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    • 1. 发明专利
    • Color image forming method
    • 彩色图像形成方法
    • JPS59162543A
    • 1984-09-13
    • JP3622883
    • 1983-03-04
    • Konishiroku Photo Ind Co Ltd
    • HOTSUTA YUUJIHIRABAYASHI SHIGETOYAMASHITA KIYOSHI
    • G03C5/08G03C7/10G03C8/08G03C8/10G03C8/30G03C7/00
    • G03C8/30
    • PURPOSE:To obtain rapidly a high-quality color image by forming a mosaic layer consisting of elements transmitting only blue, green or red light and contg. a corresponding dye (precursor) releasing substance and a silver halide emulsion layer on a transparent support and by transferring a color image to an image receiving layer. CONSTITUTION:A fine mosaic or striped filter layer 2 consisting of elements each transmitting spectrally blue light B, green light G or red light R and a blue-, green- and red-sensitive silver halide emulsion layer 3 are formed on a transparent support 1. The elements of the layer 2 transmitting blue light B contain a yellow dye (precursor) releasing substance, the elements transmitting green light G contain a magenta dye (precursor) releasing substance, and the elements transmitting red light R contain a cyan dye (precursor) releasing substance. The layer 2 contg. the dye releasing redox compounds is exposed and developed with an alkaline processing soln. contg. a color developer, and diffusible dyes are diffused and transferred to an image receiving layer 4. Thus, a high-quality color image is formed by short-time processing.
    • 目的:通过形成一个仅传输蓝色,绿色或红色光的元件组成的镶嵌层,从而快速获得高质量的彩色图像。 相应的染料(前体)释放物质和卤化银乳剂层,并且将彩色图像转印到图像接收层。 构成:在透明支撑体1上形成由各自透过光谱蓝色光B,绿色光G或红色光R以及蓝色,绿色和红色感光卤化银乳剂层3的元件构成的精细马赛克或条纹滤光层2 发送蓝光B的层2的元素含有黄色染料(前体)释放物质,透过绿色光G的元素含有品红色染料(前体)释放物质,透过红色光的元素R含有青色染料(前体 )释放物质。 第2层 染料释放氧化还原化合物用碱性处理溶胶曝光和显影。 contg。 彩色显影剂和可扩散染料扩散并转移到图像接收层4.因此,通过短时间处理形成高质量的彩色图像。
    • 2. 发明专利
    • Method for forming color image by thermal development
    • 通过热开发形成彩色图像的方法
    • JPS5955430A
    • 1984-03-30
    • JP16490382
    • 1982-09-24
    • Konishiroku Photo Ind Co Ltd
    • HOTSUTA YUUJIISHIKAWA HISASHIMASUKAWA TOYOAKI
    • G03C8/40
    • G03C8/4033
    • PURPOSE:To easily form a sharp color image, by incorporating a dye having a group capable of tanning development in a silver salt photosensitive material, stopping diffusion of the dye reacting at thermal develoment at the exposed parts to an image receiving layer, and allowing the dye at the unexposed parts alone to diffuse. CONSTITUTION:An emulsion layer B is obtained by forming on baryta paper (d) an emulsion layer (c) contg. 4-nitrobenzotriazole silver, an org. silver, a photosensitive silver halide, and a dye represented by formula( I ) in which Dye is an azo dye, anthraquinone dye, or the like; Dev is a residue of a compd. such as hydroquinone having at least two OH groups capable of tanning development or p-aminophenol; and A is a coupling group. After the layer B is exposed, a polyethylene terephthalate film (a) having an image receiving layer (b) is overlaid on the layer B, it is heated D from the paper (d) side, the dye 2 in the emulsion layer (e) reacted by tanning at the exposed part is inhibited from diffusing, and the dye 3 at the unexposed parts diffuses to the layer (b) to produce the fixed dye 4, thus forming a sharp color image.
