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1. 发明申请

US20110008630A1 HYDROPHILIC FILM 有权
标题翻译：水胶片
公开(公告)号：US20110008630A1
公开(公告)日：2011-01-13
申请号：US12933743
申请日：2009-03-19
申请人： Koju Okazaki , Noboru Kawasaki
发明人： Koju Okazaki , Noboru Kawasaki
IPC分类号： B32B27/06 , B05D3/10
CPC分类号： C03C17/30 , C03C2217/75 , C08G77/28 , C09D4/06 , C09D183/08 , Y10T428/31663
摘要： The present invention provides a hydrophilic film that has high adhesion to inorganic materials and is safer and excellent in transparency and also exhibits both very high hydrophilicity and abrasion resistance, and also provides a laminate including the hydrophilic film. The hydrophilic film is produced by applying a specific hydrophilic compound (c) having an acryloyl group and a potassium sulfonate group or the like to a surface of a layer formed from a mixture containing a silane compound (a) including one silicon atom, a mercapto group or the like, and at least one silicon-bonded group selected from the group consisting of an alkoxy group, a halogen group, and a hydroxy group, and a silane compound (b) including at least four silicon-bonded groups selected from the group consisting of an alkoxy group, a halogen group, and a hydroxy group and not including groups reactive with a carbon-carbon double bond, and allowing a reaction between at least a part of acryloyl groups contained in the hydrophilic compound (c) and at least a part of mercapto groups derived from the compound (a).
摘要翻译：本发明提供一种对无机材料具有高粘附性的亲水性膜，其透明度更安全且优异，并且亲水性和耐磨性都非常高，并且还提供了包含亲水膜的层压体。通过将具有丙烯酰基和磺酸钾基等的特定亲水性化合物（c）等涂布在由含有一个硅原子的硅烷化合物（a）的混合物形成的层的表面上，将巯基基团等，以及选自烷氧基，卤素基和羟基中的至少一个硅键合基团和包含至少四个与硅键合的基团的硅烷化合物（b），所述硅键合基团选自由烷氧基，卤素基和羟基组成的基团，不包括与碳 - 碳双键反应的基团，并且允许亲水性化合物（c）中包含的至少一部分丙烯酰基与至少一部分衍生自化合物（a）的巯基。

2. 发明授权

US09512034B2 Hydrophilic film 有权
标题翻译：亲水膜
公开(公告)号：US09512034B2
公开(公告)日：2016-12-06
申请号：US12933743
申请日：2009-03-19
申请人： Koju Okazaki , Noboru Kawasaki
发明人： Koju Okazaki , Noboru Kawasaki
IPC分类号： C03C17/30 , C09D4/06 , C09D183/08 , C08G77/28
CPC分类号： C03C17/30 , C03C2217/75 , C08G77/28 , C09D4/06 , C09D183/08 , Y10T428/31663
摘要： A hydrophilic film that has high adhesion to inorganic materials and is safer and excellent in transparency and also exhibits both very high hydrophilicity and abrasion resistance, and a laminate including the hydrophilic film. The hydrophilic film is produced by applying a specific hydrophilic compound (c) having an acryloyl group and a potassium sulfonate group or the like to a surface of a layer formed from a mixture containing a silane compound (a) including one silicon atom, a mercapto group or the like, and at least one silicon-bonded group, and a silane compound (b) including at least four silicon-bonded groups and not including groups reactive with a carbon-carbon double bond, and allowing a reaction between at least a part of acryloyl groups contained in the hydrophilic compound (c) and at least a part of mercapto groups derived from the compound (a).
摘要翻译：对无机材料具有高粘附性的亲水性膜，透明性更好，透明性优异，亲水性和耐磨性均显示出极高的亲水性，以及包含该亲水性膜的层叠体。通过将具有丙烯酰基和磺酸钾基等的特定亲水性化合物（c）等涂布在由含有一个硅原子的硅烷化合物（a）的混合物形成的层的表面上，将巯基基团等和至少一个硅键合基团，以及包含至少四个与硅键合的基团并且不包括与碳 - 碳双键反应的基团的硅烷化合物（b），并且使至少一种包含在亲水性化合物（c）中的部分丙烯酰基和衍生自化合物（a）的至少一部分巯基。

