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1. 发明授权

US08742189B2 Catalyst for the dehydroaromatisation of methane and mixtures containing methane 失效
标题翻译：用于甲烷和甲烷混合物脱氢芳构化的催化剂
公开(公告)号：US08742189B2
公开(公告)日：2014-06-03
申请号：US12937062
申请日：2009-04-08
申请人： Frank Kiesslich , Joana Coelho Tsou , Bilge Yilmaz , Sebastian Ahrens , Thomas Heidemann , Veronika Will , Christian Bechtold
发明人： Frank Kiesslich , Joana Coelho Tsou , Bilge Yilmaz , Sebastian Ahrens , Thomas Heidemann , Veronika Will , Christian Bechtold
IPC分类号： C07C15/00 , C07C15/04 , B01J29/06
CPC分类号： B01J29/48 , B01J29/7876 , B01J35/1019 , B01J2229/16 , B01J2229/186 , B01J2229/42 , C07C2/76 , C07C2529/48 , C07C15/00
摘要： The present invention relates to a catalyst for dehydroaromatizing C1-C4-aliphatics, said catalyst being obtainable by twice treating a zeolite from the group of MFI and MWW with NH4-containing mixtures, in each case with subsequent drying and calcination. The catalyst comprises molybdenum and, if appropriate, as further elements, Cu, Ni, Fe, Co, Mn, Cr, Nb, Ta, Zr, V, Zn and/or Ga.The present invention further provides a process for dehydroaromatizing a mixture comprising C1-C4-aliphatics by conversion in the presence of the catalyst.
摘要翻译：本发明涉及一种用于使C1-C4-脂肪族脱氢芳香化的催化剂，所述催化剂可通过用含有NH 4的混合物两次处理来自MFI和MWW的沸石的两种方法获得，在每种情况下随后进行干燥和煅烧。该催化剂包括钼，如果合适的话，作为另外的元素Cu，Ni，Fe，Co，Mn，Cr，Nb，Ta，Zr，V，Zn和/或Ga。本发明还提供了一种使混合物脱氢芳构化的方法在催化剂存在下通过转化而包含C1-C4-脂族烃。

2. 发明授权

US08575411B2 Method for reacting natural gas to aromatics while electrochemically removing hydrogen and electrochemically reacting the hydrogen water 有权
标题翻译：使天然气与芳族化合物反应，同时电化学去除氢气并使氢水电化学反应的方法
公开(公告)号：US08575411B2
公开(公告)日：2013-11-05
申请号：US13256536
申请日：2010-03-29
申请人： Joana Coelho Tsou , Alexander Panchenko , Annebart Engbert Wentink , Sebastian Ahrens , Thomas Heidemann
发明人： Joana Coelho Tsou , Alexander Panchenko , Annebart Engbert Wentink , Sebastian Ahrens , Thomas Heidemann
IPC分类号： C07C2/76
CPC分类号： C01B3/38 , C01B3/503 , C01B3/56 , C01B5/00 , C01B2203/02 , C01B2203/0405 , C01B2203/041 , C01B2203/043 , C01B2203/048 , C01B2203/062 , C01B2203/1241 , C07C2/76 , C10G50/00 , C10G2400/30 , Y02P20/52 , C07C15/00 , C07C15/04
摘要： The invention relates to a process for converting aliphatic hydrocarbons having from 1 to 4 carbon atoms into aromatic hydrocarbons, which comprises the steps: a) reaction of a feed stream E comprising at least one aliphatic hydrocarbon having from 1 to 4 carbon atoms in the presence of a catalyst under nonoxidative conditions to give a product stream P comprising aromatic hydrocarbons and hydrogen and b) electrochemical removal of at least part of the hydrogen formed in the reaction from the product stream P by means of a gastight membrane-electrode assembly comprising at least one selectively proton-conducting membrane and at least one electrode catalyst on each side of the membrane, where at least part of the hydrogen is oxidized to protons over the anode catalyst on the retentate side of the membrane and the protons are, after passing through the membrane on the permeate side, reacted with oxygen to form water over the cathode catalyst, with the oxygen originating from an oxygen-comprising stream O which is brought into contact with the permeate side of the membrane.
摘要翻译：本发明涉及一种将具有1至4个碳原子的脂族烃转化为芳族烃的方法，其包括以下步骤：a）在存在的情况下使包含至少一种具有1至4个碳原子的脂族烃的进料流E反应的催化剂，以产生包含芳族烃和氢的产物流P和b）通过气密的膜 - 电极组合物从产物流P电化学去除反应中形成的氢的至少一部分，该气密膜电极组件至少包括一个选择性质子传导膜和至少一个电极催化剂在膜的每一侧上，其中至少部分氢被氧化成在膜的滞留侧上的阳极催化剂上的质子，质子在通过渗透物侧的膜与氧反应，在阴极催化剂上形成水，氧气源自氧-co 令人惊奇的流O与膜的渗透侧接触。

