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1. 发明授权

US09084983B2 Catalyst and process for hydrogenating aromatics 有权
标题翻译：用于氢化芳族化合物的催化剂和方法
公开(公告)号：US09084983B2
公开(公告)日：2015-07-21
申请号：US13516124
申请日：2010-12-14
申请人： Lucia Königsmann , Daniela Mirk , Thomas Heidemann , Michael Hesse , Martin Bock , Mario Emmeluth , Jutta Bickelhaupt
发明人： Lucia Königsmann , Daniela Mirk , Thomas Heidemann , Michael Hesse , Martin Bock , Mario Emmeluth , Jutta Bickelhaupt
IPC分类号： C07C69/74 , C07C61/00 , C07C209/00 , C07C31/13 , C07C29/00 , C07C5/10 , B01J21/00 , B01J23/40 , B01J21/08 , B01J23/46 , B01J35/00 , B01J35/10 , B01J37/02 , C07C29/20 , C07C51/36 , C07C67/303 , C07C209/72
CPC分类号： B01J23/40 , B01J21/08 , B01J23/462 , B01J35/0026 , B01J35/0053 , B01J35/008 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J35/108 , B01J37/0201 , B01J37/0203 , B01J37/0205 , C07C5/10 , C07C29/20 , C07C51/36 , C07C67/303 , C07C209/72 , C07C2521/08 , C07C2523/46 , C07C2601/14 , C07C31/1355 , C07C35/21 , C07C35/08 , C07C61/08 , C07C69/75 , C07C211/35 , C07C211/36
摘要： The present invention relates to an eggshell catalyst comprising an active metal selected from the group consisting of ruthenium, rhodium, palladium, platinum and mixtures thereof, applied to a support material comprising silicon dioxide, wherein the pore volume of the support material is 0.6 to 1.0 ml/g, determined by Hg porosimetry, the BET surface area is 280 to 500 m2/g, and at least 90% of the pores present have a diameter of 6 to 12 nm, to a process for preparing this eggshell catalyst, to a process for hydrogenating an organic compound which comprises at least one hydrogenatable group using the eggshell catalyst, and to the use of the eggshell catalyst for hydrogenating an organic compound.
摘要翻译：本发明涉及包含选自钌，铑，钯，铂及其混合物的活性金属的蛋壳催化剂，其应用于包含二氧化硅的载体材料，其中载体材料的孔体积为0.6至1.0 ml / g，通过Hg孔隙率法测定，BET表面积为280-500m2 / g，并且至少90％的孔存在的直径为6至12nm，制备该蛋壳催化剂的方法为使用蛋壳催化剂氢化含有至少一个可氢化基团的有机化合物的方法，以及使用蛋壳催化剂氢化有机化合物。

2. 发明申请

US20120296111A1 CATALYST AND PROCESS FOR HYDROGENATING AROMATICS 有权
标题翻译：催化剂和加氢方法
公开(公告)号：US20120296111A1
公开(公告)日：2012-11-22
申请号：US13516124
申请日：2010-12-14
申请人： Lucia Königsmann , Daniela Mirk , Thomas Heidemann , Michael Hesse , Martin Bock , Mario Emmeluth , Jutta Bickelhaupt
发明人： Lucia Königsmann , Daniela Mirk , Thomas Heidemann , Michael Hesse , Martin Bock , Mario Emmeluth , Jutta Bickelhaupt
IPC分类号： B01J23/46 , C07C69/75 , C07C61/08 , C07C211/35 , C07C211/36 , C07C209/72 , C07C5/10 , B01J23/42 , C07C67/303 , C07C51/36 , C07C29/20 , B01J23/44 , C07C35/08
CPC分类号： B01J23/40 , B01J21/08 , B01J23/462 , B01J35/0026 , B01J35/0053 , B01J35/008 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J35/108 , B01J37/0201 , B01J37/0203 , B01J37/0205 , C07C5/10 , C07C29/20 , C07C51/36 , C07C67/303 , C07C209/72 , C07C2521/08 , C07C2523/46 , C07C2601/14 , C07C31/1355 , C07C35/21 , C07C35/08 , C07C61/08 , C07C69/75 , C07C211/35 , C07C211/36
摘要： The present invention relates to an eggshell catalyst comprising an active metal selected from the group consisting of ruthenium, rhodium, palladium, platinum and mixtures thereof, applied to a support material comprising silicon dioxide, wherein the pore volume of the support material is 0.6 to 1.0 ml/g, determined by Hg porosimetry, the BET surface area is 280 to 500 m2/g, and at least 90% of the pores present have a diameter of 6 to 12 nm, to a process for preparing this eggshell catalyst, to a process for hydrogenating an organic compound which comprises at least one hydrogenatable group using the eggshell catalyst, and to the use of the eggshell catalyst for hydrogenating an organic compound.
摘要翻译：本发明涉及包含选自钌，铑，钯，铂及其混合物的活性金属的蛋壳催化剂，其应用于包含二氧化硅的载体材料，其中载体材料的孔体积为0.6至1.0 ml / g，通过Hg孔隙率法测定，BET表面积为280-500m2 / g，并且至少90％的孔存在的直径为6至12nm，制备该蛋壳催化剂的方法为使用蛋壳催化剂氢化含有至少一个可氢化基团的有机化合物的方法，以及使用蛋壳催化剂氢化有机化合物。

