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1. 发明授权

US06864334B2 Multi-dentate late transition metal catalyst complexes and polymerization methods using those complexes 失效
标题翻译：多齿后期过渡金属催化剂配合物和使用这些配合物的聚合方法
公开(公告)号：US06864334B2
公开(公告)日：2005-03-08
申请号：US10893429
申请日：2004-07-16
申请人： Lisa Saunders Baugh , Abhimanyu Onkar Patil , Donald Norman Schulz , Robert Timothy Stibrany , Joseph Anthony Sissano , Stephen Zushma
发明人： Lisa Saunders Baugh , Abhimanyu Onkar Patil , Donald Norman Schulz , Robert Timothy Stibrany , Joseph Anthony Sissano , Stephen Zushma
IPC分类号： C07F1/00 , C08F4/44 , C08F4/54 , C08F10/02 , C08F110/02 , C08F210/02 , C08F4/06
CPC分类号： C08F4/54 , C07F1/005 , C08F10/02 , C08F110/02 , C08F210/02 , C08F220/10
摘要： The instant invention provides a late transition metal complex which can be used with an activating cocatalyst to produce polymers and copolymers. The invention also provides methods for polymerizing olefins, as well as copolymers having polar monomers incorporated therein. More specifically, the invention provides a composition having the formula LMXZn, wherein M is selected from the group consisting of Cu, Ag and Au; X is selected from the group consisting of halide, hydride, triflate, acetate, borate, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolate, nitrate, sulfate, nitrile, hydroxide and any other moiety into which a monomer can insert; Z is selected from the group consisting of halide, hydride, triflate, acetate, borate, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolate, carbon monoxide, nitrate, nitrile, hydroxide, sulfate, olefins, water, any other neutral coordinating ligand and any other moiety into which a monomer can insert; n equals 0, 1 or 2; and L is a multi-dentate nitrogen-containing ligand.
摘要翻译：本发明提供了可与活性助催化剂一起使用以产生聚合物和共聚物的后过渡金属络合物。本发明还提供了聚合烯烃的方法以及其中掺入极性单体的共聚物。更具体地，本发明提供具有式LMXZn的组合物，其中M选自Cu，Ag和Au; X选自卤化物，氢化物，三氟甲磺酸盐，乙酸盐，硼酸盐，C1至C12烷基，C1至C12烷氧基，C3至C12环烷基，C3至C12环烷氧基，芳基，硫醇盐，硝酸盐，硫酸盐，腈，氢氧化物和单体可以插入的任何其他部分; Z选自卤化物，氢化物，三氟甲磺酸盐，乙酸盐，硼酸盐，C1至C12烷基，C1至C12烷氧基，C3至C12环烷基，C3至C12环烷氧基，芳基，硫醇盐，一氧化碳，硝酸盐，腈，氢氧化物，硫酸盐，烯烃，水，任何其它中性配位配体和单体可插入的任何其它部分; n等于0,1或2; L是多齿氮含量配体。

