/0565 , H01B1/122 , H01G11/56 , H01M6/181 , H01M8/103 , H01M8/1072 , H01M10/052 , H01M2300/0085 , Y02E60/13 , Y02P70/56
摘要： A precursor composition capable to form a solid-state electrolyte having good ion conductivity and high heat-resistance, by simple curing procedure, comprising; (A) a polymerizable ion pair compound represented by formula I, (B) a cross-linker having two or more unsaturated groups co-polymerizable with the polymerizable ion pair compound (A), and (C) non-polymerizable ion pair compound. Each of R1, R2, R3, R4, R5 and R6 represents hydrogen atom, alkyl or aryl group having 1-12 carbon atoms; and each of R7 and R8 represents alkyl or aryl group having 1-12 carbon atoms. X designates either of halogen atom, AlCl4−, PF6−, BF4−, bis (oxalato) borate anion, Rf1SO3−, (NC)2N−, (Rf2Y)2N−, (Rf2Y)3C−, and (Rf2Y) 2C−Q, where Rf1 designates perfluoro alkyl or aryl group having 1-8 carbon atoms; each Rf2 designates fluorine atom, perfluoro alkyl or aryl group having 1-8 carbon atoms; Y designates —SO2—or —PO—Rf2; and Q designates —H or —CO—Rf2
摘要翻译：通过简单的固化方法能够形成具有良好离子传导性和高耐热性的固态电解质的前体组合物，其包含：（A）由式I表示的可聚合离子对化合物，（B）具有两个或多个与可聚合离子对化合物（A）可共聚的不饱和基团的交联剂，和（C）不可聚合离子对化合物。 R1，R2，R3，R4，R5和R6各自表示氢原子，具有1-12个碳原子的烷基或芳基; 并且R 7和R 8各自表示具有1-12个碳原子的烷基或芳基。 X表示卤素原子，AlCl 4，SO 4，SO 4，SO 4，双（草酸）硼酸盐阴离子，R 1，SO 3，SO 3， - （NC）（R＆lt; 2＆gt; 2）＆lt; / SUP＆gt;，（R＆lt; SUB＆gt; （R 2，Y 2）2 C 2 O 3，其中R 1，R 2， Q，其中R f1表示具有1-8个碳原子的全氟烷基或芳基; 每个R f2表示氟原子，具有1-8个碳原子的全氟烷基或芳基; Y表示-SO 2 - 或-PO-R 1/2; 并且Q表示-H或-CO-R <！ - SIPO <

3. 发明申请

US20110287325A1 METHOD FOR PREPARING AN ELECTROCHEMICAL CELL HAVING A GEL ELECTROLYTE 有权
标题翻译：用于制备具有凝胶电解质的电化学细胞的方法
公开(公告)号：US20110287325A1
公开(公告)日：2011-11-24
申请号：US12921453
申请日：2009-03-05
申请人： Karim Zaghib , Manabu Kikuta , Martin Dontigny , Abdelbas Guerfi , Michiyuki Kono
发明人： Karim Zaghib , Manabu Kikuta , Martin Dontigny , Abdelbas Guerfi , Michiyuki Kono
IPC分类号： H01M10/056 , H01M4/525 , H01M10/04 , H01M4/583 , H01M4/485 , H01M4/505 , H01M4/40
CPC分类号： H01M10/0565 , H01G11/56 , H01M2300/0085 , Y02E60/12 , Y02E60/13
摘要： The invention relates to a method for manufacturing an electrochemical cell comprising an anode and a cathode separated by a separator and a gel electrolyte. The method comprises the steps of assembling the electrodes and the separator, and injecting a liquid electrolyte composition between the electrodes, the liquid electrolyte composition comprising a polymer, an aprotic liquid solvent and a lithium salt, wherein the polymer in the liquid electrolyte composition has functional groups capable of polymerizing via cationic polymerization, and the cell is submitted to an electrochemical cycling comprising a charging step and a discharging step.
摘要翻译：本发明涉及一种用于制造电化学电池的方法，所述电化学电池包括由隔膜和凝胶电解质分离的阳极和阴极。该方法包括以下步骤：组装电极和分离器，以及在电极之间注入液体电解质组合物，该液体电解质组合物包含聚合物，非质子液体溶剂和锂盐，其中液体电解质组合物中的聚合物具有功能能够通过阳离子聚合聚合的基团，并且电池进行包括充电步骤和放电步骤的电化学循环。

