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    • 1. 发明专利
    • Nuclear reactor structural member and fuel assembly having the same
    • 核反应堆结构构件和燃料组件
    • JP2014167423A
    • 2014-09-11
    • JP2013039224
    • 2013-02-28
    • Kyocera Corp京セラ株式会社
    • ODA TAKEHIROSHINO NAOYUKINAKAMURA KIYOTAKA
    • G21C3/30G21C3/06
    • Y02E30/40
    • PROBLEM TO BE SOLVED: To provide a nuclear reactor structural member which is free from flying off of silicon carbide fiber and thus less susceptible to scratches and chips even when surface temperature of the nuclear reactor structural member, such as a fuel cladding tube and fuel channel box, rises to a high temperature of 600°C or higher, and to provide a fuel assembly having the same.SOLUTION: A nuclear reactor structural member is a tabular member made of base materials, each comprising a silicon carbide sintered body with silicon carbide fiber on a surface thereof and silicon that covers both the surface of the silicon carbide sintered body and the silicon carbide fiber. The nuclear reactor structural member is resistant to damage due to contact with fuel rods, spacers, control rods, or the like during inserting and retracting operation and contact with radioactive contaminants contained in cooling water and, since the melting point of silicon is 1410°C, the silicon carbide fiber does not fly off even when surface temperature of the nuclear reactor structural member reaches as high as 1400°C, which allows the surface of the nuclear reactor structural member to be kept resistant to damage and to be used for a long period of time.
    • 要解决的问题:提供一种核反应堆结构件,其不会脱离碳化硅纤维,因此即使在诸如燃料包层管和燃料通道的核反应堆结构件的表面温度下也不易受划痕和碎屑的影响 盒升高至600℃以上的高温,并提供具有该燃料组件的燃料组件。解决方案:核反应堆结构构件是由基材制成的板状构件,每个包括具有碳化硅的碳化硅烧结体 其表面上的纤维和覆盖碳化硅烧结体的表面和碳化硅纤维的硅。 核反应堆结构构件在插入和收回操作期间由于与燃料棒,间隔物,控制棒等的接触而受到损坏,并且与冷却水中包含的放射性污染物接触,并且由于硅的熔点为1410℃ 即使核反应堆结构件的表面温度高达1400℃,碳化硅纤维也不飞散,这使得核反应堆结构件的表面能够保持耐损坏并长期使用 一段的时间。
    • 2. 发明专利
    • Silicon nitride porous body and filter
    • 硅酸盐多孔体和过滤器
    • JP2014148429A
    • 2014-08-21
    • JP2013016824
    • 2013-01-31
    • Kyocera Corp京セラ株式会社
    • OTA MIZUHOODA TAKEHIROISHIKAWA KAZUHIRO
    • C04B38/00B01D39/20C04B35/584
    • PROBLEM TO BE SOLVED: To provide a silicon nitride porous body and a filter each unlikely to break even if thermal or mechanical impacts are impressed thereon.SOLUTION: The provided silicon nitride porous body not only includes silicon nitride as a main component but also includes a compound of zirconium. The average pore diameter thereof is 20 μm or less, and the ratio, with respect to the pore diameter of the cumulative 25 vol.% on the cumulative distribution curve of pore diameters (p25), of the pore diameter of the cumulative 75 vol.% (p75) (p75/p25) is 1.5 or less. In a case where the average pore diameter and ratio (p75/p25) of such a silicon nitride porous body are confined respectively to these ranges, it becomes possible not only to reduce the average pore diameter but also to abate diameter irregularities of pores existing within the silicon nitride porous body, and therefore, the localization of residual stresses within the silicon nitride porous body becomes unlikely. A silicon nitride porous body unlikely to break even if thermal or mechanical impacts are impressed thereon can therefore be provided.