2. 发明授权

US08426529B2 Ethylene/dicyclopentadiene copolymers and functionalized derivatives thereof 有权
标题翻译：乙烯/二环戊二烯共聚物及其官能化衍生物
公开(公告)号：US08426529B2
公开(公告)日：2013-04-23
申请号：US11801633
申请日：2007-05-10
申请人： Lisa Saunders Baugh , Abhimanyu Onkar Patil , Christian Peter Mehnert , Kevin R. Squire , Kenneth A. Cook , Caiguo Gong , Enock Berluche , Karla Schall Colle , Alan J. Oshinski , Stephen Zushma , Beverly J. Poole
发明人： Lisa Saunders Baugh , Abhimanyu Onkar Patil , Christian Peter Mehnert , Kevin R. Squire , Kenneth A. Cook , Caiguo Gong , Enock Berluche , Karla Schall Colle , Alan J. Oshinski , Stephen Zushma , Beverly J. Poole
IPC分类号： C08F8/04 , C08F8/08 , C08F236/20 , C08F232/06
CPC分类号： C08F210/02 , C08F8/04 , C08F8/08 , C08F232/00
摘要： Disclosed is a selected type of copolymer composition comprising copolymers having units derived from ethylene and dicyclopentadiene (DCPD) co-monomers. Such copolymer compositions: a) have a DCPD-derived comonomer unit content of from about 25 mole % to about 45 mole %; b) have a Weight Average Molecular Weight, Mw, of greater than about 170,000; c) comprise amorphous material and have glass transition temperatures, Tg, of from about 8° C. to about 129° C., which also fit the equation Tg (in ° C.)≧[(mole % DCPD×3.142)−4.67]; and d) comprise no significant amount of crystalline polyethylene homopolymer or crystallizable polyethylene segments within the ethylene-dicyclopentadiene copolymers. Such copolymers can be readily derivatized by hydrogenation and/or epoxidation to provide polymeric materials suitable for use as engineering thermoplastics. Also disclosed are processes for preparing and optionally further derivatizing ethylene/dicyclopentadiene copolymers having the characteristics hereinbefore described.
摘要翻译：公开了一种选择类型的共聚物组合物，其包含具有衍生自乙烯和二环戊二烯（DCPD）共聚单体的单元的共聚物。这种共聚物组合物：a）具有约25摩尔％至约45摩尔％的DCPD衍生的共聚单体单元含量; b）重均分子量Mw大于约170,000; c）包含无定形材料并且具有约8℃至约129℃的玻璃化转变温度Tg，其也符合方程式Tg（℃）= [（摩尔％DCPD×3.142） - 4.67]; 和d）在乙烯 - 二环戊二烯共聚物内不含有显着量的结晶聚乙烯均聚物或可结晶的聚乙烯链段。这样的共聚物可以通过氢化和/或环氧化来容易地衍生化，以提供适合用作工程热塑性塑料的聚合材料。还公开了制备和任选地进一步衍生具有上述特征的乙烯/二环戊二烯共聚物的方法。

3. 发明申请

US20080306215A1 Functionalization of olefin/diene copolymers 审中-公开
标题翻译：烯烃/二烯共聚物的官能化
公开(公告)号：US20080306215A1
公开(公告)日：2008-12-11
申请号：US11810499
申请日：2007-06-06
申请人： Abhimanyu Onkar Patil , Stephen Zushma , Steven P. Rucker , Christian Peter Mehnert , Raymond A. Cook , Lisa Saunders Baugh , Enock Berluche
发明人： Abhimanyu Onkar Patil , Stephen Zushma , Steven P. Rucker , Christian Peter Mehnert , Raymond A. Cook , Lisa Saunders Baugh , Enock Berluche
IPC分类号： C08C19/34
CPC分类号： C08F8/00 , C08F2800/20 , C08F210/18 , C08F210/02 , C08F210/16 , C08F8/46 , C08F8/06 , C08F8/04 , C08F8/08
摘要： A process is described for functionalizing a copolymer comprising units derived from at least one α-olefin and units derived from at least one diene, which copolymer contains at least one double bond. The process comprises reacting the copolymer with at least one functionalizing agent to introduce polar pendant oxygen-containing functional groups onto the copolymer.
摘要翻译：描述了一种用于使包含至少一种α-烯烃的单元和源自至少一种二烯的单元的共聚物官能化的方法，该共聚物含有至少一个双键。该方法包括使共聚物与至少一种官能化试剂反应以将极性侧链含氧官能团引入到共聚物上。