3. 发明授权

US08530713B2 Method for the dehydroaromatisation of mixtures containing methane by regenerating the corresponding catalysts that are devoid of precious metal 失效
标题翻译：通过再生不含贵金属的相应催化剂对包含甲烷的混合物进行脱氢芳构化的方法
公开(公告)号：US08530713B2
公开(公告)日：2013-09-10
申请号：US12937144
申请日：2009-04-01
申请人： Frank Kiesslich , Joana Coelho Tsou , Alexander Schulz
发明人： Frank Kiesslich , Joana Coelho Tsou , Alexander Schulz
IPC分类号： C07C2/76
CPC分类号： B01J38/10 , B01J29/076 , B01J29/48 , B01J29/90 , B01J37/0009 , B01J37/18 , B01J2229/20 , B01J2229/42 , C07C2/76 , C07C2529/48 , Y02P20/584 , C07C15/00
摘要： The present invention relates to a process for nonoxidative dehydroaromatization of aliphatic hydrocarbons by converting a reactant stream comprising aliphatic hydrocarbons in the presence of a catalyst which comprises at least one metallosilicate as a support, at least one element selected from the group of Mo, W and Re as an active component and at least one further transition metal which is not a noble metal as a dopant, wherein the catalyst is regenerated regularly with hydrogen under nonoxidative conditions. The further transition metal used is preferably Fe, Ni, Cu and Co.
摘要翻译：本发明涉及通过在包含至少一种金属硅酸盐作为载体的催化剂存在下转化包含脂族烃的反应物料流，选自Mo，W和W的至少一种元素的方法来进行脂族烃的非氧化脱氢芳构化的方法，以及 Re作为活性组分和至少一种不是作为掺杂剂的贵金属的过渡金属，其中催化剂在非氧化条件下用氢气规则地再生。所用的另外的过渡金属优选为Fe，Ni，Cu和Co

