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1. 发明授权

US08404788B2 Atom transfer radical polymerization process 有权
标题翻译：原子转移自由基聚合过程
公开(公告)号：US08404788B2
公开(公告)日：2013-03-26
申请号：US13026919
申请日：2011-02-14
申请人： Krzysztof Matyjaszewski , Lindsay Bombalski , Wojciech Jakubowski , Ke Min , Nicolay V. Tsarevsky , James Spanswick
发明人： Krzysztof Matyjaszewski , Lindsay Bombalski , Wojciech Jakubowski , Ke Min , Nicolay V. Tsarevsky , James Spanswick
IPC分类号： C08F4/40
CPC分类号： C08F265/04 , C08F4/40 , C08F220/18 , C08F265/00 , C08F291/00 , C08F293/00 , C08F293/005 , C08F2438/01
摘要： Embodiments of the polymerization process of the present invention are directed to polymerizing free radically polymerizable monomers in the presence of a polymerization medium initially comprising at least one transition metal catalyst and an atom transfer radical polymerization initiator. The polymerization medium may additionally comprise a reducing agent. The reducing agent may be added initially or during the polymerization process in a continuous or intermittent manner. The polymerization process may further comprises reacting the reducing agent with at least one of the transition metal catalyst in an oxidized state and a compound comprising a radically transferable atom or group to form a compound that does not participate significantly in control of the polymerization process. Embodiments of the present invention comprise reacting a reducing agent with at least one of catalyst in an oxidized state and a compound comprising a radically transferable atom or group to initiate and/or maintain catalytic activity throughout the polymerization process.
摘要翻译：本发明的聚合方法的实施方案涉及在最初包含至少一种过渡金属催化剂和原子转移自由基聚合引发剂的聚合介质的存在下使可自由基聚合的单体聚合。聚合介质可另外包含还原剂。还原剂可以以连续或间歇的方式最初或在聚合过程中加入。聚合方法可以进一步包括使还原剂与氧化态的至少一种过渡金属催化剂和包含可自由基转移的原子或基团的化合物反应，以形成不显着控制聚合过程的化合物。本发明的实施方案包括使还原剂与氧化状态的催化剂和包含可自由基转移的原子或基团的化合物中的至少一种反应，以在整个聚合过程中引发和/或维持催化活性。

2. 发明授权

US07893174B2 Atom transfer radical polymerization process 有权
标题翻译：原子转移自由基聚合过程
公开(公告)号：US07893174B2
公开(公告)日：2011-02-22
申请号：US10591426
申请日：2005-03-07
申请人： Krzysztof Matyjaszewski , Lindsay Bombalski , Wojciech Jakubowski , Ke Min , James Spanswick , Nicolay V. Tsarevsky
发明人： Krzysztof Matyjaszewski , Lindsay Bombalski , Wojciech Jakubowski , Ke Min , James Spanswick , Nicolay V. Tsarevsky
IPC分类号： C08F4/40
CPC分类号： C08F265/04 , C08F4/40 , C08F220/18 , C08F265/00 , C08F291/00 , C08F293/00 , C08F293/005 , C08F2438/01
摘要： Embodiments of the polymerization process of the present invention are directed to polymerizing free radically polymerizable monomers in the presence of a polymerization medium initially comprising at least one transition metal catalyst and an atom transfer radical polymerization initiator. The polymerization medium may additionally comprise a reducing agent. The reducing agent may be added initially or during the polymerization process in a continuous or intermittent manner. The polymerization process may further comprise reacting the reducing agent with at least one of the transition metal catalyst in an oxidized state and a compound comprising a radically transferable atom or group to form a compound that does not participate significantly in control of the polymerization process. Embodiments of the present invention comprise reacting a reducing agent with at least one of catalyst in an oxidized state and a compound comprising a radically transferable atom or group to initiate and/or maintain catalytic activity throughout the polymerization process.
摘要翻译：本发明的聚合方法的实施方案涉及在最初包含至少一种过渡金属催化剂和原子转移自由基聚合引发剂的聚合介质的存在下使可自由基聚合的单体聚合。聚合介质可另外包含还原剂。还原剂可以以连续或间歇的方式最初或在聚合过程中加入。聚合方法还可包括使还原剂与氧化态的至少一种过渡金属催化剂和包含可自由基转移的原子或基团的化合物反应，以形成不显着控制聚合方法的化合物。本发明的实施方案包括使还原剂与氧化状态的催化剂和包含可自由基转移的原子或基团的化合物中的至少一种反应，以在整个聚合过程中引发和/或维持催化活性。

