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1. 发明专利

JP2004267884A Membrane reaction apparatus and synthetic gas production method using the same 有权
公开(公告)号：JP2004267884A
公开(公告)日：2004-09-30
申请号：JP2003060948
申请日：2003-03-07
申请人： Chubu Electric Power Co Inc , Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社 , 中部電力株式会社
发明人： NAGAYA SHIGEO , FURUMURA SEIJI , WATANABE AKIZO , TACHIBANA SHINYA , KOBAYASHI KAZUTO
IPC分类号： B01D53/22 , B01D63/06 , C01B3/36 , C01B3/38 , C10L3/10
摘要： PROBLEM TO BE SOLVED: To provide a membrane reaction apparatus by which a synthetic gas having a H 2 /CO mole ratio of approximately two can be produced effectively while enlargement of a plant or increase in cost is avoided. SOLUTION: The membrane reaction apparatus having a membrane reaction apparatus body includes an air circulation area 3, which is inside the apparatus body, has an air supply port 4 and an exhaust gas discharge port 5, is demarcated with an oxygen permeable pipe 2, and is provided with a combustion catalyst 13 for burning a natural gas. The apparatus further includes a gas circulation area 6, which is also inside the apparatus body, has a feed gas supply port 7 and a synthetic gas discharge port 8, and is separated from the air circulation area 3 via the oxygen permeable pipe 2. COPYRIGHT: (C)2004,JPO&NCIPI

2. 发明专利

JP2004051428A Membrane reaction apparatus 审中-公开
公开(公告)号：JP2004051428A
公开(公告)日：2004-02-19
申请号：JP2002210990
申请日：2002-07-19
申请人： Chubu Electric Power Co Inc , Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社 , 中部電力株式会社
发明人： NAGAYA SHIGEO , FURUMURA SEIJI , WATANABE AKIZO , TACHIBANA SHINYA , KOBAYASHI KAZUTO
IPC分类号： B01D53/22 , B01D63/06 , B01J19/24 , B01J35/06 , C01B3/36 , C01B3/40 , C10L3/10
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To efficiently manufacture a synthesis gas having a molar ratio H 2 /CO of 2 while avoiding a plant from becoming large-sized and expensive. SOLUTION: The membrane reaction apparatus includes: a membrane reaction main body 1; an air flow zone 3 provided in the membrane reaction apparatus main body, having an air supply port 4 and an exhaust gas discharge port 5 and divided by a partition formed so as to contain an oxygen permeable pipe 2; and a gas flow zone 6 provided in the membrane reaction apparatus main body, having a gaseous starting material supply port 7, a synthetic gas discharge port 8 and an outside pipe 9 provided around the oxygen permeable pipe 2 to connect the gaseous supply port to the synthetic gas discharge port, and separated from the air flow zone 3 by the partition, the gas flow zone 6 including an annular zone 10 formed between the oxygen permeable pipe 2 and the outside pipe 9. COPYRIGHT: (C)2004,JPO