4. 发明授权

US08487152B2 Process for converting natural gas to aromatics with electrochemical removal of hydrogen to generate electrical power and obtain hydrogen 有权
标题翻译：通过电化学去除氢气将天然气转化为芳族化合物以产生电力并获得氢气的方法
公开(公告)号：US08487152B2
公开(公告)日：2013-07-16
申请号：US13202427
申请日：2010-03-30
申请人： Joana Coelho Tsou , Alexander Panchenko , Annebart Engbert Wentink , Sebastian Ahrens , Thomas Heidemann
发明人： Joana Coelho Tsou , Alexander Panchenko , Annebart Engbert Wentink , Sebastian Ahrens , Thomas Heidemann
IPC分类号： C07C2/76 , C07C2/42
CPC分类号： C01B3/503 , C01B3/26 , C01B3/30 , C01B2203/0277 , C01B2203/0405 , C01B2203/041 , C01B2203/048 , C01B2203/06 , C01B2203/1241 , C01B2203/1247 , C07C2/76 , C07C2523/28 , C07C2523/30 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/72 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2529/40 , H01M8/0612 , H01M2008/1095 , Y02P20/582 , C07C15/24 , C07C15/46 , C07C15/073 , C07C15/08 , C07C15/04 , C07C15/06
摘要： The present invention relates to a process for converting aliphatic hydrocarbons having 1 to 4 carbon atoms to aromatic hydrocarbons, comprising the steps of: a) converting a reactant stream E which comprises at least one aliphatic hydrocarbon having 1 to 4 carbon atoms in the presence of a catalyst under nonoxidative conditions to a product stream P comprising aromatic hydrocarbons and hydrogen, and b) electrochemically removing at least some of the hydrogen formed in the conversion from the product stream P by means of a gas-tight membrane-electrode assembly which has at least one selectively proton-conducting membrane and, on each side of the membrane, at least one electrode catalyst, at least some of the hydrogen being oxidized to protons over the anode catalyst on the retentate side of the membrane, and the protons, after passing through the membrane, on the permeate side over the cathode catalyst, are partly, in b1) reduced to hydrogen with application of a voltage, and partly, in b2) reacted with oxygen to give water to generate electrical power, the oxygen originating from an oxygen-comprising stream O which is contacted with the permeate side of the membrane.
摘要翻译：本发明涉及一种将具有1至4个碳原子的脂族烃转化成芳族烃的方法，包括以下步骤：a）在包含至少一种具有1至4个碳原子的脂族烃的反应物流E的存在下，在非氧化条件下的催化剂与包含芳族烃和氢的产物流P，以及b）通过气密膜电极组件电化学去除从产物流P的转化中形成的至少一些氢，至少一个选择性质子传导膜，并且在膜的每一侧上具有至少一个电极催化剂，至少一些氢被氧化成在膜的滞留侧上的阳极催化剂上的质子和通过后的质子通过膜，在阴极催化剂上的渗透侧，部分地，b1）通过施加电压而还原为氢，并且部分地，i n b2）与氧反应以产生水以产生电力，所述氧源来自与所述膜的渗透侧接触的含氧流O。

5. 发明申请

US20120012471A1 METHOD FOR ELECTROCHEMICALLY REMOVING HYDROGEN FROM A REACTION MIXTURE 有权
标题翻译：从反应混合物电化学去除氢的方法
公开(公告)号：US20120012471A1
公开(公告)日：2012-01-19
申请号：US13259863
申请日：2010-03-29
申请人： Joana Coelho Tsou , Alexander Panchenko , Annebart Engbert Wentink , Sebastian Ahrens , Thomas Heidemann , Guenther Huber , Albena Kostova
发明人： Joana Coelho Tsou , Alexander Panchenko , Annebart Engbert Wentink , Sebastian Ahrens , Thomas Heidemann , Guenther Huber , Albena Kostova
IPC分类号： C25B9/10 , B01D53/32
CPC分类号： H01M8/0656 , C01B3/505 , C01B2203/041 , C01B2203/048 , H01M4/92 , H01M4/921 , H01M8/0625 , H01M8/1213 , H01M2008/1095 , H01M2008/1293
摘要： The invention relates to a process for the electrochemical separation of hydrogen from a hydrogen-comprising reaction mixture R by means of a gastight membrane-electrode assembly comprising at least one selectively proton-conducting membrane and at least one electrode catalyst on each side of the membrane, where at least part of the hydrogen present in the reaction mixture R is oxidized to protons over the anode catalyst on the retentate side of the membrane and the protons are, after passing through the membrane to the permeate side,I reduced to hydrogen over the cathode catalyst and/orII reacted with oxygen over the cathode catalyst to form water, with the oxygen originating from an oxygen-comprising stream O which is brought into contact with the permeate side of the membrane,and also a reactor equipped with at least one membrane-electrode assembly.
摘要翻译：本发明涉及通过包含至少一个选择性质子传导膜和至少一个电极催化剂的气密膜 - 电极组件从含氢的反应混合物R电化学分离氢的方法其中存在于反应混合物R中的至少一部分氢被氧化成在膜的滞留侧上的阳极催化剂上的质子，质子在通过膜到达渗透侧之后被还原成氢阴极催化剂和/或II在阴极催化剂上与氧反应形成水，其中氧源源于与膜的渗透侧接触的含氧物流O，以及装有至少一个膜 - 电极组件。

