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    • 1. 发明授权
    • Integrated-circuit manufacture method with aqueous hydrogen-fluoride and
nitric-acid oxide etch
    • 具有氟化氢和硝酸氧化物蚀刻的集成电路制造方法
    • US6007641A
    • 1999-12-28
    • US818228
    • 1997-03-14
    • Landon B. VinesFelix H. FujishiroYu-Pin Han
    • Landon B. VinesFelix H. FujishiroYu-Pin Han
    • H01L21/28H01L21/306H01L21/316H01L29/51B08B3/00
    • H01L21/28202H01L21/02063H01L21/02164H01L21/02238H01L21/02255H01L21/02271H01L21/02307H01L21/31612H01L21/31662H01L29/518
    • In the manufacture of an integrated circuit, contaminated oxide is replaced by relatively pure oxide using the following steps. First, a partially manufactured integrated circuit is bathed in an aqueous solution of hydrogen peroxide and ammonium hydroxide to oxidize organic materials and weaken bonds of metal contaminants to the integrated circuit substrate. Second, an aqueous rinse removes the oxidized organic materials and metal contaminants. Third, the integrated circuit is bathed in an aqueous solution of hydrogen fluoride and nitric acid. The hydrogen fluroide etches the contaminated oxide; the nitric acid combines with calcium and metal contaminants freed as the oxide is etched. The resulting nitride byproducts are highly soluble and easily removed in the following aqueous rinse. A drying step removes rinse water from the integrated circuit. Finally, an oxide formation step provides a relatively pure oxide layer. In the case of a gate oxide, the method removes a sacrificial oxide in preparation for gate oxide growth. In the case of formation of the submetal dielectric, oxide formation involves an TEOS oxide deposition. A key advantage of the invention is the improved calcium removal due to the nitric acid.
    • 在集成电路的制造中,使用以下步骤用相对纯的氧化物代替污染的氧化物。 首先,将部分制造的集成电路沐浴在过氧化氢和氢氧化铵的水溶液中以氧化有机材料并减弱金属污染物与集成电路基板的接合。 第二,水性漂洗去除氧化的有机物质和金属污染物。 第三,将集成电路浸在氟化氢和硝酸的水溶液中。 氢氟酸蚀刻污染的氧化物; 硝酸与钙和金属污染物结合,氧化物被蚀刻掉。 所得的氮化物副产物是高度可溶的并且容易地在下列水性漂洗液中除去。 干燥步骤从集成电路中去除冲洗水。 最后,氧化物形成步骤提供相对纯的氧化物层。 在栅极氧化物的情况下,该方法除去用于栅极氧化物生长的牺牲氧化物。 在形成亚金属电介质的情况下,氧化物形成涉及TEOS氧化物沉积。 本发明的主要优点是由于硝酸而改善的钙去除。
    • 2. 发明授权
    • Integrated circuit manufacture method with aqueous hydrogen fluoride and nitric acid oxide etch
    • 具有氟化氢水溶液和硝酸氧化物蚀刻的集成电路制造方法
    • US06429144B1
    • 2002-08-06
    • US09473451
    • 1999-12-28
    • Landon B. VinesFelix H. FujishiroYu-Pin Han
    • Landon B. VinesFelix H. FujishiroYu-Pin Han
    • H01L21302
    • H01L21/31111H01L21/0206H01L21/28211H01L21/28238
    • In the manufacture of an integrated circuit, contaminated oxide is replaced by relatively pure oxide using the following steps. First, a partially manufactured integrated circuit is bathed in an aqueous solution of hydrogen peroxide and ammonium hydroxide to oxidize organic materials and weaken bonds of metal contaminants to the integrated circuit substrate. Second, an aqueous rinse removes the oxidized organic materials and metal contaminants. Third, the integrated circuit is bathed in an aqueous solution of hydrogen fluoride and nitric acid. The hydrogen fluroide etches the contaminated oxide; the nitric acid combines with calcium and metal contaminants freed as the oxide is etched. The resulting nitride byproducts are highly soluble and easily removed in the following aqueous rinse. A drying step removes rinse water from the integrated circuit. Finally, an oxide formation step provides a relatively pure oxide layer. In the case of a gate oxide, the method removes a sacrificial oxide in preparation for gate oxide growth. In the case of formation of the submetal dielectric, oxide formation involves an TEOS oxide deposition. A key advantage of the invention is the improved calcium removal due to the nitric acid.
