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1. 发明授权

US08367051B2 Preparation of functional gel particles with a dual crosslink network 有权
标题翻译：用双交联网络制备功能性凝胶颗粒
公开(公告)号：US08367051B2
公开(公告)日：2013-02-05
申请号：US12311673
申请日：2007-10-09
申请人： Krzysztof Matyjaszewski , Ke Min , Jung Kwon Oh , James Spanswick , Nicolay V. Tsarevsky
发明人： Krzysztof Matyjaszewski , Ke Min , Jung Kwon Oh , James Spanswick , Nicolay V. Tsarevsky
IPC分类号： A61K9/14 , A61K31/74
CPC分类号： C08F293/005 , C08F283/00 , C08F290/00 , C08F290/06 , C08F291/00
摘要： Functional gel particle formed from a crosslinked polymeric network including a fraction of stable crosslinks and a second fraction of cleavable crosslinks are disclosed. Functional compounds may be chemically or physically encapsulated within and/or released from the gel particle by selective cleavage of the cleavable crosslinks. The functional compounds may be delivered and released to a pre-selected target site. Peripheral or other accessible functionality on the surface of the gel particle allows attachment of a surface reactive agent, thereby modifying one or more surface properties of the gel particle. Processes of preparing the gel particles and processes of delivering the functional compounds to a target site are also disclosed.
摘要翻译：公开了由交联的聚合物网络形成的功能性凝胶颗粒，其包括稳定的交联部分和可切割交联的第二部分。官能化合物可以通过选择性裂解可切割交联而化学或物理地包封在凝胶颗粒内和/或从凝胶颗粒释放。功能性化合物可以被递送并释放到预先选择的靶位点。在凝胶颗粒表面上的周边或其他可接近的功能允许附着表面活性剂，从而改变凝胶颗粒的一个或多个表面性质。还公开了制备凝胶颗粒的方法和将功能性化合物递送至靶位点的方法。

2. 发明授权

US08404788B2 Atom transfer radical polymerization process 有权
标题翻译：原子转移自由基聚合过程
公开(公告)号：US08404788B2
公开(公告)日：2013-03-26
申请号：US13026919
申请日：2011-02-14
申请人： Krzysztof Matyjaszewski , Lindsay Bombalski , Wojciech Jakubowski , Ke Min , Nicolay V. Tsarevsky , James Spanswick
发明人： Krzysztof Matyjaszewski , Lindsay Bombalski , Wojciech Jakubowski , Ke Min , Nicolay V. Tsarevsky , James Spanswick
IPC分类号： C08F4/40
CPC分类号： C08F265/04 , C08F4/40 , C08F220/18 , C08F265/00 , C08F291/00 , C08F293/00 , C08F293/005 , C08F2438/01
摘要： Embodiments of the polymerization process of the present invention are directed to polymerizing free radically polymerizable monomers in the presence of a polymerization medium initially comprising at least one transition metal catalyst and an atom transfer radical polymerization initiator. The polymerization medium may additionally comprise a reducing agent. The reducing agent may be added initially or during the polymerization process in a continuous or intermittent manner. The polymerization process may further comprises reacting the reducing agent with at least one of the transition metal catalyst in an oxidized state and a compound comprising a radically transferable atom or group to form a compound that does not participate significantly in control of the polymerization process. Embodiments of the present invention comprise reacting a reducing agent with at least one of catalyst in an oxidized state and a compound comprising a radically transferable atom or group to initiate and/or maintain catalytic activity throughout the polymerization process.
摘要翻译：本发明的聚合方法的实施方案涉及在最初包含至少一种过渡金属催化剂和原子转移自由基聚合引发剂的聚合介质的存在下使可自由基聚合的单体聚合。聚合介质可另外包含还原剂。还原剂可以以连续或间歇的方式最初或在聚合过程中加入。聚合方法可以进一步包括使还原剂与氧化态的至少一种过渡金属催化剂和包含可自由基转移的原子或基团的化合物反应，以形成不显着控制聚合过程的化合物。本发明的实施方案包括使还原剂与氧化状态的催化剂和包含可自由基转移的原子或基团的化合物中的至少一种反应，以在整个聚合过程中引发和/或维持催化活性。