6. 发明申请

US20110060176A1 METHOD FOR THE DEHYDROAROMATISATION OF MIXTURES CONTAINING METHANE BY REGENERATING THE CORRESPONDING CATALYSTS THAT ARE DEVOID OF PRECIOUS METAL 失效
标题翻译：通过再生含有金属离子的相应催化剂脱除甲烷混合物的方法
公开(公告)号：US20110060176A1
公开(公告)日：2011-03-10
申请号：US12937144
申请日：2009-04-01
申请人： Frank Kiesslich , Joana Coelho Tsou , Alexander Schulz
发明人： Frank Kiesslich , Joana Coelho Tsou , Alexander Schulz
IPC分类号： C07C2/42
CPC分类号： B01J38/10 , B01J29/076 , B01J29/48 , B01J29/90 , B01J37/0009 , B01J37/18 , B01J2229/20 , B01J2229/42 , C07C2/76 , C07C2529/48 , Y02P20/584 , C07C15/00
摘要： The present invention relates to a process for nonoxidative dehydroaromatization of aliphatic hydrocarbons by converting a reactant stream comprising aliphatic hydrocarbons in the presence of a catalyst which comprises at least one metallosilicate as a support, at least one element selected from the group of Mo, W and Re as an active component and at least one further transition metal which is not a noble metal as a dopant, wherein the catalyst is regenerated regularly with hydrogen under nonoxidative conditions. The further transition metal used is preferably Fe, Ni, Cu and Co.
摘要翻译：本发明涉及通过在包含至少一种金属硅酸盐作为载体的催化剂存在下转化包含脂族烃的反应物料流，选自Mo，W和W的至少一种元素的方法来进行脂族烃的非氧化脱氢芳构化的方法，以及 Re作为活性组分和至少一种不是作为掺杂剂的贵金属的过渡金属，其中催化剂在非氧化条件下用氢气规则地再生。所用的另外的过渡金属优选为Fe，Ni，Cu和Co

7. 发明授权

US08796496B2 Process for preparing benzene from methane 有权
标题翻译：从甲烷制备苯的方法
公开(公告)号：US08796496B2
公开(公告)日：2014-08-05
申请号：US13393837
申请日：2010-08-23
申请人： Christian Schneider , Martin Karches , Joana Coelho Tsou , Sebastian Ahrens , Dieter Stuetzer
发明人： Christian Schneider , Martin Karches , Joana Coelho Tsou , Sebastian Ahrens , Dieter Stuetzer
IPC分类号： C07C2/76 , C07C15/02
CPC分类号： C07C2/76 , Y02P20/584 , C07C15/02
摘要： The present invention relates to a process for nonoxidatively dehydroaromatizing a reactant stream comprising C1-C4-aliphatics, comprising the steps of I. feeding reactant stream E into a reaction zone 1, converting reactant stream E under nonoxidative conditions in the presence of a particulate catalyst to a product stream P comprising aromatic hydrocarbons and discharging product stream P from reaction zone 1, II. transferring the catalyst with reduced activity as a result of deposited coke into a reaction zone 2, III. at least partly regenerating the catalyst with supply of a hydrogen-comprising gas stream H in a reaction zone 2, at least some of the coke deposited being converted to methane to form a methane-comprising gas stream M which is fed at least partly to reaction zone 1, IV. discharging the catalyst from reaction zone 2 and V. recycling at least a portion of the discharged catalyst into reaction zone 1, reaction zone 1 and reaction zone 2 being arranged spatially adjacent to one another in the same reactor.
摘要翻译：本发明涉及一种使含有C 1 -C 4脂族化合物的反应物流非氧化脱氢芳化的方法，其包括以下步骤：将反应物流E加入到反应区1中，在非氧化条件下在颗粒催化剂存在下转化反应物流E 涉及包含芳族烃并从反应区域1排出产物流P的产物流P。由于沉积的焦炭进入反应区域2，III而导致活性降低的催化剂。在反应区2中供应含氢气流H至少部分地再生催化剂，沉积的焦炭中的至少一些转化成甲烷以形成含甲烷的气流M，其至少部分地进料至反应区1，IV。从反应区2排出催化剂，并将至少一部分排出的催化剂再循环到反应区1中，反应区1和反应区2在相同的反应器中彼此空间上相邻布置。