3. 发明专利

JP2005291236A Sealing structure for connecting part between metallic tubular member and ceramic tubular member 审中-公开
标题翻译：用于连接金属管构件与陶瓷管构件之间的密封结构
公开(公告)号：JP2005291236A
公开(公告)日：2005-10-20
申请号：JP2004102980
申请日：2004-03-31
申请人： Chubu Electric Power Co Inc , Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社 , 中部電力株式会社
发明人： NAGAYA SHIGEO , FURUMURA SEIJI , WATANABE AKIZO , TACHIBANA SHINYA , KOBAYASHI KAZUTO
IPC分类号： F16J15/10 , H01M8/02
CPC分类号： Y02E60/50
摘要： PROBLEM TO BE SOLVED: To seal a connecting part of a metallic member and a ceramic member under conditions of operating temperatures as high as 800°C or more and pressure differences. SOLUTION: This sealing structure 101 of a connecting part between a metallic tubular member 112 and a ceramic tubular member 102 comprises a metallic encircling member 104 covering at least the connecting part, and a ceramic encircling member 105 covering at least part of the metallic encircling member. Coefficients of thermal expansion at operating temperatures are set to increase in the order of the ceramic encircling member 105, the ceramic tubular member 102, the metallic tubular member 112, and the metallic encircling member 104. At operating temperatures, the metallic encircling member 104 adheres to the ceramic tubular member 102 and the metallic tubular member 112, and the ceramic encircling member 105 adheres to the metallic encircling member 104, thereby sealing the connecting part. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：在操作温度高达800℃以上和压力差的条件下，密封金属构件和陶瓷构件的连接部。解决方案：金属管状构件112和陶瓷管状构件102之间的连接部分的密封结构101包括覆盖至少连接部分的金属环绕构件104和覆盖至少部分的陶瓷环绕构件105 金属环绕构件。在陶瓷环绕构件105，陶瓷管状构件102，金属管状构件112和金属环绕构件104的操作温度下的热膨胀系数被设定为增加。在操作温度下，金属环绕构件104粘附陶瓷管状构件102和金属管状构件112，并且陶瓷环绕构件105粘附到金属环绕构件104，从而密封连接部。版权所有（C）2006，JPO＆NCIPI

4. 发明专利

JP2003277009A Membrane reactor 审中-公开
标题翻译：膜反应器
公开(公告)号：JP2003277009A
公开(公告)日：2003-10-02
申请号：JP2002085202
申请日：2002-03-26
申请人： Chubu Electric Power Co Inc , Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社 , 中部電力株式会社
发明人： NAGAYA SHIGEO , FURUMURA SEIJI , WATANABE AKIZO , TACHIBANA SHINYA , KOBAYASHI KAZUTO
IPC分类号： B01D53/22 , B01J19/24 , C01B3/38
摘要： PROBLEM TO BE SOLVED: To provide a membrane reactor for obtaining synthesis gas having about 2 H
2 /CO molar ratio while avoiding that the size of a plant is made larger and the cost is increased.
SOLUTION: This membrane reactor contains a main body 1, a first region 3 which is formed in the body 1, has a gas supplying port 4 and a discharge port 5 and is divided by a partition wall containing a tube-structured part 2 at least a part of that is formed by using an oxygen-permeable membrane and a second region 6 which is also formed in the body 1, has a gas supplying port 7 and a discharge port 8 and is separated from the region 3 by the partition wall. This apparatus is constituted so that the oxygen, which is contained in the oxygen-containing gas to be supplied to one of the regions 3 and 6, permeated through the oxygen-permeable membrane and made to flow in the other of the regions 3 and 6 can be reacted with the gaseous raw material to be supplied to the other of the regions 3 and 6 together with steam.
COPYRIGHT: (C)2004,JPO
摘要翻译：要解决的问题：提供一种膜反应器，用于获得具有约2H 2 SB / CO摩尔比的合成气，同时避免了植物的尺寸变大并且成本增加。解决方案：该膜反应器包括主体1，形成在主体1中的第一区域3具有气体供给口4和排出口5，并且被分隔壁分隔，该分隔壁包含管结构部分 2，其中至少一部分通过使用透氧膜和形成在主体1中的第二区域6形成，具有气体供给口7和排出口8，并且与区域3分离隔墙。该装置构成为使供给到区域3,6的一部分的含氧气体中所含的氧气透过透氧膜并使其在区域3,6中另一方流动可以与气体原料反应以供应到区域3和6中的另一个与蒸汽一起。版权所有（C）2004，JPO