4. 发明申请

US20080015314A1 Ethylene/dicyclopentadiene copolymers and functionalized derivatives thereof 有权
标题翻译：乙烯/二环戊二烯共聚物及其官能化衍生物
公开(公告)号：US20080015314A1
公开(公告)日：2008-01-17
申请号：US11801633
申请日：2007-05-10
申请人： Lisa Saunders Baugh , Abhimanyu Onkar Patil , Christian Peter Mehnert , Kevin R. Squire , Kenneth A. Cook , Caiguo Gong , Enock Berluche , Karla Schall Colle , Alan J. Oshinski , Stephen Zushma , Beverly J. Poole
发明人： Lisa Saunders Baugh , Abhimanyu Onkar Patil , Christian Peter Mehnert , Kevin R. Squire , Kenneth A. Cook , Caiguo Gong , Enock Berluche , Karla Schall Colle , Alan J. Oshinski , Stephen Zushma , Beverly J. Poole
IPC分类号： C08L45/00
CPC分类号： C08F210/02 , C08F8/04 , C08F8/08 , C08F232/00
摘要： Disclosed is a selected type of copolymer composition comprising copolymers having units derived from ethylene and dicyclopentadiene (DCPD) co-monomers. Such copolymer compositions: a) have a DCPD-derived comonomer unit content of from about 25 mole % to about 45 mole %; b) have a Weight Average Molecular Weight, Mw, of greater than about 170,000; c) comprise amorphous material and have glass transition temperatures, Tg, of from about 8° C. to about 129° C., which also fit the equation Tg (in ° C.)≧[(mole % DCPD×3.142)−4.67]; and d) comprise no significant amount of crystalline polyethylene homopolymer or crystallizable polyethylene segments within the ethylene-dicylopentadiene copolymers. Such copolymers can be readily derivatized by hydrogention and/or epoxidation to provide polymeric materials suitable for use as engineering thermoplastics.Also disclosed are processes for preparing and optionally further derivatizing ethylene/dicyclopentadiene copolymers having the characteristics hereinbefore described. Such processes comprise: a) contacting ethylene with a polymerization mixture comprising greater than about 4.0 molar dicyclopentadiene, in the presence of a selected activated cyclopentadienyl-fluorenyl metallocene catalyst bearing a substituent, preferably a methyl substituent, at the 3-position of the cyclopentadienyl ring, under specific polymerization conditions including relatively high ethylene pressures to thereby form the desired ethylene-dicyclopentadiene copolymers within the polymerization mixture. Such copolymers are then recovered and/or further hydrogenated or functionalized.
摘要翻译：公开了一种选择类型的共聚物组合物，其包含具有衍生自乙烯和二环戊二烯（DCPD）共聚单体的单元的共聚物。这种共聚物组合物：a）具有约25摩尔％至约45摩尔％的DCPD衍生的共聚单体单元含量; b）具有大于约170,000的重均分子量，M < c）包含非晶材料，并且具有约8℃至约129℃的玻璃化转变温度，其也适合方程式T（g）（℃）] = [（摩尔％DCPDx 3.142）-4.67]; 和d）在乙烯 - 二茂二烯共聚物内不含有显着量的结晶聚乙烯均聚物或可结晶的聚乙烯链段。这样的共聚物可以通过水合和/或环氧化来容易地衍生，以提供适合用作工程热塑性塑料的聚合材料。还公开了制备和任选地进一步衍生具有上述特征的乙烯/二环戊二烯共聚物的方法。这样的方法包括：a）在选择的活化的环戊二烯基 - 芴基茂金属催化剂存在下，在含有大于约4.0摩尔二环戊二烯的聚合混合物的存在下，使乙烯与环戊二烯基环的3位具有取代基，优选甲基取代基接触在包括相对较高的乙烯压力的特定聚合条件下，从而在聚合混合物内形成所需的乙烯 - 二环戊二烯共聚物。然后回收和/或进一步氢化或官能化此类共聚物。

