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    • 2. 发明授权
    • Catalyst for purifying an exhaust gas
    • 用于净化废气的催化剂
    • US06846466B2
    • 2005-01-25
    • US09803908
    • 2001-03-13
    • Shigeji MatsumotoKoichi KasaharaYasunori Sato
    • Shigeji MatsumotoKoichi KasaharaYasunori Sato
    • B01D53/94B01D50/00B01D53/34
    • B01D53/945Y02T10/22
    • A catalyst for purifying an exhaust gas includes an upstream side catalyst and a downstream side catalyst. The upstream side catalyst is disposed on an upstream side with respect to an exhaust gas flow, and the downstream side catalyst is disposed on a downstream side with respect thereto. The upstream side catalyst includes a first loading layer, being composed of an alumina containing Ba and La at least, and a first noble metal, being held by the first loading layer and being at least one member selected from the group consisting of Pd, Pd and Rh and Pd and Pt. Alternatively, in addition to the aluminum, the first loading layer can be composed of Ce, a solid solution of Ce and Zr and a solid solution of Ce, Zr and Y in an amount as less as possible. The downstream side catalyst includes a second loading layer, being composed of at least one member selected from the group consisting of an alumina containing La, Ce, a solid solution of Ce and Zr and a solid solution of Ce, Zr and Y, and a second noble metal, being held by the second loading layer and being composed of at least one member selected from the group consisting of Pt, Pd and Rh.
    • 用于净化废气的催化剂包括上游侧催化剂和下游侧催化剂。 上游侧催化剂相对于废气流配置在上游侧,下游侧催化剂相对于其排出侧。 上游侧催化剂包括由至少含有Ba和La的氧化铝和由第一负载层保持的第一贵金属组成的第一负载层,并且是选自Pd,Pd 和Rh,Pd和Pt。 或者,除了铝之外,第一加载层可以由Ce,Ce和Zr的固溶体以及尽可能少的Ce,Zr和Y的固溶体构成。 下游侧催化剂包括第二加料层,其由选自由以下组成的组中的至少一种组成:含有La,Ce的氧化铝,Ce和Zr的固溶体以及Ce,Zr和Y的固溶体,以及 第二贵金属由第二加载层保持并且由选自Pt,Pd和Rh中的至少一种构成。
    • 9. 发明授权
    • Catalyst for purifying exhaust gases
    • 废气净化催化剂
    • US5948376A
    • 1999-09-07
    • US615789
    • 1996-03-14
    • Naoto MiyoshiTuneyuki TanizawaKazunobu IshibashiKoichi KasaharaSyuji Tateishi
    • Naoto MiyoshiTuneyuki TanizawaKazunobu IshibashiKoichi KasaharaSyuji Tateishi
    • B01D53/14B01D53/86B01D53/94B01J23/56B01J23/58B01J23/63B01J37/02
    • B01D53/945B01D53/9481B01J23/58B01J23/63B01D2255/91B01J37/0248F01N2570/16Y02T10/22
    • A catalyst for purifying exhaust gases includes a porous support, an NO.sub.x storage component including at least one member selected from the group consisting of alkaline-earth metals, rare-earth elements and alkali metals, and loaded on the porous support, a noble metal catalyst ingredient loaded on the porous support, and disposed adjacent to the NO.sub.x storage component, and ceria (CeO.sub.2) disposed away from the noble metal catalyst ingredient. By disposing the noble metal catalyst ingredient adjacent to the NO.sub.x storage component, the reduction reactions of NO.sub.x can be facilitated in fuel-rich (i.e., oxygen-lean) atmospheres without being interfered by the ceria. By disposing the ceria away from the noble metal catalyst ingredient, oxygen, which has been stored thereon in fuel-lean (i.e., oxygen-rich) atmospheres, can be released from the ceria at a controlled rate in a controlled amount in fuel-rich (i.e., oxygen-lean) atmospheres, and thereby the released oxygen can be inhibited from reacting with HC and CO in fuel-rich (i.e., oxygen-lean) atmospheres. Thus, the catalyst is improved in terms of NO.sub.x purifying performance.
    • 用于净化废气的催化剂包括多孔载体,包含选自碱土金属,稀土元素和碱金属中的至少一种的负载在多孔载体上的NOx储存组分,贵金属催化剂 负载在多孔载体上并且邻近于NOx储存组分设置的成分和远离贵金属催化剂成分的二氧化铈(CeO 2)。 通过将贵金属催化剂成分配置在与NOx存储成分相邻的位置,可以在不受二氧化铈干扰的情况下,富含燃料(即贫氧)的气氛中的NOx的还原反应变得容易。 通过将二氧化铈置于贵金属催化剂成分之外,其中储存在贫燃料(即富氧)气氛中的氧可以以受控的量在二氧化铈中以富含燃料的方式从二氧化铈中释放出来 (即,贫氧)气氛,从而可以抑制释放的氧与富含燃料(即贫氧)气氛中的HC和CO反应。 因此,NOx净化性能提高了催化剂。