4. 发明申请

US20060276620A1 Process for manufacturing a pellet-shaped nonionic alkylene oxide resin 审中-公开
标题翻译：丸状非离子型环氧烷树脂的制造方法
公开(公告)号：US20060276620A1
公开(公告)日：2006-12-07
申请号：US11442188
申请日：2006-05-25
申请人： Fumihide Tamura , Izuho Okada , Hideo Wakami , Taketo Toba , Makoto Mizushima , Shigetaka Takamiya , Shinichi Horo , Michiyuki Kono , Manabu Kikuta , Masaki Tezuka , Hiroshi Tanaka , Takao Yokohashi
发明人： Fumihide Tamura , Izuho Okada , Hideo Wakami , Taketo Toba , Makoto Mizushima , Shigetaka Takamiya , Shinichi Horo , Michiyuki Kono , Manabu Kikuta , Masaki Tezuka , Hiroshi Tanaka , Takao Yokohashi
IPC分类号： C08F6/10
CPC分类号： C08J3/12 , C08G65/30 , C08J2371/02
摘要： An object of the present invention is to provide a manufacturing process by which a pellet-shaped nonionic alkylene oxide resin can be obtained in a manner which is excellent in stability, economical efficiency and productivity and easy, wherein the pellet-shaped nonionic alkylene oxide resin, as a high-molecular material useful in a variety of applications, has a suitable molecular weight Mw and physical properties and is also excellent in the stability of the physical properties and further is also excellent in the handling property after the manufacture. As a means of achieving this object, the process for manufacturing a pellet-shaped nonionic alkylene oxide resin, according to the present invention, comprises the steps of: obtaining a nonionic alkylene oxide resin having fluidity by volatilizing a solvent from a nonionic alkylene oxide resin solution obtained in advance by solution polymerization; and then pelletizing the nonionic alkylene oxide resin having fluidity.
摘要翻译：本发明的目的是提供一种以稳定性，经济效率和生产率优异的方式获得丸状非离子环氧烷烃树脂的制备方法，其中颗粒状非离子环氧烷树脂作为可用于各种应用的高分子材料，具有合适的分子量Mw和物理性质，并且物理性能的稳定性也优异，并且在制造后的处理性也优异。作为实现该目的的手段，根据本发明的颗粒状非离子性环氧烷烃树脂的制造方法包括以下步骤：通过使来自非离子性环氧烷树脂的溶剂挥发而获得具有流动性的非离子环氧烷烃树脂溶液聚合预先得到的溶液; 然后造粒具有流动性的非离子环氧烷烃树脂。

5. 发明申请

US20060223995A1 Superhigh purity ionic liquid 失效
标题翻译：超高纯度离子液体
公开(公告)号：US20060223995A1
公开(公告)日：2006-10-05
申请号：US11356799
申请日：2006-02-17
申请人： Hirofumi Uchimura , Manabu Kikuta
发明人： Hirofumi Uchimura , Manabu Kikuta
IPC分类号： C07F9/02 , C07D279/12 , C07D265/28 , C07D213/20 , C07D239/02
CPC分类号： C07D233/54 , B01J35/12 , H01G11/20 , H01G11/60 , H01G11/62
摘要： An ionic liquid with an extremely low content of an impurity such as halogen ions which can be obtained easily at a relatively reduced cost, the ionic liquid comprising a pair of a cation K+ and an anion A− represented by the general formula (1) in which the content of an alkali metal as an impurity is 5 ppm or less and the content of a halogen ion is 1 ppm or less, the cation being preferably selected from the group represented by the following general formula (2) obtained by quarternizing a tertiary amine compound or a tertiary phosphine compound by using an acid ester represented by the following general formula (3) and then conducting salt exchange: in which R1 to R4 in the formula (2) each independently represents a linear or branched alkyl group of 1 to 8 carbon atoms, X represents a hetero atom and R in the formula (3) represents a linear or branched alkyl group of 1 to 8 carbon atoms.
摘要翻译：具有极低含量杂质如离子的离子液体，其可以以相对降低的成本容易地获得，离子液体包含一对阳离子K +和阴离子A SUP 作为杂质的碱金属的含量为5ppm以下，卤素离子的含量为1ppm以下的通式（1）表示的化合物，优选选自通过使用由以下通式（3）表示的酸酯季铵化叔胺化合物或叔膦化合物，然后进行盐交换而获得的由以下通式（2）表示的基团：其中R 1，式（2）中的R 4〜R 4各自独立地表示1〜8个碳原子的直链或支链烷基，X表示杂原子，式（3）中的R表示具有1至8个碳原子的直链或支链烷基。