5. 发明申请

US20090318597A1 Polymer compositions comprising cyclic olefin polymers, polyolefin modifiers, and fillers 有权
标题翻译：包含环烯烃聚合物，聚烯烃改性剂和填料的聚合物组合物
公开(公告)号：US20090318597A1
公开(公告)日：2009-12-24
申请号：US11820559
申请日：2007-06-20
申请人： Kevin R. Squire , Alan J. Oshinski , Kevin D. Robinson , Christian Peter Mehnert , Marsha M. Arvedson , Beverly J. Poole , Abhimanyu Onkar Patil , Lisa Saunders Baugh , Karla Schall Colle
发明人： Kevin R. Squire , Alan J. Oshinski , Kevin D. Robinson , Christian Peter Mehnert , Marsha M. Arvedson , Beverly J. Poole , Abhimanyu Onkar Patil , Lisa Saunders Baugh , Karla Schall Colle
IPC分类号： C08K5/04 , C08K3/34 , C08L45/00 , C08L67/02
CPC分类号： C08L23/0823 , C08K3/34 , C08L23/16 , C08L51/06 , C08L53/02 , C08L2666/06 , C08L2666/02 , C08L2666/24
摘要： A polymer composition comprises (a) least 40 wt % (based upon the weight of the composition) of a cyclic olefin polymer comprising at least one acyclic olefin and at least 20 wt % of one or more cyclic olefins (based upon the weight of the cyclic olefin polymer), wherein at least a portion of the cyclic olefin polymer has a glass transition temperature of greater than 100° C.; (b) an acyclic olefin polymer modifier in an amount up to 40 wt % (based upon the weight of the composition); and (c) at least 10 wt % (based upon the weight of the composition) of one of more fillers. The polymer composition has a notched Izod impact resistance measured at 23° C. of greater than 100 J/m and a flexural modulus (1% secant method) of greater than 1400 MPa.
摘要翻译：聚合物组合物包含（a）至少40重量％（基于组合物的重量）包含至少一个非环烯烃和至少20重量％的一种或多种环烯烃的环烯烃聚合物（基于环烯烃聚合物），其中至少一部分环烯烃聚合物的玻璃化转变温度大于100℃; （b）至多40重量％（基于组合物的重量）的非环烯烃聚合物改性剂; 和（c）至少10重量％（基于组合物的重量）为更多填料之一。聚合物组合物在23℃下测得的切口悬臂梁式冲击强度大于100J / m，挠曲模量（1％割线法）大于1400MPa。

6. 发明授权

US08344070B2 Polymer compositions comprising cyclic olefin polymers, polyolefin modifiers, and fillers 有权
公开(公告)号：US08344070B2
公开(公告)日：2013-01-01
申请号：US11820559
申请日：2007-06-20
申请人： Kevin R. Squire , Alan J. Oshinski , Kevin D. Robinson , Christian Peter Mehnert , Marsha M. Arvedson , Beverly J. Poole , Abhimanyu Onkar Patil , Lisa Saunders Baugh , Karla Schall Colle
发明人： Kevin R. Squire , Alan J. Oshinski , Kevin D. Robinson , Christian Peter Mehnert , Marsha M. Arvedson , Beverly J. Poole , Abhimanyu Onkar Patil , Lisa Saunders Baugh , Karla Schall Colle
IPC分类号： C08L45/00 , C08L23/00 , C08L23/04 , C08F8/00
CPC分类号： C08L23/0823 , C08K3/34 , C08L23/16 , C08L51/06 , C08L53/02 , C08L2666/06 , C08L2666/02 , C08L2666/24
摘要： A polymer composition comprises (a) least 40 wt % (based upon the weight of the composition) of a cyclic olefin polymer comprising at least one acyclic olefin and at least 20 wt % of one or more cyclic olefins (based upon the weight of the cyclic olefin polymer), wherein at least a portion of the cyclic olefin polymer has a glass transition temperature of greater than 100° C.; (b) an acyclic olefin polymer modifier in an amount up to 40 wt % (based upon the weight of the composition); and (c) at least 10 wt % (based upon the weight of the composition) of one of more fillers. The polymer composition has a notched Izod impact resistance measured at 23° C. of greater than 100 J/m and a flexural modulus (1% secant method) of greater than 1400 MPa.