5. 发明专利

JP2012061442A Membrane vessel for dehydrator 有权
标题翻译：用于脱水器的薄膜容器
公开(公告)号：JP2012061442A
公开(公告)日：2012-03-29
申请号：JP2010209228
申请日：2010-09-17
申请人： Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社
发明人： TANAKA YUKIO , TACHIBANA SHINYA , OZORA HIROYUKI , OGINO SHINJI , HIRAYAMA HARUAKI
IPC分类号： B01D63/00 , B01D63/06
CPC分类号： B01D63/00 , B01D61/366 , B01D61/368 , B01D63/066 , B01D65/00 , B01D2313/08 , B01D2313/086 , B01D2313/20
摘要： PROBLEM TO BE SOLVED: To provide a membrane vessel, by which the flow velocity of a fluid to be processed is increased in the membrane vessel to be used for a dehydrator and thus sufficient performance of water separation can be obtained.SOLUTION: The present invention is a membrane vessel 6 to be used for a dehydrator 1. The membrane vessel 6 includes: a casing 10 having a fluid inlet 14 into which a fluid to be processed flows, and a fluid outlet 16 from which the fluid to be processed flows; and a membrane vessel body 9 having a plurality of flow channels 11 disposed in parallel in the direction in which the fluid to be processed flows. The plurality of flow channels 11 are provided with a most upstream portion 11A that is connected to the fluid inlet 14, and a most downstream portion 11C that is connected to the fluid outlet 16. Turn-back sections 15 and 17 for turning back the direction of flow of the fluid to be processed in the opposite direction are disposed between the most upstream portion 11A and the most downstream portion 11C such that the fluid to be processed that has flowed into the fluid inlet 14 flows through the most upstream portion 11A to the most downstream portion 11C via the turn-back sections 15 and 17.
摘要翻译：要解决的问题：提供一种膜容器，通过该膜容器，在用于脱水机的膜容器中待处理流体的流速增加，从而可以获得足够的水分离性能。解决方案：本发明是用于脱水机1的膜容器6.膜容器6包括：壳体10，其具有流体入口14，待处理流体流入该流体入口14，以及流体出口16，待处理的流体流动; 以及膜容器主体9，其具有沿着待处理流体流动方向平行设置的多个流路11。多个流动通道11设置有连接到流体入口14的最上游部分11A和连接到流体出口16的最下游部分11C。用于回转方向的回转部分15和17 在最上游部分11A和最下游部分11C之间设置待加工流体相反方向的流动，使得流入流体入口14的待处理流体流过最上游部分11A流到最下游部分11C经由折回部分15和17.版权所有（C）2012，JPO＆INPIT

6. 发明专利

JP2011104559A Method and apparatus for regenerating co2 absorbing solution 审中-公开
标题翻译：用于再生二氧化碳吸收溶液的方法和装置
公开(公告)号：JP2011104559A
公开(公告)日：2011-06-02
申请号：JP2009264951
申请日：2009-11-20
申请人： Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社
发明人： TACHIBANA SHINYA , TANAKA YUKIO , HIRAYAMA HARUAKI
IPC分类号： B01D53/62 , B01D53/14 , B01D61/36
CPC分类号： Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： PROBLEM TO BE SOLVED: To provide a method and an apparatus for regenerating a CO 2 absorbing solution capable of reducing the latent heat and sensible heat of the evaporation of water at the time of regeneration in a process for regenerating the CO 2 absorbing solution such as an amine aqueous solution or the like and capable of reducing the energy loss of water in the process for regenerating the CO 2 absorbing solution. SOLUTION: A dehydration process for preferentially passing the water present in a CO 2 rich absorbing solution on the primary side 1b of a membrane unit 1 and condensing/separating the water of the CO 2 rich absorbing solution on the secondary side 1c of the membrane unit 1 to lower the concentration of water is performed between a CO 2 absorbing process and a CO 2 leaning process. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供一种能够再生CO 2 SBR吸收溶液的方法和装置，其能够在再生时减少水蒸发的潜热和显热用于再生CO 2 SBS吸收溶液如胺水溶液等的方法，并且在再生CO 2 SB吸收溶液的过程中能够降低水的能量损失。解决方案：优选使存在于富集SB 2的吸收溶液中的水在膜单元1的初级侧1b上并将CO 的水冷凝/分离的脱水方法在CO单元1的二次侧1c上富集吸收溶液，以降低水的浓度在CO SB＆gt; 2＆lt; SB＆gt;吸收过程和CO 2 倾斜过程。版权所有（C）2011，JPO＆INPIT