3. 发明授权

US08809588B2 Method for producing aromatic amines 有权
标题翻译：生产芳香胺的方法
公开(公告)号：US08809588B2
公开(公告)日：2014-08-19
申请号：US13320384
申请日：2010-05-05
申请人： Lucia Konigsmann , Ekkehard Schwab , Michael Hesse , Christian Schneider , Thomas Heidemann , Celine Liekens , Jutta Bickelhaupt , Dirk Theis
发明人： Lucia Konigsmann , Ekkehard Schwab , Michael Hesse , Christian Schneider , Thomas Heidemann , Celine Liekens , Jutta Bickelhaupt , Dirk Theis
IPC分类号： C07C209/00
CPC分类号： C07C209/36 , C07C211/46
摘要： The invention relates to a process for preparing aromatic amines by catalytically hydrogenating the corresponding aromatic nitro compound, which comprises using a copper catalyst with a support comprising SiO2, the SiO2 having been prepared by wet grinding and subsequent spray drying.
摘要翻译：本发明涉及通过催化氢化相应的芳族硝基化合物来制备芳族胺的方法，其包括使用具有包含SiO 2的载体的铜催化剂，通过湿法研磨和随后的喷雾干燥制备的SiO 2。

4. 发明申请

US20120065431A1 METHOD FOR PRODUCING AROMATIC AMINES 有权
标题翻译：生产芳香胺的方法
公开(公告)号：US20120065431A1
公开(公告)日：2012-03-15
申请号：US13320384
申请日：2010-05-05
申请人： Lucia Koenigsmann , Ekkehard Schwab , Michael Hesse , Christian Schneider , Thomas Heidemann , Celine Liekens , Jutta Bickelhaupt , Dirk Theis
发明人： Lucia Koenigsmann , Ekkehard Schwab , Michael Hesse , Christian Schneider , Thomas Heidemann , Celine Liekens , Jutta Bickelhaupt , Dirk Theis
IPC分类号： C07C209/36
CPC分类号： C07C209/36 , C07C211/46
摘要： The invention relates to a process for preparing aromatic amines by catalytically hydrogenating the corresponding aromatic nitro compound, which comprises using a copper catalyst with a support comprising SiO2, the SiO2 having been prepared by wet grinding and subsequent spray drying.
摘要翻译：本发明涉及通过催化氢化相应的芳族硝基化合物来制备芳族胺的方法，其包括使用具有包含SiO 2的载体的铜催化剂，通过湿法研磨和随后的喷雾干燥制备的SiO 2。

