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    • 1. 发明授权
    • Dielectric ceramic composition
    • 介电陶瓷组合物
    • US5093757A
    • 1992-03-03
    • US649463
    • 1991-02-05
    • Kouji KawakitaSuzushi KimuraHideyuki OkinakaYouichiro YokotaniMariko Ishikawa
    • Kouji KawakitaSuzushi KimuraHideyuki OkinakaYouichiro YokotaniMariko Ishikawa
    • C04B35/472C04B35/499H01G4/12
    • H01G4/1254C04B35/472C04B35/499
    • The invention relates to a dielectric ceramic composition that can be baked in a short time in the atmosphere, neutral atmosphere or reducing atmosphere at baking temperature of 800.degree. to 1000.degree. C. In the ceramic components expressed by PbTi.sub.X (Mg.sub.1/2 Nb.sub.2/3).sub.Y (Ni.sub.1/2 W.sub.1/2)ZO.sub.3 (where X+Y+Z=1), PbO is added by 1.0 to 25.0 mol % and NiO by 1.0 to 15.0 mol % as subsidiary components, to the temporarily baked powder of the main component dielectric ceramic composition composed in the pentagonal region having the vertices at compositions A, B, C, D, E expressed by numerical values in the following square brackets, in the system of trigonometric coordinates having the vertices at PbTiO.sub.3, Pb(Mg.sub.1/3 Nb.sub.2/3)O.sub.3 and Pb(Ni.sub.1/2 W.sub.1/2)O.sub.3,A is x=2.5, y=9.5, z=2.5;B is x=12.5, y=85.0, z=2.5,C is x=60.0, y=10.0, z=30.0,D is x=40.0, y=10.0, z=50.0,E is x=2.5, y=90.0, z=7.5 (where all untis are mol %)so that a laminate ceramic capacitor or thick film capacitor of large capacity that can be baked densely in a short time at low baking temperature of below 1000.degree. C. will be obtained.
    • 本发明涉及一种可在大气中,中性气氛或还原气氛下在800〜1000℃烘烤温度下短时间烘烤的电介质陶瓷组合物。在PbTiX(Mg1 / 2Nb2 / 3)表示的陶瓷成分中, Y(Ni1 / 2W1 / 2)ZO3(其中X + Y + Z = 1),PbO的添加量为1.0〜25.0mol%,NiO为1.0〜15.0mol%作为辅助成分,添加到主成分 在具有在PbTiO3,Pb(Mg1 / 3Nb2 / Pb)的顶点的三角坐标系统中,在具有由以下方括号中的数值表示的组成A,B,C,D,E的顶点的五边形区域中组成的介电陶瓷组合物, 3)O3和Pb(Ni1 / 2W1 / 2)O3,A为x = 2.5,y = 9.5,z = 2.5; B为x = 12.5,y = 85.0,z = 2.5,C为x = 60.0,y = 10.0,z = 30.0,D为x = 40.0,y = 10.0,z = 50.0,E为x = 2.5,y = 90.0,z = 7.5(其中全部为mol%),从而将获得能够在低于1000℃的低烘烤温度下在短时间内密集烘烤的大容量的层压陶瓷电容器或厚膜电容器。
    • 3. 发明授权
    • Conductive paste composition for via hole filling and printed circuit
board using the same
    • 用于通孔填充的导电糊组合物和使用其的印刷电路板
    • US6096411A
    • 2000-08-01
    • US38625
    • 1998-03-12
    • Seiichi NakataniKouji KawakitaTatsuo Ogawa
    • Seiichi NakataniKouji KawakitaTatsuo Ogawa
    • C08K3/00C08K3/08C08L63/00H05K1/09H05K3/40H05K3/46B32B3/00
    • H05K3/4069C08K3/08H05K1/095C08K2003/085H05K2201/0355H05K2203/1461H05K3/4652Y10S428/901Y10T428/24917
    • The invention related to a paste for via hole filling which enables inner via hole connection between electrode layers without employing through hole plating techniques, and a multi-layered printed circuit board using the same. The conductive paste composition of the invention comprises a) 70-90 wt % of copper particles of an average particle size of 0.5-8 .mu.m; b) 0.5-15 wt % of insulating particles of an average particle size of 8-20 .mu.m; and, c) 6-17 wt % of heat setting type liquid epoxy resin, in order to exhibit low viscosity and low volatility. The conductive paste is printed and filled into through holes passing through a laminated substrate which is provide with copper foils on both sides thereof, to form a printed circuit board in which the via holes are electrically connected after thermosetting. By adding insulating particles of large particle size, the amount of copper particles to be added is decreased so that a via hole connection of low specific resistance and high reliability is obtained, and improvements in a decrease of viscosity and continuous printability of the paste itself can be achieved.
    • 本发明涉及一种用于通孔填充的糊剂,其能够在不使用通孔电镀技术的情况下实现电极层之间的内部通孔连接,以及使用该糊状物的多层印刷电路板。 本发明的导电糊组合物包含a)70-90重量%的平均粒径为0.5-8μm的铜颗粒; b)0.5-15重量%的平均粒径为8-20μm的绝缘颗粒; 和c)6-17重量%的热固定型液体环氧树脂,以显示低粘度和低挥发性。 将导电性糊料印刷填充到通过其两侧设置有铜箔的层叠基板的通孔中,形成印刷电路基板,其中通孔在热固化后电连接。 通过添加大粒径的绝缘粒子,可以减少添加的铜粒子的量,从而获得低电阻率和高可靠性的通孔连接,并且可以提高糊剂本身的粘度和连续印刷性的降低 实现。