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    • 6. 发明授权
    • Moldability modifier and polypropylene resin composition using the same
    • 成型性改性剂和使用其的聚丙烯树脂组合物
    • US08211978B2
    • 2012-07-03
    • US12294100
    • 2007-03-23
    • Yukihito ZankaYuji RyoshoKen ShimizuMasashi ShimouseShigeo Mizukami
    • Yukihito ZankaYuji RyoshoKen ShimizuMasashi ShimouseShigeo Mizukami
    • C08L53/00C08L23/00C08L23/04C09J7/02C08K5/00
    • C08L53/00C08F297/08C08F297/083C08K3/34C08K5/1345C08K5/526C08L23/16C08L2666/24C08L2666/02C08L2666/04
    • A moldability modifier capable of improving molding processability, and a polypropylene resin composition using the same suitable for automobile exterior parts are provided. The invention relates to a moldability modifier comprising propylene block copolymer (A) containing from 80 to 98 wt % of a propylene homopolymer portion (A1) and from 2 to 20 wt % of a propylene/ethylene random copolymer portion (A2), wherein the MFR of (A1) is 300 g/10 min or more, the ethylene content of (A2) is from 10 to 70 wt %, the [η] of (A2) is 6.5 dl/g or more, and the MFR as a whole is 40 g/10 min or more; and propylene block copolymer (B) containing from 20 to 79 wt % of a propylene polymer portion (B1) and from 21 to 80 wt % of a propylene/ethylene random copolymer portion (B2), wherein the MFR of (B1) is 20 g/10 min or more, the ethylene content of (B2) is from 20 to 70 wt %, the [η] of (B2) is from 2.5 to 9.0 dl/g, and the MFR as a whole is from 0.1 to 50 g/10 min; and a polypropylene resin composition using the same.
    • 提供能够提高成型加工性的成型性改性剂和使用该成型性改性剂的适用于汽车外用部件的聚丙烯树脂组合物。 本发明涉及含有丙烯均聚物部分(A1)80〜98重量%和丙烯/乙烯无规共聚物部分(A2)2〜20重量%的丙烯嵌段共聚物(A)的成型性改性剂,其中, (A1)的MFR为300g / 10分钟以上,(A2)的乙烯含量为10〜70重量%,(A2)的[(e)]为6.5dl / g以上,MFR 整体为40g / 10min以上; 丙烯聚合物部分(B1)20〜79重量%,丙烯 - 乙烯无规共聚物部分(B2)21〜80重量%的丙烯嵌段共聚物(B),(B1)的MFR为20 g / 10分钟以上时,(B2)的乙烯含量为20〜70重量%,(B2)的乙烯含量为2.5〜9.0dl / g,MFR为0.1〜 50克/ 10分钟; 和使用其的聚丙烯树脂组合物。
    • 8. 发明授权
    • Method for producing an optical material having a high refractive index
    • 具有高折射率的光学材料的制造方法
    • US5424339A
    • 1995-06-13
    • US177387
    • 1994-01-05
    • Yukihito ZankaTsutomu IsakaYutaka Tamura
    • Yukihito ZankaTsutomu IsakaYutaka Tamura
    • C08G18/67C08F2/46C08F220/38G02B1/04G02C7/02
    • C08F220/38G02B1/041
    • An optical material with a high refractive index comprising a resin which is obtainable by polymerization and curing of a composition comprising the following components (A), (B) and (C):component (A): a sulfur-containing (meth)acrylic monomer represented by the following formula [I], or a mixture of the monomer [I] and a sulfur-containing (meth)acrylic monomer represented by the following formula [II]: ##STR1## in each of which formulas, R.sup.1 represents a hydrogen atom or a methyl group, R.sup.2 and R.sup.3 independently represent a hydrocarbyl group of 1 to 12 carbon atoms, X represents a halogen atom except fluorine, and n represents 0 or an integer of 1 to 4, provided that those groups which are in plurality may be the same or different,the weight ratio of the compound [I]/the compound [II] being from 10/0 to 1/9;component (B): a hydroxy(meth)acrylic monomer represented by the following formula [III]: ##STR2## wherein R.sup.5 represents a hydrogen atom or a methyl group, R.sup.4 represents a hydrocarbyl group of 1 to 20 carbon atoms which may or may not contain an ether oxygen atom, Y represents a halogen atom except fluorine, and m represents 0 or an integer of 1 or 2, provided that those groups which are in plurality may be the same or different, and p is 1 or 2,the weight ratio of the component (A)/the component (B) being from 95/5 to 50/50; andcomponent (C): an isocyanate compound having a plurality of --NCO groups,the ratio (--NCO/--OH) of the number of --NCO group in the component (C) to the total number of --OH group in the components (A) and (B) being from 0.2 to 3.The above material for lenses has a low specific gravity and improved refractive index, transparency and impact resistance.