3. 发明授权

US07893174B2 Atom transfer radical polymerization process 有权
标题翻译：原子转移自由基聚合过程
公开(公告)号：US07893174B2
公开(公告)日：2011-02-22
申请号：US10591426
申请日：2005-03-07
申请人： Krzysztof Matyjaszewski , Lindsay Bombalski , Wojciech Jakubowski , Ke Min , James Spanswick , Nicolay V. Tsarevsky
发明人： Krzysztof Matyjaszewski , Lindsay Bombalski , Wojciech Jakubowski , Ke Min , James Spanswick , Nicolay V. Tsarevsky
IPC分类号： C08F4/40
CPC分类号： C08F265/04 , C08F4/40 , C08F220/18 , C08F265/00 , C08F291/00 , C08F293/00 , C08F293/005 , C08F2438/01
摘要： Embodiments of the polymerization process of the present invention are directed to polymerizing free radically polymerizable monomers in the presence of a polymerization medium initially comprising at least one transition metal catalyst and an atom transfer radical polymerization initiator. The polymerization medium may additionally comprise a reducing agent. The reducing agent may be added initially or during the polymerization process in a continuous or intermittent manner. The polymerization process may further comprise reacting the reducing agent with at least one of the transition metal catalyst in an oxidized state and a compound comprising a radically transferable atom or group to form a compound that does not participate significantly in control of the polymerization process. Embodiments of the present invention comprise reacting a reducing agent with at least one of catalyst in an oxidized state and a compound comprising a radically transferable atom or group to initiate and/or maintain catalytic activity throughout the polymerization process.
摘要翻译：本发明的聚合方法的实施方案涉及在最初包含至少一种过渡金属催化剂和原子转移自由基聚合引发剂的聚合介质的存在下使可自由基聚合的单体聚合。聚合介质可另外包含还原剂。还原剂可以以连续或间歇的方式最初或在聚合过程中加入。聚合方法还可包括使还原剂与氧化态的至少一种过渡金属催化剂和包含可自由基转移的原子或基团的化合物反应，以形成不显着控制聚合方法的化合物。本发明的实施方案包括使还原剂与氧化状态的催化剂和包含可自由基转移的原子或基团的化合物中的至少一种反应，以在整个聚合过程中引发和/或维持催化活性。

4. 发明申请

US20110218306A1 ATOM TRANSFER RADICAL POLYMERIZATION PROCESS 有权
标题翻译：原子转移自由基聚合方法
公开(公告)号：US20110218306A1
公开(公告)日：2011-09-08
申请号：US13026919
申请日：2011-02-14
申请人： Krzysztof Matyjaszewski , Lindsay Bombalski , Wojciech Jakubowski , Ke Min , James Spanswick , Nicolay V. Tsarevsky
发明人： Krzysztof Matyjaszewski , Lindsay Bombalski , Wojciech Jakubowski , Ke Min , James Spanswick , Nicolay V. Tsarevsky
IPC分类号： C08F120/06 , C08F112/08 , C08F118/02 , C08G63/08
CPC分类号： C08F265/04 , C08F4/40 , C08F220/18 , C08F265/00 , C08F291/00 , C08F293/00 , C08F293/005 , C08F2438/01
摘要： Embodiments of the polymerization process of the present invention are directed to polymerizing free radically polymerizable monomers in the presence of a polymerization medium initially comprising at least one transition metal catalyst and an atom transfer radical polymerization initiator. The polymerization medium may additionally comprise a reducing agent. The reducing agent may be added initially or during the polymerization process in a continuous or intermittent manner. The polymerization process may further comprises reacting the reducing agent with at least one of the transition metal catalyst in an oxidized state and a compound comprising a radically transferable atom or group to form a compound that does not participate significantly in control of the polymerization process. Embodiments of the present invention comprise reacting a reducing agent with at least one of catalyst in an oxidized state and a compound comprising a radically transferable atom or group to initiate and/or maintain catalytic activity throughout the polymerization process.
摘要翻译：本发明的聚合方法的实施方案涉及在最初包含至少一种过渡金属催化剂和原子转移自由基聚合引发剂的聚合介质的存在下使可自由基聚合的单体聚合。聚合介质可另外包含还原剂。还原剂可以以连续或间歇的方式最初或在聚合过程中加入。聚合方法可以进一步包括使还原剂与氧化态的至少一种过渡金属催化剂和包含可自由基转移的原子或基团的化合物反应，以形成不显着控制聚合过程的化合物。本发明的实施方案包括使还原剂与氧化状态的催化剂和包含可自由基转移的原子或基团的化合物中的至少一种反应，以在整个聚合过程中引发和/或维持催化活性。

