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    • 10. 发明授权
    • Polyvinylidene chloride compositions and their use in monofilament structures
    • 聚偏二氯乙烯组合物及其在单丝结构中的应用
    • US08309634B2
    • 2012-11-13
    • US13059461
    • 2009-08-06
    • Douglas E. BeyerValerie Renard
    • Douglas E. BeyerValerie Renard
    • C08K5/1515B28B3/20
    • D01F6/32
    • The present invention includes a monofilament obtainable by extruding a composition comprising: (a) at least one vinylidene chloride polymer/methyl acrylate interpolymer having at most about 6 weight percent methyl acrylate mer units in the polymer; and (b) at least about three weight percent total plasticizer, of which about 0.5 weight percent based on total composition weight is an epoxy plasticizer or combination thereof through a die such that monofilament is formed. Optionally, and preferably in extruders wherein the composition of (a) and (b) exhibits less uniformity in extrusion than is desired, at least one methacrylic polymer is also added. The invention also includes a process of extruding a composition of at least (a) and (b) to form a monofilament.
    • 本发明包括通过挤出组合物可获得的单丝,所述组合物包含:(a)在聚合物中至多约6重量%的丙烯酸甲酯单体单元的至少一种偏二氯乙烯聚合物/丙烯酸甲酯互聚物; 和(b)至少约3重量%的总增塑剂,其中基于总组合物重量的约0.5重量%是环氧增塑剂或其组合,通过模头形成单丝。 任选地,优选在挤出机中,其中(a)和(b)的组合物在挤出中的均匀性显示出比所需的更小的均匀性,还加入至少一种甲基丙烯酸类聚合物。 本发明还包括挤出至少(a)和(b)的组合物以形成单丝的方法。