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1. 发明专利

JP2004051428A Membrane reaction apparatus 审中-公开
公开(公告)号：JP2004051428A
公开(公告)日：2004-02-19
申请号：JP2002210990
申请日：2002-07-19
申请人： Chubu Electric Power Co Inc , Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社 , 中部電力株式会社
发明人： NAGAYA SHIGEO , FURUMURA SEIJI , WATANABE AKIZO , TACHIBANA SHINYA , KOBAYASHI KAZUTO
IPC分类号： B01D53/22 , B01D63/06 , B01J19/24 , B01J35/06 , C01B3/36 , C01B3/40 , C10L3/10
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To efficiently manufacture a synthesis gas having a molar ratio H 2 /CO of 2 while avoiding a plant from becoming large-sized and expensive. SOLUTION: The membrane reaction apparatus includes: a membrane reaction main body 1; an air flow zone 3 provided in the membrane reaction apparatus main body, having an air supply port 4 and an exhaust gas discharge port 5 and divided by a partition formed so as to contain an oxygen permeable pipe 2; and a gas flow zone 6 provided in the membrane reaction apparatus main body, having a gaseous starting material supply port 7, a synthetic gas discharge port 8 and an outside pipe 9 provided around the oxygen permeable pipe 2 to connect the gaseous supply port to the synthetic gas discharge port, and separated from the air flow zone 3 by the partition, the gas flow zone 6 including an annular zone 10 formed between the oxygen permeable pipe 2 and the outside pipe 9. COPYRIGHT: (C)2004,JPO

2. 发明专利

JP2003183004A METHOD FOR MANUFACTURING SYNTHETIC GAS, AND SYSTEM FOR MANUFACTURING LIQUID FUEL AND SYSTEM FOR GENERATING FUEL CELL-ELECTRIC POWER UTILIZING THIS 审中-公开
公开(公告)号：JP2003183004A
公开(公告)日：2003-07-03
申请号：JP2001381536
申请日：2001-12-14
申请人： MITSUBISHI HEAVY IND LTD , CHUBU ELECTRIC POWER
发明人： TACHIBANA SHINYA , KOBAYASHI KAZUTO , NAGAYA SHIGEO , FURUMURA SEIJI , WATANABE AKIZO
IPC分类号： C01B3/38 , C01B3/36 , C10G2/00 , H01M8/06 , H01M8/10
摘要： PROBLEM TO BE SOLVED: To obtain a synthetic gas of H 2 /CO=2 while avoiding a large-scaled or high-cost plant and to effectively utilize this synthetic gas. SOLUTION: The method for manufacturing a synthetic gas comprises a combination of a steam reforming reaction and a partial oxidation reaction of a raw material gas by means of a membrane reactor 11 using an oxygen- permeable membrane, and is characterized in that the mole ratio of S(steam)/C, that of O 2 /C and that of CO 2 /C are regulated by regulating the quantities of the natural gas, H 2 O and CO 2 which are fed into the above membrane reactor 11 and by regulating the quantity of O 2 which permeates through the oxygen permeable membrane. COPYRIGHT: (C)2003,JPO

3. 发明专利

JP2004267884A Membrane reaction apparatus and synthetic gas production method using the same 有权
公开(公告)号：JP2004267884A
公开(公告)日：2004-09-30
申请号：JP2003060948
申请日：2003-03-07
申请人： Chubu Electric Power Co Inc , Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社 , 中部電力株式会社
发明人： NAGAYA SHIGEO , FURUMURA SEIJI , WATANABE AKIZO , TACHIBANA SHINYA , KOBAYASHI KAZUTO
IPC分类号： B01D53/22 , B01D63/06 , C01B3/36 , C01B3/38 , C10L3/10
摘要： PROBLEM TO BE SOLVED: To provide a membrane reaction apparatus by which a synthetic gas having a H 2 /CO mole ratio of approximately two can be produced effectively while enlargement of a plant or increase in cost is avoided. SOLUTION: The membrane reaction apparatus having a membrane reaction apparatus body includes an air circulation area 3, which is inside the apparatus body, has an air supply port 4 and an exhaust gas discharge port 5, is demarcated with an oxygen permeable pipe 2, and is provided with a combustion catalyst 13 for burning a natural gas. The apparatus further includes a gas circulation area 6, which is also inside the apparatus body, has a feed gas supply port 7 and a synthetic gas discharge port 8, and is separated from the air circulation area 3 via the oxygen permeable pipe 2. COPYRIGHT: (C)2004,JPO&NCIPI

