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1. 发明授权

US06566572B2 Process for producing 9,10-diphenylanthracene 失效
公开(公告)号：US06566572B2
公开(公告)日：2003-05-20
申请号：US09788550
申请日：2001-02-21
申请人： Kuniaki Okamoto , Tomimasa Kurita , Atsunori Sano
发明人： Kuniaki Okamoto , Tomimasa Kurita , Atsunori Sano
IPC分类号： C07C128
CPC分类号： C07C1/327 , C07C1/321 , C07C1/325 , C07C1/326 , C07C1/328 , C07C2603/24 , C07C15/28
摘要： 9,10-Diphenylanthracene, which can be produced applicably for industrial use in one or two process steps by subjecting a 9,10-dihalogenoanthracene and a metal or half-metal phenyl compound to a cross-coupling reaction.

2. 发明授权

US5516919A Process for producing ascorbic acid derivative 失效
标题翻译：生产抗坏血酸衍生物的方法
公开(公告)号：US5516919A
公开(公告)日：1996-05-14
申请号：US423988
申请日：1995-04-18
申请人： Atsunori Sano , Kuniaki Okamoto , Jun Ebashi
发明人： Atsunori Sano , Kuniaki Okamoto , Jun Ebashi
IPC分类号： C07F9/655 , C07D307/62
CPC分类号： C07F9/65515
摘要： Metal salts or substitutted or non-substituted ammonium salts of ascorbic acid derivatives can be produced in high yield by treating an acidic aqueous solution containing ascorbic acid-2-phosphate or ascorbic acid-2-sulfate with a porous adsorbent such as activated carbon, followed by treating the adsorbent with a basic aqueous solution containing e.g. a metal salt of an organic acid or substituted or non-substituted ammonium salt ion to elute the desired salt of ascorbic acid derivative.
摘要翻译：通过用多孔吸附剂如活性炭处理含有抗坏血酸-2-磷酸或抗坏血酸-2-硫酸的酸性水溶液，可以高收率地生产抗坏血酸衍生物的金属盐或取代或未取代的铵盐，随后通过用含有例如的碱性水溶液处理吸附剂有机酸的金属盐或取代或未取代的铵盐离子洗脱所需的抗坏血酸衍生物盐。

3. 发明授权

US06716792B2 Compound, oxide or lewis acid of metal carried on crosslinked polymer 失效
标题翻译：载有交联聚合物的金属的化合物，氧化物或路易斯酸
公开(公告)号：US06716792B2
公开(公告)日：2004-04-06
申请号：US09881214
申请日：2001-06-15
申请人： Kuniaki Okamoto , Mutsumi Sato , Atsunori Sano
发明人： Kuniaki Okamoto , Mutsumi Sato , Atsunori Sano
IPC分类号： B01J2026
CPC分类号： C08F8/42 , B01J23/466 , B01J31/06 , B01J31/1625 , C08K2201/013
摘要： The present invention relates to {circle around (1)} a metal oxide or metallic Lewis acid composition comprising the metal oxide or the metallic Lewis acid carried on a cross-linked polymer compound, {circle around (2)} a metal compound composition comprising the metal compound carried on a cross-linked product of a polymer compound containing a cross-linkable condensing functional group and/or a polymer containing a polymerizable double bond formed by a condensation reaction, {circle around (3)} a method for producing a metal compound composition comprising the metal compound carried on a cross-linked polymer compound, which comprises mixing a non-cross-linked polymer compound containing a cross-linkable condensing functional group and/or a polymer compound containing a polymerizable double bond formed by a condensation reaction with a metal compound, and then cross-linking the polymer compound, {circle around (4)} a carrier for carrying a metal compound comprising a 1st polymer compound containing a cross-linkable condensing functional group and/or a 2nd polymer compound containing a polymerizable double bond formed by a condensation reaction as a non-cross-linked polymer compound and {circle around (5)} a method for improving solvent resistance, heat resistance and durability of a metal compound comprising mixing a non-cross-linked polymer compound containing a cross-linkable condensing functional group and/or a polymer compound containing a polymerizable double bond formed by a condensation reaction with a metal compound, and then cross-linking said polymer compounds.
摘要翻译：本发明涉及{围绕（1个金属氧化物或金属路易斯酸组合物，其包含金属氧化物或交联聚合物化合物上携带的金属路易斯酸，{圆周（2为包含载有金属化合物的金属化合物组合物在含有可交联缩合官能团的高分子化合物和/或含有通过缩合反应形成的可聚合双键的聚合物的交联产物上，{圆周（3）制备包含该金属的金属化合物组合物的方法在交联聚合物化合物上携带的化合物，其包括将含有可交联缩合官能团的非交联聚合物化合物和/或含有通过缩合反应形成的可聚合双键的高分子化合物与金属化合物混合，然后交联高分子化合物{圆周（4是用于承载包含第1聚合物化合物的金属化合物的载体）制备可交联的缩合官能团和/或含有通过缩合反应形成的可聚合双键的第二聚合物化合物作为非交联聚合物化合物和{圆周（5）一种提高耐溶剂性，耐热性和金属化合物的耐久性包括将含有可交联缩合官能团的非交联聚合物化合物和/或含有通过缩合反应形成的可聚合双键的高分子化合物与金属化合物混合，然后将所述聚合物化合物。