6. 发明授权

US5332780A Compositions containing allylformamide copolymers 失效
标题翻译：含有烯丙基甲酰胺共聚物的组合物
公开(公告)号：US5332780A
公开(公告)日：1994-07-26
申请号：US44591
申请日：1993-04-08
申请人： Naoki Kitazawa , Manabu Kikuta , Hiroshi Hotta , Yutaka Nakayama , Hideyuki Sumi
发明人： Naoki Kitazawa , Manabu Kikuta , Hiroshi Hotta , Yutaka Nakayama , Hideyuki Sumi
IPC分类号： C08L67/02 , C08L69/00 , C08L77/00 , C08L101/02 , C08L33/24
CPC分类号： C08L69/00 , C08L101/02 , C08L67/02 , C08L77/00 , C08L2205/08
摘要： Thermoplastic resin compositions having the following component A-1 or A-2, component B and component C:(A-1): a polymer component having a functional group capable of reacting with an amino group, or(A-2): a composition of component (A-1) and a resin that is non-reactive with an amino group and is different from the resin used in the following component B(B) a thermoplastic resin component that is non-reactive with an amino group under the conditions required to mold the entire resin composition; and(C) a graft copolymer obtained by a graft reaction of a thermoplastic polymer, with a compound (I), or a copolymer having the repeating unit (II) and the repeating unit of an ethylenic unsaturated monomer, ##STR1## wherein R.sup.1 -R.sup.4, the same or different represent a hydrogen atom, an alkyl group, a cycloalkyl group, an aryl group or an aralkyl group.
摘要翻译：具有以下组分A-1或A-2，组分B和组分C的热塑性树脂组合物：（A-1）：具有能够与氨基反应的官能团的聚合物组分，或（A-2）：组分（A-1）的组成和与氨基不反应并且与以下组分B（B）中使用的树脂不同的树脂，与下述氨基不具有反应性的热塑性树脂组分模制整个树脂组合物所需的条件; （C）通过热塑性聚合物与化合物（I）或具有重复单元（II）的共聚物和烯属不饱和单体的重复单元的接枝反应获得的接枝共聚物，（II）其中R 1 -R 4相同或不同表示氢原子，烷基，环烷基，芳基或芳烷基。

7. 发明授权

US07605271B2 Superhigh purity ionic liquid 失效
标题翻译：超高纯度离子液体
公开(公告)号：US07605271B2
公开(公告)日：2009-10-20
申请号：US11356799
申请日：2006-02-17
申请人： Hirofumi Uchimura , Manabu Kikuta
发明人： Hirofumi Uchimura , Manabu Kikuta
IPC分类号： C07D233/02
CPC分类号： C07D233/54 , B01J35/12 , H01G11/20 , H01G11/60 , H01G11/62
摘要： Provided is an ionic liquid, represented by the formula K+A−, having a very low content of impurities, especially a low content of halogen ions and/or a low content of alkali metal, wherein K+is a quaternary ammonium ion, for example an imidazolium ion. Also provided is a quaternarization process for making the ionic liquid in reacted with an acid ester such as a sulfate or phosphate.
摘要翻译：提供一种离子液体，其由式K + A-表示，具有非常低的杂质含量，特别是低含量的卤素离子和/或低含量的碱金属，其中K +是季铵离子，用于例如咪唑鎓离子。还提供了使离子液体与酸酯如硫酸盐或磷酸盐反应的季铵化方法。