4. 发明专利

JP2005291236A Sealing structure for connecting part between metallic tubular member and ceramic tubular member 审中-公开
标题翻译：用于连接金属管构件与陶瓷管构件之间的密封结构
公开(公告)号：JP2005291236A
公开(公告)日：2005-10-20
申请号：JP2004102980
申请日：2004-03-31
申请人： Chubu Electric Power Co Inc , Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社 , 中部電力株式会社
发明人： NAGAYA SHIGEO , FURUMURA SEIJI , WATANABE AKIZO , TACHIBANA SHINYA , KOBAYASHI KAZUTO
IPC分类号： F16J15/10 , H01M8/02
CPC分类号： Y02E60/50
摘要： PROBLEM TO BE SOLVED: To seal a connecting part of a metallic member and a ceramic member under conditions of operating temperatures as high as 800°C or more and pressure differences. SOLUTION: This sealing structure 101 of a connecting part between a metallic tubular member 112 and a ceramic tubular member 102 comprises a metallic encircling member 104 covering at least the connecting part, and a ceramic encircling member 105 covering at least part of the metallic encircling member. Coefficients of thermal expansion at operating temperatures are set to increase in the order of the ceramic encircling member 105, the ceramic tubular member 102, the metallic tubular member 112, and the metallic encircling member 104. At operating temperatures, the metallic encircling member 104 adheres to the ceramic tubular member 102 and the metallic tubular member 112, and the ceramic encircling member 105 adheres to the metallic encircling member 104, thereby sealing the connecting part. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：在操作温度高达800℃以上和压力差的条件下，密封金属构件和陶瓷构件的连接部。解决方案：金属管状构件112和陶瓷管状构件102之间的连接部分的密封结构101包括覆盖至少连接部分的金属环绕构件104和覆盖至少部分的陶瓷环绕构件105 金属环绕构件。在陶瓷环绕构件105，陶瓷管状构件102，金属管状构件112和金属环绕构件104的操作温度下的热膨胀系数被设定为增加。在操作温度下，金属环绕构件104粘附陶瓷管状构件102和金属管状构件112，并且陶瓷环绕构件105粘附到金属环绕构件104，从而密封连接部。版权所有（C）2006，JPO＆NCIPI

5. 发明专利

JP2003277009A Membrane reactor 审中-公开
标题翻译：膜反应器
公开(公告)号：JP2003277009A
公开(公告)日：2003-10-02
申请号：JP2002085202
申请日：2002-03-26
申请人： Chubu Electric Power Co Inc , Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社 , 中部電力株式会社
发明人： NAGAYA SHIGEO , FURUMURA SEIJI , WATANABE AKIZO , TACHIBANA SHINYA , KOBAYASHI KAZUTO
IPC分类号： B01D53/22 , B01J19/24 , C01B3/38
摘要： PROBLEM TO BE SOLVED: To provide a membrane reactor for obtaining synthesis gas having about 2 H
2 /CO molar ratio while avoiding that the size of a plant is made larger and the cost is increased.
SOLUTION: This membrane reactor contains a main body 1, a first region 3 which is formed in the body 1, has a gas supplying port 4 and a discharge port 5 and is divided by a partition wall containing a tube-structured part 2 at least a part of that is formed by using an oxygen-permeable membrane and a second region 6 which is also formed in the body 1, has a gas supplying port 7 and a discharge port 8 and is separated from the region 3 by the partition wall. This apparatus is constituted so that the oxygen, which is contained in the oxygen-containing gas to be supplied to one of the regions 3 and 6, permeated through the oxygen-permeable membrane and made to flow in the other of the regions 3 and 6 can be reacted with the gaseous raw material to be supplied to the other of the regions 3 and 6 together with steam.
COPYRIGHT: (C)2004,JPO
摘要翻译：要解决的问题：提供一种膜反应器，用于获得具有约2H 2 SB / CO摩尔比的合成气，同时避免了植物的尺寸变大并且成本增加。解决方案：该膜反应器包括主体1，形成在主体1中的第一区域3具有气体供给口4和排出口5，并且被分隔壁分隔，该分隔壁包含管结构部分 2，其中至少一部分通过使用透氧膜和形成在主体1中的第二区域6形成，具有气体供给口7和排出口8，并且与区域3分离隔墙。该装置构成为使供给到区域3,6的一部分的含氧气体中所含的氧气透过透氧膜并使其在区域3,6中另一方流动可以与气体原料反应以供应到区域3和6中的另一个与蒸汽一起。版权所有（C）2004，JPO