    • 目的:为了容易地形成清晰的彩色图像,通过在银盐感光材料中加入具有能够鞣制显影的基团的染料,停止在曝光部分的热显影反应的染料扩散到图像接收层,并允许 染料在未曝光部分单独扩散。 构成:通过在baryta纸(d)上形成乳剂层(c),获得乳液层B。 4-硝基苯并三唑银。 银,感光卤化银和由式(I)表示的染料,其中染料是偶氮染料,蒽醌染料等; Dev是compd的一个残差。 例如具有至少两个能够鞣制显影的OH基团的对苯二酚或对氨基苯酚; A是偶联基团。 在B层暴露后,将具有图像接收层(b)的聚对苯二甲酸乙二醇酯膜(a)覆盖在层B上,从纸(d)侧加热D,将乳液层(e )被暴露部分的鞣制反应被抑制扩散,并且未曝光部分的染料3扩散到层(b)以产生固定染料4,从而形成清晰的彩色图像。
    • 3. 发明专利
    • Method for forming color image by thermal development
    • 通过热开发形成彩色图像的方法
    • JPS5955429A
    • 1984-03-30
    • JP16490282
    • 1982-09-24
    • Konishiroku Photo Ind Co Ltd
    • HOTSUTA YUUJIMASUKAWA TOYOAKIISHIKAWA HISASHI
    • G03C8/40
    • G03C8/404
    • PURPOSE:To easily obtain a sharp color image, by thermally developing a silver salt photosensitive material contg. a dye to imagewise harden said material, and controlling diffusion of the dye from the hardened part to an image receiving layer. CONSTITUTION:The thermodevelopable photosensitive layer B is obtained by forming a dye layer (d) contg. a dye 1 dispersed in gelatin on baryta paper (c), and laminating on the layer (d) an emulsion layer (c) contg. a photosensitive silver halide, a tanning developing agent, and a silver salt or an org. acid salt of silver represented, e.g., by the shown formula in which R is NO2; R , R are each halogen, OH, sulfo, its salt, COOH, CN, carbamoyl, alkyl, alkoxy, aryl, NH2, or the like; m is 0, 1, or 2; and n is 0 or 1. A photosensitive material is obtained by laminating on the layer B, a polyethylene base sheet (a) coated with an image receiving layer (b) having dispersed titanium white. It is exposed (C) from the layer (A) and then, heated (D) from the baryta paper (e) at 80-200 deg.C for 1-60sec. The layer (c) at the exposed parts is developed by tanning to restrict diffusion of the dye 1 to the layer (b), and the dye 1 at the unexposed parts diffuses to the layer (b) to fix 3 it, thus obtaining a sharp color image.
    • 目的:为了容易地获得清晰的彩色图像,通过热显影银盐感光材料, 用于成像硬化所述材料的染料,以及控制染料从硬化部分到图像接收层的扩散。 构成:热可发光感光层B通过形成染料层(d)而获得。 将分散在明胶纸上的染料1(c),并在层(d)上层压乳剂层(c) 感光卤化银,鞣制显影剂和银盐或有机溶剂。 例如通过其中R 1是NO 2所示的式表示的银的酸式盐; R 2,R 3各自为卤素,OH,磺基,其盐,COOH,CN,氨基甲酰基,烷基,烷氧基,芳基,NH 2等; m是0,1或2; 并且n为0或1.通过层压在涂覆有具有分散的钛白色的图像接收层(b)的聚乙烯基片(a)的层B上获得感光材料。 从层(A)暴露(C),然后在80-200℃下从重晶石纸(e)加热(D)1-60秒。 曝光部分的层(c)通过鞣制显影以限制染料1向层(b)的扩散,并且染料1在未曝光部分扩散到层(b)以固定3,从而获得 清晰的彩色图像。
    • 4. 发明专利
    • Color image forming method
    • 彩色图像形成方法
    • JPS59166953A
    • 1984-09-20
    • JP4277783
    • 1983-03-14
    • Konishiroku Photo Ind Co Ltd
    • HOTSUTA YUUJIHIRABAYASHI SHIGETOYAMASHITA KIYOSHI
    • G03C5/08G03C7/10G03C8/08G03C8/30G03C7/00
    • G03C8/30
