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    • 1. 发明申请
    • Superhigh purity ionic liquid
    • 超高纯度离子液体
    • US20060223995A1
    • 2006-10-05
    • US11356799
    • 2006-02-17
    • Hirofumi UchimuraManabu Kikuta
    • Hirofumi UchimuraManabu Kikuta
    • C07F9/02C07D279/12C07D265/28C07D213/20C07D239/02
    • C07D233/54B01J35/12H01G11/20H01G11/60H01G11/62
    • An ionic liquid with an extremely low content of an impurity such as halogen ions which can be obtained easily at a relatively reduced cost, the ionic liquid comprising a pair of a cation K+ and an anion A− represented by the general formula (1) in which the content of an alkali metal as an impurity is 5 ppm or less and the content of a halogen ion is 1 ppm or less, the cation being preferably selected from the group represented by the following general formula (2) obtained by quarternizing a tertiary amine compound or a tertiary phosphine compound by using an acid ester represented by the following general formula (3) and then conducting salt exchange: in which R1 to R4 in the formula (2) each independently represents a linear or branched alkyl group of 1 to 8 carbon atoms, X represents a hetero atom and R in the formula (3) represents a linear or branched alkyl group of 1 to 8 carbon atoms.
    • 具有极低含量杂质如离子的离子液体,其可以以相对降低的成本容易地获得,离子液体包含一对阳离子K +和阴离子A SUP 作为杂质的碱金属的含量为5ppm以下,卤素离子的含量为1ppm以下的通式(1)表示的化合物,优选选自 通过使用由以下通式(3)表示的酸酯季铵化叔胺化合物或叔膦化合物,然后进行盐交换而获得的由以下通式(2)表示的基团:其中R 1, 式(2)中的R 4〜R 4各自独立地表示1〜8个碳原子的直链或支链烷基,X表示杂原子,式(3)中的R表示 具有1至8个碳原子的直链或支链烷基。