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    • 1. 发明授权
    • Methods for preparing composites of substrate-molecular sieve
    • 制备底物分子筛复合材料的方法
    • US08771639B2
    • 2014-07-08
    • US12311486
    • 2008-01-04
    • Kyung Byung YoonJin Seok LeeJae Hyun KimYoung Ju LeeNak Cheon Jeong
    • Kyung Byung YoonJin Seok LeeJae Hyun KimYoung Ju LeeNak Cheon Jeong
    • C01B33/36C01B39/00C01F7/00
    • C01B39/02
    • The present invention relates to a method for preparing composites of substrate-molecular sieve, in particular, to a method for preparing a composite of substrate-molecular sieve, which comprises applying a physical pressure to molecular sieve crystals against a substrate to form a chemical bond between the molecular sieve crystal and the substrate. The present invention requiring no solvents, reactors and other equipments enables molecular sieve crystals to be stably attached to the surface of substrates through various chemical bonds, particularly ionic present invention ensures the synthesis of substrate-molecular sieve composites with enhanced attachment rate, degree of lateral close packing (DCP) and attachment strength in more time-saving and energy-saving manners. The present method works well for molecular sieve crystals with lager sizes (e.g., more than 3 μm) with no generation of parasitic crystals. Furthermore, the present invention shows excellent applicability to large substrates, enabling the mass production of substrate-molecular sieve composites.
    • 本发明涉及一种制备底物分子筛复合材料的方法,特别涉及一种制备底物 - 分子筛复合材料的方法,该方法包括向分子筛晶体施加物理压力以抵抗基质以形成化学键 在分子筛晶体和基底之间。 不需要溶剂,反应器等设备的本发明使得分子筛晶体能够通过各种化学键稳定地附着于基底表面,特别是离子本发明确保了底物分子筛复合物的合成,具有增强的附着率, 紧密包装(DCP)和附件强度更节省时间和节能的方式。 本发明的方法适用于具有较大尺寸(例如大于3μm)的分子筛晶体,而不产生寄生晶体。 此外,本发明对大基材显示出优异的适用性,能够批量生产基质分子筛复合材料。
    • 2. 发明申请
    • Methods for preparing composites of substrate-molecular sieve
    • 制备底物分子筛复合材料的方法
    • US20090246122A1
    • 2009-10-01
    • US12311486
    • 2008-01-04
    • Kyung Byung YoonJin Seok LeeJae Hyun KimYoung Ju LeeNak Cheon Jeong
    • Kyung Byung YoonJin Seok LeeJae Hyun KimYoung Ju LeeNak Cheon Jeong
    • C01B39/02C07F7/02
    • C01B39/02
    • The present invention relates to a method for preparing composites of substrate-molecular sieve, which comprises applying a physical pressure to molecular sieve crystals against a substrate to form a chemical bond between the molecular sieve crystal and the substrate. The present invention requiring no solvents, reactors and other equipments enables molecular sieve crystals to be stably attached to the surface of substrates through various chemical bonds, particularly ionic present invention ensures the synthesis of substrate-molecular sieve composites with enhanced attachment rate, degree of lateral close packing (DCP) and attachment strength in more time-saving method works well for molecular sieve crystals with lager sizes (e.g., more than 3 μm) with no generation of parasitic crystals. Furthermore, the present invention shows excellent applicability to large substrates, enabling the mass production of substrate-molecular sieve composites.
    • 本发明涉及一种制备底物分子筛复合材料的方法,该方法包括向分子筛结晶施加物理压力以在基底上形成分子筛晶体与基底之间的化学键。 不需要溶剂,反应器等设备的本发明使得分子筛晶体能够通过各种化学键稳定地附着于基底表面,特别是离子本发明确保了底物分子筛复合物的合成,具有增强的附着率, 紧密封装(DCP)和附件强度更节省时间的方法适用于较大尺寸(例如超过3 mum)的分子筛晶体,不产生寄生晶体。 此外,本发明对大基材显示出优异的适用性,能够批量生产基质分子筛复合材料。
    • 4. 发明授权
    • Method of preparing substrates—molecular sieve layers complex using ultrasound and apparatuses used therein
    • 使用超声波制备底物 - 分子筛层复合物的方法及其中使用的装置
    • US08288302B2
    • 2012-10-16
    • US11629375
    • 2005-06-23
    • Kyung Byung YoonJin Seok LeeKwang HaYun-Jo LeeYong Chang
    • Kyung Byung YoonJin Seok LeeKwang HaYun-Jo LeeYong Chang
    • B01J29/06
    • C23C22/02B82Y15/00C03C17/002C03C17/007C03C17/009C03C2217/23C03C2217/465C03C2217/475C23C26/00C23C30/00
    • The present invention relates to a method for preparing substrate-molecular sieve layer complex by vising ultra-sound and apparatuses used therein, more particularly to a method for preparing substrate-molecular sieve layer complex by combining substrate, coupling compound and molecular sieve particle, wherein covalent, ionic, coordinate or hydrogen bond between a substrate and a coupling compound; molecular sieve particle and coupling compound; coupling compounds; coupling compound and intermediate coupling compound is induced by using 15 KHz-100 MHz of ultrasound instead of simple reflux to combine substrate and molecular sieve particles by various processes, further to reduce time and energy, to retain high binding velocity, binding strength, binding intensity and density remarkably, to attach molecular sieve particle uniformly onto all substrates combined with coupling compound selectively, even though substrate with coupling compound and substrate without coupling compound exist together; and apparatuses installed therein, which can improve to produce substrate-molecular sieve layer complex in a large scale.