    • PURPOSE:To reproduce a color hard copy of high quality image from a highly concd. information record by arranging at least three kinds of dye donors in mosaic, imagewise exposing a hotosensitive element to a single light trhough this mosaic layer, and diffusion transferring dye released from said dye donors to an image receiving element. CONSTITUTION:A mosaic layer 2 is formed on a substrate 1 by arranging mosaic finely divided different regions each contg. each of at least there kinds of dye donors capable of releasing each of dyes different from each other or their precursors, and a photosensitive element having a silver halide emulsion layer 3 photosensitive to, e.g. a >=600nm wavelength region is exposed imagewise to a single color light through the mosaic layer 2, and brought into contact with an alkaline processing soln. in the presence of a developer to form a distribution of the diffusive dyes or precursors corresponding to the imagewise exposure. A color image is formed on an image receiving element 4 as a result of diffusion transfer of said imagewise distribution. Consequently, high quality color image signals recorded on a highly concnd. information recorder, such as a magentictape, magnetic disc, or optical disc, can be easily reproduced as a high image quality color hard copy.
    • 目的:从高度凝视中复制高质量图像的彩色硬拷贝。 通过将至少三种染色供体镶嵌在马赛克中,将感光元件成像曝光到该镶嵌层中的单一光线,以及从所述染料供体释放到图像接收元件的扩散转移染料的信息记录。 构成:镶嵌层2通过布置马赛克细分的不同区域而形成在基板1上。 至少有各种染料供体能够释放彼此不同的各种染料或其前体,以及具有感光性的例如卤化银乳剂层3的感光元件。 a> = 600nm波长区域通过马赛克层2成像曝光于单色光,并与碱性处理溶液接触。 在显影剂的存在下形成对应于成像曝光的漫射染料或前体的分布。 作为所述图像分布的扩散转移的结果,在图像接收元件4上形成彩色图像。 因此,高品质的彩色图像信号被记录在一个高度的结果上。 诸如magentictape,磁盘或光盘的信息记录器可以容易地被复制为高图像质量的彩色硬拷贝。
    • 5. 发明专利
    • Formation of color image
    • 形成彩色图像
    • JPS59162544A
    • 1984-09-13
    • JP3775683
    • 1983-03-07
    • Konishiroku Photo Ind Co Ltd
    • HIRABAYASHI SHIGETOHOTSUTA YUUJIYAMASHITA KIYOSHI
    • G03C7/00G03C8/10G03C8/30G03G8/00H04N1/46
    • G03C8/30
    • PURPOSE:To obtain an image rapidly by forming on a transparent substrate, a mosaic-shaped or other-shaped layer transmitting only each of blue, green, and red lights and contg. each of color couplers capable of releasing a dye or dye precursor corresponding to each color, and a silver halide emulsion layer, and transferring a color image to an image receiving layer. CONSTITUTION:A fine mosaic-shaped or stripe-shaped layer 2 transmitting only each of blue B, green G, and red R lights and contg. each of color couplers capable of releasing each of yellow dye for blue B, a magenta dye for green G, and a cyan dye for red R, or each of their precursors is formed on a transparent substrate 1. Said layer 2 serves as a filter layer, too. A silver halide layer 3 sensitive to blue, green, and red lights is formed on the layer 2. This photosensitive element is exposed and diffusive dyes are released from said color couplers contained in the layer 2 by using a color developing agent contg. a p-phenylenediamine type compd. to diffuse said dyes to an image receiving layer 4. As a result, rapid development and fixation processing is enabled and a high quality image is obtained.