    • 要解决的问题:提供一种氮化硅多孔体和过滤器,即使在其上施加热或机械冲击时也不会破裂。解决方案:所提供的氮化硅多孔体不仅包括氮化硅作为主要成分,而且包括 锆化合物。 其平均孔径为20μm以下,相对于孔径的累积分布曲线(p25)的累积25体积%的孔径的累积75体积%的孔径的比例。 %(p75)(p75 / p25)为1.5以下。 在这种氮化硅多孔体的平均孔径和比(p75 / p25)分别被限制在这些范围的情况下,不仅可以降低平均孔径,而且可以减轻存在于其中的孔内的直径不规则性 氮化硅多孔体,因此,氮化硅多孔体内的残余应力的定位变得不可能。 因此,可以提供即使在其上施加热或机械冲击也不会破裂的氮化硅多孔体。
    • 4. 发明专利
    • Boron carbide powder, method for manufacturing the same, and boron carbide-based compact and boron carbide-based sintered compact using the same
    • 碳硼化物粉末,其制造方法和基于碳硼化物的复合材料和基于碳硼化物的烧结压片
    • JP2008239471A
    • 2008-10-09
    • JP2007223294
    • 2007-08-29
    • Kyocera Corp京セラ株式会社
    • KAYAMA TEPPEIHORIUCHI NOBUOKINAKANISHI MASAHITOODA TAKEHIRO
    • C01B31/36C04B35/563C04B35/628
    • PROBLEM TO BE SOLVED: To solve the following problem: a lipophilic film formed on a surface of boron carbide powder cannot thoroughly inhibit a reaction of water with the boron carbide powder, and if the temperature rises to about 200-300°C, the lipophilic film thermally decomposes and hot steam penetrates the surface of boron carbide powder to oxidize the boron carbide powder, consequently a sintered compact obtained from the powder has many pores and high hardness and high strength specific to boron carbide are not exhibited. SOLUTION: Boron carbide powder containing carbon simple substance or silicon simple substance and having a boron hydroxide-containing layer on a surface thereof is provided. When the specific surface area of the boron carbide powder is represented by X (m 2 /g) and the oxygen content of the boron hydroxide in the layer by Y (mass%), the boron carbide powder satisfies 0 COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题为了解决以下问题:在碳化硼粉末的表面上形成的亲脂性膜不能完全抑制水与碳化硼粉末的反应,并且如果温度升至约200-300℃ ,亲油性膜热分解,热蒸汽穿透碳化硼粉末的表面以氧化碳化硼粉末,因此从粉末获得的烧结体具有许多孔,并且不显示出高硬度和高碳化硼特性的高强度。 解决方案:提供含有碳单体或硅单体并在其表面上含有氢氧化硼的层的碳化硼粉末。 当碳化硼粉末的比表面积由X(m 2 / g)表示,层中的氢氧化硼的氧含量为Y(质量%)时,碳化硼粉末满足 0
    • 5. 发明专利
    • Silicon nitride sintered compact, and member for semiconductor manufacturing unit and member for liquid crystal manufacturing unit using the same
    • 硅酸盐烧结紧固件,半导体制造单元的部件和使用其的液晶制造单元的部件
    • JP2007169118A
    • 2007-07-05
    • JP2005370703
    • 2005-12-22
    • Kyocera Corp京セラ株式会社
    • KAYAMA TEPPEIODA TAKEHIROOSHIMA KAZUYOSHITAKIGAWA KAZUAKI
    • C04B35/584H01L21/683
    • PROBLEM TO BE SOLVED: To provide a silicon nitride sintered compact having a practically large mechanical strength and a small coefficient of thermal expansion, and small grinding resistance. SOLUTION: This silicon nitride sintered compact is mainly composed of β-Si 3 N 4 , and it contains 5-30 vol% Si 2 N 2 O (silicon oxynitride) and 1-10 vol% β-RE 2 Si 2 O 7 (RE is an element in the group III of the periodical table). The sintered compact keeps a strong mechanical strength due to a composition composed mainly of β-Si 3 N 4 , and has a small grinding resistance due to a composition having 5-30 vol% Si 2 N 2 O and also has a small coefficient of thermal expansion of the grain boundary layer and a small residual stress in the sintered compact due to a composition having the range of 1-10 vol% β-RE 2 Si 2 O 7 , and further the sintered compact exhibits excellent processability allowing a smooth grinding process and the working of high dimensional accuracy due to its small grinding force. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供具有实际大的机械强度和小的热膨胀系数以及小的耐磨性的氮化硅烧结体。 该解决方案:该氮化硅烧结体主要由β-Si 3 SBS 4 组成,并且含有5-30体积%的Si 2 SB> N 2(氮氧化硅)和1-10体积%的β-RE 2 2 >(RE是期刊第三组元素)。 该烧结体由于主要由β-Si 3 S N 4 组成的组合物而保持强大的机械强度,由于组成为5-30 vol%Si 2 2 O,并且由于具有以下成分的组成,在烧结体中也具有小的晶界面热膨胀系数和小的残余应力 范围为1-10体积%的β-RE 2 2 7 ,此外,烧结体表现出优异的加工性,允许平滑的研磨工艺 并且由于其小的研磨力而具有高尺寸精度的工作。 版权所有(C)2007,JPO&INPIT
    • 7. 发明专利
    • Molten-metal-resistant member and method for manufacturing the same
    • 耐金属材料及其制造方法
    • JP2005179176A
    • 2005-07-07
    • JP2004247330
    • 2004-08-26
    • Kyocera Corp京セラ株式会社
    • OKAWA YOSHIHIROODA TAKEHIRO
    • C04B35/584C04B41/91