3. 发明授权

US10040947B2 Primer composition 有权
公开(公告)号：US10040947B2
公开(公告)日：2018-08-07
申请号：US12921775
申请日：2009-03-09
申请人： Koju Okazaki
发明人： Koju Okazaki
IPC分类号： C09D5/00 , B05D7/00 , C08G77/28 , C09D4/06 , C09D181/02 , C09D183/08
摘要： The present invention aims to provide a primer composition that can give good adhesion between an acrylic resin and an inorganic substrate, such as a substrate formed of metal, metal oxide, glass, ceramic, cement, or mortar and is suitably used as a primer for bonding them together. The primer composition is produced by mixing (a) a polythiol having at least two mercapto groups in one molecule, (b) a silane compound having at least one functional group and at least one alkoxysilyl group in one molecule, the at least one functional group being reactive with a mercapto group, and water.

4. 发明申请

US20140154451A1 MONOLAYER FILM AND HYDROPHILIC MATERIAL COMPRISING THE SAME 有权
标题翻译：单层膜和包含它的水解材料
公开(公告)号：US20140154451A1
公开(公告)日：2014-06-05
申请号：US14234941
申请日：2011-07-25
申请人： Koju Okazaki
发明人： Koju Okazaki
IPC分类号： C09K3/18 , C09D5/00 , C09D5/16
CPC分类号： C09K3/18 , B05D1/185 , C08F220/38 , C09D4/00 , C09D5/00 , C09D5/1668 , C09D133/06 , C09D133/14 , C09K8/16 , Y10T428/1462 , Y10T428/263 , Y10T428/2848 , Y10T428/31938 , C08F2220/382 , C08F222/1006
摘要： The invention provides monolayer films which not only have hydrophilicity and are excellent in such properties as antifogging properties, antifouling properties, antistatic properties and anti-condensation properties but also tend to exhibit excellent transparency even with a large film thickness and excellent scratch resistance, as well as stacks having the monolayer film. The monolayer film is obtained by preparing a mixture including a monomer composition and a solvent, the monomer composition including a specific monomer and a polyvalent monomer having two or more (meth)acryloyl groups and being free of sulfonic group, carboxyl group and phosphoric group in a specific molar ratio, the solvent having a specific solubility parameter σ; applying the mixture onto a substrate and removing at least part of the solvent; and polymerizing the monomer composition to produce a monolayer film having at least one anionic hydrophilic group selected from a sulfonic group, a carboxyl group and a phosphoric group and a specific anion concentration ratio (Sa/Da) of the anion concentration (Sa) at the outer surface to the anion concentration (Da) at the middle point between the inner surface in contact with the substrate and the outer surface.
摘要翻译：本发明提供了单层膜，其不仅具有亲水性，并且在防雾性，防污性，抗静电性和抗缩合性等性能方面优异，而且即使具有大的膜厚度和优异的耐刮擦性也倾向于表现出优异的透明性，以及作为具有单层膜的堆叠。通过制备包含单体组合物和溶剂的混合物获得单层膜，该单体组合物包含特定单体和具有两个或更多个（甲基）丙烯酰基并且不含磺酸基，羧基和磷酸基的多价单体特定摩尔比，具有特定溶解度参数的溶剂; 将混合物施加到基材上并除去至少一部分溶剂; 并且使单体组合物聚合以制备具有至少一个选自磺酸基，羧基和磷酸基的阴离子亲水基团的单层膜和阴离子浓度（Sa）的特定阴离子浓度比（Sa / Da）外表面与底物接触的内表面与外表面之间的中点处的阴离子浓度（Da）。