6. 发明公开

EP2226114A4 DEHYDRATING SYSTEM AND METHOD 审中-公开
标题翻译：脱水系统和方法
公开(公告)号：EP2226114A4
公开(公告)日：2013-12-04
申请号：EP08868848
申请日：2008-12-24
申请人： MITSUBISHI HEAVY IND LTD
发明人： YUKUMOTO ATSUHIRO , OSORA HIROYUKI , SEIKI YOSHIO , HIRAYAMA HARUAKI , KOBAYASHI KAZUTO , TANAKA YUKIO
IPC分类号： B01D61/36 , B01D61/58 , B01D67/00 , B01D71/02 , B01D71/38 , B01D71/56
CPC分类号： B01D61/362 , B01D67/0048 , B01D71/027 , B01D71/028 , B01D71/38 , B01D71/56 , B01D71/64 , B01D2313/38 , B01D2317/022 , B01D2317/027 , B01D2323/12 , C07C29/76 , C07C31/08

7. 发明公开

EP1623758A4 CATALYST FOR DIMETHYL CARBONATE SYNTHESIS 有权转让
标题翻译：催化剂的碳酸二甲酯
公开(公告)号：EP1623758A4
公开(公告)日：2007-08-22
申请号：EP04728019
申请日：2004-04-16
申请人： MITSUBISHI HEAVY IND LTD
发明人： OSORA HIROYUKI , KOBAYASHI KAZUTO , SEIKI YOSHIO , YASUTAKE TOSHINOBU , IIJIMA MASAKI , OGUCHI AKIRA
IPC分类号： B01J27/053 , B01J27/16 , B01J27/18 , C07B61/00 , C07C68/04 , C07C69/96
CPC分类号： B01J27/053 , B01J27/16 , C07C68/04 , Y02P20/544 , C07C69/96
摘要： An economical catalyst for dimethyl carbonate synthesis is disclosed which has a high conversion rate under supercritical conditions of CO2 and can be handled easily. The catalyst for dimethyl carbonate synthesis is obtained by loading SO42- or PO43- on a carrier composed of a compound having a solid acid site, and used for producing dimethyl carbonate from acetone dimethyl acetal and CO2 in supercritical state. The compound having a solid acid site is preferably one or more of ZrO2, Al2O3 and TiO2.