7. 发明专利

JP2008143724A Reaction tube for hydrogen production, hydrogen production apparatus equipped with the same, and hydrogen production method 有权
标题翻译：用于氢生产的反应管，装有氢的生产装置和氢生产方法
公开(公告)号：JP2008143724A
公开(公告)日：2008-06-26
申请号：JP2006329866
申请日：2006-12-06
申请人： Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社
发明人： FUJIMOTO YOSHIMASA , TANAKA YUKIO , TACHIBANA SHINYA , KOBAYASHI KAZUTO
IPC分类号： C01B3/38 , C01B3/56
摘要： PROBLEM TO BE SOLVED: To provide: a reaction tube for hydrogen production, with which the durability of a hydrogen separation membrane and a formed catalyst can be enhanced and the usable formed catalyst is not confined and which does not need a pacer; a hydrogen production apparatus equipped with the same, and a hydrogen production method.
SOLUTION: The reaction tube 10A for hydrogen production is equipped with: a raw material gas supply tube 102 for supplying a raw material gas G into a reaction tube main body 101; a pair of formed catalysts 105 for reforming the raw material gas G to hydrogen; and a hydrogen separation membrane module 106 which is interposed between the pair of formed catalysts 105 and has a hydrogen separation membrane selectively permeating only hydrogen. The reaction tube 10A is characterized by having a pair of first holder 11A-1 and a first holder 11A-2 which are provided on the inner wall 101a of the reaction tube main body 101 and hold the hydrogen separation membrane module 106 and the formed catalysts 105 while allowing them to have a tolerance in the reaction tube main body 101.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供：用于制氢的反应管，可以提高氢分离膜和形成的催化剂的耐久性，并且可用的成形催化剂不受限制，不需要起搏器; 配备有氢制造装置的氢制造装置和氢制造方法。解决方案：用于制氢的反应管10A配备有：原料气体供给管102，用于将原料气体G供应到反应管主体101中; 一对形成的催化剂105，用于将原料气体G重整成氢; 以及插入在一对成形催化剂105之间并具有仅选择性渗透氢气的氢分离膜的氢分离膜组件106。反应管10A的特征在于具有一对第一保持件11A-1和第一保持件11A-2，它们设置在反应管主体101的内壁101a上并保持氢分离膜组件106和形成的催化剂同时允许它们在反应管主体101中具有公差。版权所有（C）2008，JPO＆INPIT

8. 发明专利

JP2008133143A Apparatus and method for producing hydrogen 有权
标题翻译：用于生产氢的装置和方法
公开(公告)号：JP2008133143A
公开(公告)日：2008-06-12
申请号：JP2006318689
申请日：2006-11-27
申请人： Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社
发明人： TACHIBANA SHINYA , KOBAYASHI KAZUTO , FUJIMOTO YOSHIMASA , TANAKA YUKIO
IPC分类号： C01B3/38
摘要： PROBLEM TO BE SOLVED: To provide an apparatus for producing hydrogen which prevents a radiant heat to a hydrogen producing reaction tube and has a simple composition and a method for producing hydrogen.
SOLUTION: The apparatus for producing hydrogen 10A consists of a hydrogen producing reaction tube 101 which is installed in the main body of the apparatus for producing hydrogen 100a and has a preparatory reforming catalyst part 107 in its inside containing a preparatory reforming catalyst which preparatorily reforms a raw material gas G where the raw material gas G is reformed into hydrogen and only the hydrogen formed is collected, a burner 113 which is installed at the main body of the apparatus for producing hydrogen 100a and heats the hydrogen producing reaction tube 101, and a steam generating part 12 which is installed at the main body of the apparatus for producing hydrogen 100a and generates steam 11 to be supplied to the raw material gas G. The burner 113 is installed opposite to the preparatory reforming catalyst part 107 which is located in the hydrogen producing reaction tube 101 and the steam generating part 12 is installed between the hydrogen producing reaction tube 101 and the burner 113.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供一种用于制造氢的装置，其防止对制氢反应管的辐射热，并且具有简单的组成和生产氢的方法。解决方案：用于制造氢气的装置10A包括氢制造反应管101，该制氢反应管101安装在用于生产氢气的装置100a的主体中，并且在其内部具有准备重整催化剂部分107，该制备重整催化剂部分107含有制备重整催化剂，对原料气体G重整成氢气并仅收集形成的氢气的原料气体G进行预先改造，安装在生产氢气的装置的主体上的燃烧器113加热制氢反应管101 以及蒸汽发生部12，其安装在用于生产氢气的装置的主体上，并产生供给原料气体G的蒸汽11.燃烧器113安装在与制备重整催化剂部分107相对的位置位于制氢反应管101中，蒸汽产生部12安装在制氢反应管之间 101和燃烧器113.版权所有（C）2008，JPO＆INPIT