8. 发明申请

US20120022310A1 PROCESS FOR PREPARING AROMATICS FROM METHANE 审中-公开
标题翻译：从甲烷制备芳族化合物的方法
公开(公告)号：US20120022310A1
公开(公告)日：2012-01-26
申请号：US13186592
申请日：2011-07-20
申请人： Christian SCHNEIDER , Sebastian Ahrens , Kati Bachmann , Joana Coelho Tsou , Thomas Heidemann , Annebart Engbert Wentink
发明人： Christian SCHNEIDER , Sebastian Ahrens , Kati Bachmann , Joana Coelho Tsou , Thomas Heidemann , Annebart Engbert Wentink
IPC分类号： C07C2/00
CPC分类号： C07C2/76 , B01J8/1827 , B01J8/388 , B01J2208/00513 , B01J2208/00991 , C07C2521/04 , C07C2523/28 , C07C2523/30 , C07C2523/34 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/50 , C07C2523/52 , C07C2523/72 , C07C2523/745 , C07C2523/75 , C07C2523/755 , Y02P20/584 , C07C15/04 , C07C15/06 , C07C15/073 , C07C15/08 , C07C15/46 , C07C15/24
摘要： The present invention relates to a process for carrying out endothermic, heterogeneously catalyzed reactions in which the reaction of the starting materials is carried out in the presence of a mixture of inert heat transfer particles and catalyst particles, where the catalyst particles are regenerated in a nonoxidative atmosphere at regular intervals and the heat of reaction required is introduced by separating off the inert heat transfer particles, heating the heat transfer particles in a heating zone and recirculating the heated heat transfer particles to the reaction zone. The process of the invention is particularly suitable for the nonoxidative dehydroaromatization of C1-C4-aliphatics in the presence of zeolite-comprising catalysts.
摘要翻译：本发明涉及一种进行吸热异相催化反应的方法，其中原料的反应在惰性传热颗粒和催化剂颗粒的混合物存在下进行，其中催化剂颗粒在非氧化反应中再生通过分离惰性传热颗粒，加热加热区中的传热颗粒并将加热的传热颗粒再循环到反应区而引入需要的反应热。本发明的方法特别适用于在含沸石的催化剂存在下C1-C4-脂族烃的非氧化脱氢芳构化。

9. 发明申请

US20120012467A1 PROCESS FOR CONVERTING NATURAL GAS TO AROMATICS WITH ELECTROCHEMICAL REMOVAL OF HYDROGEN 有权
标题翻译：将天然气转化为具有电化学去除氢的芳族化合物的方法
公开(公告)号：US20120012467A1
公开(公告)日：2012-01-19
申请号：US13260053
申请日：2010-03-30
申请人： Joana Coelho Tsou , Alexander Panchenko , Annebart Engbert Wentink , Sebastian Ahrens , Thomas Heidemann
发明人： Joana Coelho Tsou , Alexander Panchenko , Annebart Engbert Wentink , Sebastian Ahrens , Thomas Heidemann
IPC分类号： B01D53/32 , C25B1/02
CPC分类号： C01B3/503 , B01D2256/16 , B01D2258/06 , C01B3/26 , C01B3/30 , C01B2203/0277 , C01B2203/0405 , C01B2203/041 , C01B2203/048 , C01B2203/06 , C01B2203/1241 , C01B2203/1247 , C07C2/76 , H01M8/0656 , Y02P20/582 , C07C15/02
摘要： The present invention relates to a process for converting aliphatic hydrocarbons having 1 to 4 carbon atoms to aromatic hydrocarbons in the presence of a catalyst under nonoxidative conditions, wherein at least some of the hydrogen formed in the conversion electrochemically removed is by means of a gas-tight membrane-electrode assembly.
摘要翻译：本发明涉及一种在非氧化条件下在催化剂存在下将具有1至4个碳原子的脂族烃转化为芳族烃的方法，其中在电化学去除的转化中形成的至少一些氢是通过气 - 薄膜电极组件。