7. 发明申请

US20080033112A1 Polymer compositions comprising cyclic olefin copolymers and polyolefin modifiers 审中-公开
标题翻译：包含环烯烃共聚物和聚烯烃改性剂的聚合物组合物
公开(公告)号：US20080033112A1
公开(公告)日：2008-02-07
申请号：US11820739
申请日：2007-06-20
申请人： Kevin R. Squire , Alan J. Oshinski , Kevin D. Robinson , Christian Peter Mehnert , Marsha M. Arvedson , Beverly J. Poole , Abhimanyu Onkar Patil , Lisa Saunders Baugh , Karla Schall Colle
发明人： Kevin R. Squire , Alan J. Oshinski , Kevin D. Robinson , Christian Peter Mehnert , Marsha M. Arvedson , Beverly J. Poole , Abhimanyu Onkar Patil , Lisa Saunders Baugh , Karla Schall Colle
IPC分类号： C08L23/00
CPC分类号： C08L23/0823 , C08L23/16 , C08L53/00 , C08L2314/06 , C08L2666/24 , C08L2666/06
摘要： A polymer composition comprises (a) greater than 50 wt % (based upon the weight of the composition) of a cyclic olefin copolymer comprising at least one acyclic olefin and at least 20 weight % of one or more cyclic olefins (based upon the weight of the cyclic olefin copolymer), wherein at least a portion of the cyclic olefin copolymer has a glass transition temperature of greater than 150° C.; and (b) less than 50 wt % (based upon the weight of the composition) of an acyclic olefin polymer modifier, at least a portion of the modifier having a glass transition temperature of less than −30° C.; and no portion of the modifier having a softening point greater than +30° C., wherein the Bicerano solubility parameter of the modifier being no more than 0.6 J0.5/cm1.5 less than the Bicerano solubility parameter of the cyclic olefin copolymer. The polymer composition has a notched Izod impact resistance measured at 23° C. of greater than 500 J/m and a heat distortion temperature measured using a 0.46 MPa load of greater than 135° C.
摘要翻译：聚合物组合物包含（a）大于50重量％（基于组合物的重量）的包含至少一种非环烯烃和至少20重量％的一种或多种环烯烃的环烯烃共聚物（基于环烯烃共聚物），其中至少一部分环烯烃共聚物的玻璃化转变温度大于150℃; 和（b）小于50重量％（基于组合物的重量）非环烯烃聚合物改性剂，至少一部分改性剂的玻璃化转变温度低于-30℃; 并且所述改性剂的任何部分的软化点大于+ 30℃，其中所述改性剂的二辛醇溶解度参数不大于0.6J / 小于环烯烃共聚物的Bicerano溶解度参数。该聚合物组合物在23℃下测得的切口悬臂梁式冲击强度大于500J / m，并且使用大于135℃的0.46MPa载荷测量的热变形温度。

8. 发明授权

US06689852B2 Modifiers for improved olefin polymerization with activated neutral aluminum compounds 失效
标题翻译：改性烯烃聚合与活化的中性铝化合物
公开(公告)号：US06689852B2
公开(公告)日：2004-02-10
申请号：US10046809
申请日：2002-01-15
申请人： Lisa Saunders Baugh , Joseph Anthony Sissano
发明人： Lisa Saunders Baugh , Joseph Anthony Sissano
IPC分类号： C08F452
CPC分类号： C08F10/00 , C08F110/02 , C08F4/52 , C08F2500/03
摘要： The present invention is for a transition metal-free catalyst system for synthesizing high molecular weight, linear polymers. The system comprises a catalyst composition having: (a) a neutral compound having the formula AlR3, wherein R is an alkyl or hydride group; (b) a Lewis acid or Lewis acid derivative cocatalyst different from the neutral compound, wherein the cocatalyst reacts with the neutral compound to form an initiator; and (c) an activity-enhancing modifier, wherein the modifier reacts with the initiator to form the catalyst composition. The instant invention is also directed to a method for polymerizing at least one olefinic monomer comprising the step of contacting a feed containing the olefinic monomer under polymerization conditions with the transition metal-free catalyst composition.
摘要翻译：本发明是用于合成高分子量线型聚合物的无过渡金属催化剂体系。该系统包括具有以下成分的催化剂组合物：（a）具有式AlR 3的中性化合物，其中R是烷基或氢化物基团; （b）不同于中性化合物的路易斯酸或路易斯酸衍生物助催化剂，其中助催化剂与中性化合物反应形成引发剂; 和（c）活性增强改性剂，其中改性剂与引发剂反应形成催化剂组合物。本发明还涉及聚合至少一种烯烃单体的方法，该方法包括使聚合条件下含有烯属单体的进料与无过渡金属的催化剂组合物接触的步骤。

