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    • 1. 发明授权
    • Imaging member containing a copolymer of styrene and ethyl acrylate
    • 含有苯乙烯和丙烯酸乙酯共聚物的成像构件
    • US4853307A
    • 1989-08-01
    • US140441
    • 1988-01-04
    • Man C. TamSteven BloembergenGregory J. KovacsCarol A. JenningsRafik O. LoutfySandra J. GardnerMichael G. Taylor
    • Man C. TamSteven BloembergenGregory J. KovacsCarol A. JenningsRafik O. LoutfySandra J. GardnerMichael G. Taylor
    • G03G5/02G03G13/22G03G17/08
    • G03G13/22G03G17/08
    • An imaging system including a migration imaging member comprising a substrate and an electrically insulating softening layer adjacent the substrate, the softenable layer comprising a fracturable layer of electrically photosensitive migration marking material located substantially at or near the surface of the softenable layer spaced from the substrate, and a copolymer of styrene and ethyl acrylate in at least one layer adjacent the substrate, the copolymer comprising between about 40 and about 80 mole percent styrene, between about 20 and about 60 mole percent ethyl acrylate, the copolymer having a M.sub.n between about 4,000 and about 35,000, a M.sub.w between about 10,000 and about 80,000, a T.sub.g between about 30.degree. C. and about 75.degree. C., and a melt viscosity between about 1.times.10.sup.2 poise and about 1.times.10.sup.6 poise at 115.degree. C.The migration imaging member may be imaged by charging, imagewise exposing to activating radiation and developing with heat, solvent vapor, or solvent vapor pretreatment followed by heat. Some embodiments of the imaged member, wherein the softenable layer contains a charge transport material, may be utilized as a master in a zeroprinting process. The copolymer of styrene and ethyl acrylate may be in an adhesive layer of charge transport spacing layer between the substrate and the sofenable layer, or in the softenable layer itself. If desired, the copolymer in any of the aforesaid layers may be a terpolymer of styrene, ethyl acrylate and a copolymerizable organic acid having carbon-to-carbon unsaturation or a copolymerizable derivative of the organic acid.
    • 一种成像系统,其包括迁移成像构件,所述迁移成像构件包括基底和邻近所述基底的电绝缘软化层,所述可软化层包括位于所述可软化层的与所述基底隔开的表面的表面附近或附近的电光敏迁移标记材料的可破裂层, 和苯乙烯和丙烯酸乙酯在邻近基材的至少一层中的共聚物,所述共聚物包含约40至约80摩尔%的苯乙烯,约20至约60摩尔%的丙烯酸乙酯,所述共聚物的Mn在约4,000和 约35,000,约10,000至约80,000的Mw,约30℃至约75℃之间的Tg,以及在115℃下约1×102泊至约1×10 6泊的熔体粘度。迁移成像构件可以是 通过充电成像,成像暴露于活化辐射并用热,溶剂蒸气或溶剂蒸气预处理进行显影 加热。 成像构件的一些实施方案,其中可软化层含有电荷传输材料,可以在压印过程中用作母体。 苯乙烯和丙烯酸乙酯的共聚物可以在基材和可渗透层之间或在可软化层本身中的电荷输送间隔层的粘合剂层中。 如果需要,任何上述层中的共聚物可以是苯乙烯,丙烯酸乙酯和具有碳 - 碳不饱和键的可共聚有机酸或有机酸的可共聚衍生物的三元共聚物。
    • 3. 发明授权
    • Processes for preparing copolymers
    • 制备共聚物的方法
    • US6124409A
    • 2000-09-26
    • US929457
    • 1992-08-12
    • T. Hwee NgHadi K. MahabadiMan C. TamGregory J. KovacsEric M. PetersRafik O. Loutfy
    • T. Hwee NgHadi K. MahabadiMan C. TamGregory J. KovacsEric M. PetersRafik O. Loutfy
    • C08F2/00C08F2/06C08F2/18C08F4/38
    • C08F2/001C08F2/06Y10S526/921
    • Disclosed is a process for preparing copolymers which comprises, in the order stated: (1) adding monomers containing unsaturated carbon-to-carbon bonds, a first polymerization initiator, a second polymerization initiator, and a solvent to a reaction vessel; (2) purging the resulting solution with an inert gas; (3) sealing the reaction vessel and pressurizing it by addition of an inert gas to a pressure of from about 20 to about 600 kilopascals over ambient atmospheric pressure; (4) maintaining the temperature within the pressurized reaction vessel at a temperature of from about 50 to about 100.degree. C. for a period of from about 60 to about 300 minutes; (5) thereafter maintaining the temperature within the pressurized reaction vessel at a temperature of from about 80 to about 115.degree. C. for a period of from about 30 to about 300 minutes, wherein the temperature in step (5) is higher than the temperature in step (4); and (6) subsequently maintaining the temperature within the pressurized reaction vessel at a temperature of from about 115 to about 160.degree. C. for a period of from about 30 to about 180 minutes, wherein the temperature in step (6) is higher than the temperature in step (5). Polymers prepared according to the process of the present invention can be particularly useful in migration imaging members.