5. 发明申请

US20120289747A1 CATALYSTS FOR THE HYDROGENATION OF AROMATIC AMINES 审中-公开
标题翻译：催化剂用于加氢芳族氨基酸
公开(公告)号：US20120289747A1
公开(公告)日：2012-11-15
申请号：US13468689
申请日：2012-05-10
申请人： Lucia Königsmann , Thomas Heidemann , Martin Bock , Joachim Pfeffinger , Benjamin Koch
发明人： Lucia Königsmann , Thomas Heidemann , Martin Bock , Joachim Pfeffinger , Benjamin Koch
IPC分类号： C07C209/72 , B01J21/08
CPC分类号： C07C209/72 , B01J21/08 , B01J23/462 , B01J35/0013 , B01J35/006 , B01J35/0066 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J37/0205 , B01J37/18 , C07C2601/14 , C07C211/35 , C07C211/36
摘要： The present invention relates to a catalyst comprising 4% by weight of ruthenium (Ru) or more and a support material comprising silicon dioxide, wherein the nitrogen content of the catalyst after the last drying or calcination is in the range from 1 to 3% by weight, and also catalyst precursors thereof. The present patent application further relates to a process for producing an Ru-comprising catalyst, which comprises the steps impregnation, drying, calcination and reduction. In addition, the present patent application relates to a process for hydrogenating organic substances in the presence of catalysts of the invention or catalysts produced according to the invention, and also a process for producing downstream products from cycloaliphatic amines prepared according to the invention.
摘要翻译：本发明涉及包含4重量％的钌（Ru）或更多的催化剂和包含二氧化硅的载体材料，其中在最后的干燥或煅烧之后的催化剂的氮含量在1至3％的范围内由重量，以及它们的催化剂前体。本专利申请还涉及一种制备含Ru催化剂的方法，该方法包括浸渍，干燥，煅烧和还原的步骤。此外，本专利申请涉及在本发明的催化剂或根据本发明制备的催化剂存在下氢化有机物的方法，以及由根据本发明制备的脂环族胺生产下游产物的方法。

6. 发明授权

US08975460B2 Process for preparing acetylene by the Sachsse-Bartholomé process 有权
标题翻译：通过Sachsse-Bartholomé工艺制备乙炔的方法
公开(公告)号：US08975460B2
公开(公告)日：2015-03-10
申请号：US13183683
申请日：2011-07-15
申请人： Lucia Königsmann , Maximilian Vicari , Thomas Heidemann , Dirk Groβschmidt , Jürgen Michel
发明人： Lucia Königsmann , Maximilian Vicari , Thomas Heidemann , Dirk Groβschmidt , Jürgen Michel
IPC分类号： C07C5/02 , C07C5/03 , C07C2/78
CPC分类号： C07C2/78 , C07C11/24
摘要： A process is proposed for preparing acetylene by the Sachsse-Bartholomé process by combustion of a natural gas/oxygen mixture in one or more burners to obtain a cracking gas which is cooled in two or more stages in burner columns, each burner having one or more burner columns assigned thereto, and said cracking gas being quenched with pyrolysis oil in the first cooling stage, to obtain a low boiler fraction comprising benzene, toluene and xylene from the one or more burner columns, which is cooled with direct cooling water and separated in a phase separator into an aqueous phase and an organic phase which comprises benzene, toluene and xylene and is fully or partly introduced to the top of the one or more burner columns as a return stream, wherein the organic phase comprising benzene, toluene and xylene from the phase separator, prior to full or partial recycling to the top of the one or more burner columns, is supplied to a selective hydrogenation over a catalyst which comprises at least one platinum group metal on an inorganic metal oxide as support, comprising 0.05 to 5% by weight of platinum group metal, based on the total weight of the catalyst, and wherein the selective hydrogenation is performed at a pressure in the range from 10 to 70 bar gauge and a temperature in the range from 0 to 100° C.
摘要翻译：提出了一种通过Sachsse-Bartholomé方法通过在一个或多个燃烧器中燃烧天然气/氧气混合物来制备乙炔的方法，以获得在燃烧器柱中两级或更多级冷却的裂化气体，每个燃烧器具有一个或多个燃烧器列，并且在第一冷却阶段，所述裂解气体用热解油淬火，以从一个或多个燃烧器柱获得包含苯，甲苯和二甲苯的低沸点馏分，其用直接冷却水冷却并分离相分离器进入水相和有机相，其包含苯，甲苯和二甲苯，并作为回流完全或部分地引入到一个或多个燃烧器塔的顶部，其中有机相包含苯，甲苯和二甲苯在完全或部分再循环到一个或多个燃烧器塔的顶部之前，将相分离器供应到催化剂上的选择性氢化，所述催化剂包括在l 在一个无机金属氧化物上的一个铂族金属作为载体，包含0.05-5重量％的铂族金属，基于催化剂的总重量，其中选择性氢化在10〜 70巴规，温度范围为0至100℃。