4. 发明授权

US6013826A Method formation of a carbon-carbon bond 失效
标题翻译：方法形成碳 - 碳键
公开(公告)号：US6013826A
公开(公告)日：2000-01-11
申请号：US63825
申请日：1998-04-22
申请人： Yasuyuki Kita , Atsunori Sano , Takahiro Yamaguchi , Masahisa Oka , Masato Matsugi , Kentoku Gotanda
发明人： Yasuyuki Kita , Atsunori Sano , Takahiro Yamaguchi , Masahisa Oka , Masato Matsugi , Kentoku Gotanda
IPC分类号： B01J31/02 , C07B37/02 , C07B39/00 , C07C253/30 , C07C255/00
CPC分类号： C07B39/00 , B01J31/0235 , C07B37/02 , C07C253/30 , B01J2231/323
摘要： A method for an addition reaction with the formation of an additional carbon--carbon bond comprising reacting an .alpha.-halogeno carboxylic acid derivative with an alkene in the presence of a catalyst shown by the general formula (1): ##STR1## wherein R.sub.1 is a lower alkyl group.
摘要翻译：一种形成另外的碳 - 碳键的加成反应的方法，包括在由通式（1）表示的催化剂存在下使α-卤代羧酸衍生物与烯烃反应：其中R1是低级烷基。

5. 发明授权

US5300634A Process for producing maltooligosaccharide derivative 失效
标题翻译：生产麦芽低聚糖衍生物的方法
公开(公告)号：US5300634A
公开(公告)日：1994-04-05
申请号：US878266
申请日：1992-05-04
申请人： Atsunori Sano , Naoki Teno
发明人： Atsunori Sano , Naoki Teno
IPC分类号： C07H3/06 , C12Q1/40 , C07H15/00
CPC分类号： C12Q1/40 , C07H3/06 , C12Q2334/10
摘要： A maltooligosaccharide derivative very useful, for example, as a precursor of a modified oligosaccharide derivative having one or more modifying groups at the 6-position or the 4- and 6-positions of the non-reducing end glucose residue which can be effectively used as a substrate for determining .alpha.-amylase activity or an intermediate thereof, can be produced by reacting a compound of the formula: ##STR1## with a compound of the formula: ##STR2## to convert at least the hydroxyl groups at the 4- and 6-positions of non-reducing end glucose residue of the compound of the formula (1) into a cyclic boric acid ester, acylating the reaction product, and then treating the acylated product.
摘要翻译：非常有用的麦芽低聚糖衍生物，例如作为在非还原性末端葡萄糖残基的6位或4位和6位上具有一个或多个修饰基团的修饰的寡糖衍生物的前体，其可以有效地用作用于确定（α） - 淀粉酶活性的底物或其中间体可以通过使下式化合物：（* CHEMICAL STRUCTURE *）（1）与下式化合物反应来制备：（* CHEMICAL STRUCTURE *）（2 ）将至少将式（1）化合物的非还原性末端葡萄糖残基的4-位和6-位的羟基转化成环状硼酸酯，酰化反应产物，然后处理酰化产物。