    • 目的:通过在透明基板上形成马赛克形状或其他形状的层,只传输蓝色,绿色和红色光中的每一种,并快速获得图像。 能够释放对应于每种颜色的染料或染料前体的每个成色剂和卤化银乳剂层,并将彩色图像转印到图像接收层。 构成:细微的马赛克状或条状层2仅透过蓝色B,绿色G和红色R灯中的每一个, 每个能够释放蓝色B的黄色染料,用于绿色G的品红色染料和用于红色R的青色染料或其前体的每种颜色成色剂形成在透明基材1上。所述层2用作过滤器 层也是。 在层2上形成对蓝色,绿色和红色光敏感的卤化银层3.通过使用彩色显影剂接触,该感光元件被曝光并且扩散染料从包含在层2中的所述颜色耦合器释放。 对苯二胺类化合物 以将所述染料漫射到图像接收层4.结果,能够进行快速显影和定影处理,并且获得高质量的图像。
    • 6. 发明专利
    • Thermal transfer recording medium
    • 热转印记录介质
    • JPS59194892A
    • 1984-11-05
    • JP6911583
    • 1983-04-21
    • Konishiroku Photo Ind Co Ltd
    • HOTSUTA YUUJIKITAMURA SHIGEHIRO
    • B41M5/392B41J31/00B41M5/26B41M5/39B41M5/395
    • B41M5/39B41M5/395
    • PURPOSE:To provide a thermal transfer recording medium capable of obtaining a favorable image quality while suppressing deterioration of preservability with an increase in sensitivity, wherein a thermally transferrable coloring agent is dispersed in a water-soluble binder resin in the state of being dissolved in a nonvolatile solvent. CONSTITUTION:In a thermal transfer recording medium in which a coloring agent layer comprising a thermally transferrable coloring agent and a binder is provided on a base, the binder is a water-soluble resin, e.g., gelatin, PVA or water-soluble polyvinyl acetal, and the thermally transferrable coloring agent, e.g., a compound of formula I or II, is dispersed in the water-soluble binder resin in the state of being dissolved in a nonvolatile solvent, e.g., dibutyl phthalate, tricresyl phosphate or dioctyl phthalate. An image obtained is high in transfer density and has a multi-gradation property. In addition, notwithstanding the high sensitivity of the recording medium, deterioration of thermal stability can be suppressed, and a favorable image can be obtained even after long-time preservation.
    • 目的:提供能够获得良好图像质量的热转印记录介质,同时以增加灵敏度抑制保存性的劣化,其中将热转印着色剂分散在水溶性粘合剂树脂中,溶解在 非挥发性溶剂。 构成:在其中在基材上设置包含热转印着色剂和粘合剂的着色剂层的热转印记录介质中,粘合剂为水溶性树脂,例如明胶,PVA或水溶性聚乙烯醇缩醛, 并且可热转移着色剂,例如式I或II的化合物以溶解在非挥发性溶剂中的状态分散在水溶性粘合剂树脂中,例如邻苯二甲酸二丁酯,磷酸三甲苯酯或邻苯二甲酸二辛酯。 所得到的图像的传送密度高,具有多层次性。 此外,尽管记录介质的灵敏度高,但是可以抑制热稳定性的劣化,并且即使长时间保存也能获得良好的图像。
    • 7. 发明专利
    • Formation of color image
    • 形成彩色图像
    • JPS59164552A
    • 1984-09-17
    • JP3868883
    • 1983-03-08
    • Konishiroku Photo Ind Co Ltd
    • HIRABAYASHI SHIGETOHOTSUTA YUUJIYAMASHITA KIYOSHI
    • G03C5/08G03C7/10G03C8/08G03C8/30G03C7/00
    • G03C8/30
    • PURPOSE:To obtain a color image high in quality by forming a mosaic layer consisting of finely divided regions contg. each of 3 kinds of dye donors separately, and a photosensitive silver halide emulsion layer on a transparent support, exposing it to single color light, and developing it. CONSTITUTION:A mosaic layer 2 formed on a transparent support 1 consists of a large number of finely divided regions contg. each of dye donors of Y, M, and C releasing each of yellow, magenta, and cyan diffusive dyes or their precursors selectively and alternately. Further, a photosensitive silver halide emulsion layer 3 is formed on the layer 2. The mosaic layer is exposed to laser beams through the support 1 and developed with an alkaline developing soln. As a result, only the regions of the mosaic layer 2 corresponding to the exposed parts are developed and the diffusive dyes are diffused and transferred to the image receiving layer of an image receiving element 4 to form an image.