5. 发明授权

US06664425B2 Process for producing 1,3-bis(3-aminophenoxy)benzene 有权
标题翻译： 1,3-双（3-氨基苯氧基）苯的制备方法
公开(公告)号：US06664425B2
公开(公告)日：2003-12-16
申请号：US10220708
申请日：2002-09-05
申请人： Naoki Tomoshige , Yasuhiro Nukii , Masaru Wada , Koju Okazaki , Hidetoshi Hayashi
发明人： Naoki Tomoshige , Yasuhiro Nukii , Masaru Wada , Koju Okazaki , Hidetoshi Hayashi
IPC分类号： C07C21300
CPC分类号： C07C213/06 , C07C217/90
摘要： 1,3-Bis(3-aminophenoxy)benzene effective, for example, as a raw material for highly heat-resistant polyimide is produced industrially at a high yield by a reaction between 1,3-difluorobenzene and an alkali metal salt of 3-aminophenol.
摘要翻译：作为高耐热性聚酰亚胺的原料有效的1,3-双（3-氨基苯氧基）苯通过1,3-二氟苯与3-金属盐的碱金属盐的反应，以高产率工业生产，氨基苯酚。

6. 发明授权

US06482918B2 Selenium-containing transparent optical material 有权
标题翻译：含硒透明光学材料
公开(公告)号：US06482918B2
公开(公告)日：2002-11-19
申请号：US09934858
申请日：2001-08-23
申请人： Koju Okazaki , Mamoru Tanaka , Shiro Honma , Hiroyuki Morijiri , Yoshinobu Kanemura , Masahiko Kusumoto
发明人： Koju Okazaki , Mamoru Tanaka , Shiro Honma , Hiroyuki Morijiri , Yoshinobu Kanemura , Masahiko Kusumoto
IPC分类号： C08G6500
CPC分类号： C07D421/14 , C07C391/00 , C07D331/02 , C07D345/00 , C08F30/00 , C08G18/3876 , C08G18/3897 , C08G18/7642 , C08G18/77 , C08G75/02 , C08G75/045 , G02B1/041 , C08L81/00 , C08L85/00
摘要： There are herein disclosed a transparent optical material containing at least one selenium atom, a plastic lens comprising the transparent optical material, and methods for preparing them. In addition, there are also disclosed novel selenium-containing compounds represented by the following formulae (1), (2) and (4) which are useful for the transparent optical material and the plastic lens: wherein symbols are as defined in the specification.
摘要翻译：这里公开了含有至少一个硒原子的透明光学材料，包含透明光学材料的塑料透镜及其制备方法。此外，还公开了可用于透明光学材料和塑料透镜的由下式（1），（2）和（4）表示的新颖的含硒化合物：其中符号如说明书中所定义。

7. 发明授权

US06300464B2 Polymerizable composition 有权
标题翻译：可聚合组合物
公开(公告)号：US06300464B2
公开(公告)日：2001-10-09
申请号：US09745448
申请日：2000-12-26
申请人： Hiroyuki Morijiri , Seiichi Kobayashi , Koju Okazaki , Chitoshi Shimakawa , Akinori Ryu , Yoshinobu Kanemura
发明人： Hiroyuki Morijiri , Seiichi Kobayashi , Koju Okazaki , Chitoshi Shimakawa , Akinori Ryu , Yoshinobu Kanemura
IPC分类号： C08G7508
CPC分类号： C08G75/08 , C07D303/34 , C07D331/02 , C08G59/302 , C08G65/22 , G02B1/04 , C08L81/00
摘要： An optical resin prepared by curing a polymerizable composition comprising a (thio)epoxy compound having at least one intramolecular disulfide bond exhibits a considerably high refractive index while maintaining good optical properties and a high Abbe number. In addition, the above polymerizable composition to which is added primary and/or secondary amines as an yellowing inhibitor in a proportion of 0.001 to 0.5 of the total molar number of NH2 and NH groups in the amines to the total molar number of thioepoxy and epoxy groups in the (thio)epoxy compound having at least one intramolecular disulfide bond, can provide a transparent resin in which yellowing and reduction in heat resistance associated therewith are adequately prevented while maintaining a high refractive index.
摘要翻译：通过固化包含具有至少一个分子内二硫键的（硫代）环氧化合物的可聚合组合物制备的光学树脂显示相当高的折射率，同时保持良好的光学性能和高的阿贝数。此外，上述可聚合组合物中加入伯胺和/或仲胺作为泛黄抑制剂，其比例为胺的总NH 2和NH基总数的0.001至0.5，硫代环氧和环氧基的总摩尔数具有至少一个分子内二硫键的（硫代）环氧化合物中的基团可以提供透明树脂，其中在保持高折射率的同时充分防止与其相关的黄变和降低的耐热性。

