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    • 1. 发明授权
    • Process for producing water-absorbent cross-linked, carboxyalkylated
cellulose-containing material
    • 生产吸水性交联羧甲烷基化纤维素的材料的方法
    • US5725601A
    • 1998-03-10
    • US691098
    • 1996-08-01
    • Kozo TajiriMasayo MaedaHaruo Tsukamoto
    • Kozo TajiriMasayo MaedaHaruo Tsukamoto
    • A61L15/28C08B15/00D04H1/64A61L15/00
    • C08B15/005A61L15/28D04H1/587D04H1/64
    • A water absorbent cross-linked, carboxyalkylated cellulose-containing material is produced by impregnating a cellulose-containing material with an aqueous reaction solution including a carboxyalkylating agent, an alkali metal hydroxide, and a cross-linking agent dissolved in water in an initial content of 50 to 90% by weight, the molar ratio of the carboxylating agent to glucose groups of cellulose being 0.7 to 2.0; adjusting the water content of the aqueous reaction solution impregnated in the cellulose-containing material to 20 to 60% by weight and of at least 5% by weight below the initial water content by evaporating a portion of water; and subjecting the water content-adjusted cellulose-containing material to a simultaneous cross-linking and carboxylating reaction procedure at 50.degree. to 110.degree. C., while maintaining the water content at 20 to 60% and of at least 5% by weight below the initial water content.
    • 含水吸收剂交联的含羧烷基化纤维素的材料是通过用包含羧基烷化剂,碱金属氢氧化物和溶解在水中的交联剂的含水反应溶液浸渍含纤维素材料来制备的,其初始含量为 50〜90重量%,羧化剂与纤维素的葡萄糖基摩尔比为0.7〜2.0; 通过蒸发一部分水,将浸渍在含纤维素的材料中的水性反应溶液的水含量调节至低于初始含水量的20至60重量%和至少5重量% 并将含水量调节的含纤维素材料在50℃至110℃下进行同时的交联和羧化反应过程,同时保持水含量为20至60%且至少5重量%低于 初始含水量。