7. 发明申请

US20120245389A1 PROCESS FOR HYDROGENATING NITRILES 审中-公开
标题翻译：加氢处理方法
公开(公告)号：US20120245389A1
公开(公告)日：2012-09-27
申请号：US13427308
申请日：2012-03-22
申请人： Christof Wilhelm Wigbers , Christoph Müller , Wolfgang Mägerlein , Martin Ernst , Thomas Heidemann , Johann-Peter Melder , Lucia Königsmann , Milind Joshi , Oliver Bey , Bernd Stein
发明人： Christof Wilhelm Wigbers , Christoph Müller , Wolfgang Mägerlein , Martin Ernst , Thomas Heidemann , Johann-Peter Melder , Lucia Königsmann , Milind Joshi , Oliver Bey , Bernd Stein
IPC分类号： C07C209/48
CPC分类号： C07C209/48 , C07C2601/14 , C07C211/36 , C07C211/09
摘要： The present invention relates to a process for hydrogenating organic nitriles by means of hydrogen in the presence of a catalyst in a reactor, where the shaped body catalyst is arranged in a fixed bed, wherein the shaped body in the shape of spheres or rods has in each case a diameter 3 mm or less, in the shape of tablets a height of 4 mm or less, and in the case of all other geometries in each case has an equivalent diameter L=1/a′ of 0.70 mm or less, where a′ is the external surface area per unit volume (mms2/mmp3), where: a ′ = A p V p , where Ap is the external surface area of the catalyst particle (mms2) and Vp is the volume of the catalyst particle (mmp3). The present invention further relates to a process for preparing downstream products of isophoronediamine (IPDA) or N,N-dimethylaminopropylamine (DMAPA) from amines prepared according to the invention.
摘要翻译：本发明涉及一种在反应器中催化剂存在下通过氢气氢化有机腈的方法，其中成形体催化剂布置在固定床中，其中球体或棒状的成形体具有每个壳体的直径为3mm以下，片状形状为4mm以下，在各种情况下，所有其他几何形状的等效直径L = 1 / a'为0.70mm以下，其中 a'是每单位体积的外表面积（mms2 / mmp3），其中：a'= A p V p，其中Ap是催化剂颗粒的外表面积（mms2），Vp是催化剂颗粒的体积 mmp3）。本发明还涉及由根据本发明制备的胺制备异佛尔酮二胺（IPDA）或N，N-二甲基氨基丙胺（DMAPA）的下游产物的方法。

8. 发明申请

US20120022308A1 PROCESS FOR PREPARING ACETYLENE BY THE SACHSSE-BARTHOLOME PROCESS 有权
标题翻译：通过SACHSSE-BARTHOLOME工艺制备乙烯的方法
公开(公告)号：US20120022308A1
公开(公告)日：2012-01-26
申请号：US13183683
申请日：2011-07-15
申请人： Lucia Königsmann , Maximilian Vicari , Thomas Heidemann , Dirk Großschmidt , Jürgen Michel
发明人： Lucia Königsmann , Maximilian Vicari , Thomas Heidemann , Dirk Großschmidt , Jürgen Michel
IPC分类号： C07C4/22
CPC分类号： C07C2/78 , C07C11/24
摘要： A process is proposed for preparing acetylene by the Sachsse-Bartholomé process by combustion of a natural gas/oxygen mixture in one or more burners to obtain a cracking gas which is cooled in two or more stages in burner columns, each burner having one or more burner columns assigned thereto, and said cracking gas being quenched with pyrolysis oil in the first cooling stage, to obtain a low boiler fraction comprising benzene, toluene and xylene from the one or more burner columns, which is cooled with direct cooling water and separated in a phase separator into an aqueous phase and an organic phase which comprises benzene, toluene and xylene and is fully or partly introduced to the top of the one or more burner columns as a return stream, wherein the organic phase comprising benzene, toluene and xylene from the phase separator, prior to full or partial recycling to the top of the one or more burner columns, is supplied to a selective hydrogenation over a catalyst which comprises at least one platinum group metal on an inorganic metal oxide as support, comprising 0.05 to 5% by weight of platinum group metal, based on the total weight of the catalyst, and wherein the selective hydrogenation is performed at a pressure in the range from 10 to 70 bar gauge and a temperature in the range from 0 to 100° C.
摘要翻译：提出了一种通过Sachsse-Bartholomé方法通过在一个或多个燃烧器中燃烧天然气/氧气混合物来制备乙炔的方法，以获得在燃烧器柱中两级或更多级冷却的裂化气体，每个燃烧器具有一个或多个燃烧器列，并且在第一冷却阶段，所述裂解气体用热解油淬火，以从一个或多个燃烧器柱获得包含苯，甲苯和二甲苯的低沸点馏分，其用直接冷却水冷却并分离相分离器进入水相和有机相，其包含苯，甲苯和二甲苯，并作为回流完全或部分地引入到一个或多个燃烧器塔的顶部，其中有机相包含苯，甲苯和二甲苯在完全或部分再循环到一个或多个燃烧器塔的顶部之前，将相分离器供应到催化剂上的选择性氢化，所述催化剂包括在l 在一个无机金属氧化物上的一个铂族金属作为载体，包含0.05-5重量％的铂族金属，基于催化剂的总重量，其中选择性氢化在10〜 70巴规，温度范围为0至100℃。