    • 本发明涉及一种通过超声波和其中使用的装置制备底物 - 分子筛层复合物的方法,更具体地涉及一种通过将底物,偶联化合物和分子筛颗粒组合制备底物 - 分子筛层复合物的方法,其中 底物和偶联化合物之间的共价,离子,配位或氢键; 分子筛颗粒和偶联剂; 偶联化合物; 通过使用15KHz-100MHz的超声波而不是简单回流来诱导偶联化合物和中间偶联化合物,以通过各种方法将底物和分子筛颗粒结合在一起,进一步减少时间和能量,以保持高结合速度,结合强度,结合强度 和密度显着地将分子筛颗粒均匀地附着在与偶联化合物组合的所有基材上,即使具有偶联化合物的底物和没有偶联化合物的底物一起存在; 以及安装在其中的装置,其可以改进以大规模生产基质 - 分子筛层复合物。
    • 5. 发明申请
    • Method of Preparing Substrates - Molecular Sieve Layers Complex Using Ultrasound and Apparatuses Used Therein
    • 使用其中使用的超声波和设备制备底物 - 分子筛层复合物的方法
    • US20080254969A1
    • 2008-10-16
    • US11629375
    • 2005-06-23
    • Kyung Byung YoonJin Seok LeeKwang HaYun-Jo LeeYong Chang
    • Kyung Byung YoonJin Seok LeeKwang HaYun-Jo LeeYong Chang
    • B01J29/40B01J29/22
    • C23C22/02B82Y15/00C03C17/002C03C17/007C03C17/009C03C2217/23C03C2217/465C03C2217/475C23C26/00C23C30/00
    • The present invention relates to a method for preparing substrate-molecular sieve layer complex by vising ultra-sound and apparatuses used therein, more particularly to a method for preparing substrate-molecular sieve layer complex by combining substrate, coupling compound and molecular sieve particle, wherein covalent, ionic, coordinate or hydrogen bond between a substrate and a coupling compound; molecular sieve particle and coupling compound; coupling compounds; coupling compound and intermediate coupling compound is induced by using 15 KHz-100 MHz of ultrasound instead of simple reflux to combine substrate and molecular sieve particles by various processes, further to reduce time and energy, to retain high binding velocity, binding strength, binding intensity and density remarkably, to attach molecular sieve particle uniformly onto all substrates combined with coupling compound selectively, even though substrate with coupling compound and substrate without coupling compound exist together; and apparatuses installed therein, which can improve to produce substrate-molecular sieve layer complex ina large scale.
    • 本发明涉及一种通过超声波和其中使用的装置制备底物 - 分子筛层复合物的方法,更具体地涉及一种通过将底物,偶联化合物和分子筛颗粒组合制备底物 - 分子筛层复合物的方法,其中 底物和偶联化合物之间的共价,离子,配位或氢键; 分子筛颗粒和偶联剂; 偶联化合物; 通过使用15KHz-100MHz的超声波而不是简单回流来诱导偶联化合物和中间偶联化合物,以通过各种方法将底物和分子筛颗粒结合在一起,进一步减少时间和能量,以保持高结合速度,结合强度,结合强度 和密度显着地将分子筛颗粒均匀地附着在与偶联化合物组合的所有基材上,即使具有偶联化合物的底物和没有偶联化合物的底物一起存在; 安装在其中的装置,其可以大规模地改进生产基质 - 分子筛层复合物。