10. 发明申请

US20110303550A1 PROCESS FOR CONVERTING NATURAL GAS TO AROMATICS WITH ELECTROCHEMICAL REMOVAL OF HYDROGEN TO GENERATE ELECTRICAL POWER AND OBTAIN HYDROGEN 有权
标题翻译：使用电化学去除氢气生成电力和氢气的天然气转化为芳族化合物的方法
公开(公告)号：US20110303550A1
公开(公告)日：2011-12-15
申请号：US13202427
申请日：2010-03-30
申请人： Joana Coelho Tsou , Alexander Panchenko , Annebart Engbert Wentink , Sebastian Ahrens , Thomas Heidemann
发明人： Joana Coelho Tsou , Alexander Panchenko , Annebart Engbert Wentink , Sebastian Ahrens , Thomas Heidemann
IPC分类号： C25B3/02
CPC分类号： C01B3/503 , C01B3/26 , C01B3/30 , C01B2203/0277 , C01B2203/0405 , C01B2203/041 , C01B2203/048 , C01B2203/06 , C01B2203/1241 , C01B2203/1247 , C07C2/76 , C07C2523/28 , C07C2523/30 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/72 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2529/40 , H01M8/0612 , H01M2008/1095 , Y02P20/582 , C07C15/24 , C07C15/46 , C07C15/073 , C07C15/08 , C07C15/04 , C07C15/06
摘要： The present invention relates to a process for converting aliphatic hydrocarbons having 1 to 4 carbon atoms to aromatic hydrocarbons, comprising the steps of: a) converting a reactant stream E which comprises at least one aliphatic hydrocarbon having 1 to 4 carbon atoms in the presence of a catalyst under nonoxidative conditions to a product stream P comprising aromatic hydrocarbons and hydrogen, and b) electrochemically removing at least some of the hydrogen formed in the conversion from the product stream P by means of a gas-tight membrane-electrode assembly which has at least one selectively proton-conducting membrane and, on each side of the membrane, at least one electrode catalyst, at least some of the hydrogen being oxidized to protons over the anode catalyst on the retentate side of the membrane, and the protons, after passing through the membrane, on the permeate side over the cathode catalyst, are partly, in b1) reduced to hydrogen with application of a voltage, and partly, in b2) reacted with oxygen to give water to generate electrical power, the oxygen originating from an oxygen-comprising stream O which is contacted with the permeate side of the membrane.
摘要翻译：本发明涉及一种将具有1至4个碳原子的脂族烃转化成芳族烃的方法，包括以下步骤：a）在包含至少一种具有1至4个碳原子的脂族烃的反应物流E的存在下，在非氧化条件下的催化剂与包含芳族烃和氢的产物流P，以及b）通过气密膜电极组件电化学去除从产物流P的转化中形成的至少一些氢，至少一个选择性质子传导膜，并且在膜的每一侧上具有至少一个电极催化剂，至少一些氢被氧化成在膜的滞留侧上的阳极催化剂上的质子和通过后的质子通过膜，在阴极催化剂上的渗透侧，部分地，b1）通过施加电压而还原为氢，并且部分地，i n b2）与氧反应以产生水以产生电力，所述氧源来自与所述膜的渗透侧接触的含氧流O。

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