    • 具有高折射率的光学材料,其包含通过聚合和固化包含以下组分(A),(B)和(C)的组合物获得的树脂:组分(A):含硫(甲基)丙烯酸 由下式[I]表示的单体或由下式[II]表示的单体[I]和含硫(甲基)丙烯酸类单体的混合物的组合:< IMAGE> 在每个式中,R 1表示氢原子或甲基,R 2和R 3独立地表示1〜12个碳原子的烃基,X表示氟以外的卤素原子,n表示0或1〜4的整数 如果化合物[I] /化合物[II]的重量比为10/0〜1/9,则多个的那些基团可以相同或不同, 组分(B):由下式[III]表示的羟基(甲基)丙烯酸类单体:其中,R 5表示氢原子或甲基,R 4表示碳原子数1〜20的烃基, 可以含有或不含有醚氧原子,Y表示除氟以外的卤素原子,m表示0或1或2的整数,条件是这些基团可以相同或不同,p为1或 2,成分(A)/成分(B)的重量比为95/5〜50/50; 和(C)成分:具有多个-NCO基的异氰酸酯化合物,(C)成分中的-NCO基数与成分中的-OH基总数的比(-NCO / -OH) (A)和(B)为0.2至3.上述用于透镜的材料具有低比重和改善的折射率,透明度和耐冲击性。
    • 10. 发明授权
    • Thermoplastic resin composition improved in terms of prevention of mold
contamination
    • 热塑性树脂组合物在防止霉菌污染方面得到改善
    • US5889099A
    • 1999-03-30
    • US804403
    • 1997-02-21
    • Takayuki NagaiToshio NiimiYukihito ZankaIkuo TsutsumiHiroki Sato
    • Takayuki NagaiToshio NiimiYukihito ZankaIkuo TsutsumiHiroki Sato
    • C08K3/34C08K5/00C08K5/098C08K5/17C08K5/526C08L53/00C08J5/10C08L23/16
    • C08K5/005C08L53/00
    • A thermoplastic resin composition improved in terms of prevention of mold contamination, comprising the following components (A) to (G):component (A): 55 to 75% by weight of a propylene-ethylene block copolymer including a propylene homopolymer moiety having a melt flow rate of 15 to 50 g/10 min. and an isotactic pentad fraction of at least 0.97, said block copolymer having a melt flow rate of 10 to 30 g/10 min. and an ethylene content of 2 to 6% by weight,component (B): 0 to 10% by weight of an ethylene-propylene copolymer rubber having a melting temperature of 30.degree. to 60.degree. C. and a melt flow rate of 0.2 to 2 g/10 min.,component (C): 5 to 15% by weight of an ethylene-.alpha.-olefin copolymer rubber having a melting temperature of 60.degree. to 100.degree. C. and a melt flow rate of 0.3 to 2 g/10 min.,component (D): 15 to 25% by weight of a talc having an average particle diameter of up to 5 .mu.m and a specific surface area of at least 3.5 m.sup.2 /g,the total amount of components (A) to (D) being 100% by weight,component (E): 0.05 to 2 parts by weight of a hindered amine having a structure represented by the following formula (I): ##STR1## component (F): 0.01 to 1 part by weight of a triaryl phosphite, and component (G): 0.05 to 4 parts by weight of a metal salt represented by the following general formula (VIII):(RCOO).sub.2 X (VIII)wherein R is a monovalent hydrocarbon group having a molecular weight of 290 to 500, and X is zinc, magnesium or calcium,the respective amounts of components (E) to (G) being based on 100 parts by weight of the sum of components (A) to (D).
    • 包含以下组分(A)至(G))的组分(A):55至75重量%的包含丙烯均聚物部分的丙烯 - 乙烯嵌段共聚物,其具有 熔体流动速率为15〜50g / 10min。 和全同立构五单元组分数至少为0.97,所述嵌段共聚物的熔体流动速率为10至30g / 10min。 乙烯含量为2〜6重量%,成分(B):0〜10重量%的熔融温度为30〜60℃的乙烯 - 丙烯共聚物橡胶,熔体流动速率为0.2〜 2g / 10分钟,成分(C):5〜15重量%的熔融温度为60〜100℃的乙烯-α-烯烃共聚物橡胶,熔体流动速率为0.3〜2g / 10分钟,成分(D):15〜25重量%的平均粒径为5μm以下,比表面积为3.5m 2 / g以上的滑石,成分(A)的总量 至(D)为100重量%,组分(E):0.05-2重量份具有由下式(I)表示的结构的受阻胺:亚磷酸三芳基酯的重量和组分(G):0.05 至4重量份由以下通式(VIII)表示的金属盐:(RCOO)2 X(VIII)其中R是分子量为290至500的一价烃基,X为锌,镁 (E)至(G)的各自的量基于100重量份的组分(A)至(D)的总和。