8. 发明授权

US06100362A Sulfur-containing urethane-based resin and composition and process for producing the resin 失效
标题翻译：含硫氨基甲酸酯类树脂及其制造方法
公开(公告)号：US06100362A
公开(公告)日：2000-08-08
申请号：US946347
申请日：1997-10-07
申请人： Koju Okazaki , Yoshinobu Kanemura , Teruyuki Nagata
发明人： Koju Okazaki , Yoshinobu Kanemura , Teruyuki Nagata
IPC分类号： G02B1/04 , C07C319/20 , C07C321/14 , C08G18/30 , C08G18/38 , C08G18/52 , C08G18/77
CPC分类号： C08G18/775 , C07C321/14 , C08G18/3876 , C08G18/52 , G02B1/041
摘要： A polythiol having four or more functional groups, a process for producing the polythiol comprising reacting thiourea with a specific compound, a sulfur-containing urethane-based resin prepared from the polythiol and a lens made of the resin. The resin has a high refractive index, and low dispersion of refractive index, is lightweight, colorless and transparent, has no optical distortion, and has excellent characteristics in weatherability, dye-affinity, heat resistance, impact resistance and machinability.
摘要翻译：具有四个或更多个官能团的多硫醇，一种制备多硫醇的方法，包括使硫脲与特定化合物反应，由多硫醇制备的含硫氨基甲酸酯基树脂和由树脂制成的透镜。该树脂折射率高，折射率分散性低，重量轻，无色透明，无变形，耐候性，染料亲合性，耐热性，耐冲击性和切削性优异。

9. 发明授权

US5194559A Optical urethane resins and plastic lenses comprising the same 失效
标题翻译：光学脲醛树脂和包含其的塑料镜片
公开(公告)号：US5194559A
公开(公告)日：1993-03-16
申请号：US854583
申请日：1992-03-20
申请人： Koju Okazaki , Masahiko Kusumoto , Hiroyuki Yamashita , Teruyuki Nagata
发明人： Koju Okazaki , Masahiko Kusumoto , Hiroyuki Yamashita , Teruyuki Nagata
IPC分类号： C08G18/38 , C08G18/70 , C08G18/77 , C08G18/80 , G02B1/04
CPC分类号： C08G18/8064 , C08G18/3876 , C08G18/70 , C08G18/775 , G02B1/04
摘要： Optical urethane resins according to the present invention are each obtained by reacting an active hydrogen compound with an isocyanate compound containing as a stabilizer a phenolic compound. Owing to their low yellowness, high light transmittance and optical-strain-free quality, these resins are useful as optical materials for plastic lenses or the like which are required to be colorless, transparent and uniform.

10. 发明申请

US20130156959A1 SINGLE-LAYER FILM AND HYDROPHILIC MATERIAL COMPRISING THE SAME 有权
标题翻译：单层薄膜和包含它的水解材料
公开(公告)号：US20130156959A1
公开(公告)日：2013-06-20
申请号：US13812779
申请日：2011-07-25
申请人： Koju Okazaki
发明人： Koju Okazaki
IPC分类号： C08G75/24
CPC分类号： C08G75/24 , C08F2/38 , C08F222/1006 , C08J7/047 , C09D4/00
摘要： There is stably provided a hydrophilic cured product, such as a single-layer film, in which anionic hydrophilic groups are concentrated at a surface that is in contact with the air and which is excellent in transparency and adhesion to a substrate and tends to be rarely cracked. The hydrophilic cured product or single-layer film comprising a resin composition is produced by applying a mixture containing a polyvalent monomer (II) having two or more (meth) acryloyl groups and a compound (IV) having a specific group and a sulfonic acid group to a substrate or the like, drying the mixture if necessary, and then performing polymerization.
摘要翻译：稳定地提供亲水性固化物，例如单层膜，其中阴离子亲水基团在与空气接触的表面上浓缩，并且透明性和对基材的粘合性优异，并且倾向于很少破裂了含有树脂组合物的亲水性固化物或单层膜通过涂布含有具有两个以上（甲基）丙烯酰基的多元单体（II）和具有特定基团和磺酸基的化合物（IV）加入到基材等中，根据需要干燥混合物，然后进行聚合。

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