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    • 1. 发明授权
    • Via structure and method of manufacture
    • 通过结构和制造方法
    • US6080660A
    • 2000-06-27
    • US32682
    • 1998-02-27
    • Kun-Chih WangHsiao-Pang ChouWen-Yi HsiehTri-Rung Yew
    • Kun-Chih WangHsiao-Pang ChouWen-Yi HsiehTri-Rung Yew
    • H01L21/311H01L21/768H01L21/4763
    • H01L21/31116H01L21/76802H01L21/76805
    • A method for manufacturing a via structure comprising the steps of providing a semiconductor substrate, and then forming conductive line and dielectric layer over the substrate. Next, a photolithographic and a first etching operation are conducted so that an opening in the dielectric layer exposing the conductive line surface is formed. The first etching operation uses several etchants including fluorobutane, which has the highest concentration. Since there is a re-entrance structure at the bottom of the opening, a second etching operation is performed. In the second etching operation, a portion of the conductive line is etched for a fixed time interval to control the degree of etching. Consequently, a slanting surface is formed at the bottom of the opening and the re-entrance structure is eliminated. With a planarized bottom, step coverage of subsequently deposited material is increased.
    • 一种用于制造通孔结构的方法,包括以下步骤:提供半导体衬底,然后在衬底上形成导电线和电介质层。 接下来,进行光刻和第一蚀刻操作,从而形成暴露导电线表面的电介质层中的开口。 第一蚀刻操作使用多种蚀刻剂,包括具有最高浓度的氟代丁烷。 由于在开口的底部存在再入口结构,因此进行第二蚀刻操作。 在第二蚀刻操作中,导电线的一部分被蚀刻固定的时间间隔以控制蚀刻程度。 因此,在开口的底部形成倾斜表面,并且消除了再入口结构。 在平坦化的底部,随后沉积材料的阶梯覆盖率增加。
    • 3. 发明授权
    • Method of fabricating DRAM capacitor
    • 制造DRAM电容的方法
    • US06479344B2
    • 2002-11-12
    • US09542715
    • 2000-04-04
    • Kuo-Tai HuangWen-Yi HsiehTri-Rung Yew
    • Kuo-Tai HuangWen-Yi HsiehTri-Rung Yew
    • H01L218242
    • H01L28/75H01L21/28568H01L21/3211H01L27/10852H01L28/55
    • A method of fabricating a DRAM capacitor uses tungsten nitride in the process of forming a capacitor. The structure of the capacitor is simple and the process is easily executed. Furthermore, the invention provides a method of forming tungsten nitride, comprising a step of implanting nitrogen into a tungsten silicide layer and a step of executing a rapid thermal process under ammonia gas to form a tungsten nitride layer on the surface of the tungsten silicide layer. The method of fabricating a DRAM capacitor comprises forming the tungsten silicide layer after forming a part smaller than a bottom electrode of the capacitor from doped polysilicon and forming tungsten nitride on the surface of the tungsten nitride layer.
    • 制造DRAM电容器的方法在形成电容器的过程中使用氮化钨。 电容器的结构简单,易于执行。 此外,本发明提供了一种形成氮化钨的方法,包括将氮气注入到硅化钨层中的步骤以及在氨气下执行快速热处理以在硅化钨层的表面上形成氮化钨层的步骤。 制造DRAM电容器的方法包括在从掺杂多晶硅形成小于电容器的底部电极的部分之后形成硅化钨层,并在氮化钨层的表面上形成氮化钨。
    • 4. 发明授权
    • Method for forming a DRAM cell electrode
    • 用于形成DRAM单元电极的方法
    • US5994181A
    • 1999-11-30
    • US858398
    • 1997-05-19
    • Wen-Yi HsiehTri-Rung Yew
    • Wen-Yi HsiehTri-Rung Yew
    • H01L21/02H01L21/8242
    • H01L27/10852H01L28/60H01L28/82
    • A polysilicon layer is subsequently deposited on the dielectric layer by using CVD. Next, photolithography and etching process are used to etch the doped polysilicon layer, and form a bottom electrode of DRAM cell capacitor with U shape in cross section view. The next step of the formation is the deposition of a dielectric film along the surface of the bottom electrode of DRAM cell capacitor. Typically, the dielectric film is preferably formed of high dielectric film such as tantalum oxide (Ta.sub.2 0.sub.5). A conductive layer is deposited over the dielectric film. The conductive layer is used as the top storage node and is formed of titanium nitride(TiN). The methods of forming the top storage node, including sputtered-TiN, collimated-sputtering TiN, and CVD/MOCVD-TiN deposition. The purposes of sputtered-TiN and collimated-sputtering TiN processes can improve the poor step coverage of deep well of bottom electrode of DRAM cell capacitor and protect the Ta.sub.2 0.sub.5 from C, Cl, F contamination during CVD/MOCVD-TiN deposition process.
