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    • 4. 发明授权
    • Method of forming polymer particles
    • 形成聚合物颗粒的方法
    • US07273570B2
    • 2007-09-25
    • US11178091
    • 2005-07-08
    • Stewart W. BlairLloyd A. LoboTomas G. McHugh
    • Stewart W. BlairLloyd A. LoboTomas G. McHugh
    • B29B9/10
    • B01F5/22B01J19/1887B01J2219/00094B01J2219/00096C08J3/16
    • The present invention is a method of manufacturing polymer particles. The method includes providing an oil in water emulsion, wherein the oil phase comprises a volatile solvent and at least one water insoluble polymer. The volatile solvent has a solubility of not more than 10% in water and the water insoluble polymer has a weight average molecular weight of at least 2000. The water insoluble polymer is soluble in the volatile solvent. The emulsion is supplied to a rotating surface of a rotating surface reactor. The temperature of the rotating surface is maintained at the boiling point of said solvent or greater. The rotating surface of the reactor spins at a speed sufficient to cause the emulsion to spread over the rotating surface as a continuously flowing thin film wherein a vapor phase containing the volatile solvent is removed. The water insoluble polymer particles are then collected as a slurry of polymer particles and water.
    • 本发明是制造聚合物颗粒的方法。 该方法包括提供水包油乳液,其中油相包含挥发性溶剂和至少一种水不溶性聚合物。 挥发性溶剂在水中的溶解度不超过10%,水不溶性聚合物的重均分子量至少为2000.水不溶性聚合物可溶于挥发性溶剂。 将乳液供给到旋转表面反应器的旋转表面。 旋转表面的温度保持在所述溶剂的沸点以上。 反应器的旋转表面以足以使乳液作为连续流动的薄膜扩散在旋转表面上的速度旋转,其中除去含有挥发性溶剂的气相。 然后将水不溶性聚合物颗粒作为聚合物颗粒和水的浆料收集。
    • 5. 发明授权
    • Process for the preparation of concentrated dye-water compositions
    • 浓缩染料 - 水组合物的制备方法
    • US06750002B2
    • 2004-06-15
    • US10058395
    • 2002-01-28
    • James E. NovakJeffrey S. BaugherDirk J. HasbergLloyd A. Lobo
    • James E. NovakJeffrey S. BaugherDirk J. HasbergLloyd A. Lobo
    • G03C1005
    • G03C1/005C09B67/0073C09B67/0084G03C1/12
    • A process for preparing a concentrated photographic spectral sensitizing dye-water composition which comprises adding an anionic sensitizing dye to an aqueous medium in the substantial absence of organic solvent, and agitating the combined dye and aqueous medium, wherein the anionic dye forms a liquid-crystalline dye phase in the aqueous medium and the agitation is performed in the presence of a nonionic surfactant having an HLB of less than 12 and an aqueous solubility at 25° C. of greater than 10 ppm, which nonionic surfactant is in the aqueous medium at a level of from 10 to 1000 ppm. In a specific embodiment of the invention, where the viscosity (at 0.1 s−1 shear rate) of the dye-water composition in the absence of the nonionic surfactant would be greater than 100 cp and especially where such viscosity would be greater than 500 cp, the surfactant is preferably present at a level sufficient to substantially reduce air entrainment during agitation of the dye-water composition.
    • 一种制备浓缩照相光谱增感染料 - 水组合物的方法,其包括在基本上不存在有机溶剂的情况下向阴离子增感染料添加阴离子敏化染料,并搅拌组合的染料和水性介质,其中阴离子染料形成液晶 在水性介质中的染料相和在HLB小于12的非离子表面活性剂和25℃下的水溶性在大于10ppm的情况下进行搅拌,该非离子表面活性剂在水性介质中为 水平为10〜1000ppm。 在本发明的一个具体实施方案中,其中在不存在非离子表面活性剂的情况下,染料 - 水组合物的粘度(0.1s -1剪切速率)将大于100cp,特别是在这种粘度将大于 500cp,表面活性剂优选以足以在搅拌染料 - 水组合物期间基本上减少空气夹带的水平存在。
    • 6. 发明授权
    • Coating fluid for imaging element comprising solubilized collagen gelatin and hardener
    • 用于成像元件的涂布液包括溶解的胶原明胶和硬化剂
    • US06589326B1
    • 2003-07-08
    • US10158681
    • 2002-05-30
    • Andrew M. HoweLloyd A. LoboGary L. Santee
    • Andrew M. HoweLloyd A. LoboGary L. Santee
    • G03C1047
    • G03C1/047C07K14/78C09D189/06G03C1/30
    • An aqueous coating fluid is described comprising gelatin at a concentration of at least 1 wt % and gelatin hardener at a level from 1-200 effective &mgr;mole hardener per gram of coating fluid, wherein at least 20% of the gelatin comprises a gelatin prepared from hydrolysis of ossein using sodium or potassium hydroxide. Relative improvements are obtained in reducing the rate of chemical gelation of a coating fluid containing gelatin and a hardener, without the need for chemically modifying functional groups of the gelatin. The invention further enables an increase in coating fluid concentration, increase in the fluid viscosity, reduction in the ratio of added anionic polymer to gelatin, and/or increase in the pH of a coating fluid containing gelatin and a hardener, without detrimentally increasing the rate of chemical gelation of the coating fluid. The invention also enables the inclusion of relatively more reactive hardeners in a coating fluid containing gelatin, and/or the inclusion of relatively higher molecular weight gelatin in a coating fluid containing hardener, without detrimentally increasing the rate of chemical gelation of the coating fluid. Each such advantage may be achieved either individually, or in combinations to varying extents.
