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1. 发明授权

US5367033A Biodegradable ethylene polymer having ester bonds in the main chain and process for production of the same 失效
标题翻译：在主链中具有酯键的可生物降解的乙烯聚合物及其生产方法
公开(公告)号：US5367033A
公开(公告)日：1994-11-22
申请号：US8838
申请日：1993-01-25
申请人： Naohiro Mikawa , Satoshi Ueki , Naomi Koyama , Hiroyuki Furuhashi , Tetsuya Morioka , Shigeyuki Toki
发明人： Naohiro Mikawa , Satoshi Ueki , Naomi Koyama , Hiroyuki Furuhashi , Tetsuya Morioka , Shigeyuki Toki
IPC分类号： C08F8/00 , C08G63/00 , C08G63/85 , C08G63/12
CPC分类号： C08G63/85 , C08F8/00 , C08G63/00
摘要： An ethylene polymer which Is capable of being degraded by microorganisms is provided which comprises a recurring unit represented by the general formula ##STR1## in which R is a divalent hydrocarbon group containing 2 to 20 carbon atoms, R' is a divalent hydrocarbon group containing 1 to 20 carbon atoms and A is a polyethylene segment comprising a recurring unit represented by the formula --CH.sub.2.CH.sub.2 -- and having a number average molecular weight (Mn) of 300 to 300,000, and the ethylene polymer having a number average molecular weight (Mn) of 500 to 5,000,000.
摘要翻译：提供能够被微生物降解的乙烯聚合物，其包含由通式“IMAGE”或“IMAGE”表示的重复单元，其中R是含有2至20个碳原子的二价烃基，R'是二价含有1至20个碳原子的烃基，A是包含由式-CH 2 CH 2表示的重复单元并且具有300至300,000的数均分子量（＆amp;上升＆Mn）的聚乙烯链段，并且具有数平均分子量（＆upbar＆Mn）为500〜5,000,000。

2. 发明授权

US5382634A Terminal-modifed polyolefins 失效
标题翻译：末端改性的聚烯烃
公开(公告)号：US5382634A
公开(公告)日：1995-01-17
申请号：US232304
申请日：1994-04-25
申请人： Naomi Koyama , Miyuki Usui , Hiroyuki Furuhashi , Satoshi Ueki
发明人： Naomi Koyama , Miyuki Usui , Hiroyuki Furuhashi , Satoshi Ueki
IPC分类号： C08F8/00 , C08F297/08 , C08F210/06 , C08F210/16
CPC分类号： C08F8/00
摘要： The object of the present invention is to provide such a polyolefin that only the terminal of polypropylene or ethylene-propylene random copolymer is modified with a (meth)acrylic derivative unit to give a substantially monodipersed system. The feature thereof consists in such a polyolefin that the terminal of polypropylene or ethylene-propylene random copolymer obtained by living polymerization is modified with a (meth)acrylic derivative unit. As the (meth)acrylic derivative, there are used vinyl methacrylate, allyl methacrylate, trimethylsiloxyethyl methacrylate, 2-trimethylsiloxypropyl methacrylate, N, N-dimethylaminoethyl methacrylate, N,N-diethylaminoethyl methacrylate, glycidyl methacrylate, acrylic acid chloride and like.
摘要翻译：本发明的目的是提供这样的聚烯烃，只有聚丙烯或乙烯 - 丙烯无规共聚物的末端用（甲基）丙烯酸衍生物单元进行改性，得到基本上单体系统。其特征在于这样的聚烯烃，其中通过活性聚合获得的聚丙烯或乙烯 - 丙烯无规共聚物的末端用（甲基）丙烯酸衍生物单元改性。作为（甲基）丙烯酸衍生物，使用甲基丙烯酸乙烯酯，甲基丙烯酸烯丙酯，甲基丙烯酸三甲基甲硅烷氧基乙酯，甲基丙烯酸2-三甲基甲硅烷基丙酯，甲基丙烯酸N，N-二甲基氨基乙酯，甲基丙烯酸N，N-二乙基氨基乙酯，甲基丙烯酸缩水甘油酯，丙烯酰氯等。