5. 发明申请

US20100143286A1 Preparation of functional gel particles with a dual crosslink network 有权
标题翻译：用双交联网络制备功能性凝胶颗粒
公开(公告)号：US20100143286A1
公开(公告)日：2010-06-10
申请号：US12311673
申请日：2007-10-09
申请人： Krzystof Matyjaszewski , Ke Min , Jung Kwon Oh , James Spanswick , Nicolay V. Tsarevsky
发明人： Krzystof Matyjaszewski , Ke Min , Jung Kwon Oh , James Spanswick , Nicolay V. Tsarevsky
IPC分类号： A61K31/74 , C08K11/00 , A61K8/72
CPC分类号： C08F293/005 , C08F283/00 , C08F290/00 , C08F290/06 , C08F291/00
摘要： Functional gel particle formed from a crosslinked polymeric network including a fraction of stable crosslinks and a second fraction of cleavable crosslinks are disclosed. Functional compounds may be chemically or physically encapsulated within and/or released from the gel particle by selective cleavage of the cleavable crosslinks. The functional compounds may be delivered and released to a pre-selected target site. Peripheral or other accessible functionality on the surface of the gel particle allows attachment of a surface reactive agent, thereby modifying one or more surface properties of the gel particle. Processes of preparing the gel particles and processes of delivering the functional compounds to a target site are also disclosed.
摘要翻译：公开了由交联的聚合物网络形成的功能性凝胶颗粒，其包括稳定的交联部分和可切割交联的第二部分。官能化合物可以通过选择性裂解可切割交联而化学或物理地包封在凝胶颗粒内和/或从凝胶颗粒释放。功能性化合物可以被递送并释放到预先选择的靶位点。在凝胶颗粒表面上的周边或其他可接近的功能允许附着表面活性剂，从而改变凝胶颗粒的一个或多个表面性质。还公开了制备凝胶颗粒的方法和将功能性化合物递送至靶位点的方法。

6. 发明申请

US20110060107A1 PREPARATION OF FUNCTIONAL POLYMERS 审中-公开
标题翻译：功能聚合物的制备
公开(公告)号：US20110060107A1
公开(公告)日：2011-03-10
申请号：US12877589
申请日：2010-09-08
申请人： Krzysztof Matyjaszewski , Brent S. Sumerlin , Nicolay V. Tsarevsky , James Spanswick
发明人： Krzysztof Matyjaszewski , Brent S. Sumerlin , Nicolay V. Tsarevsky , James Spanswick
IPC分类号： C08F8/30
CPC分类号： C08F8/30 , C08F293/005 , C08F2438/01 , C08F2438/03
摘要： The process of the present invention is directed toward conducting highly selective, high yield post polymerization reactions on polymers to prepare functionalized polymers. An embodiment of the present invention comprises conducting click chemistry reactions on polymers. Preferably, the polymers were prepared by controlled polymerization processes. Therefore, embodiments of the present invention comprise processes for the preparation of polymers comprising conducting a click chemistry reaction on a functional group attached to a polymer, wherein the polymer has a molecular weight distribution of less than 2.0. The functional polymers may be prepared by converting an attached functional unit on the polymer thereby providing site specific functional materials, site specific functional materials comprising additional functionality, or chain extended functional materials.Embodiments of the process of the present invention include functionalization reactions, chain extensions reactions, to form block copolymer linking reactions, and attaching side chains to form graft copolymers, for example.
摘要翻译：本发明的方法涉及在聚合物上进行高选择性，高收率的后聚合反应以制备官能化聚合物。本发明的一个实施方案包括对聚合物进行点击化学反应。优选地，通过控制聚合方法制备聚合物。因此，本发明的实施方案包括制备聚合物的方法，包括在连接到聚合物上的官能团上进行点击化学反应，其中聚合物的分子量分布小于2.0。官能聚合物可以通过在聚合物上转化附着的官能单元来制备，从而提供位点特异性功能材料，包含附加官能团的位点特异性功能材料或链延伸的功能材料。本发明方法的实施方案包括例如官能化反应，延伸链反应，形成嵌段共聚物连接反应和连接侧链以形成接枝共聚物。