3. 发明申请

US20110218306A1 ATOM TRANSFER RADICAL POLYMERIZATION PROCESS 有权
标题翻译：原子转移自由基聚合方法
公开(公告)号：US20110218306A1
公开(公告)日：2011-09-08
申请号：US13026919
申请日：2011-02-14
申请人： Krzysztof Matyjaszewski , Lindsay Bombalski , Wojciech Jakubowski , Ke Min , James Spanswick , Nicolay V. Tsarevsky
发明人： Krzysztof Matyjaszewski , Lindsay Bombalski , Wojciech Jakubowski , Ke Min , James Spanswick , Nicolay V. Tsarevsky
IPC分类号： C08F120/06 , C08F112/08 , C08F118/02 , C08G63/08
CPC分类号： C08F265/04 , C08F4/40 , C08F220/18 , C08F265/00 , C08F291/00 , C08F293/00 , C08F293/005 , C08F2438/01
摘要： Embodiments of the polymerization process of the present invention are directed to polymerizing free radically polymerizable monomers in the presence of a polymerization medium initially comprising at least one transition metal catalyst and an atom transfer radical polymerization initiator. The polymerization medium may additionally comprise a reducing agent. The reducing agent may be added initially or during the polymerization process in a continuous or intermittent manner. The polymerization process may further comprises reacting the reducing agent with at least one of the transition metal catalyst in an oxidized state and a compound comprising a radically transferable atom or group to form a compound that does not participate significantly in control of the polymerization process. Embodiments of the present invention comprise reacting a reducing agent with at least one of catalyst in an oxidized state and a compound comprising a radically transferable atom or group to initiate and/or maintain catalytic activity throughout the polymerization process.
摘要翻译：本发明的聚合方法的实施方案涉及在最初包含至少一种过渡金属催化剂和原子转移自由基聚合引发剂的聚合介质的存在下使可自由基聚合的单体聚合。聚合介质可另外包含还原剂。还原剂可以以连续或间歇的方式最初或在聚合过程中加入。聚合方法可以进一步包括使还原剂与氧化态的至少一种过渡金属催化剂和包含可自由基转移的原子或基团的化合物反应，以形成不显着控制聚合过程的化合物。本发明的实施方案包括使还原剂与氧化状态的催化剂和包含可自由基转移的原子或基团的化合物中的至少一种反应，以在整个聚合过程中引发和/或维持催化活性。

4. 发明申请

US20070276101A1 Atom Transfer Radical Polymerization Process 有权
标题翻译：原子转移自由基聚合方法
公开(公告)号：US20070276101A1
公开(公告)日：2007-11-29
申请号：US10591426
申请日：2005-03-07
申请人： Krzysztof Matyjaszewski , Lindsay Bombalski , Wojciech Jakubowski , Ke Min , James Spanswick , Nicolay Tsarevsky
发明人： Krzysztof Matyjaszewski , Lindsay Bombalski , Wojciech Jakubowski , Ke Min , James Spanswick , Nicolay Tsarevsky
IPC分类号： C08F251/00 , C08F4/06 , C08F8/00
CPC分类号： C08F265/04 , C08F4/40 , C08F220/18 , C08F265/00 , C08F291/00 , C08F293/00 , C08F293/005 , C08F2438/01
摘要： Embodiments of the polymerization process of the present invention are directed to polymerizing free radically polymerizable monomers in the presence of a polymerization medium initially comprising at least one transition metal catalyst and an atom transfer radical polymerization initiator. The polymerization medium may additionally comprise a reducing agent. The reducing agent may be added initially or during the polymerization process in a continuous or intermittent manner. The polymerization process may further comprise reacting the reducing agent with at least one of the transition metal catalyst in an oxidized state and a compound comprising a radically transferable atom or group to form a compound that does not participate significantly in control of the polymerization process. Embodiments of the present invention comprise reacting a reducing agent with at least one of catalyst in an oxidized state and a compound comprising a radically transferable atom or group to initiate and/or maintain catalytic activity throughout the polymerization process.
摘要翻译：本发明的聚合方法的实施方案涉及在最初包含至少一种过渡金属催化剂和原子转移自由基聚合引发剂的聚合介质的存在下使可自由基聚合的单体聚合。聚合介质可另外包含还原剂。还原剂可以以连续或间歇的方式最初或在聚合过程中加入。聚合方法还可包括使还原剂与氧化态的至少一种过渡金属催化剂和包含可自由基转移的原子或基团的化合物反应，以形成不显着控制聚合方法的化合物。本发明的实施方案包括使还原剂与氧化状态的催化剂和包含可自由基转移的原子或基团的化合物中的至少一种反应，以在整个聚合过程中引发和/或维持催化活性。