9. 发明授权

US07285609B2 Olefin polymerization catalyst system useful for polar monomers 有权
标题翻译：烯烃聚合催化剂体系可用于极性单体
公开(公告)号：US07285609B2
公开(公告)日：2007-10-23
申请号：US10844683
申请日：2004-05-13
申请人： Lisa Saunders Baugh , Enock Berluche , Paul Veinbergs Hinkle , Francis Charles Rix , Donald Norman Schulz
发明人： Lisa Saunders Baugh , Enock Berluche , Paul Veinbergs Hinkle , Francis Charles Rix , Donald Norman Schulz
IPC分类号： C08F4/44 , B01J31/38
CPC分类号： C07F15/04 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/02 , C08F210/16 , C08F232/08 , C08F2500/03 , C08F2500/09 , C08F2500/10 , C08F4/80 , C08F232/00 , C08F216/04 , C08F210/14 , C08F2500/05 , C08F4/7031 , C08F4/7022
摘要： This invention relates to a polymerization method comprising contacting at least one olefin monomer, at least one polar monomer, an optional activator, and a catalyst compound represented by the formula: wherein M is selected from groups 3-11 of the periodic table; L1 represents a formal anionic ligand, L2 represents a formal neutral ligand, a is an integer greater than or equal to 1; b is greater than or equal to 0; c is greater than or equal to 1, E is nitrogen or phosphorus, Ar0 is arene, R1-R4 are, each independently, selected from hydrogen, hydrocarbyl, substituted hydrocarbyl or functional group, provided however that R3 and R4 do not form a naphthyl ring, N is nitrogen and O is oxygen.
摘要翻译：本发明涉及聚合方法，其包括使至少一种烯烃单体，至少一种极性单体，任选的活化剂和由下式表示的催化剂化合物：其中M选自周期表的第3-11组; L 1表示正式的阴离子配体，L 2表示正式的中性配体，a是大于或等于1的整数; b大于或等于0; c大于或等于1，E是氮或磷，Ar 0是芳烃，R 1 -R 4是各自独立地其中R 3选自氢，烃基，取代的烃基或官能团，但是R 3和R 4不形成萘环，N为氮，O为氧。

10. 发明授权

US07247687B2 Late transition metal catalysts for olefin polymerization and oligomerization 有权
标题翻译：用于烯烃聚合和低聚的后期过渡金属催化剂
公开(公告)号：US07247687B2
公开(公告)日：2007-07-24
申请号：US10517104
申请日：2003-07-17
申请人： Vladimir Kuzunich Cherkasov , Michael Paviovich Bubnov , Nikolay Olegovich Druzhkov , Valentina Nikolavena Glushakova , Irina Alexandrovna Teplova , Nina Aleksandrovna Skorodumova , Gleb Arsent′evich Abakumov , Cynthia A. Ballinger , Kevin R. Squire , Jo Ann Marie Canich , Enock Berluche , Lisa Saunders Baugh , Donald Norman Schulz , Baiyi Zhao
发明人： Vladimir Kuzunich Cherkasov , Michael Paviovich Bubnov , Nikolay Olegovich Druzhkov , Valentina Nikolavena Glushakova , Irina Alexandrovna Teplova , Nina Aleksandrovna Skorodumova , Gleb Arsent′evich Abakumov , Cynthia A. Ballinger , Kevin R. Squire , Jo Ann Marie Canich , Enock Berluche , Lisa Saunders Baugh , Donald Norman Schulz , Baiyi Zhao
IPC分类号： C07F15/00 , C08F4/70
CPC分类号： B01J31/0214 , B01J31/1805 , B01J31/1815 , B01J2231/12 , B01J2531/845 , B01J2531/847 , C07F15/0066 , C07F15/045 , C07F15/065 , C08F10/00 , C08F210/16 , C08F2410/03 , C08F4/025 , C08F210/06 , C08F2500/03 , C08F210/14 , C08F4/7037 , C08F4/7027 , C08F4/7006 , C08F4/52 , C08F4/7042 , C08F4/7004
摘要： This invention relates to a transition metal compound represented by the formula LMX wherein M is a Group 3 to 11 metal L is a bulky bidentate or tridentate neutral ligand that is bonded to M by two or three heteroatoms and at least one heteroatom is nitrogen; X is a substituted or unsubstituted catecholate ligand provided that the substituted catecholate ligand does not contain a 1,2-diketone functionality.
摘要翻译：本发明涉及由式LMX表示的过渡金属化合物，其中M为第3至11族金属，L为通过两个或三个杂原子与至少一个杂原子与氮键合至M的体积大的二齿或三齿中性配体; X是取代或未取代的儿茶酚酸酯配体，条件是取代的儿茶酚酸配体不含有1,2-二酮官能团。

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