7. 发明授权

US07056455B2 Process for the preparation of nanostructured materials 有权
公开(公告)号：US07056455B2
公开(公告)日：2006-06-06
申请号：US10118519
申请日：2002-04-06
申请人： Krzysztof Matyjaszewski , Tomasz Kowalewski , David N. Lambeth , James Spanswick , Nicolay V. Tsarevsky
发明人： Krzysztof Matyjaszewski , Tomasz Kowalewski , David N. Lambeth , James Spanswick , Nicolay V. Tsarevsky
IPC分类号： D01F9/12
CPC分类号： H01G9/155 , B82Y10/00 , B82Y15/00 , B82Y30/00 , B82Y40/00 , C01B3/0021 , C01B32/05 , C01B32/162 , C04B35/524 , C04B35/63424 , C04B35/63444 , C04B38/0022 , C04B2111/00801 , C04B2111/0081 , C04B2111/00827 , C04B2111/00844 , C04B2111/00853 , C04B2235/5288 , D01F9/14 , G03F7/0002 , G11C2213/81 , H01G11/36 , H01M4/58 , H01M4/583 , H01M4/96 , Y02E60/13 , Y02E60/325 , Y02E60/327 , Y10S521/918 , Y10S521/919 , C04B38/0054
摘要： The present invention comprises a novel process for the preparation of carbon based structured materials with controlled topology, morphology and functionality. The nanostructured materials are prepared by controlled carbonization, or pyrolysis, of precursors comprising phase separated copolymers. The precursor materials are selected to phase separate and self organize in bulk, in solution, in the presence of phase selective solvents, at surfaces, interfaces or during fabrication, into articles, fibers or films exhibiting well-defined, self-organized morphology or precursors of well-defined, self-organized, bi- or tri-phasic morphology. Compositional control over the (co)polymers provides control over the structure of the phase separated precursor whose organization therein dictates the nanostructure of the material obtained after carbonization or pyrolysis, wherein each dimension of the formed structure can be predetermined. When the precursor morphology is selected to comprise cylindrical domains this procedure additionally allows for the direct formation of two dimensional nanowire grids or arrays of oriented nanostructures on surfaces. When these nanowire grids or arrays are perpendicularly oriented to the surface applications include field emitters, high surface area electrodes, electronic devices such as diodes and transistors, tools for AMF tips and elements of molecular electronics. When the first nanostructured morphology is selected to form cylinders parallel to the surface then nanowire arrays are formed after pyrolysis. When the composition of the first nanostructured morphology is selected to comprise a continuous precursor matrix then a continuous carbon based nanostructured material is formed. The internal structure of the carbon based material can be selected to comprise perpendicular pores or an interconnected array of pores. The carbon based structures can additionally find application in photovoltaics, supercapacitors, batteries, fuel cells, computer memory, carbon electrodes, carbon foams, actuators and hydrogen storage.

8. 发明授权

US08349410B2 Modification of surfaces with polymers 有权
标题翻译：用聚合物改性表面
公开(公告)号：US08349410B2
公开(公告)日：2013-01-08
申请号：US11894010
申请日：2007-08-17
申请人： Jinyu Huang , Alan J. Russell , Nicolay V. Tsarevsky , Krzysztof Matyjaszewski
发明人： Jinyu Huang , Alan J. Russell , Nicolay V. Tsarevsky , Krzysztof Matyjaszewski
IPC分类号： C09D5/14 , C08F2/46 , C08J7/14 , C08F8/02 , C08F220/34
CPC分类号： C08L33/14 , C08F120/34 , C08F255/02 , C08F265/06 , C08F291/00 , C08F293/005 , C08L53/00
摘要： A polymer formed by controlled radical polymerization includes groups that can be modified after controlled radical polymerization to form a radical. The polymer can be the reaction product of a controlled radical polymerization of radically polymerizable monomers, wherein at least one of the radically polymerizable monomers includes at least one group that can be modified after the controlled radical polymerization to form a radical. A compound includes a first group that is stimulated upon application of energy to the molecule to tether the molecule to a surface or to another polymer chain and a second group comprising a controlled radical polymerization initiator functionality. A block copolymer includes at least a first segment to impart a predetermined functionality to a target surface and at least a second segment including functional groups to interact with the targeted surface to attach the block copolymer to the surface. The first segment can free of functional groups that interact with the surface to attach the block copolymer to the surface.
摘要翻译：通过受控自由基聚合形成的聚合物包括可以在受控自由基聚合反应形成基团之后进行改性的基团。聚合物可以是可自由基聚合的单体的受控自由基聚合的反应产物，其中至少一种可自由基聚合的单体包括至少一个可在受控自由基聚合之后修饰以形成基团的基团。化合物包括在向分子施加能量以将分子束缚至表面或另一聚合物链时被刺激的第一组和包含受控自由基聚合引发剂官能团的第二组。嵌段共聚物包括至少一个赋予靶表面预定官能度的第一链段和至少一个包含官能团的第二链段以与目标表面相互作用以将该嵌段共聚物连接到该表面上。第一段可以没有与表面相互作用的官能团，以将嵌段共聚物附着在表面上。