5. 发明授权

US08367051B2 Preparation of functional gel particles with a dual crosslink network 有权
标题翻译：用双交联网络制备功能性凝胶颗粒
公开(公告)号：US08367051B2
公开(公告)日：2013-02-05
申请号：US12311673
申请日：2007-10-09
申请人： Krzysztof Matyjaszewski , Ke Min , Jung Kwon Oh , James Spanswick , Nicolay V. Tsarevsky
发明人： Krzysztof Matyjaszewski , Ke Min , Jung Kwon Oh , James Spanswick , Nicolay V. Tsarevsky
IPC分类号： A61K9/14 , A61K31/74
CPC分类号： C08F293/005 , C08F283/00 , C08F290/00 , C08F290/06 , C08F291/00
摘要： Functional gel particle formed from a crosslinked polymeric network including a fraction of stable crosslinks and a second fraction of cleavable crosslinks are disclosed. Functional compounds may be chemically or physically encapsulated within and/or released from the gel particle by selective cleavage of the cleavable crosslinks. The functional compounds may be delivered and released to a pre-selected target site. Peripheral or other accessible functionality on the surface of the gel particle allows attachment of a surface reactive agent, thereby modifying one or more surface properties of the gel particle. Processes of preparing the gel particles and processes of delivering the functional compounds to a target site are also disclosed.
摘要翻译：公开了由交联的聚合物网络形成的功能性凝胶颗粒，其包括稳定的交联部分和可切割交联的第二部分。官能化合物可以通过选择性裂解可切割交联而化学或物理地包封在凝胶颗粒内和/或从凝胶颗粒释放。功能性化合物可以被递送并释放到预先选择的靶位点。在凝胶颗粒表面上的周边或其他可接近的功能允许附着表面活性剂，从而改变凝胶颗粒的一个或多个表面性质。还公开了制备凝胶颗粒的方法和将功能性化合物递送至靶位点的方法。

6. 发明申请

US20110060107A1 PREPARATION OF FUNCTIONAL POLYMERS 审中-公开
标题翻译：功能聚合物的制备
公开(公告)号：US20110060107A1
公开(公告)日：2011-03-10
申请号：US12877589
申请日：2010-09-08
申请人： Krzysztof Matyjaszewski , Brent S. Sumerlin , Nicolay V. Tsarevsky , James Spanswick
发明人： Krzysztof Matyjaszewski , Brent S. Sumerlin , Nicolay V. Tsarevsky , James Spanswick
IPC分类号： C08F8/30
CPC分类号： C08F8/30 , C08F293/005 , C08F2438/01 , C08F2438/03
摘要： The process of the present invention is directed toward conducting highly selective, high yield post polymerization reactions on polymers to prepare functionalized polymers. An embodiment of the present invention comprises conducting click chemistry reactions on polymers. Preferably, the polymers were prepared by controlled polymerization processes. Therefore, embodiments of the present invention comprise processes for the preparation of polymers comprising conducting a click chemistry reaction on a functional group attached to a polymer, wherein the polymer has a molecular weight distribution of less than 2.0. The functional polymers may be prepared by converting an attached functional unit on the polymer thereby providing site specific functional materials, site specific functional materials comprising additional functionality, or chain extended functional materials.Embodiments of the process of the present invention include functionalization reactions, chain extensions reactions, to form block copolymer linking reactions, and attaching side chains to form graft copolymers, for example.
摘要翻译：本发明的方法涉及在聚合物上进行高选择性，高收率的后聚合反应以制备官能化聚合物。本发明的一个实施方案包括对聚合物进行点击化学反应。优选地，通过控制聚合方法制备聚合物。因此，本发明的实施方案包括制备聚合物的方法，包括在连接到聚合物上的官能团上进行点击化学反应，其中聚合物的分子量分布小于2.0。官能聚合物可以通过在聚合物上转化附着的官能单元来制备，从而提供位点特异性功能材料，包含附加官能团的位点特异性功能材料或链延伸的功能材料。本发明方法的实施方案包括例如官能化反应，延伸链反应，形成嵌段共聚物连接反应和连接侧链以形成接枝共聚物。