8. 发明申请

US20050197485A1 Process for production of ethylene oxide copolymer 审中-公开
标题翻译：生产环氧乙烷共聚物的方法
公开(公告)号：US20050197485A1
公开(公告)日：2005-09-08
申请号：US11051168
申请日：2005-02-05
申请人： Koichiro Saeki , Kazuo Takei , Toshiaki Kuriyama , Masashi Yukitake , Taketo Toba , Makoto Mizushima , Michiyuki Kono , Manabu Kikuta , Masahito Nishiura
发明人： Koichiro Saeki , Kazuo Takei , Toshiaki Kuriyama , Masashi Yukitake , Taketo Toba , Makoto Mizushima , Michiyuki Kono , Manabu Kikuta , Masahito Nishiura
IPC分类号： C08G65/02 , C08G18/48 , C08G65/08 , C08G65/14 , C08G65/26 , C08G65/34
CPC分类号： C08G65/2696 , C08G18/4837 , C08G65/08
摘要： An object of the present invention is to provide a process which can produce, easily and with good productivity and reproducibility, an ethylene oxide copolymer provided with desired compositional ratios of monomers and a desired molecular weight and further with a desired melting point. As a means of achieving this object, a process according to the present invention for production of an ethylene oxide copolymer is a process comprising a step of polymerizing a monomer mixture including ethylene oxide as a main component, thereby producing the ethylene oxide copolymer, with the process being characterized in that the polymerization step includes at least one step each of the following steps: a step in which only the ethylene oxide is supplied to thus polymerize it; and a step in which the ethylene oxide and another monomer are supplied to thus polymerize them.
摘要翻译：本发明的一个目的是提供一种可以制备具有期望组成比的单体和所需分子量并进一步具有所需熔点的环氧乙烷共聚物，能够容易地且具有良好的生产率和再现性的方法。作为实现该目的的手段，根据本发明的环氧乙烷共聚物的制造方法是包括使包含环氧乙烷作为主要成分的单体混合物聚合的步骤，从而制备环氧乙烷共聚物，方法的特征在于聚合步骤包括以下步骤中的至少一个步骤：仅供给环氧乙烷以使其聚合的步骤; 并且提供环氧乙烷和其它单体从而聚合它们的步骤。

9. 发明授权

US5420210A Formamide group-containing copolymer, process for producing the same, and thermoplastic resin composition containing the same 失效
标题翻译：含酰胺基的共聚物，其制造方法，含有该共聚物的热塑性树脂组合物
公开(公告)号：US5420210A
公开(公告)日：1995-05-30
申请号：US921343
申请日：1992-07-29
申请人： Naoki Kitazawa , Hiroshi Hotta , Hideyuki Sumi , Manabu Kikuta
发明人： Naoki Kitazawa , Hiroshi Hotta , Hideyuki Sumi , Manabu Kikuta
IPC分类号： C08F8/32 , C08F214/00 , C08F216/36 , C08F220/54 , C08F222/40
CPC分类号： C08F8/32 , C08F2800/10
摘要： A novel formamide group-containing copolymer, or a salt thereof, which can be used as a high-molecular weight amino reagent, a starting material for functional high-molecular weight compounds, a starting material for adhesives, a polymer compatibilizer, a resin modifier, etc., and can undergo hydrolysis to give a copolymer containing a primary amino group, and a novel copolymer containing a primary amino group obtained by hydrolysis.
摘要翻译：可用作高分子量氨基试剂的新型含甲酰胺基团的共聚物或其盐，功能性高分子化合物的起始原料，粘合剂原料，聚合物相容剂，树脂改性剂等，并且可以进行水解，得到含有伯氨基的共聚物，以及含有通过水解获得的伯氨基的新型共聚物。

10. 发明授权

US08828609B2 Method for preparing an electrochemical cell having a gel electrolyte 有权
标题翻译：制备具有凝胶电解质的电化学电池的方法
公开(公告)号：US08828609B2
公开(公告)日：2014-09-09
申请号：US12921453
申请日：2009-03-05
申请人： Karim Zaghib , Manabu Kikuta , Martin Dontigny , Abdelbast Guerfi , Michiyuki Kono
发明人： Karim Zaghib , Manabu Kikuta , Martin Dontigny , Abdelbast Guerfi , Michiyuki Kono
IPC分类号： H01M10/0565 , H01M10/04 , H01G11/56
CPC分类号： H01M10/0565 , H01G11/56 , H01M2300/0085 , Y02E60/12 , Y02E60/13
摘要： The invention relates to a method for manufacturing an electrochemical cell comprising an anode and a cathode separated by a separator and a gel electrolyte. The method comprises the steps of assembling the electrodes and the separator, and injecting a liquid electrolyte composition between the electrodes, the liquid electrolyte composition comprising a polymer, an aprotic liquid solvent and a lithium salt, wherein the polymer in the liquid electrolyte composition has functional groups capable of polymerizing via cationic polymerization, and the cell is submitted to an electrochemical cycling comprising a charging step and a discharging step.
摘要翻译：本发明涉及一种用于制造电化学电池的方法，所述电化学电池包括由隔膜和凝胶电解质分离的阳极和阴极。该方法包括以下步骤：组装电极和分离器，以及在电极之间注入液体电解质组合物，该液体电解质组合物包含聚合物，非质子液体溶剂和锂盐，其中液体电解质组合物中的聚合物具有功能能够通过阳离子聚合聚合的基团，并且电池进行包括充电步骤和放电步骤的电化学循环。

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