6. 发明授权

US5081243A Process for producing 3-tetrazolyl pyrido[1,2-a]pyrimidine derivatives 失效
标题翻译：生产3-四唑啉基吡啶（1,2-A）吡嗪衍生物的方法
公开(公告)号：US5081243A
公开(公告)日：1992-01-14
申请号：US483191
申请日：1990-02-22
申请人： Atsunori Sano , Masami Ishihara , Jun Yoshihara , Hiroyoshi Nawa
发明人： Atsunori Sano , Masami Ishihara , Jun Yoshihara , Hiroyoshi Nawa
IPC分类号： C07D401/12 , C07D471/04
CPC分类号： C07D401/12 , C07D471/04
摘要： 3-Tetrazolylpyrido[1,2-a]pyrimidin-4-one derivatives useful as an antiallergy agent are produced by reacting a cyano derivative of pyrido[1,2-a]pyrimidin-4-one compound with (i) hydrazoic acid, followed by hydrolysis, or with (ii) a salt of hydrazoic acid, reacting the resulting product with an acid or a base, followed by hydrolysis.

7. 发明授权

US07741242B2 Palladium catalyst composition 失效
标题翻译：钯催化剂组合物
公开(公告)号：US07741242B2
公开(公告)日：2010-06-22
申请号：US10527699
申请日：2003-09-01
申请人： Shu Kobayashi , Atsunori Sano , Keiji Oono
发明人： Shu Kobayashi , Atsunori Sano , Keiji Oono
IPC分类号： B01J23/44 , B01J37/00
CPC分类号： B01J31/06 , B01J2231/44 , B01J2231/645 , B01J2231/70 , C07B2200/11 , C07C17/16 , C07C41/16 , C07C45/29 , C07C45/62 , C07C67/343 , C07D303/16 , C07F15/006 , C07F15/0066 , C07C22/04 , C07C47/232 , C07C49/213 , C07C69/618 , C07C43/215
摘要： The present invention discloses 1) a catalyst composition consisting of a crosslinked organic polymer compound and a palladium catalyst, wherein said catalyst is physically carried on said crosslinked organic polymer compound, 2) a manufacturing method of the above catalyst composition 1), characterized by homogenizing a straight chain organic polymer compound, having a crosslinkable functional group, and a palladium catalyst in a solvent dissolving said straight chain organic polymer compound, then depositing a composition thus formed and subjecting the crosslinkable functional group in said deposit to a crosslinking reaction, 3) a method for substitution reaction at an allyl position, characterized by reacting an allyl carbonate and a neucleophilic agent in the presence of the above catalyst composition 1), and 4) a method for oxidizing an alcohol, characterized by subjecting the above catalyst composition 1) to reaction with an alcohol.
摘要翻译：本发明公开了1）由交联的有机高分子化合物和钯催化剂组成的催化剂组合物，其中所述催化剂物理地携带在所述交联的有机高分子化合物上，2）上述催化剂组合物1）的制备方法，其特征在于均化具有可交联官能团的直链有机高分子化合物和溶解所述直链有机高分子化合物的溶剂中的钯催化剂，然后沉积由此形成的组合物，并对所述沉积物中的可交联官能团进行交联反应; 3）在烯丙基位置进行取代反应的方法，其特征在于在上述催化剂组合物1）的存在下使碳酸烯丙酯和亲核试剂反应，和4）一种氧化醇的方法，其特征在于将上述催化剂组合物1）与酒精反应。