7. 发明授权

US07056455B2 Process for the preparation of nanostructured materials 有权
公开(公告)号：US07056455B2
公开(公告)日：2006-06-06
申请号：US10118519
申请日：2002-04-06
申请人： Krzysztof Matyjaszewski , Tomasz Kowalewski , David N. Lambeth , James Spanswick , Nicolay V. Tsarevsky
发明人： Krzysztof Matyjaszewski , Tomasz Kowalewski , David N. Lambeth , James Spanswick , Nicolay V. Tsarevsky
IPC分类号： D01F9/12
CPC分类号： H01G9/155 , B82Y10/00 , B82Y15/00 , B82Y30/00 , B82Y40/00 , C01B3/0021 , C01B32/05 , C01B32/162 , C04B35/524 , C04B35/63424 , C04B35/63444 , C04B38/0022 , C04B2111/00801 , C04B2111/0081 , C04B2111/00827 , C04B2111/00844 , C04B2111/00853 , C04B2235/5288 , D01F9/14 , G03F7/0002 , G11C2213/81 , H01G11/36 , H01M4/58 , H01M4/583 , H01M4/96 , Y02E60/13 , Y02E60/325 , Y02E60/327 , Y10S521/918 , Y10S521/919 , C04B38/0054
摘要： The present invention comprises a novel process for the preparation of carbon based structured materials with controlled topology, morphology and functionality. The nanostructured materials are prepared by controlled carbonization, or pyrolysis, of precursors comprising phase separated copolymers. The precursor materials are selected to phase separate and self organize in bulk, in solution, in the presence of phase selective solvents, at surfaces, interfaces or during fabrication, into articles, fibers or films exhibiting well-defined, self-organized morphology or precursors of well-defined, self-organized, bi- or tri-phasic morphology. Compositional control over the (co)polymers provides control over the structure of the phase separated precursor whose organization therein dictates the nanostructure of the material obtained after carbonization or pyrolysis, wherein each dimension of the formed structure can be predetermined. When the precursor morphology is selected to comprise cylindrical domains this procedure additionally allows for the direct formation of two dimensional nanowire grids or arrays of oriented nanostructures on surfaces. When these nanowire grids or arrays are perpendicularly oriented to the surface applications include field emitters, high surface area electrodes, electronic devices such as diodes and transistors, tools for AMF tips and elements of molecular electronics. When the first nanostructured morphology is selected to form cylinders parallel to the surface then nanowire arrays are formed after pyrolysis. When the composition of the first nanostructured morphology is selected to comprise a continuous precursor matrix then a continuous carbon based nanostructured material is formed. The internal structure of the carbon based material can be selected to comprise perpendicular pores or an interconnected array of pores. The carbon based structures can additionally find application in photovoltaics, supercapacitors, batteries, fuel cells, computer memory, carbon electrodes, carbon foams, actuators and hydrogen storage.

8. 发明申请

US20090312505A1 Polymerization Process with catalyst reactivation 有权
标题翻译：催化剂再活化聚合过程
公开(公告)号：US20090312505A1
公开(公告)日：2009-12-17
申请号：US11990841
申请日：2006-08-28
申请人： Krzysztof Matyjaszewski , Wojciech Jakubowski , James Spanswick
发明人： Krzysztof Matyjaszewski , Wojciech Jakubowski , James Spanswick
IPC分类号： C08F4/42
CPC分类号： C08F2/40 , C08F4/04 , C08F4/40 , C08F212/08 , C08F212/10 , Y02P20/584 , C08F220/12
摘要： Polymerization processes of the present invention comprise low catalyst concentration. Embodiments include a polymerization process comprising polymerizing free radically (co)polymerizable monomers in a polymerization medium comprising one or more radically (co)polymerizable monomers, a transition metal catalyst complex capable of participating in a one electron redox reaction with an ATRP initiator; a free radical initiator; and an ATRP initiator; (wherein the concentration of transition metal catalyst complex in the polymerization medium is less than 100 ppm). Further embodiments include a polymerization process, comprising polymerizing one or more radically (co)polymerizable monomers in the presence of at least one transition metal catalyst complex; and an ATRP initiator; and a reducing agent; wherein the transition metal catalyst complex is present at less than 10″3 mole compared to the moles of radically transferable atoms or groups present on the ATRP initiator.
摘要翻译：本发明的聚合方法包括低催化剂浓度。实施方案包括聚合方法，其包括在包含一种或多种自由基（共）可聚合单体的聚合介质中自由基（共）可聚合单体聚合，能够与ATRP引发剂参与一电子氧化还原反应的过渡金属催化剂络合物; 自由基引发剂; 和ATRP引发剂; （其中聚合介质中过渡金属催化剂配合物的浓度小于100ppm）。另外的实施方案包括聚合方法，包括在至少一种过渡金属催化剂络合物的存在下聚合一种或多种自由基（共）可聚合单体; 和ATRP引发剂; 和还原剂; 其中与ATRP引发剂上存在的可自由基转移的原子或基团的摩尔数相比，过渡金属催化剂络合物的存在量小于10'3摩尔。

