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    • 6. 发明申请
    • Hydrophobically and Cationically Modified Relative Permeability Modifiers and Associated Methods
    • 疏水和阳离子改性相对渗透性改性剂及相关方法
    • US20120264885A1
    • 2012-10-18
    • US13534166
    • 2012-06-27
    • Larry S. EoffB. Raghava ReddyEldon D. Dalrymple
    • Larry S. EoffB. Raghava ReddyEldon D. Dalrymple
    • C08F265/06
    • C09K8/508
    • Methods comprising providing a relative permeability modifier that comprises a hydrophilic polymer backbone with a hydrophobic modification and incorporating at least one cationic compound onto the hydrophilic polymer backbone. The hydrophilic polymer is one or more of: a polyacrylamide; a polyvinylamine; a poly(vinylamine/vinyl alcohol); an alkyl acrylate polymer; cellulose; chitosan; a polyamide; a polyetheramine; a polyhydroxyetheramine; a polylysine; a polysulfone; a gum; or a starch. The hydrophobic modification is achieved either by reacting the hydrophilic polymer with a hydrophobic compound or by a polymerization reaction product of a hydrophilic monomer and a hydrophobically modified hydrophilic monomer. The hydrophobic compound has an alkyl chain length from 4 to 22 carbons and is one or more of: an alkyl acrylate; an alkyl methacrylate; an alkyl acrylamide; an alkyl methacrylamide; or an alkyl dimethylammoniumethyl methacrylate halide.
    • 方法包括提供相对渗透性调节剂,其包含具有疏水性修饰的亲水性聚合物主链并将至少一种阳离子化合物并入亲水性聚合物主链上。 亲水性聚合物是以下中的一种或多种:聚丙烯酰胺; 聚乙烯胺 聚(乙烯胺/乙烯醇); 丙烯酸烷基酯聚合物; 纤维素; 壳聚糖; 聚酰胺; 聚醚胺 聚羟基胺; 聚赖氨酸 聚砜; 口香糖 或淀粉。 通过使亲水性聚合物与疏水化合物反应或通过亲水性单体和疏水改性的亲水性单体的聚合反应产物来实现疏水改性。 疏水性化合物的烷基链长度为4〜22个碳原子,为丙烯酸烷基酯中的一种或多种。 甲基丙烯酸烷基酯 烷基丙烯酰胺; 烷基甲基丙烯酰胺; 或烷基二甲基铵乙基甲基丙烯酸酯卤化物。
    • 8. 发明授权
    • Well treatment fluid and methods with oxidized polysaccharide-based polymers
    • 处理液和氧化多糖类聚合物的方法
    • US07007752B2
    • 2006-03-07
    • US10727365
    • 2003-12-04
    • B. Raghava ReddyLarry S. EoffEldon D. Dalrymple
    • B. Raghava ReddyLarry S. EoffEldon D. Dalrymple
    • E21B43/00
    • C09K8/12C09K8/512C09K8/685C09K8/887
    • The present invention provides a well treatment fluid for use in a well, the well treatment fluid comprising water; an amine-based polymer; an polysaccharide-based polymer; and an oxidizing agent that is capable of at least partially oxidizing at least the polysaccharide-based polymer. The present invention also provides a method of treating a subterranean formation penetrated by a wellbore, the method comprising the steps of: (a) forming a well treatment fluid comprising water; an amine-based polymer; a polysaccharide-based polymer; and an oxidizing agent that is capable of at least partially oxidizing at least a portion of the polysaccharide-based polymer; and (b) contacting the well treatment fluid with the subterranean formation. The present invention also provides a method of treating a subterranean formation penetrated by a wellbore, the method comprising the steps of: (a) forming a well treatment fluid comprising water; an amine-based polymer; and a polysaccharide-based polymer; (b) contacting the subterranean formation with the well treatment fluid; and (c) contacting the subterranean formation with an oxidizing agent that is capable of at least partially oxidizing at least a portion of the polysaccharide-based polymer in the well treatment fluid present therein.
    • 本发明提供了用于井的井处理流体,井处理流体包括水; 胺基聚合物; 多糖类聚合物; 以及能够至少部分氧化至少多糖类聚合物的氧化剂。 本发明还提供了一种处理由井筒渗透的地层的方法,所述方法包括以下步骤:(a)形成包含水的井处理流体; 胺基聚合物; 多糖类聚合物; 以及能够至少部分氧化所述多糖类聚合物的至少一部分的氧化剂; 和(b)使井处理流体与地层接触。 本发明还提供了一种处理由井筒渗透的地层的方法,所述方法包括以下步骤:(a)形成包含水的井处理流体; 胺基聚合物; 和多糖类聚合物; (b)使地层与井处理流体接触; 和(c)使所述地下层与氧化剂接触,所述氧化剂能够至少部分地氧化存在于其中的井处理流体中至少一部分多糖基聚合物。