8. 发明授权

US06414159B2 Method for preparation of a quaternary ammonium salt 有权
标题翻译：季铵盐的制备方法
公开(公告)号：US06414159B2
公开(公告)日：2002-07-02
申请号：US09779743
申请日：2001-02-09
申请人： Kimihiko Sano , Yoji Urano , Takuhiro Kimura , Atsunori Sano
发明人： Kimihiko Sano , Yoji Urano , Takuhiro Kimura , Atsunori Sano
IPC分类号： C07D21320
CPC分类号： C07D213/20 , C07D231/12 , C07D233/56 , C07D249/08
摘要： The present invention provides a method for preparation of a quaternary ammonium salt comprising reacting an alkyl halide with 2 equimolar amount or more per the alkyl halide of a pyridine compound or an N-lower alkyl imidazole at 120° C. to 350° C., and a method for the continuous production of a quatemary ammonium salt comprises introducing continuously an alkyl halide and 2 equimolar amount or more per the alkyl halide of a pyridine compound or an N-lower alkyl imidazole into a pipe reactor from the one end thereof under heating at 120 to 350° C. to pass through the pipe reactor wherein a reaction is allowed to take place, and taking out continuously the resulting quaternary ammonium salt from the other end of the reactor.
摘要翻译：本发明提供了一种制备季铵盐的方法，包括使卤代烷与卤代吡啶化合物或N-低级烷基咪唑的烷基卤化物在120℃至350℃下反应2摩尔以上，和连续生产季铵盐的方法包括在加热下从其一端连续引入吡啶化合物或N-低级烷基咪唑的烷基卤化物的烷基卤和2当量等于或更多的烷基卤化物进入管式反应器在120至350℃下通过允许发生反应的管式反应器，并从反应器的另一端连续取出所得的季铵盐。

9. 发明授权

US5393876A Process for producing maltooligosaccharide derivatives 失效
标题翻译：麦芽低聚糖衍生物的制备方法
公开(公告)号：US5393876A
公开(公告)日：1995-02-28
申请号：US44627
申请日：1993-04-09
申请人： Atsunori Sano , Satoshi Hashizume , Hiroyuki Tsurumoto
发明人： Atsunori Sano , Satoshi Hashizume , Hiroyuki Tsurumoto
IPC分类号： C07H13/02 , C07H13/04 , C07H15/203 , C08B37/00 , C07H15/00 , C07H15/04
CPC分类号： C07H13/04 , C07H15/203
摘要： A polyacyl maltooligosaccharide derivative which is a precursor of a maltooligosaccharide derivative having modified groups at the 6-position or 4- and 6-positions of non-reducing end glucose unit and being effectively used as a substrate for measuring .alpha.-amylase activity, can be produced under mild conditions by crosslinking OH groups in the non-reducing end glucose unit of oligosaccharide with a benzylidene group having an alkoxy group, followed by acylation and treatment with a dilute acid.
摘要翻译：作为在非还原性末端葡萄糖单元的6位或4位和6位具有改性基团并且有效地用作测定α-淀粉酶活性的底物的具有修饰基团的麦芽低聚糖衍生物的前体的多酰基麦芽低聚糖衍生物可以是通过将低聚糖的非还原性末端葡萄糖单元中的OH基与具有烷氧基的亚苄基交联，然后进行酰化和用稀酸处理，在温和条件下生产。

10. 发明授权

US5254688A Process for producing pyrido[1,2-a]pyrimidine derivative 失效
标题翻译：制备吡啶并[1,2-a]嘧啶衍生物的方法
公开(公告)号：US5254688A
公开(公告)日：1993-10-19
申请号：US717591
申请日：1991-06-19
申请人： Atsunori Sano , Motoshige Sumino , Masami Ishihara , Kazuo Maruhashi
发明人： Atsunori Sano , Motoshige Sumino , Masami Ishihara , Kazuo Maruhashi
IPC分类号： C07D471/04 , C07D239/10
CPC分类号： C07D471/04
摘要： A pyrido[1,2-a]pyrimidine derivative which is useful as an antiallergic agent can be produced from a 2-aminopyridine derivative or a hydrazoic acid salt thereof by a one-pot and substantially one-step process.

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