3. 发明授权

US5334678A Both ends-modified olefin polymers and processes for the production thereof 失效
标题翻译：两末端改性烯烃聚合物及其生产方法
公开(公告)号：US5334678A
公开(公告)日：1994-08-02
申请号：US26085
申请日：1993-03-04
申请人： Hiroyuki Furuhashi , Naomi Koyama , Satoshi Ueki
发明人： Hiroyuki Furuhashi , Naomi Koyama , Satoshi Ueki
IPC分类号： C08F8/00 , C08F10/00 , C08F110/00 , C08F110/02 , C08F210/02 , C08F210/18 , C08F110/06
CPC分类号： C08F8/00 , C08F210/02 , C08F210/18
摘要： Polymers of olefins such as ethylene and propylene, having functional groups introduced into both the ends thereof, can be provided which are useful as macromonomers for polycondensation. This new polymer comprises a recurring unit represented by the general formula --(--CH.sub.2.CHR--)-- and having functional groups bonded to both the ends of the polymer and a number average molecular weight of 300 to 500,000, the functional groups being selected from the group consisting of H.sub.2 C.dbd.CH-- group and ##STR1## wherein X is --OH, --OR.sup.1, a halogen atom or --SO.sub.3 R.sup.2, R.sup.1 is a hydrocarbon group of 1 to 5 carbon atoms and R.sup.2 is a halogen-substituted or non-substituted hydrocarbon group of 1 to 20 carbon atoms.
摘要翻译：可以提供可引入两端具有官能团的烯烃如乙烯和丙烯的聚合物，其可用作缩聚的大分子单体。该新型聚合物包含由通式 - （ - CH 2 CHR - ）表示的重复单元，并且具有与聚合物两端键合的官能团和数均分子量为300至500,000，该官能团选自由H2C = CH-基和组成的组，其中X是-OH，-OR1，卤原子或-SO3R2，R1是1至5个碳原子的烃基，R2是卤素取代或非取代的，取代的1-20个碳原子的烃基。

4. 发明授权

US5177043A .alpha.-olefin polymerization catalyst component 失效
标题翻译：（ALPHA） - 烯烃聚合催化剂组分
公开(公告)号：US5177043A
公开(公告)日：1993-01-05
申请号：US663850
申请日：1991-03-22
申请人： Naomi Koyama , Hiroyuki Furuhashi , Miyuki Usui , Tomoko Okano , Masahide Murata , Satoshi Ueki , Akira Nakano
发明人： Naomi Koyama , Hiroyuki Furuhashi , Miyuki Usui , Tomoko Okano , Masahide Murata , Satoshi Ueki , Akira Nakano
IPC分类号： C08F4/656 , C08F4/658 , C08F10/00
CPC分类号： C08F10/00 , Y10S526/904
摘要： This invention relates to a catalytic component for the polymerization of .alpha.-olefins and provides a catalytic component of magnesium support type capable of exhibiting a high stereoregularity while maintaining an improved strength as well as a high catalytic activity. The features thereof consist in a catalyst component for the polymerization of .alpha.-olefins obtained by contacting (A) a solid component comprising, as essential components, magnesium, titanium, a halogen and an electron-donating compound with (D) an olefin in the presence of (B) a trialkylaluminum and (C) a dimethoxy group-containing compound represented by the general formula R.sup.1 R.sup.2 Si(OCH.sub.3).sub.2 where R.sup.1 and R.sup.2 are, same or different, aliphatic hydrocarbon groups with 1 to 10 carbon atoms and having a volume, calculated by the quantum chemistry calculation, of 230 to 500 .ANG..sup.3 and an electron density of oxygen atoms in the methoxy group, calculated similarly, ranging from 0.685 to 0.800 A. U. (atomic unit) and a catalyst component for the polymerization of .alpha.-olefins obtained by contacting (A) a solid component comprising, as essential components, a metal oxide, magnesium, titanium, a halogen and an electron-donating compound with (D) an olefin in the presence of (B) a trialkylaluminum and (C) a dimethoxy group-containing compound represented by the general formula R.sup.1 R.sup.2 Si(OCH.sub.3).sub.2 where R.sup.1 and R.sup.2 are, same or different, aliphatic hydrocarbon groups with 1 to 10 carbon atoms and having a volume calculated by the quantum chemistry calculation, of 170 to 500 .ANG..sup.3 and an electron density of oxygen atoms in the methoxy group, calculated similarly, ranging from 0.690 to 0.800 A. U. (atomic unit) or the volume in the range of 200 to 500 .ANG..sup.3 and the electron density in the range of 0.685 to 0.800 A. U.

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