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    • 5. 发明申请
    • TAILORABLE POLYIMIDE PREPOLYMER BLENDS, CROSSLINKED, POLYIMIDES, AND ARTICLES FORMED THEREFROM
    • 可修饰的聚酰亚胺预聚物共混物,交联的聚酰亚胺和其形成的物品
    • US20080058476A1
    • 2008-03-06
    • US11928210
    • 2007-10-30
    • Stephen WhitekerWarren RonkLisa Shafer
    • Stephen WhitekerWarren RonkLisa Shafer
    • C08J3/24
    • C08G73/10C08G73/101C08G73/1014C08L79/08C08L2205/02C08L2666/20
    • A tailorable polyimide prepolymer blend including a diamine component including 1,3-phenylenediamine (mPDA), Bisaniline M, and 1,4-phenylenediamine (pPDA), a dianhydride component including 3,4,3′,4′-benzophenonetetracarboxylic dianhydride (BTDA) and 3,4,3′,4′-biphenyltetracarboxylic dianhydride (BPDA), and an end group component. The components may be provided as a monomeric mixture. The prepolymer blend, prior to cure, may provide at least one predetermined prepolymer blend property; and the cured prepolymer blend may provide a crosslinked polyimide matrix having at least one predetermined crosslinked matrix property. Articles formed from the tailorable polyimide prepolymer blend may include powders, neat resins, coating materials, films, adhesives, fibers, composites, laminates, prepregs and parts.
    • 包含二胺组分包括1,3-苯二胺(mPDA),双苯胺M和1,4-苯二胺(pPDA)的二聚体组分包括3,4,3',4'-二苯甲酮四羧酸二酐(BTDA )和3,4,3',4'-联苯四羧酸二酐(BPDA)和端基组分。 组分可以作为单体混合物提供。 预聚物共混物在固化之前可以提供至少一种预定的预聚物共混物性质; 并且固化的预聚物共混物可以提供具有至少一种预定的交联基质特性的交联的聚酰亚胺基体。 由可调节的聚酰亚胺预聚物共混物形成的制品可以包括粉末,纯树脂,涂料,膜,粘合剂,纤维,复合材料,层压材料,预浸料和部件。
    • 6. 发明申请
    • FIBER REINFORCED GAS TURBINE ENGINE COMPONENT
    • 纤维增强气体涡轮发动机部件
    • US20070265420A1
    • 2007-11-15
    • US11383092
    • 2006-05-12
    • Warren RonkStephen Whiteker
    • Warren RonkStephen Whiteker
    • C08G69/26
    • C08G73/101
    • A gas turbine engine component comprising a fiber reinforced matrix. The matrix includes a crosslinked matrix including an R1 group and a an R2 group, and/or an M group. The R1 group and R2 group independently comprise the formula: wherein V is a tetravalent substituted or unsubstituted aromatic monocyclie or polycyclic linking structure; and R is a substituted or unsubstituted divalent organic radical. R2 structure is different than the structure for R1. The M group, when present, is selected from the group consisting of a diamine structure, a dianhydride structure and an end group structure, with the M group being in the reacted or unreacted form. The crosslinked matrix has a glass transition temperature and a thermal oxidative stability sufficient to provide component stability for operational temperature up to about 550° F.
    • 一种燃气涡轮发动机部件,包括纤维增强基体。 该基质包括含有R 1和R 2基团和/或M基团的交联基质。 R 1基团和R 2 H 2基团独立地包含下式:其中V是四价取代或未取代的芳族单环或多环连接结构; 并且R是取代或未取代的二价有机基团。 R 2结构不同于R 1'的结构。 当M基团存在时,选自二胺结构,二酐结构和端基结构,M基团处于反应或未反应形式。 交联基质具有足以提供高达约550°F的操作温度的组分稳定性的玻璃化转变温度和热氧化稳定性。