9. 发明授权

US08729331B2 Method for electrochemically removing hydrogen from a reaction mixture 有权
标题翻译：从反应混合物中电化学除去氢的方法
公开(公告)号：US08729331B2
公开(公告)日：2014-05-20
申请号：US13259863
申请日：2010-03-29
申请人： Joana Coelho Tsou , Alexander Panchenko , Annebart Engbert Wentink , Sebastian Ahrens , Thomas Heidemann , Guenther Huber , Albena Kostova
发明人： Joana Coelho Tsou , Alexander Panchenko , Annebart Engbert Wentink , Sebastian Ahrens , Thomas Heidemann , Guenther Huber , Albena Kostova
IPC分类号： C07C7/144
CPC分类号： H01M8/0656 , C01B3/505 , C01B2203/041 , C01B2203/048 , H01M4/92 , H01M4/921 , H01M8/0625 , H01M8/1213 , H01M2008/1095 , H01M2008/1293
摘要： The invention relates to a process for the electrochemical separation of hydrogen from a hydrogen-comprising reaction mixture R by means of a gastight membrane-electrode assembly comprising at least one selectively proton-conducting membrane and at least one electrode catalyst on each side of the membrane, where at least part of the hydrogen present in the reaction mixture R is oxidized to protons over the anode catalyst on the retentate side of the membrane and the protons are, after passing through the membrane to the permeate side, I reduced to hydrogen over the cathode catalyst and/or II reacted with oxygen over the cathode catalyst to form water, with the oxygen originating from an oxygen-comprising stream O which is brought into contact with the permeate side of the membrane, and also a reactor equipped with at least one membrane-electrode assembly.
摘要翻译：本发明涉及通过包含至少一个选择性质子传导膜和至少一个电极催化剂的气密膜 - 电极组件从含氢的反应混合物R电化学分离氢的方法其中存在于反应混合物R中的至少一部分氢被氧化成在膜的滞留侧上的阳极催化剂上的质子，质子在通过膜到达渗透侧之后被还原成氢阴极催化剂和/或II在阴极催化剂上与氧反应形成水，其中氧源源于与膜的渗透侧接触的含氧物流O，以及装有至少一个膜 - 电极组件。

10. 发明授权

US08529869B2 Catalysts and method for the hydroamination of olefins 有权
标题翻译：烯烃水解催化剂和方法
公开(公告)号：US08529869B2
公开(公告)日：2013-09-10
申请号：US13265457
申请日：2010-04-19
申请人： Thomas Heidemann , Jens Kehrer
发明人： Thomas Heidemann , Jens Kehrer
IPC分类号： C01B39/46 , C07C209/60
CPC分类号： B01J29/7057 , B01J29/7007 , B01J37/0201 , B01J2229/186 , C07C209/60 , C07C211/07
摘要： The present invention relates to a hydroamination catalyst comprising boron beta zeolites, wherein the hydroamination catalyst is doped with lithium, and also a process for producing it. The present patent application further relates to a process for preparing amines by reaction of ammonia or primary or secondary amines with olefins at elevated temperatures and pressures in the presence of the hydroamination catalyst of the invention.
摘要翻译：本发明涉及包含硼沸石的水解催化剂，其中所述水化催化剂掺杂有锂，并且还涉及其生产方法。本专利申请还涉及在本发明的水解催化剂存在下，在升高的温度和压力下，通过氨或伯胺或仲胺与烯烃的反应来制备胺的方法。

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