    • PROBLEM TO BE SOLVED: To solve the problems that cracks and fissures are liable to occur due to repeated use when a member to be exposed to molten metal is formed of a silicon nitride and that the oxide, dust, etc., in the metal element in the molten metal are liable to stick when the silicon nitride is used as a member to be immersed with the molten metal. SOLUTION: The molten-metal-resistant member comprises a silicon nitride-based sintered material having crystals of the silicon nitride and a grain boundary layer containing at least one of a metal element of ≥1,000°C in melting point, wherein the concentration of the metal silicide on the surface of the silicon nitride-based sintered material is made lower than that of the interior thereof. COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:为了解决当暴露于熔融金属的构件由氮化硅形成并且氧化物,灰尘等在反复使用时容易发生裂纹和裂缝的问题 当氮化硅用作浸入熔融金属的构件时,熔融金属中的金属元素容易粘附。 解决方案:耐熔融金属构件包括具有氮化硅晶体和含有熔点≥1,000℃的金属元素中的至少一种的晶界层的氮化硅基烧结材料,其中, 氮化硅系烧结体的表面上的金属硅化物的浓度比其内部低。 版权所有(C)2005,JPO&NCIPI
    • 8. 发明专利
    • Ceramic sintered body, and corrosion resistant member, filter and antihalation member using the same
    • 陶瓷烧结体,耐腐蚀成员,过滤器和防腐剂成员
    • JP2014005190A
    • 2014-01-16
    • JP2012238085
    • 2012-10-29
    • Kyocera Corp京セラ株式会社
    • HIRANO YOSHINORIOTA MIZUHOISHIKAWA KAZUHIROODA TAKEHIRO
    • C04B35/584A01K87/04
    • PROBLEM TO BE SOLVED: To provide a ceramic sintered body in which a grain boundary phase is hardly corroded even when being exposed to an acid or an alkaline component, and which can maintain high mechanical strength; and to provide a corrosion resistant member, a filter and an antihalation member using the same.SOLUTION: A ceramic sintered body contains 80 mass% or more silicon nitride with respect to the whole mass, and also contains at least one kind of monticellite and merwinite in a grain boundary phase of a crystal of the silicon nitride. Since the amount of a corrosive amorphous phase constituting the grain boundary phase becomes relatively small owing to existence of at least one kind of monticellite and merwinite in the grain boundary phase, mechanical strength is hardly deteriorated even when being exposed to an acid or an alkaline component.
    • 要解决的问题:提供即使暴露于酸或碱性成分也难以腐蚀晶界相并且能够保持高机械强度的陶瓷烧结体; 并提供耐腐蚀性构件,过滤器和使用其的防晕构件。解决方案:陶瓷烧结体相对于整个物质含有80质量%以上的氮化硅,并且还含有至少一种蒙脱石和镁矿 在氮化硅的晶体的晶界相中。 由于晶界相中由于存在至少一种蒙脱石和锂锰矿,所以构成晶界相的腐蚀性非晶相的量变得相对较小,即使在暴露于酸或碱性成分的情况下,机械强度几乎不劣化 。
    • 9. 发明专利
    • Member for molten metal, and heater tube
    • 用于金属和加热管的会员
    • JP2012106920A
    • 2012-06-07
    • JP2011236105
    • 2011-10-27
    • Kyocera Corp京セラ株式会社
    • OTA MIZUHOODA TAKEHIRO
    • C04B35/584
    • PROBLEM TO BE SOLVED: To provide a member for a molten metal composed of a silicon nitride-based sintered compact, which is excellent in mechanical properties and thermal shock resistance, is highly reliable, and can be used for a long period.SOLUTION: The member for a molten metal is composed of a silicon nitride-based sintered compact having a columnar crystal 1 containing silicon nitride as a main component and a grain boundary phase 2 containing an oxide of a metal element as a main component. The silicon nitride-based sintered compact has open pores 3 on its surface; inside the open pores 3, a plurality of second columnar crystals 1b having a larger diameter than the first columnar crystals 1a present inside the silicon nitride sintered compact are present so as to entangle with each other. The erosion of the grain boundary phase 2 on the inner surface of the open pores 3 by the molten metal is suppressed, so mechanical properties and thermal shock resistance of the silicon nitride sintered compact itself can be improved. The molten metal less reacts with and attaches to the grain boundary phase 2, so the member for a molten metal can be used over a long period.
    • 要解决的问题:为了提供由机械性能和耐热冲击性优异的氮化硅基烧结体组成的熔融金属的构件,是高度可靠的,并且可以长时间使用。 解决方案:用于熔融金属的构件由具有包含氮化硅作为主要成分的柱状晶体1和含有以金属元素的氧化物为主要成分的晶界相2的氮化硅基烧结体组成 。 氮化硅基烧结体在其表面上具有开孔3; 在开孔3的内部存在多个第二柱状晶体1b,该第二柱状晶体1b的直径大于存在于氮化硅烧结体内部的第一柱状晶体1a,以便彼此缠结。 通过熔融金属在开孔3的内表面上的晶界相2的侵蚀被抑制,因此能够提高氮化硅烧结体本身的机械特性和耐热冲击性。 熔融金属与晶界相2较少反应并附着在晶界2上,所以可以长时间使用熔融金属的构件。 版权所有(C)2012,JPO&INPIT