    • 目的:通过形成由细分区域组成的镶嵌层来获得高质量的彩色图像。 分别在3种染料供体中分别加入3种染料供体,并在透明载体上涂上感光卤化银乳剂层,将其曝光于单色光并显影。 构成:形成在透明支撑体1上的马赛克层2由大量细分区域构成。 每个Y,M和C的染料供体都选择性地和交替地释放黄色,品红色和青色漫射染料或其前体中的每一种。 此外,在层2上形成感光性卤化银乳剂层3.马赛克层通过支撑体1暴露于激光束,并用碱性显影溶液显影。 结果,只有与曝光部分相对应的马赛克层2的区域被显影,并且漫射染料被扩散并转移到图像接收元件4的图像接收层以形成图像。
    • 8. 发明专利
    • Thermal transfer image-forming method
    • 热转印成像方法
    • JPS59159398A
    • 1984-09-08
    • JP3551683
    • 1983-03-03
    • Konishiroku Photo Ind Co Ltd
    • MASUKAWA TOYOAKIHOTSUTA YUUJI
    • G03C7/00B41M5/34B41M5/382B41M5/392
    • B41M5/38207B41M5/345B41M5/38214
    • PURPOSE:To obtain an image-forming method simple in operation, favorable in image quality and excellent from the viewpoint of environmental problems, by a method wherein a sublimable coloring matter is produced in a hydrophilic binder on a base by a silver halide coupler-in-type color developing method, and the coloring matter is transferred by a thermal pattern. CONSTITUTION:A photosensitive material comprising an undercoat layer 2 and a silver halide emulsion layer 3 provided on a base 1 is exposed to light 5 imagewise in a mosaic pattern through a photo-mask 4 for the first color, e.g., cyan color, followed by a coupler-in-type color developing treatment to produce a cyan pattern 5a. Similarly, the second and third patterns 5b, 5c are produced by using photo-masks 4, and the film is deprived of silver by a bleach fixing step. An image-receiving sheet is brought into contact with the thus obtained coloring matter doner sheet, and is exposed imagewise to multicolor spectral light containing the absorption wavelength of the coloring matter doner layer 3 through an original by a number of times corresponding to the kinds of mosaic picture elements to produce a thermal pattern, thereby producing a multicolor image.
    • 目的:为了获得操作简单的图像形成方法,从环境问题的观点出发,优良的图像形成方法,其中通过卤化银成色剂在基底上的亲水性粘合剂中产生升华性着色剂的方法 型彩色显影法,色素通过热图案转印。 构成:设置在基体1上的底涂层2和卤化银乳剂层3的感光材料通过用于第一种颜色的光掩模4(例如,青色)以马赛克图案成像曝光,然后以 用于产生青色图案5a的成色剂型彩色显影处理。 类似地,通过使用光掩模4制造第二图案5b和第三图案5c,并且通过漂白定影步骤剥离膜。 使图像接收片与如此获得的着色剂层相接触,并通过原稿将包含着色剂层3的吸收波长的多色光谱图像曝光成多次, 马赛克图像元素以产生热图案,从而产生多色图像。
    • 9. 发明专利
    • Image forming element
    • 图像形成元素
    • JPS5975248A
    • 1984-04-27
    • JP18614282
    • 1982-10-25
    • Konishiroku Photo Ind Co Ltd
    • MASUKAWA TOYOAKIHOTSUTA YUUJIHIRABAYASHI SHIGETO
    • G03C7/00B41M5/382B41M5/41G03C1/498G03C7/04G03C8/40
    • G03C8/4046
    • PURPOSE:To obtain a full color hard copy through one time thermotransfer, by incorporating thermotransferable dyes each having a different hue on a part of each different filter of a mosaic filter layer. CONSTITUTION:The mosaic filter layer 2 of this invention is formed on a substrate 1. Filter dyes are selectively mixed so as to give each microelement of the layer 2 a spectal transmission characteristic of blue B, green G, and red R, and further, e.g., yellos, magenta, and cyan thermotransferable dye or a thermotransferable dye donor, such as thermotransferable leucodye are mixed into each element. The filter 2 is coated with, e.g., a thermodevelopable photosensitive layer 3, and exposed to whole-surface flash of high illuminance? ight or IR rays. At that time, since a silver image in the layer 3 converts the absorbed light into heat, the thermotransferable dyes contained in the filter elements are transferred by the heat generated in the development part.