9. 发明申请

US20110065875A1 POLYMERIZATION PROCESS WITH CATALYST REACTIVATION 审中-公开
标题翻译：具有催化反应的聚合方法
公开(公告)号：US20110065875A1
公开(公告)日：2011-03-17
申请号：US12949466
申请日：2010-11-18
申请人： Krzysztof Matyjaszewski , Wojciech Jakubowski , James Spanswick
发明人： Krzysztof Matyjaszewski , Wojciech Jakubowski , James Spanswick
IPC分类号： C08F4/42
CPC分类号： C08F2/40 , C08F4/04 , C08F4/40 , C08F212/08 , C08F212/10 , Y02P20/584 , C08F220/12
摘要： Polymerization processes of the present invention comprise low catalyst concentration. Embodiments include a polymerization process comprising polymerizing free radically (co)polymerizable monomers in a polymerization medium comprising one or more radically (co)polymerizable monomers, a transition metal catalyst complex capable of participating in a one electron redox reaction with an ATRP initiator; a free radical initiator; and an ATRP initiator; (wherein the concentration of transition metal catalyst complex in the polymerization medium is less than 100 ppm). Further embodiments include a polymerization process, comprising polymerizing one or more radically (co)polymerizable monomers in the presence of at least one transition metal catalyst complex; an ATRP initiator; and a reducing agent; wherein the transition metal catalyst complex is present at less than 10−3 mole compared to the moles of radically transferable atoms or groups present on the ATRP initiator.
摘要翻译：本发明的聚合方法包括低催化剂浓度。实施方案包括聚合方法，其包括在包含一种或多种自由基（共）可聚合单体的聚合介质中自由基（共）可聚合单体聚合，能够与ATRP引发剂参与一电子氧化还原反应的过渡金属催化剂络合物; 自由基引发剂; 和ATRP引发剂; （其中聚合介质中过渡金属催化剂配合物的浓度小于100ppm）。另外的实施方案包括聚合方法，包括在至少一种过渡金属催化剂络合物的存在下聚合一种或多种自由基（共）可聚合单体; ATRP引发剂; 和还原剂; 其中与ATRP引发剂上存在的可自由基转移的原子或基团的摩尔数相比，过渡金属催化剂络合物的存在量小于10-3摩尔。

10. 发明授权

US07893173B2 Polymerization process with catalyst reactivation 有权
标题翻译：催化剂再活化聚合过程
公开(公告)号：US07893173B2
公开(公告)日：2011-02-22
申请号：US11990841
申请日：2006-08-28
申请人： Krzysztof Matyjaszewski , Wojciech Jakubowski , James Spanswick
发明人： Krzysztof Matyjaszewski , Wojciech Jakubowski , James Spanswick
IPC分类号： C08F4/00 , C08F2/00 , C08F4/04
CPC分类号： C08F2/40 , C08F4/04 , C08F4/40 , C08F212/08 , C08F212/10 , Y02P20/584 , C08F220/12
摘要： Polymerization processes of the present invention comprise low catalyst concentration. Embodiments include a polymerization process comprising polymerizing free radically (co)polymerizable monomers in a polymerization medium comprising one or more radically (co)polymerizable monomers, a transition metal catalyst complex capable of participating in a one electron redox reaction with an ATRP initiator; a free radical initiator; and an ATRP initiator; (wherein the concentration of transition metal catalyst complex in the polymerization medium is less than 100 ppm). Further embodiments include a polymerization process, comprising polymerizing one or more radically (co)polymerizable monomers in the presence of at least one transition metal catalyst complex; and an ATRP initiator; and a reducing agent; wherein the transition metal catalyst complex is present at less than 10″3 mole compared to the moles of radically transferable atoms or groups present on the ATRP initiator.
摘要翻译：本发明的聚合方法包括低催化剂浓度。实施方案包括聚合方法，其包括在包含一种或多种自由基（共）可聚合单体的聚合介质中自由基（共）可聚合单体聚合，能够与ATRP引发剂参与一电子氧化还原反应的过渡金属催化剂络合物; 自由基引发剂; 和ATRP引发剂; （其中聚合介质中过渡金属催化剂配合物的浓度小于100ppm）。另外的实施方案包括聚合方法，包括在至少一种过渡金属催化剂络合物的存在下聚合一种或多种自由基（共）可聚合单体; 和ATRP引发剂; 和还原剂; 其中与ATRP引发剂上存在的可自由基转移的原子或基团的摩尔数相比，过渡金属催化剂络合物的摩尔数小于10 -3。

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