    • 随后通过使用CVD将多晶硅层沉积在电介质层上。 接下来,使用光刻和蚀刻工艺来蚀刻掺杂多晶硅层,并且在横截面图中形成具有U形的DRAM单元电容器的底部电极。 形成的下一步是沿着DRAM单元电容器的底部电极的表面沉积电介质膜。 通常,电介质膜优选由诸如氧化钽(Ta 2 O 5)的高介电膜形成。 导电层沉积在电介质膜上。 导电层用作顶部存储节点并且由氮化钛(TiN)形成。 形成顶部存储节点的方法包括溅射TiN,准直溅射TiN和CVD / MOCVD-TiN沉积。 溅射TiN和准直溅射TiN工艺的目的可以改善DRAM单元电容器底部电极深阱的差的覆盖范围,并在CVD / MOCVD-TiN沉积过程中保护Ta205不受C,Cl,F污染。
    • 6. 发明授权
    • Method of fabricating DRAM capacitor
    • 制造DRAM电容的方法
    • US06218238B1
    • 2001-04-17
    • US09172458
    • 1998-10-14
    • Kuo-Tai HuangWen-Yi HsiehTri-Rung Yew
    • Kuo-Tai HuangWen-Yi HsiehTri-Rung Yew
    • H01L218242
    • H01L28/75H01L21/28568H01L21/3211H01L27/10852H01L28/55
    • A method of fabricating a DRAM capacitor uses tungsten nitride in the process of forming a capacitor. The structure of the capacitor is simple and the process is easily executed. Furthermore, the invention provides a method of forming tungsten nitride, comprising a step of implanting nitrogen into a tungsten silicide layer and a step of executing a rapid thermal process under ammonia gas to form a tungsten nitride layer on the surface of the tungsten silicide layer. The method of fabricating a DRAM capacitor comprises forming the tungsten silicide layer after forming a part smaller than a bottom electrode of the capacitor from doped polysilicon and forming tungsten nitride on the surface of the tungsten nitride layer.
    • 制造DRAM电容器的方法在形成电容器的过程中使用氮化钨。 电容器的结构简单,易于执行。 此外,本发明提供了一种形成氮化钨的方法,包括将氮气注入到硅化钨层中的步骤以及在氨气下执行快速热处理以在硅化钨层的表面上形成氮化钨层的步骤。 制造DRAM电容器的方法包括在从掺杂多晶硅形成小于电容器的底部电极的部分之后形成硅化钨层,并在氮化钨层的表面上形成氮化钨。
    • 10. 发明授权
    • Method for forming charge storage structure
    • 电荷储存结构形成方法
    • US5994183A
    • 1999-11-30
    • US996696
    • 1997-12-23
    • Kuo-Tai HuangWen-Yi HsiehTri-Rung Yew
    • Kuo-Tai HuangWen-Yi HsiehTri-Rung Yew
    • H01L21/02H01L21/285H01L21/768H01L21/8242H01L27/108
    • H01L28/60H01L21/28518H01L27/10852
    • A method for forming a high capacitance charge storage structure that can be applied to a substrate wafer having MOS transistor already formed thereon. The method is to form an insulating layer above the substrate wafer. Next, a contact window exposing a source/drain region is formed in the insulating layer. Then, a tungsten suicide layer, which functions as a lower electrode for the charge storage structure, is formed over the substrate. Thereafter, a tungsten nitride layer is formed over the tungsten silicide layer, and then a dielectric layer is formed over the tungsten nitride layer. The dielectric layer is preferably a tantalum oxide layer. Finally, a titanium nitride layer, which functions as an upper electrode for the charge storage structure, is formed over the tantalum oxide layer.
    • 一种用于形成可以应用于已经形成有MOS晶体管的衬底晶片的高电容电荷存储结构的方法。 该方法是在衬底晶片之上形成绝缘层。 接下来,在绝缘层中形成暴露源极/漏极区域的接触窗口。 然后,在基板上形成用作电荷存储结构的下电极的硅化钨层。 此后,在硅化钨层之上形成氮化钨层,然后在氮化钨层上形成电介质层。 电介质层优选为氧化钽层。 最后,在钽氧化物层上形成用作电荷存储结构的上电极的氮化钛层。