    • 目的:通过一次性热转印获得全彩色硬拷贝,通过在马赛克滤光层的每个不同滤光片的一部分上并入具有不同色调的热转印染料。 构成:本发明的马赛克滤色器层2形成在基板1上。选择性地混合滤色器,以便使层2的每个微元件具有蓝色B,绿G和红R的光谱透射特性, 例如,将yellos,品红色和青色的热转印染料或热转印染料供体(例如可热转印的白血病)混合到每个元件中。 过滤器2涂覆有例如热可发光感光层3,并暴露于高照度的全表面闪光? 光线或红外线。 此时,由于层3中的银图像将吸收的光转换成热,所以过滤元件中包含的热转印染料通过显影部分中产生的热量而被转印。
    • 10. 发明专利
    • Heat development type color photosensitive silver salt material
    • 热开发型彩色感光银盐材料
    • JPS595239A
    • 1984-01-12
    • JP11249582
    • 1982-07-01
    • Konishiroku Photo Ind Co Ltd
    • HOTSUTA YUUJIMASUKAWA TOYOAKI
    • G03C7/00G03C1/40G03C8/40
    • G03C1/40
    • PURPOSE:To form easily a clear image by simple operation, by using a sublimable leuco dye as a developing agent incorporated in a heat development type color photosensitive silver salt material. CONSTITUTION:The desired heat development type color photosensitive silver salt material is obtd. by incorporating a leuco dye represented by the formula (where each of R1 and R2 is lower alkyl, and X is phenyl or the like) into a layer other than an image receiving layer. The leuco dye is sublimed by heating to reduce imagewise Ag in a photosensitive layer, and the dye itself is oxidized to form color. At the same time, the dye loses its sublimability. When the material is imagewise exposed and heated, the leuco dye 4 is sublimed and diffused in the photosensitive silver salt layer 2. In the exposed part A, Ag is reduced by the dye 4 to form a silver image,the dye 4 itself is oxidized to form a color image, and the dye 4 loses its sublimability and stays in the layer 2. In the unexposed part B, the dye 4 passes through the layer 2 and reaches the image receiving layer 3, where it reacts with a coupler and forms color.
    • 目的:通过简单的操作,通过使用可升华的无色染料作为加热显影型彩色光敏银盐材料中的显影剂,容易地形成清晰的图像。 构成:所需的热显影型彩色感光银盐材料。 通过将由式(其中R1和R2各自为低级烷基,X为苯基等)表示的无色染料加入到除图像接收层以外的层中。 通过加热使无色染料升华以减少感光层中的成像Ag +,并且染料本身被氧化形成颜色。 同时,染料失去其升华性。 当材料成像曝光和加热时,无色染料4升华并扩散到感光银盐层2中。在曝光部分A中,Ag +被染料4还原以形成银图像,染料4 本身被氧化以形成彩色图像,并且染料4失去其升华性并停留在层2中。在未曝光部分B中,染料4通过层2并到达图像接收层3,其中它与 耦合器并形成颜色。