    • 在集成电路的制造中,使用以下步骤用相对纯的氧化物代替污染的氧化物。 首先,将部分制造的集成电路沐浴在过氧化氢和氢氧化铵的水溶液中以氧化有机材料并减弱金属污染物与集成电路基板的接合。 第二,水性漂洗去除氧化的有机物质和金属污染物。 第三,将集成电路浸在氟化氢和硝酸的水溶液中。 氢氟酸蚀刻污染的氧化物; 硝酸与钙和金属污染物结合,氧化物被蚀刻掉。 所得的氮化物副产物是高度可溶的并且容易地在下列水性漂洗液中除去。 干燥步骤从集成电路中去除冲洗水。 最后,氧化物形成步骤提供相对纯的氧化物层。 在栅极氧化物的情况下,该方法除去用于栅极氧化物生长的牺牲氧化物。 在形成亚金属电介质的情况下,氧化物形成涉及TEOS氧化物沉积。 本发明的主要优点是由于硝酸而改善的钙去除。
    • 4. 发明授权
    • Methods and apparatus for fabricationg anti-fuse devices
    • 制造反熔丝器件的方法和装置
    • US5789795A
    • 1998-08-04
    • US579824
    • 1995-12-28
    • Ivan SanchezYu-Pin HanMiguel A. DelgadoYing-Tsong Loh
    • Ivan SanchezYu-Pin HanMiguel A. DelgadoYing-Tsong Loh
    • H01L23/525H01L29/00
    • H01L23/5252H01L2924/0002
    • An integrated circuit having a semiconductor substrate and an anti-fuse structure formed on the semiconductor substrate. The anti-fuse structure includes a metal-one layer and an anti-fuse layer disposed above the metal-one layer. The anti-fuse layer has a first resistance value when the anti-fuse structure is unprogrammed and a second resistance value lower than the first resistance value when the anti-fuse structure is programmed. There is further provided an etch stop layer disposed above the anti-fuse layer, and an inter-metal oxide layer disposed above the etch stop layer with the inter-metal oxide layer has a via formed therein. Additionally, there is further provided a metal-two layer disposed above the inter-metal oxide layer. In this structure, a portion of the metal-two layer is in electrical contact with the anti-fuse layer through the via in the inter-metal oxide layer.
    • 具有形成在半导体衬底上的半导体衬底和抗熔丝结构的集成电路。 反熔丝结构包括金属一层和设置在金属一层上方的抗熔丝层。 当抗熔丝结构未被编程时,抗熔丝层具有第一电阻值,并且当编程防熔丝结构时,抗熔丝层具有低于第一电阻值的第二电阻值。 还提供了设置在反熔丝层上方的蚀刻停止层,并且设置在蚀刻停止层上方的金属间氧化物层与金属间氧化物层在其中形成通孔。 此外,还提供了设置在金属间氧化物层上方的金属二层。 在该结构中,金属二层的一部分通过金属间氧化物层中的通孔与抗熔融层电接触。
    • 6. 发明授权
    • Pad oxide protect sealed interface isolation
    • 垫氧化物保护密封接口隔离
    • US5256895A
    • 1993-10-26
    • US863519
    • 1992-03-31
    • Frank R. BryantYu-Pin HanFu-Tai Liou
    • Frank R. BryantYu-Pin HanFu-Tai Liou
    • H01L21/32H01L21/762H01L27/12H01L23/48H01L29/40
    • H01L21/32H01L21/76205
    • Field oxide regions are formed between drive regions of a silicon substrate by forming over the substrate a sandwich of silicon dioxide, silicon nitride and silicon dioxide layers, opening the layers to expose a portion of the silicon substrate, removing a layer of the exposed substrate, forming side wall spacers on the edges of the opening, removing a layer of the silicon substrate exposed between the side wall spacers, and then reaching the exposed substrate for the thermal oxidation of the exposed substrate for forming the field oxide region. In those structures in which the field oxide is buried in the substrate as shown in FIG. 12, it may be feasible to use thicker field oxide regions and thereby to reduce the need for the heavily doped surface layer under the field oxide.
    • 通过在衬底上形成二氧化硅,氮化硅和二氧化硅层的夹层来形成在硅衬底的驱动区之间的场氧化物区域,打开这些层以暴露硅衬底的一部分,去除暴露的衬底的一层, 在开口的边缘上形成侧壁间隔物,去除暴露在侧壁间隔物之间​​的硅衬底层,然后到达暴露的衬底,用于暴露衬底的热氧化以形成场氧化物区域。 在如图1所示的那些场地氧化物埋在衬底中的那些结构中。 如图12所示,可以使用较厚的场氧化物区域,从而减少对场氧化物下的重掺杂表面层的需要。
    • 8. 发明授权
    • Method of making antifuse structures using implantation of both neutral
and dopant species
    • 使用中性和掺杂物种植物制造反熔丝结构的方法
    • US5783467A
    • 1998-07-21
    • US582844
    • 1995-12-29
    • Yu-Pin HanYing-Tsong LohIvan Sanchez
    • Yu-Pin HanYing-Tsong LohIvan Sanchez
    • H01L21/8246H01L27/112H01L21/82
    • H01L27/11206H01L27/112
    • An antifuse structure includes a first electrode, a layer of enhanced amorphous silicon over the first electrode, and a second electrode over the layer of enhanced amorphous silicon. The layer of enhanced amorphous silicon is formed by an ion-implantation of a neutral species and a dopant species into a deposited layer of amorphous silicon, such that the antifuse structure will have a stable conductive link in a programmed state and such that it will be less susceptible to off-state leakage in an unprogrammed state. A method for making an antifuse structure includes forming a lower electrode, depositing an amorphous silicon layer over the lower electrode, ion-implanting a neutral species and a dopant species into the amorphous silicon layer, and forming an upper electrode over the amorphous silicon layer.
    • 反熔丝结构包括第一电极,在第一电极上方的增强非晶硅层,以及增强非晶硅层上的第二电极。 通过将中性物质和掺杂剂物质的离子注入到非晶硅的沉积层中形成增强非晶硅层,使得反熔丝结构将在编程状态下具有稳定的导电链路,并且使得其将被 在非编程状态下较不易于断态泄漏。 制造反熔丝结构的方法包括形成下电极,在下电极上沉积非晶硅层,将中性物质和掺杂剂物质离子注入到非晶硅层中,以及在非晶硅层上形成上电极。