    • 公开了一种制备共聚物的方法,其顺序包括:(1)向反应容器中加入含有不饱和碳 - 碳键的单体,第一聚合引发剂,第二聚合引发剂和溶剂; (2)用惰性气体吹扫所得溶液; (3)密封反应容器并通过在环境大气压下加入约20至约600千帕斯卡的惰性气体对其加压; (4)将加压反应容器内的温度维持在约50至约100℃的温度下约60至约300分钟; (5)之后将加压反应容器内的温度保持在约80至约115℃的温度下约30至约300分钟的时间,其中步骤(5)中的温度高于温度 在步骤(4)中; 和(6)随后将加压反应容器内的温度保持在约115至约160℃的温度下约30至约180分钟的时间,其中步骤(6)中的温度高于 步骤(5)中的温度。 根据本发明的方法制备的聚合物可以在迁移成像构件中特别有用。
    • 8. 发明授权
    • Migration imaging process
    • 移植成像过程
    • US06180297B2
    • 2001-01-30
    • US08432291
    • 1995-05-01
    • Man C. TamEdward G. Zwartz
    • Man C. TamEdward G. Zwartz
    • G03G1710
    • G03G17/10
    • Disclosed is a process which comprises (a) providing a migration imaging member comprising (1) a substrate, (2) an infrared or red light radiation sensitive layer comprising a pigment predominantly sensitive to infrared or red light radiation, and (3) a softenable layer comprising a softenable material, a charge transport material, and a photosensitive migration marking material predominantly sensitive to radiation at a wavelength other than that to which the infrared or red light sensitive pigment is predominantly sensitive; (b) uniformly charging the imaging member; (c) subsequent to step (b), uniformly exposing the charged imaging member to a source of activating radiation with a wavelength to which the migration marking material is sensitive, wherein a filter comprising the infrared or red light radiation sensitive pigment is situated between the radiation source and the imaging member; (d) subsequent to step (b), exposing the imaging member to infrared or red light radiation at a wavelength to which the infrared or red light radiation sensitive pigment is sensitive in an imagewise pattern, thereby forming an electrostatic latent image on the imaging member; and (e) subsequent to steps (c) and (d), causing the softenable material to soften, thereby enabling the migration marking material to migrate through the softenable material toward the substrate in an imagewise pattern.
    • 公开了一种方法,其包括(a)提供迁移成像构件,其包括(1)基底,(2)包含主要对红外或红光辐射敏感的颜料的红外或红光辐射敏感层,和(3)可软化 层,其包含可软化材料,电荷传输材料和主要对红外或红色光敏颜料主要敏感的波长以外的波长的辐射敏感的光敏迁移标记材料; (b)对成像构件均匀充电; (c)在步骤(b)之后,将所充电的成像构件均匀地暴露于迁移标记材料敏感的波长的激活辐射源,其中包含红外或红光辐射敏感颜料的滤光器位于 辐射源和成像构件; (d)在步骤(b)之后,以成像图案将成像构件暴露于红外或红光敏感颜料敏感的波长处的红外或红光辐射,从而在成像构件上形成静电潜像 ; 和(e)步骤(c)和(d)之后,使可软化材料软化,从而使迁移标记材料能够以可成形图案向基材迁移通过可软化材料。
    • 9. 发明授权
    • Colored cyber toner using multicolored gyricon spheres
    • 彩色网络碳粉使用多彩陀螺球
    • US06699570B2
    • 2004-03-02
    • US09985825
    • 2001-11-06
    • Naveen ChopraSteven GeorgesPeter M. KazmaierSammy Y.H. RoMan C. TamFrancisco E. TorresSophie V. Vandebroek
    • Naveen ChopraSteven GeorgesPeter M. KazmaierSammy Y.H. RoMan C. TamFrancisco E. TorresSophie V. Vandebroek
    • B32B300
    • B32B5/02B32B2554/00Y10T428/24835Y10T428/25Y10T428/2915Y10T428/2982Y10T442/2418
    • A dynamic reimageable document or electric paper can be formed from ordinary substrates such as paper, transparencies or fabric by printing of microencapsulated Gyricon beads onto one or more discrete surface areas of the substrate. The substrate can include both fixed print regions formed by conventional fixed ink processes and dynamic reimageable regions formed by the Gyricon beads. The Gyricon beads are preferably bichromal and of contrasting colors, such as black/white so as to be changeable to display two states by selective application of electromagnetic force to the beads. By providing bichromal beads in differing color combinations, such as red/white and black/white, a multi-colored document can be achieved in which various fields of the document, representing text, images or graphics, may be in differing colors. Moreover, operations to perform both imaging or erasure can act on the discrete reimageable regions so that the versatility of the electric paper can be enhanced. The Gyricon beads may be dispersed in a solution to form a liquid Gyricon toner that can be directly marked, such as by a jet nozzle, into a desired pattern on the substrate.
    • 通过将微胶囊化Gyricon珠粒印刷到基底的一个或多个离散的表面区域上,可以由诸如纸,透明胶片或织物的普通基材形成动态可再成像的文件或电纸。 衬底可以包括通过常规固定油墨工艺形成的固定印刷区域和由Gyricon珠形成的动态可再形成区域。 Gyricon珠子优选是双色的,并且具有对比色,例如黑色/白色,以便通过选择性地向珠粒施加电磁力来显示两种状态。 通过提供不同颜色组合的双色珠,例如红/白和黑/白,可以实现多色文档,其中表示文本,图像或图形的文档的各个领域可以具有不同的颜色。 此外,执行成像或擦除的操作可以作用于离散的可再成像区域,使得可以增强电纸的通用性。 Gyricon珠可以分散在溶液中以形成液体Gyricon调色剂,其可以通过喷嘴直接标记成基底上所需的图案。