9. 发明专利

JP2006097526A Temperature increasing device for on-vehicle type hydrogen production system 审中-公开
标题翻译：用于车载式氢气生产系统的温度增加装置
公开(公告)号：JP2006097526A
公开(公告)日：2006-04-13
申请号：JP2004283330
申请日：2004-09-29
申请人： Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社
发明人： TACHIBANA SHINYA , KOBAYASHI KAZUTO , TANAKA YUKIO
IPC分类号： F02M27/02 , C01B3/38 , H01M8/06
CPC分类号： Y02T10/126
摘要： PROBLEM TO BE SOLVED: To provide a temperature increasing device for an on-vehicle type hydrogen production system for maintaining a temperature of reaction tubes of a hydrogen separation type reformer even during traveling without any loss of time for every destination. SOLUTION: The temperature increasing device for an on-vehicle type hydrogen production system has a heater 3 started by the driving of engine power of a vehicle. The on-vehicle type hydrogen production system has the hydrogen separation type reformer 1, which has a reaction parts 11, 12. The reaction parts 11, 12 are constituted of reaction tubes filled with reforming catalysts, and provided with a hydrogen transmission part 14 partitioned by a hydrogen separation membrane and a combustion gas passage 15 heating the reaction pipes. The hydrogen separation type reformer 1 has a combustion part 13 generating combustion gas for heating the reaction pipe parts 11, 12, and the reaction pipes are preheated with a means utilizing the heat from the heater 3. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：为了提供一种用于车载式氢气生产系统的升温装置，用于即使在行驶期间也保持氢分离型重整器的反应管的温度，而不会对每个目的地造成任何时间的损失。解决方案：用于车载氢气生产系统的升温装置具有通过驾驶车辆的发动机功率而启动的加热器3。车载氢气生产系统具有氢分离型重整器1，其具有反应部件11,12。反应部件11,12由填充有重整催化剂的反应管构成，并且设置有分隔的氢传递部分14 通过氢分离膜和燃烧气体通道15加热反应管。氢分离型重整器1具有产生用于加热反应管部分11,12的燃烧气体的燃烧部分13，并且利用来自加热器3的热量的装置对反应管进行预热。版权所有（C）2006 ，JPO＆NCIPI

10. 发明专利

JP2004175584A System and process for hydrogen production 有权
公开(公告)号：JP2004175584A
公开(公告)日：2004-06-24
申请号：JP2002340531
申请日：2002-11-25
申请人： Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社
发明人： TACHIBANA SHINYA , KOBAYASHI KAZUTO , FUJIMOTO YOSHIMASA , TANAKA YUKIO
IPC分类号： C01B3/38 , C01B3/56
摘要： PROBLEM TO BE SOLVED: To provide a system and a process for hydrogen production which efficiently remove steam from a reformed gas or off-gas, make effective use of the steam and improve hydrogen production efficiency.
SOLUTION: The system contains a steam reformer 6 which produces hydrogen from a hydrocarbon and water as raw materials through steam reforming reaction and a steam-separating apparatus 17. The steam is separated from a steam-containing gas obtained after the steam reforming reaction by the steam-separating apparatus 17, and the off-gas from which the steam has been separated by the steam-separating apparatus 17 is burned in the steam reformer.
COPYRIGHT: (C)2004,JPO

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