8. 发明公开

EP1101812A4 METHOD FOR CONVERTING CHLORINE-CONTAINING WASTE PLASTIC TO OIL 有权
标题翻译： PROCESS氯气废塑料与油的转换
公开(公告)号：EP1101812A4
公开(公告)日：2004-07-21
申请号：EP99926929
申请日：1999-07-05
申请人： TOHOKU ELECTRIC POWER CO , MITSUBISHI HEAVY IND LTD
发明人： SAITO YOSHIHISA , MORIYA TAKEHIKO , TABATA MASANORI , UKAWA NAOHIKO , KANEKO MASATO , KOBAYASHI KAZUTO , HASEGAWA SHIGEO , MATSUBARA WATARU , IWASAKI KENJI , OHSHIMA MICHIO
IPC分类号： C10G1/04 , C10G1/10 , B09B3/00 , C10J3/46
CPC分类号： C10G1/04 , C10G1/10
摘要： A method for converting a chlorine-containing waste plastic comprising heating the mixture of a waste plastic containing a chlorine-containing plastic with an aqueous solution of an alkali metal carbonate or a hydroxide or carbonate of an alkaline earth metal or an aqueous solution containing a plurality of these compounds, which is adjusted to have a concentration of dissolved oxygen as low as 0.5 mg/liter or less, to liberate the chlorine in the waste plastic and decompose the waste plastic in the process of transferring to a supercritical condition or under a supercritical condition, or comprising heating an aqueous solution of an alkali metal carbonate or a hydroxide or carbonate of an alkaline earth metal or an aqueous solution containing a plurality of these compounds, and admixing a molten waste plastic containing a chlorine-containing plastic into this aqueous solution in the process of transferring to a supercritical condition or under a supercritical condition, wherein the concentration of dissolved oxygen in the aqueous solution is adjusted to 0.5 mg/liter or less before or upon admixing of the waste plastic, to thereby liberate the chlorine in the waste plastic and decompose the waste plastic.

9. 发明公开

EP1541217A4 SEPARATOR, REACTOR, AND PROCESS FOR PRODUCING AROMATIC CARBOXYLIC ACID 审中-公开
标题翻译：分离器，反应器和方法生产芳族CARBONSûURE
公开(公告)号：EP1541217A4
公开(公告)日：2011-10-26
申请号：EP03791433
申请日：2003-08-29
申请人： MITSUBISHI HEAVY IND LTD , MITSUBISHI CHEM CORP
发明人： SEIKI YOSHIO , KOBAYASHI KAZUTO , TAKEUCHI YOSHIYUKI , OSORA HIROYUKI , AKIMOTO KEIICHI , MATSUMOTO NORITAKA , NUMATA MOTOKI , SHIMAZU HIROAKI
IPC分类号： B01J8/00 , B01D3/14 , B01D3/42 , B01D53/26 , C07C51/265 , C07C51/44 , C07C51/47
CPC分类号： B01J8/009 , B01D3/14 , B01D3/143 , B01D3/4205 , B01D53/268 , B01J2219/00006 , C07C51/265 , C07C51/44 , C07C51/47 , Y10S159/03 , Y10S159/27 , Y10S159/28 , C07C63/26

10. 发明公开

EP0814143A2 Method and apparatus for converting a plastic waste into oil 失效
标题翻译： Öl的Verfahren und Apparat zur Konvertierung vonKunststoffabfällen
公开(公告)号：EP0814143A2
公开(公告)日：1997-12-29
申请号：EP97401152
申请日：1997-05-26
申请人： MITSUBISHI HEAVY IND LTD
发明人： MATSUBARA WATARU , KOBAYASHI KAZUTO , MAKIHARA HIROSHI , IIJIMA MASAKI
IPC分类号： B09B3/00 , C08J11/00 , C10G1/10
CPC分类号： C10G1/10
摘要： A method of converting a plastic waste into oil by decomposing the plastic waste by a reaction using water in a supercritical or near supercritical region as a reaction medium. In this method, the reaction is conducted by using a tubular continuous reactor. The present invention further provides an apparatus therefor. Moreover, the present invention provides a method of converting a plastic waste into oil by conducting the reaction after hydrogen chloride is removed by performing the pyrolysis of the plastic waste in the case that the plastic waste contain chlorine. The present invention further provides an apparatus for performing this method.
摘要翻译：通过使用超临界或近超临界区域中的水作为反应介质的反应，通过使塑料废物分解来将塑料废物转化为油的方法。在该方法中，通过使用管状连续反应器进行反应。本发明还提供了一种装置。此外，本发明提供了一种在塑料废物含有氯的情况下通过进行塑性废物的热分解而在除去氯化氢之后通过进行反应来将塑料废物转化为油的方法。本发明还提供一种用于执行该方法的装置。

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