9. 发明授权

US08871831B2 Modification of surfaces with polymers 有权
标题翻译：用聚合物改性表面
公开(公告)号：US08871831B2
公开(公告)日：2014-10-28
申请号：US14065370
申请日：2013-10-28
申请人： Jinyu Huang , Alan J. Russell , Nicolay V. Tsarevsky , Krzysztof Matyjaszewski
发明人： Jinyu Huang , Alan J. Russell , Nicolay V. Tsarevsky , Krzysztof Matyjaszewski
IPC分类号： C08L33/00 , C08L39/00 , C08F120/34 , C08F220/34 , C09D5/14 , C08L53/00 , C08F255/02 , C08F293/00 , C08L33/14 , C08F291/00 , C08F265/06
CPC分类号： C08L33/14 , C08F120/34 , C08F255/02 , C08F265/06 , C08F291/00 , C08F293/005 , C08L53/00
摘要： A polymer formed by controlled radical polymerization includes groups that can be modified after controlled radical polymerization to form a radical. The polymer can be the reaction product of a controlled radical polymerization of radically polymerizable monomers, wherein at least one of the radically polymerizable monomers includes at least one group that can be modified after the controlled radical polymerization to form a radical.
摘要翻译：通过受控自由基聚合形成的聚合物包括可以在受控自由基聚合反应形成基团之后进行改性的基团。聚合物可以是可自由基聚合的单体的受控自由基聚合的反应产物，其中至少一种可自由基聚合的单体包括至少一个可在受控自由基聚合之后修饰以形成基团的基团。

10. 发明申请

US20080139689A1 Modification of surfaces with polymers 有权
标题翻译：用聚合物改性表面
公开(公告)号：US20080139689A1
公开(公告)日：2008-06-12
申请号：US11894010
申请日：2007-08-17
申请人： Jinyu Huang , Alan J. Russell , Nicolay V. Tsarevsky , Krzysztof Matyjaszewski
发明人： Jinyu Huang , Alan J. Russell , Nicolay V. Tsarevsky , Krzysztof Matyjaszewski
IPC分类号： B29C71/04
CPC分类号： C08L33/14 , C08F120/34 , C08F255/02 , C08F265/06 , C08F291/00 , C08F293/005 , C08L53/00
摘要： A polymer formed by controlled radical polymerization includes groups that can be modified after controlled radical polymerization to form a radical. The polymer can be the reaction product of a controlled radical polymerization of radically polymerizable monomers, wherein at least one of the radically polymerizable monomers includes at least one group that can be modified after the controlled radical polymerization to form a radical. A compound includes a first group that is stimulated upon application of energy to the molecule to tether the molecule to a surface or to another polymer chain and a second group comprising a controlled radical polymerization initiator functionality. A block copolymer includes at least a first segment to impart a predetermined functionality to a target surface and at least a second segment including functional groups to interact with the targeted surface to attach the block copolymer to the surface. The first segment can free of functional groups that interact with the surface to attach the block copolymer to the surface.
摘要翻译：通过受控自由基聚合形成的聚合物包括可以在受控自由基聚合反应形成基团之后进行改性的基团。聚合物可以是可自由基聚合的单体的受控自由基聚合的反应产物，其中至少一种可自由基聚合的单体包括至少一个可在受控自由基聚合之后修饰以形成基团的基团。化合物包括在向分子施加能量以将分子束缚至表面或另一聚合物链时被刺激的第一组和包含受控自由基聚合引发剂官能团的第二组。嵌段共聚物包括至少一个赋予靶表面预定官能度的第一链段和至少一个包含官能团的第二链段以与目标表面相互作用以将该嵌段共聚物连接到该表面上。第一段可以没有与表面相互作用的官能团，以将嵌段共聚物附着在表面上。

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