    • 描述了一种水性涂布液,其包含浓度为至少1重量%的明胶和每克包衣液的1-200个有效莫莫尔固化剂的明胶硬化剂,其中至少20%的明胶包括由水解制备的明胶 使用氢氧化钠或氢氧化钾。 在降低含有明胶和硬化剂的涂布液的化学凝胶化速率的同时,可以获得相对的改进,而不需要化学改性明胶的官能团。 本发明还能够增加涂布液的浓度,增加流体粘度,降低加入的阴离子聚合物与明胶的比例和/或增加含有明胶和硬化剂的涂布液的pH,而不会不利地增加速率 的涂料液化学凝胶化。 本发明还能够在含有明胶的涂布液中包含相对更多的反应性硬化剂,和/或在含有硬化剂的涂布液中包含相对较高分子量的明胶,而不会不利地提高涂布液的化学凝胶化速率。 每个这样的优点可以单独实现,也可以以不同程度的组合来实现。
    • 9. 发明授权
    • Photographic elements coated on transparent support with reflective protective overcoat
    • 照相元件涂在透明支架上,带反光保护罩
    • US06586165B2
    • 2003-07-01
    • US09844230
    • 2001-04-27
    • Kevin M. DonovanGlenn M. BrownLloyd A. Lobo
    • Kevin M. DonovanGlenn M. BrownLloyd A. Lobo
    • G03C1795
    • G03C1/7614G03C1/76G03C2001/7635G03C2007/3027Y10S430/151
    • The present invention is a photographic element which includes, in order, a transparent support, at least one silver halide emulsion layer superposed on the support, optionally a white or diffuse reflective layer, and a processing-solution-permeable protective layer on the backside, which protective layer becomes water-resistant in the final product without lamination or fusing. The present invention is also directed to a method of making a photographic print involving developing the photographic element. The resulting print is viewed through the support, which provides protection against scratches and stains, while the polymeric overcoat provides water and stain protection to the reverse of the print where minor scratches or damage are not critical, since the image is not viewed from this side. Thus, this invention provides for a tough, stain resistant and transparent viewing surface and a stain resistant back side, which is permeable to processing solutions.
    • 本发明涉及一种照相元件,其中依次包括透明支持体,叠置在支持体上的至少一个卤化银乳剂层,任选地为白色或漫反射层,背面为处理剂溶液可渗透的保护层, 该保护层在最终产品中不会层压或熔化而变得耐水。 本发明还涉及一种制造涉及显影照相元件的照相印刷品的方法。 通过支撑件观察所得到的印刷品,其提供防划伤和污渍的保护,而聚合物外涂层对印刷品的相反部分提供防水和防污染,其中轻微的划痕或损伤不是关键的,因为从该侧看不到图像 。 因此,本发明提供了对加工溶液是可渗透的韧性,耐污染和透明的观察表面和防污背面。
    • 10. 发明授权
    • Method for processing a photographic element comprising a simultaneously coated protective overcoat
    • 用于处理包含同时涂覆的保护性外涂层的照相元件的方法
    • US06432623B1
    • 2002-08-13
    • US09844050
    • 2001-04-27
    • Kevin M. DonovanLloyd A. Lobo
    • Kevin M. DonovanLloyd A. Lobo
    • G03C526
    • G03C1/7614Y10S430/136
    • A method of processing a photographic imaging element to obtain a protective overcoat is disclosed, which overcoat provides, in the final product, resistance to fingerprints, common stains, and spills. More particularly, the present invention involves a processing-solution-permeable overcoat that becomes water and stain resistant in the photochemically processed product. The overcoat formulation comprises at least one water-dispersible hydrophobic polymer interspersed with a water-soluble polymer. During development or thereafter, before drying, the water-soluble polymer is removed to a significant extent. Subsequently, the imaged element is dried at an elevated temperature to facilitate coalescence of the overcoat to thereby provide enhanced stain resistance and water-resistance.
    • 公开了一种处理照相成像元件以获得保护性外涂层的方法,该外涂层在最终产品中提供对指纹,常见污渍和溢出物的抵抗性。 更具体地说,本发明涉及一种在光化学处理产品中变得防水和防污的加工溶液渗透性外涂层。 外涂层制剂包含至少一种散布有水溶性聚合物的水分散性疏水性聚合物。 在显影过程中或此后,在干燥之前,将水溶性聚合物除去至显着的程度。 随后,将成像元件在升高的温度下干燥以促进外涂层的聚结,从而提供增强的耐污染性和耐水性。